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1 tion (associated with the outer coordination sphere).
2 h interactions in the secondary coordination sphere.
3 2)H, within a metal's secondary coordination sphere.
4 ements and changes to the metal coordination sphere.
5 (H)] cofactor in its functional coordination sphere.
6 e used to infer the location and size of the sphere.
7 ived less attention than in the human health sphere.
8 ased design of functionalized polymer/carbon spheres.
9 y of docetaxel-resistant and patient-derived spheres.
10 for colloidal polymer derived porous carbon spheres.
11 deviate from random loose packings for hard spheres.
12 eraction of Mie resonances in the individual spheres.
13 the smallest spheres to 98% for the largest spheres.
14 produces single-handed chiral supramolecular spheres.
15 esonant elements, e.g. high index dielectric spheres.
16 ility and their ability to form colonies and spheres.
17 molecular gel formulated inside discrete gel spheres.
18 d their proliferation and formation of panco spheres.
19 0.1 vs 1.04 +/- 0.2) (P = 0.0001), residual sphere (- 0.01 +/- 0.2 vs + 0.29 +/- 0.7 vs + 0.27 +/- 0
21 eveals dense accumulations of organic-matter spheres (30-50 mum diameter) of probable algal cyst orig
22 copolymer composition can form well-defined spheres (4 degrees C), worms (22 degrees C) or vesicles
23 > 2.49 based on deviation from a perfect 3D sphere, a 92.7% in-sample and 91.2% out-of-sample accura
26 to the encounter rate between (equal volume) spheres aggregating either by differential settling or d
27 lly steer solid objects (3-mm-diameter glass spheres), along preprogrammed paths, in a water bath, an
30 ated with SE (spherical equivalent; combined sphere and 1/2 cylinder) (p = 0.031, Spearman's rho 0.23
32 tual and i.Scription refractions on both the sphere and cylinder values [(t = 3.12, p < 0.01), (t = 5
33 ificant differences found when comparing the sphere and cylinder values between the habitual and subj
35 ysis has greatly focused on the coordination sphere and electronic effects for the design of function
36 zing the pretreatment parameters using outer-sphere and inner-sphere redox couples, we measured pH by
37 ted reasoning that now prevail in the public sphere and offer an actual example of how clearly stated
40 cases, the exact nature of the coordination sphere and the oxidation state of the metal is of utmost
42 oring binding of NeutrAvidin to biotinylated spheres and binding of immunoglobulin G to spheres funct
43 coli cell is a cylinder flanked by two half spheres and calculating the volumes of bacterial compart
46 treating the cocrystallization of deformable spheres and to formulate new hypotheses about the factor
47 or the hot spheres, and between 81.4% (28-mm sphere) and 87% (37-mm sphere) for the cold spheres for
48 ion of anion (associated to the coordination sphere) and alkali cation (associated with the outer coo
49 -sized pill, swell rapidly into a large soft sphere, and maintain robustness under repeated mechanica
50 sphere) to 83.9% (22-mm sphere) for the hot spheres, and between 81.4% (28-mm sphere) and 87% (37-mm
52 nhancements are not anticipated for metallic spheres, and very small increases (by a factor of a few)
56 Calculations of the bulk modulus reveal that spheres are more compressible than rods in the wurtzite
57 development of polymer derived porous carbon spheres are provided based on the controlled synthesis o
63 s the fatty-acid-induced formation of tumour spheres as well as tumorigenesis induced by high-fat die
64 esponsible for enantioinduction in the inner-sphere asymmetric Tsuji allylic alkylation is C-C bond f
65 in the structure of the Co(II) coordination sphere at the core of human superoxide dismutase 1 (SOD)
66 mediates revealed that the open coordination sphere at zirconium, imparted by the tethered bis(ureate
69 activation and assess the influence of outer sphere atoms, in two Rubisco forms of contrasted O(2)/CO
71 Electrochemical analysis of S-free carbon spheres baseline demonstrates that both the carbon matri
72 a particular class of higher-order Poincare sphere beams, are generalized forms of waves carrying or
73 ck associated with aggregation of equal-size spheres because they collide by virtue of their orientat
75 lusion criteria were emmetropic eyes, with a sphere between -0.25 and +0.50 diopters (D), cylinder of
76 rom "elevation against the anterior best fit sphere (BFS)," "elevation against the posterior BFS" "ax
78 ylpyridinium iodide, provides an early outer-sphere charge-transfer excited state that reports on sol
81 d by the in situ spectroscopic data of inner-sphere complexation of phytic acid at the ferrihydrite-w
82 from Tc(VII) to Tc(IV) and subsequent inner-sphere complexation of Tc(IV)-Tc(IV) dimers onto a Fe ox
85 rect bonds with the mineral surface as inner-sphere complexes, and phosphate groups in polyphosphate
86 les were tested for beer detoxification, and spheres composed of alginate and activated carbon or pec
92 l role of intramolecular second coordination sphere effects exerted by the phosphonate groups in lowe
93 lectron transfer with secondary coordination sphere effects in the metal-organic framework Co(2)(OH)(
95 ticle characterization, the breadth of inner-sphere electrochemical reactions makes this a promising
96 ic analysis of field-effect-controlled outer-sphere electrochemistry on ultrathin back-gated ZnO work
97 lective adsorption mechanism involving outer-sphere electron transfer from the framework to form supe
98 apable of binding O(2) through such an outer-sphere electron transfer mechanism represents a promisin
99 ical formation, and contrasts with the outer-sphere electron transfer pathway observed for (PPh(3))(4
100 dynamic properties, consistent with an outer-sphere electron transfer process, the set of ligated Co(
101 ition, outer-sphere electron transfer, inner-sphere electron transfer, and concerted halogen-atom abs
102 could take place: oxidative addition, outer-sphere electron transfer, inner-sphere electron transfer
103 whereas the larger particles were defective spheres, ellipsoids, and bacilliform cylinders, with reg
105 ne (PDMS) show that the manufactured diamond spheres, even though possessing a rough surface, can be
111 sphere) and 87% (37-mm sphere) for the cold spheres for a given sphere-to-background ratio of 4:1.
113 between 81.4% (28-mm sphere) and 87% (37-mm sphere) for the cold spheres for a given sphere-to-backg
114 ed from 54.3% (10-mm sphere) to 83.9% (22-mm sphere) for the hot spheres, and between 81.4% (28-mm sp
115 of stem cell factors and stemnness markers, sphere formation and self-renewal, along with growth of
116 Wound healing and Matrigel invasion assay, sphere formation assay, and in vivo mice tumor model wer
118 ZNF498 decreased the proportion of SP cells, sphere formation capacity and single cell clonogenicity.
119 tes, reactive oxygen species production, and sphere formation in vehicle- or gemcitabine-treated mono
122 not SMO signaling inhibition, reduces tumor sphere formation, a characteristics of tumor initiating
123 ysis revealed increased migration, invasion, sphere formation, and tumor development in mice after TG
124 4s is a key ATG7 downstream regulator of the sphere formation, invasion, and lung metastasis of BCs,
125 erated SP cells exhibit greater capacity for sphere formation, single cell clonogenicity, and in vivo
126 ng flow cytometry and characterized by tumor sphere formation, tumor formation in nude mice, and expr
131 ation and apoptosis and additionally blocked sphere-forming ability of medulloblastoma stem-like canc
132 cancer cell lines reduced their invasive and sphere-forming activities in culture and formation of or
134 m a rearrangement of the copper coordination sphere from a five-coordinate distorted square pyramid t
137 in a novel 3D heterotypic glioblastoma brain sphere (gBS) model consisting of glioblastoma tumor cell
138 assic isotropic supramolecular micellar-like spheres, generated from conical dendrons, is unknown.
140 tic barrier, entropic contributions to outer sphere H(2) splitting lead to a unique temperature depen
141 and (BNPA(Ph2)O(-)) with second coordination sphere H-bonding groups has been synthesized for stabili
142 se include reactions initiated through outer-sphere, halide-to-metal, and metal-to-ligand charge-tran
143 Here, we synthesize a pair of hollow carbon sphere (HCS) nanoreactors with presynthesized PdCu nanop
144 s easily leachable 8- to 9-coordinated outer-sphere hydrated complexes, dominantly onto kaolinite.
146 parameters for discernible inner- and second-sphere hydration events, and discuss their application t
147 and computational data indicate that second-sphere hydrogen bonding induces structural distortion of
148 the catalyst follows the prototypical "outer sphere" hydrogenation mechanism, comprehensive studies o
150 ence of the increased rigidity of the ligand sphere in 1 was provided by proton T(2) relaxation NMR e
151 ving the location of the Cu(II) coordination sphere in the N42C Az mutant, proximal to the (larger) s
154 crofluidic system can enumerate micron-sized spheres in a single assay using barcoded particles of va
155 lls that overexpressed KDM3A formed foci and spheres in culture and formed tumors and metastases in m
156 leted of PAF1 formed smaller and fewer tumor spheres in culture and orthotopic tumors and metastases
157 found that peripheral implantation of these spheres in mice led to remarkable improvements in genera
160 Spherical lesions were emulated by acquiring sphere-in-air data and combining them with the phantom d
167 g also promoted fragmentation of the ceramic spheres into micron-size particulate matter, which provi
168 n initial assembly of identical "deformable" spheres into two or more size- or shape-distinct sets of
169 water] and a range of model potentials (hard sphere, inverse power, Lennard-Jones, and Weeks-Chandler
171 se reactions are likely facilitated by inner-sphere iron-CIP complexes formed via the sluggish conver
172 bound, while for the WT Az that coordination sphere is closest to the other Au electrode, with which
173 During regeneration, a hollow bilayered sphere is formed that undergoes osmotically driven shape
176 sing computer simulations, we find that hard sphere-like liquids have on intermediate and large scale
177 concentration gradient-tailored agglomerated-sphere LLOs are designed with linearly decreasing Mn and
178 th a proton hosted in the outer coordination sphere, [mCH]Cu(kappa(2)-O(2)N)(ClO(4))(2) (3), also rea
179 g spectra extracted from double integrating sphere measurements, good PSD estimates were obtained fo
181 tivity of naked In(I)(+) ions, with an outer sphere mechanism for the C-N bond formation and a potent
185 cussed, including comparisons between "outer sphere" mechanisms and "metal-ligand cooperation" mechan
187 ype R2lox and targeted primary and secondary sphere mutants indicate that the efficiency of C-H bond
189 aracterized, indicating a key role of second-sphere N-H residues as proton donors during N(2) O reduc
191 n, the functionalization of colloidal carbon sphere nanoreactors, including the nanoengineering of co
193 charged and strongly electron-donating outer sphere nucleophile, result in the lowest reaction barrie
194 yst is a Ni-pai-allyl complex, and the outer-sphere nucleophilic attack of H-bonded amine aggregates
195 inhibition of miR-155 decreased PNF-derived sphere numbers in vitro, and we identified Maf as a miR-
196 orming measurements with a (252)Cf source, a sphere of 4.5 kg of alpha-phase weapons-grade plutonium
197 lkylamine group into the second coordination sphere of an Fe(II) complex allows to switch its reactiv
198 a mean difference in spherical equivalent or sphere of less than 0.5 diopters (D); most were less tha
199 ade plutonium known as the BeRP ball, a 6 kg sphere of neptunium, and a canister of 3.4 kg of plutoni
204 where at some stage, the first coordination sphere of the metal center becomes seven coordinated.
206 stematic control of the primary coordination sphere of the Ru(2) sites within an isoreticular family
207 ch is evaluated experimentally with metallic spheres of known diameters ranging from 0.79 to 3.18 mm.
211 s afforded spherical assembly attached small spheres on the surface, which retained ribonuclease acti
212 c wrinkling induced by the impact of a solid sphere onto an ultrathin polymer sheet floating on water
213 tion, that could proceed via either an inner-sphere or an outer-sphere mechanism, remained unclear.
216 intermolecular electron transfer to an outer-sphere oxidant coupled to intramolecular proton transfer
219 nd spherical equivalent (-1.42 D vs. -0.50 D sphere; P = 0.02) on objective refraction, mean keratome
220 introduce the notion of a "crystallographic sphere packing," defined to be one whose limit set is th
221 L) = 0.25 - 0.33) situated between the sigma-sphere phase and hexagonally close-packed cylinders.
222 Here, we report the discovery of the A15 sphere phase in single-component diblock copolymer melts
223 energy for a series of mutations at a second sphere phenylalanine positioned in proximity to the boun
224 ne that performs the extrusion into 3D using spheres placed along the topological skeletons of the 2D
228 azolium groups in the secondary coordination sphere promote the formation of a local hydration shell
230 the 4Cu(I) :1S redox state, use of a second-sphere proton donor, and reactivity dependence on both p
231 complexes may serve as models for the inner-sphere protonolysis reactions required for catalytic tur
234 001) correlated positively with age, whereas sphere (r = -0.23; P < 0.001), J0 (r = -0.31; P < 0.001)
237 isk electrodes for the oxidation of an outer-sphere redox couple (ferrocene methanol) and two inner-s
238 ox couple (ferrocene methanol) and two inner-sphere redox couples (potassium ferrocyanide and dopamin
239 ment parameters using outer-sphere and inner-sphere redox couples, we measured pH by reducing the sur
241 radical cross-coupling products via an outer-sphere reductive elimination step via triplet spin state
243 ge to the PCET process by lowering the inner-sphere reorganization energy by limiting the elongation
244 TPA(+/0) make them excellent probes of outer-sphere reorganization energy, lambda(o), as lambda(i) <<
247 d with catalytic species, analogous to outer-sphere residue cooperativity within the active sites of
248 Here, we identified a second coordination sphere residue that directs the divergent reactivity of
250 the mesostructural evolution of amphiphilic sphere-rod conjugates (giant lipids), and study the role
252 lacks a mechanism to ensure that the patchy spheres select the staggered orientation of tetrahedral
254 on [VSOTF], effective range of focus [EROF], sphere shift [SS], EROF-SS), pupil size measurements at
255 usly reported isotope effects suggests outer-sphere-single-electron transfer or S(N)2 as possible und
258 asic ionic liquid gels, and ionic liquid gel spheres structured via a modified Stober synthesis formi
261 e independent role of isomerism of secondary sphere substituents over their nature, a factor often ov
266 erritories organized into an inner and outer sphere that are removed from the centrosome at different
267 e lipid bilayer-enclosed, cytosol-containing spheres that, when released by plants and phytopathogens
269 bond formation and bond activation at the Al sphere: thus, not only does it undergo electron redistri
270 nematic structures that range from roughened spheres to 'flower' shapes to branched filamentous netwo
273 covery coefficients varied from 54.3% (10-mm sphere) to 83.9% (22-mm sphere) for the hot spheres, and
275 issions, and monodispersed polystyrene latex spheres under controlled laboratory conditions and also
276 n the shear wave field and around the silica spheres using finite element modelling, giving clarity t
277 te two differently shaped objects (cubes and spheres) using only touch (in darkness) or vision (in li
280 hanistically, secretion of exosomes by these spheres was essential for enhancing survival while produ
281 and distinguish complexes with several inner-sphere water ligands by inspection of temperature-depend
282 sensitive paraCEST agent that lacks an inner-sphere water molecule but contains one Ln-bound -OH grou
283 oxylate oxygen atom, and its remaining inner-sphere water molecules make hydrogen bonding interaction
284 f the complexes has a single, integral inner-sphere water that exchanges rapidly on the NMR timescale
286 to produce strong shear or strain around the sphere, which requires careful tuning of the viscous bou
287 r because the convex geometry of the ceramic spheres widened the waterjet and reduced its velocity by
288 morphology of the resulting nickel particles-spheres, wires and chains-could be controlled through an
289 e favors SUV(25) followed by SUV(peak) for a sphere with a volume of 14 mm(3) (SUV(P14)) as optimal m
290 s manipulation of the secondary coordination sphere with proton relays and these enhance overall reac
291 izes and uptakes were used: 9.89-mm-diameter spheres with 6:1 (lung) and 3:1 (cylinder) local activit
292 y concentration uptakes and 4.95-mm-diameter spheres with 9.6:1 (lung) and 4.5:1 (cylinder) local act
293 nt rates loaded with a lung insert and 6 hot spheres with a 12:1 target-to-background ratio of (177)L
295 sely, this paper establishes that Riemannian spheres with all geodesics closed and sufficiently many
297 tate cancer patients, on docetaxel-resistant spheres with stem cell characteristics, on CSCs obtained
298 dendrons self-assemble to form micellar-like spheres, with a molar mass of up to 1.1 x 10(6) g/mol, t
301 rmation of sterically-stabilized PGMA-PMOEMA spheres, worms or vesicles, depending on the precise rea