ライフサイエンスコーパス: spectroscopically

1 ) within the {W18O56} cage could be followed spectroscopically.

2 ed platinacyclobutane that has been observed spectroscopically.

3 r this inactive COR variant was demonstrated spectroscopically.

4 at cryogenic temperatures, and characterized spectroscopically.

5 temperature inert matrixes and characterized spectroscopically.

6 the pyrene polymer core that can be followed spectroscopically.

7 ed the production of Hg(0) that was observed spectroscopically.

8 charge-transfer complexes have been observed spectroscopically.

9 ry to track and actually "see" the mechanism spectroscopically.

10 in argon matrices at 15 K and characterized spectroscopically.

11 ese complexes was probed computationally and spectroscopically.

12 termediates either isolated or characterized spectroscopically.

13 4b), have been synthesized and characterized spectroscopically.

14 hich was also characterized structurally and spectroscopically.

15 ach dipyrrinone was synthesized and examined spectroscopically.

16 with the CO recombination kinetics measured spectroscopically.

17 of structural regions of the protein probed spectroscopically.

18 m Hall effect, has proved difficult to probe spectroscopically.

19 C5R5) and Cr2(CO)5(C5R5)2 have been detected spectroscopically.

20 lbenzene core have been prepared and studied spectroscopically.

21 ared by the hot injection method and studied spectroscopically.

22 three methods and characterized the product spectroscopically.

23 he Keap1 sensor for inducers is demonstrated spectroscopically.

24 egrees C to remove the addends, and analyzed spectroscopically.

25 nthesized and characterized structurally and spectroscopically.

26 t which can be readily detected and analyzed spectroscopically.

27 d detect the formation of Rh hydride species spectroscopically.

28 ement could never be unambiguously evidenced spectroscopically.

29 ropanone could be observed and characterized spectroscopically.

30 y, but differed both chromatographically and spectroscopically.

31 ted in low-temperature matrices and observed spectroscopically.

32 s predicted by DFT calculations and observed spectroscopically.

33 cles were investigated electrochemically and spectroscopically.

34 node was elucidated both computationally and spectroscopically.

35 scattering and infrared molecular absorption spectroscopically.

36 ted-are largely unknown because they are not spectroscopically accessible from the ground state.

37 many-body molecular dynamics, which enables spectroscopically accurate simulations of water from the

38 tal ion, which are difficult to study due to spectroscopically active and complex backgrounds, short

39 abled the inclusion of analytes that are not spectroscopically active and were not among the original

40 Co(IV) to be isolated and studied against a spectroscopically active Co(III) background.

41 o-field splitting parameters that create two spectroscopically addressable transitions, with one bein

42 the interstitial fluid could be measured by spectroscopically addressing the sensor through an optic

43 This study aims to spectroscopically analyze brains from free-flying birds

44 certainties of 25 to 50 per cent if measured spectroscopically and 90 to 150 per cent if measured pho

45 intermediates have been fully characterized spectroscopically and analytically.

46 rhodium compounds with dsDNA were determined spectroscopically and are in the order Rh1 << Rh2 < Rh3.

47 roximately 70% to an epoxyalcohol identified spectroscopically and by chemical synthesis as 9R,10S-ep

48 ignal from myelin suspensions is shown, both spectroscopically and by imaging, to scale with concentr

49 r a second addition of H(2)O(2), as observed spectroscopically and by mass spectrometry.

50 d their conformational behavior was examined spectroscopically and by molecular modeling.

51 Both III and IV have been characterized spectroscopically and by single-crystal X-ray diffractio

52 These species, characterized spectroscopically and by X-ray crystallography, feature

53 Compound 10, characterized spectroscopically and by X-ray crystallography, was tran

54 ium complexes, which have been characterized spectroscopically and by X-ray crystallography.

55 (3))(5), has been prepared and characterized spectroscopically and by X-ray crystallography.

56 few examples of Fe(V) species that could be spectroscopically and chemically characterized.

57 While Cu sites are spectroscopically and chemically distinct away from thes

58 arallels and contrasts are drawn between the spectroscopically and computationally supported mechanis

59 This lithium-rich zincate has also been spectroscopically and crystallographically characterized

60 -Pn (Pn=P, As) coupling products, which were spectroscopically and crystallographically characterized

61 to afford phosphonium salts, which have been spectroscopically and crystallographically characterized

62 ne 4, whose molecular structure is confirmed spectroscopically and crystallographically, is investiga

63 d these processes can be followed optically, spectroscopically and crystallographically.

64 C3H6)(CO)3(PMe3)2(NO)]BF4 were characterized spectroscopically and crystallographically.

65 and the microfluidic channels prepared were spectroscopically and electrochemically analyzed.

66 ted Ru complex, 4(2-), has been isolated and spectroscopically and electrochemically characterized.

67 s been prepared and thoroughly characterized spectroscopically and electrochemically.

68 omologs in other organisms, we characterized spectroscopically and functionally the Fe(II), Fe(II)-NO

69 tidine-glutamate pair formation, as observed spectroscopically and in the crystal structure, determin

70 ss could be verified by gel electrophoresis, spectroscopically and in vitro confocal imaging studies.

71 om Rhodobacter capsulatus have been examined spectroscopically and kinetically.

72 idopsis thaliana has been characterized both spectroscopically and kinetically.

73 uried" metallic structures are characterized spectroscopically and modeled using rigorous coupled wav

74 This charge-transfer transition is observed spectroscopically and probed using resonance Raman spect

75 ACN)(S(2)SiMe(2)) (2) that was characterized spectroscopically and structurally by resonance Raman, E

76 CH(3))] (2) bearing a pendant thioether, are spectroscopically and structurally characterized.

77 All compounds were spectroscopically and structurally characterized.

78 lly bound azide ligand has been prepared and spectroscopically and structurally characterized.

79 The shell growth is characterized both spectroscopically and structurally.

80 is formed, whose structure was investigated spectroscopically and theoretically.

81 Ar3(*+) --> 2TiO2/Ru(III)-NAr3) was observed spectroscopically and was modeled by Monte Carlo simulat

82 the regio- and stereoisomers were determined spectroscopically and, in many cases, using single-cryst

83 -aryl fluoride intermediates can be detected spectroscopically and/or isolated during these transform

84 halosporin sulfone was examined kinetically, spectroscopically, and crystallographically.

85 r-induced, solvent-free nature, was followed spectroscopically, and found to occur concurrently with

86 s complex was characterized structurally and spectroscopically, and its electronic structure is discu

87 e pMMO metal centers have been characterized spectroscopically, and the first pMMO crystal structure

88 re have been structurally confirmed and also spectroscopically, and the Ti-Nnitride bonding has been

89 trodes were characterized electrochemically, spectroscopically, and with electron microscopy.

90 om ITO to Ru(III)P or TPA(+) were quantified spectroscopically as a function of applied potential (E(

91 lex, which is characterized structurally and spectroscopically as a mononuclear side-on (eta(2)) mang

92 N(n)(-*) radical anion was directly observed spectroscopically as an intermediate in the charge-separ

93 cs of covalent modification can be monitored spectroscopically at 354 nm in the presence of the QD an

94 ungstic acid complexes, which are determined spectroscopically at 765 nm.

95 oles in function, yet are difficult to study spectroscopically because of their sparse population.

96 The cluster has been investigated spectroscopically both experimentally and theoretically

97 ses in water are slow and difficult to probe spectroscopically but are fundamental to the performance

98 guing latter possibility cannot be confirmed spectroscopically, but hints of it may be present in the

99 ure of the [B12 Cl11 ](-) anion is confirmed spectroscopically by the observation of a blue shift of

100 natural organic matter (NOM) were addressed spectroscopically by the sorption of paramagnetic nitrox

101 these high-symmetry models, were explored by spectroscopically calibrated bonding calculations, and t

102 data for Hase I, which, in conjunction with spectroscopically calibrated density functional theory (

103 Spectroscopically calibrated quantum-chemical computatio

104 hole transport in the dye monolayer observed spectroscopically can be explained by incomplete coverag

105 OF for electrochemical CO(2) fixation and to spectroscopically capture the reaction intermediates in

106 agraphic telescope in space could detect and spectroscopically characterize nearby exoplanetary syste

107 Here, we spectroscopically characterize the DNA-mediated oxidatio

108 scan FTIR (s2-FTIR) spectroscopy was used to spectroscopically characterize the photoproduct, W, and

109 In an effort to spectroscopically characterize this species in P450BM3,

110 and phenyldihalomethide carbanions have been spectroscopically characterized and computationally inve

111 The cyclic dimers 12 and 22 were spectroscopically characterized and found to direct thei

112 The new compounds have been spectroscopically characterized and their redox potentia

113 roxide species 3, which could be trapped and spectroscopically characterized at -50 degrees C.

114 The borirenes were isolated and spectroscopically characterized by multinuclear NMR, IR,

115 ylgermane cation radicals were generated and spectroscopically characterized by nanosecond transient

116 that of ligated diboranes and diborenes, was spectroscopically characterized during photolysis of di-

117 Complex 2 is the first spectroscopically characterized example, to our knowledg

118 Spectroscopically characterized Fe(V) species are exceed

119 Spectroscopically characterized for the first time, 1 (+

120 NO(2))(TC-6,6)] complex was structurally and spectroscopically characterized from the reaction mixtur

121 2 is the first spectroscopically characterized high spin oxo-Fe(V) comp

122 riafulvene cyclopropenium salt, and has been spectroscopically characterized in [D8 ]THF solution at

123 Free borylenes (R-B:) have only been spectroscopically characterized in the gas phase or in m

124 Here we purified and spectroscopically characterized light-harvesting complex

125 mpare the C-H bond oxidizing capabilities of spectroscopically characterized synthetic heme iron(IV)

126 omplex 2 with KC(8); it was structurally and spectroscopically characterized, and also studied by den

127 These stable adducts were spectroscopically characterized, and in one case, the B-

128 )-propenyl)(H), was independently generated, spectroscopically characterized, and observed to convert

129 his proposed mechanism have been isolated or spectroscopically characterized, including two new iridi

130 arge separated radical ion paired complex is spectroscopically characterized, with thermodynamic reve

131 R = Me, nPr, nBu] have been synthesized and spectroscopically characterized.

132 )dien)(CH(3)CN)](2+) (7) was synthesized and spectroscopically characterized.

133 ol)CO(2))Ag] (3), which was structurally and spectroscopically characterized.

134 H4)2Sn AriPrs (4) that were structurally and spectroscopically characterized.

135 ith appropriate cations and structurally and spectroscopically characterized.

136 the monomeric (IPr**)CuH complex, which was spectroscopically characterized.

137 rio cholerae, and the H-NOX protein has been spectroscopically characterized.

138 dedicated facility for directly imaging and spectroscopically characterizing extrasolar planets.

139 The identity of 2 was confirmed spectroscopically, chemically, crystallographically, and

140 The constructs were characterized spectroscopically, chromatographically, and electrophore

141 ushed the performance of these, in principle spectroscopically complimentary, techniques well beyond

142 data set of light curves for 247,000 known, spectroscopically confirmed quasars with a temporal base

143 Here we report three spectroscopically confirmed type IIn supernovae, at reds

144 xisting structural templates and generated a spectroscopically constrained model of the hHv1 dimer ba

145 The excited singlet S1 state is spectroscopically dark, whereas photoexcitation to highe

146 -Fe(ii) and alpha-O-are challenging to probe spectroscopically: data from bulk techniques such as X-r

147 An NMR spectroscopically derived structure of a TEL fragment, d

148 ere not visibly detectable against quartz or spectroscopically detectable against polytetrafluoroethy

149 [Re(DPPBT)(3)], no reaction with ethylene is spectroscopically detectable consistent with the determi

150 rrence rate of approximately 1 in 10,000 for spectroscopically detectable giant planets in close orbi

151 These spectroscopically detectable states represent a chemical

152 to the ionization of the internal groups was spectroscopically detectable, especially in the less sta

153 capped on both ends with NMM, supporting the spectroscopically determined 1:1 stoichiometry.

154 termination of acidity in ice cores based on spectroscopically determined color changes of two common

155 at conductance value exactly correlates with spectroscopically determined molecular redox states.

156 It was spectroscopically determined that heating the platinum s

157 We have spectroscopically determined the relative angle between

158 on kinetics of neutravidin to the surface by spectroscopically determining the fractional occupancy a

159 terest from other naturally occurring lipids spectroscopically, deuterium labels were introduced.

160 ft selective suppression of signals that are spectroscopically different from the signal of interest.

161 n (NBD-Coum) construct, which fragments into spectroscopically differentiable products upon nucleophi

162 mitted light signals that were collected and spectroscopically dispersed, in essence creating a senso

163 a monomer contains a FAD redox cofactor, two spectroscopically distinct [2Fe-2S] clusters, and a moly

164 amagnetic (S=0) 8-Fe cluster, containing two spectroscopically distinct Fe sites that appear in a 3:1

165 ting NADH:quinone oxidoreductase forms three spectroscopically distinct flavin radicals as follows: 1

166 Two spectroscopically distinct forms of this cluster have be

167 These excimers are spectroscopically distinct from singlet and triplet exci

168 CmlI-peroxo is spectroscopically distinct from the well characterized a

169 No spectroscopically distinct intermediates are observed in

170 that melting/refolding occurred without any spectroscopically distinct intermediates, yet the relaxa

171 iophenol, we present a novel approach toward spectroscopically distinct NIR dyes for which the degree

172 The OH group can occupy any one of the five spectroscopically distinct sites in the distorted pentag

173 3ReO3 on silica-alumina contain two types of spectroscopically distinct sites.

174 25 degrees C, but slowly converts to another spectroscopically distinct species with a lambda(max) at

175 indicates that at low salt there is a third spectroscopically distinct species, while at higher salt

176 = 0, 1, or 2) as well as two mechanisms with spectroscopically distinct starting structures (F(1) and

177 ICT excitation reveal the appearance of two spectroscopically distinct states having different dynam

178 heterogeneous protein environments that are spectroscopically distinct.

179 transition frequency shifts, we were able to spectroscopically distinguish sites with different occup

180 posite direction of this shift enabled us to spectroscopically distinguish the target from nonspecifi

181 aramagnetic resonance (EPR) spectroscopy, we spectroscopically distinguish two Cu(II) binding sites o

182 rocarbon interior of the droplets, which are spectroscopically distinguishable and allow for chemical

183 +) and acts as a synergistic anion to give a spectroscopically distinguishable intermediate, Fe(3+)Fb

184 The successful use of spectroscopically distinguishable labels on membrane-emb

185 However, we identified a suitable pair of spectroscopically distinguishable labels, which allows t

186 Here we show how the combination of spectroscopically distinguishable nitroxide and gadolini

187 -phase and interfacial acetonitrile are thus spectroscopically distinguishable.

188 Two conformational isomers of triplet 3 are spectroscopically distinguishable.

189 he ligand bound versus unbound states can be spectroscopically distinguished.

190 Co) and characterized crystallographically, spectroscopically, electrochemically, and computationall

191 bstrate, has been prepared and characterized spectroscopically, electrochemically, and with a solid s

192 The latter has been spectroscopically elucidated by NMR via C-H coupled and

193 the cluster species extracted from NifEN is spectroscopically equivalent and functionally interchang

194 PEG bears a large number of spectroscopically equivalent protons exhibiting a narrow

195 e rapid phase to form a heme-protein complex spectroscopically equivalent to that of the wild-type in

196 residues of Ca(II)- and Mn(II)-bound CP are spectroscopically equivalent.

197 area of host-guest organic chemistry, or to spectroscopically evaluate in-depth the intramolecular e

198 methano[10]annulene unit is synthesized and spectroscopically evaluated.

199 i(IV) species was observed and characterized spectroscopically for a nickelacycle system.

200 s fundamentally interesting because it forms spectroscopically identifiable complexes with water at a

201 O(n) linkages, which favor the reactivity of spectroscopically identified *CH(3)O intermediates, that

202 In this study, we spectroscopically identified methylglyoxal diol (MGD) an

203 Surface-bound morantel was spectroscopically identified using second harmonic gener

204 We spectroscopically identify reduced Pd clusters in our F8

205 we use the 'Campanile' nano-optical probe to spectroscopically image exciton recombination within mon

206 characterize large populations of such tags spectroscopically in a high-throughput flow-based platfo

207 onding diazo compound precursors and studied spectroscopically in cryogenic matrices (N(2) or Ar) at

208 dene (MeC3Me, (3)3), which was characterized spectroscopically in cryogenic matrices.

209 species have been trapped and characterized spectroscopically in enzymatic and biomimetic reactions,

210 SLNs were identified spectroscopically in photoacoustic images.

211 tive bound states can be created and studied spectroscopically in present-day experiments with ultrac

212 It is possible to watch the reaction spectroscopically in real time, determine when it reache

213 ve) intermediate that is fleetingly detected spectroscopically in solution versus that rigorously def

214 rations in the surface region are identified spectroscopically in varying bulk pH solutions, and are

215 ic variations should therefore be detectable spectroscopically in X-ray observations of solar analogs

216 e deuteration of the matrix lipid to make it spectroscopically inactive.

217 n radical (Compound I) intermediate which is spectroscopically indistinguishable from those that perf

218 ative where the T1 Cu has been replaced by a spectroscopically innocent Hg2+ ion has led to a detaile

219 ecific Oct1-DNA complex, sparsely-populated, spectroscopically "invisible" states reveal their footpr

220 roteins can offer fundamental information on spectroscopically "invisible" steps.

221 plementary parallel ion pair-pi repulsion is spectroscopically irrelevant, in part because of charge

222 magnetic semimetal Co(3)Sn(2)S(2), we verify spectroscopically its classification as a time-reversal

223 been shown to be suitable for preparation of spectroscopically labeled lysophosphatidylcholines.

224 d by the development of instrumentation that spectroscopically maps nanotube contents inside undistur

225 S,39R)-azaspiracid-3 chromatographically and spectroscopically matched naturally occurring azaspiraci

226 As expected, spectroscopically measurable unwinding penetrates approx

227 spectral approach to spatially delineate and spectroscopically measure single nanotube fluorescence i

228 Conventional MR imaging findings, spectroscopically measured absolute NAA and choline conc

229 GATA proteins as potential targets for lead, spectroscopically monitored metal-binding titrations wer

230 roach described here shows the potential for spectroscopically monitoring changes in macromolecular o

231 ctrochemical FT-IR setup was demonstrated by spectroscopically monitoring microstructured polymer dep

232 ng effluent Fe(II) (aq) concentration and by spectroscopically monitoring the hematite dissolution fr

233 led us to the use of the less-sensitive but spectroscopically more robust 2.9 mum laser.

234 for the 8-propionate in the formation of the spectroscopically native P(r) dark states of these bilip

235 The bis-thiocyanato Ru(II) complex has been spectroscopically (NMR and UV-vis), electrochemically, a

236 undetectable for the H2IMes system, but was spectroscopically observable for the IMes system.

237 exciplexes as the dominant, kinetically and spectroscopically observable intermediate.

238 that exhibit reactivity with O2 and lead to spectroscopically observable metal-oxygen species, and/o

239 Continued operation leads to spectroscopically observable Ni oxidation and another st

240 ting C-C reductive elimination occurs from a spectroscopically observable Ni(II)-dialkyl intermediate

241 The spectroscopically observable tris(thiolate) complex [Ru(

242 We spectroscopically observe coherent interaction between t

243 Starting from the spectroscopically observed 1,2-mu-peroxo diferric P inte

244 , nonmetallic nitrenes have so far only been spectroscopically observed at low temperatures, despite

245 A basic iron(IV) oxo species has yet to be spectroscopically observed in a histidine-ligated heme e

246 (2))](+) lead to accurate predictions of the spectroscopically observed IVCT transition energies.

247 pectedly similar to that found in cryogenic, spectroscopically observed phosphinidene species.

248 -XYL)(O2)](2+) complex, only a P species was spectroscopically observed.

249 Spectroscopically observing the translational and rotati

250 ))) and the oxidized catalyst was quantified spectroscopically on nanosecond and longer time scales.

251 ash-quench experiments and could be observed spectroscopically on the nanoseconds to microseconds tim

252 plex under these conditions is verified with spectroscopically orthogonal nitroxide and Gd(III)-based

253 The energy transfer process was spectroscopically probed by excitation-emission mapping:

254 tuent on one pyridyl ligand arm, affording a spectroscopically pure end-on bound disulfido-dicopper(I

255 nsities reveal a remarkable correlation that spectroscopically quantifies the linear interdependence

256 cavity at the cluster surface, and they are spectroscopically quite similar to internalized cavity i

257 t doubly pi(2)pi*(2) excited state, which is spectroscopically rather dark.

258 The acetal (H1C1) groups suffice to spectroscopically resolve approximately 20 different sta

259 Spectroscopically resolved carbohydrates include more th

260 itions into d orbitals of t(2g) symmetry are spectroscopically resolved for all four complexes, the e

261 IR spectroscopy to reveal equilibria between spectroscopically resolved substates of the lipidated si

262 ly oxidized form of the blue dimer [4,5] was spectroscopically resolved within the time frame of the

263 factor in the active site of VHPOs contains "spectroscopically silent" V(V), which does not change ox

264 It is spectroscopically similar to red copper nitrosocyanin, b

265 x supernovae are stellar explosions that are spectroscopically similar to some type Ia supernovae at

266 half-reaction of 2-KPCC was kinetically and spectroscopically similar to that of a typical DSOR, GSH

267 is the finding that the autofluorescence was spectroscopically similar to the bisretinoids that const

268 arsenate species could not be differentiated spectroscopically, since their U-As distances were equal

269 These compounds are spectroscopically, structurally, and stereodynamically v

270 structure of doubly ionized benzene has been spectroscopically studied for the first time.

271 None of the complexes observed spectroscopically subsequent to [(FI)Ti(CH2CMe3)2](+) is

272 ew Ac compounds that have been characterized spectroscopically, success has only been reported for si

273 Of several dozen galaxies observed spectroscopically that are candidates for having a redsh

274 Raman multivariate curve resolution to probe spectroscopically the hydrophobic hydration shell and, u

275 If the complex ML(n) could be observed spectroscopically, the absorbance of the product A(p) fo

276 atomic molecule, N(2) is difficult to detect spectroscopically through infrared or millimeter-wavelen

277 Roaming has been identified spectroscopically through static product channel-resolve

278 electron-hole pairs (excitons) are accessed spectroscopically through their allowed single-quantum t

279 eme 19 in the article) which was also proven spectroscopically to be non-identical to the naturally o

280 Subsequently, it was measured spectroscopically to be z = 6.29 +/- 0.01, in agreement

281 tures, for example nanorods, have been shown spectroscopically to display increased multiple exciton

282 ng the oxygen redox couple, which we observe spectroscopically to persist for 500 charge/discharge cy

283 ific and site selective C-H hydroxylation is spectroscopically trapped, and its catalytic reactivity

284 t class of molecular assembly categorized as spectroscopically uncoupled molecules.

285 In spectroscopically underdetermined structure elucidation

286 ociated with either competing aggregation or spectroscopically unfavorable size and exchange rates ha

287 ve a small population of molecules that were spectroscopically unique from the large population of mo

288 This intermediate was observed spectroscopically upon addition of a pyridine base to pr

289 The oils were differentiated spectroscopically using intensity ratio for specific Ram

290 addition, these compounds have been examined spectroscopically (UV-vis-NIR, IR) in all accessible red

291 ry of peptide constructs, we show that three spectroscopically (UV/visible and electron paramagnetic

292 Spectroscopically validated computations corroborate the

293 Spectroscopically validated density functional theory ca

294 Spectroscopically validated DFT calculations are used he

295 Spectroscopically validated electronic structure calcula

296 As yet, methods for their detection have not spectroscopically verified the chemical composition of m

297 of phycoerythrin (PE) extracted, determined spectroscopically, was used as the response variable.

298 bistriazole/phen macrocycles, characterized spectroscopically, were obtained in 65-70% yield.

299 strong affinity to HSA that was investigated spectroscopically with compound 3h.

300 produced within the film, which is analyzed spectroscopically, yielding a detection limit of 0.830 p