コーパス検索結果 (1語後でソート)
通し番号をクリックするとPubMedの該当ページを表示します
1 cid catalyzed by Pd2+ cation in concentrated sulfuric acid.
2 acidity comparable to that of 100% anhydrous sulfuric acid.
3 ulfate anions and by one or two molecules of sulfuric acid.
4 d silica gel and a mixture of silica gel and sulfuric acid.
5 oduct of the Friedel-Crafts acylation in hot sulfuric acid.
6 es to acetic acid at 180 degrees C in liquid sulfuric acid.
7 onor and a hydrogen bond acceptor toward the sulfuric acid.
8 termediate alcohol 14 was then cyclized with sulfuric acid.
9 ion is carried out in the presence of dilute sulfuric acid.
10 23-diselenaporphyrin (4), respectively, with sulfuric acid.
11 e in the presence of lower concentrations of sulfuric acid.
12 acid more slowly on heating in concentrated sulfuric acid.
13 phile environments, rather than concentrated sulfuric acid.
14 by iodic acid with little contribution from sulfuric acid.
15 rated from naturally occurring fluorspar and sulfuric acid.
16 after reacting the shale oil distillate with sulfuric acid.
17 cally originate from the oxidizer, water, or sulfuric acid.
18 le microcrystals of graphite in concentrated sulfuric acid.
19 chemical composition when SOA was exposed to sulfuric acid.
20 studies on organic chemistry in concentrated sulfuric acid.
21 studies on organic chemistry in concentrated sulfuric acid.
22 transformed to value-added chemicals such as sulfuric acid.
23 ene) glycol 250 diacid (PEG 250 diacid), and sulfuric acid.
24 dicator solution of potassium dichromate and sulfuric acid.
25 a protactinium complex using boric acid and sulfuric acid.
26 molecules known to be stable in concentrated sulfuric acid.
27 nd secondary organic aerosol associated with sulfuric acid.
28 r biogenic organic compounds, in addition to sulfuric acid.
29 hich oxidizes methane to methyl bisulfate in sulfuric acid.
30 molybdate in the presence of 50.0 mmol L(-1) sulfuric acid.
31 annot be explained only by the nucleation of sulfuric acid.
32 ssible cyanohydrin derivatives in methanolic sulfuric acid.
33 (III) intermediate in concentrated or fuming sulfuric acid.
34 Pt(II) "Periana-Catalytica" catalyst in 98% sulfuric acid.
35 s, of which one example is the production of sulfuric acid.
36 rescence quantum yield for quinine in 0.05 M sulfuric acid.
37 blue when exposed to mixtures of iodine and sulfuric acid.
38 Milk was wet-ashed by using nitric and sulfuric acids.
39 calcite slurry dissolution with carbonic and sulfuric acids.
40 peracetic acid (300 mM, 2.3 wt%) and dilute sulfuric acid (100 mM, 1.0 wt%) at 120 degrees C for 5 m
42 often been coupled with strong and corrosive sulfuric acids (2-3 M), leading to severe electrode corr
43 precursor molecules seeded into concentrated sulfuric acid, a result that is corroborated by domain k
44 ce source material for mineral dust, in pH 2 sulfuric acid, acetic acid, and oxalic acid, respectivel
45 ur findings reveal the multifaceted roles of sulfuric acid, acting as a dispersion medium, a dehydrat
47 bility of nucleic acid bases in concentrated sulfuric acid advances the idea that chemistry to suppor
49 low-power method for collecting micron-sized sulfuric acid aerosols in bulk from the atmosphere of Ve
50 ormation without the intentional addition of sulfuric acid, although contamination could not be exclu
52 easurements of rates of nucleation involving sulfuric acid, ammonia, ions, and organic compounds cond
54 f HIO(3) particles are rapid, even exceeding sulfuric acid-ammonia rates under similar conditions.
55 droplets are composed of concentrated liquid sulfuric acid-an aggressive solvent that is assumed to r
57 uster sequentially loses ammonia followed by sulfuric acid and (2) a one-step pathway whereby the clu
58 intercalation compound (GIC) in concentrated sulfuric acid and (2) oxidizing and exfoliating the stag
60 ERN CLOUD chamber, we show that nitric acid, sulfuric acid and ammonia form particles synergistically
61 New particle formation via the ion-mediated sulfuric acid and ammonia molecular clustering mechanism
64 ine complex is quantitatively extracted from sulfuric acid and can be recovered from the column by el
67 lus, to extract valuable metals by producing sulfuric acid and ferric ions that dissolve sulfidic min
68 tea, fresh tea leaves, and weeds) with 0.1 M sulfuric acid and from soil with 0.1 M sulfuric acid met
69 to generate low-volatility products such as sulfuric acid and high-molecular weight organics that nu
70 atosphere, in the heterogeneous formation of sulfuric acid and in the formation of aerosols, in H(2)S
71 water molecules, and also in the presence of sulfuric acid and its complexes with one and two water m
73 of carbon single-walled nanotubes (SWNTs) in sulfuric acid and Nafion was investigated using solid-st
75 tic seabird-influenced particles can grow by sulfuric acid and organic vapour condensation to diamete
77 nucleation and heteromolecular nucleation of sulfuric acid and organics and reproduces the profile of
78 volving the formation of clusters containing sulfuric acid and oxidized organic molecules from the ve
79 ving Outdoor Droplets) chamber at CERN, that sulfuric acid and oxidized organic vapors at atmospheric
83 of peracetic acid (PAA) and Amplon (blend of sulfuric acid and sodium sulfate) at a poultry processin
85 entieth century, leading to the formation of sulfuric acid and to the precarious state that they are
87 2-3 nm most likely occurs by condensation of sulfuric acid and water, implying that anthropogenic sul
88 tratospheric aerosols primarily consisted of sulfuric acid and water, many also contained meteoritic
89 anotube fibers were swollen in oleum (fuming sulfuric acid), and organic spacer groups were covalentl
90 esulfonic acid is formed simultaneously with sulfuric acid, and both are found in particles in coasta
91 liquid and solid particles containing water, sulfuric acid, and in some cases nitric acid) that are f
92 ximately 37 wt.%) and 20% (v/v) concentrated sulfuric acid ( approximately 98 wt.%) at room temperatu
93 issolved Fe(3+) in varying concentrations of sulfuric acid are shown to be good candidates for explai
94 erchloric acid rather than quinine in 0.05 M sulfuric acid as a standard solution for the determinati
95 under solar UV light produces first gaseous sulfuric acid as an intermediate product before surface-
96 cular the methanolysis of ethyl acetate with sulfuric acid as catalyst, is used as a model reaction t
98 Sulfonation of 5 and 6 with concentrated sulfuric acid at 100 degrees C gave sulfonated derivativ
99 tween 0.4 and 28.6% degradation in 98% (w/w) sulfuric acid at ~25 degrees C, over the span of 14 days
101 d, sulfur dioxide, and sulfur polymers, with sulfuric acid being about 50 times as abundant as the ot
103 the major product when solutions of bromate, sulfuric acid, bromide, and chloride ions are frozen.
104 hen the aerosol particles are acidified with sulfuric acid but stops entirely only under dry conditio
107 nt and further establishes that concentrated sulfuric acid can sustain a diverse range of organic che
109 rongly confirm that inorganic acids, such as sulfuric acid, catalyze particle-phase heterogeneous rea
113 c liquids can form from planetary materials: Sulfuric acid combined with nitrogen-containing organic
114 rmation of an unusually stable aromatic acid-sulfuric acid complex, which likely leads to a reduced n
116 uric acid in the Venus cloud temperature and sulfuric acid concentration range, using UV spectroscopy
117 quantitatively determined and the gas-phase sulfuric acid concentration required to incorporate the
118 aterial, which spatially correlates with the sulfuric acid concentration, is identified as radiolytic
120 cids are stable in the range of Venus' cloud sulfuric acid concentrations (81% and 98% w/w, the rest
121 that the AP-ID-CIMS allows quantification of sulfuric acid concentrations and is capable of detecting
124 evant for environments characterized by high sulfuric acid concentrations, for example, during the tr
125 evated SO(2) and OH levels leads to enhanced sulfuric acid concentrations, promoting particle formati
130 ducts are either bare sulfuric acid dimer or sulfuric acid dimer complexed with a water molecule.
131 cases, the reaction products are either bare sulfuric acid dimer or sulfuric acid dimer complexed wit
132 t particles acquire a large mass fraction of sulfuric acid during atmospheric aging, considerably alt
133 on was observed from 0.1 M Na(2)SO(4) in 95% sulfuric acid during multibubble sonoluminescence (MBSL)
135 teraction between biogenic organic acids and sulfuric acid enhances nucleation and initial growth of
137 HH and GG dipeptides are stable in 98% w/w sulfuric acid for at least 4 months, while II, LL, VV, P
139 Sensitivity analysis shows that substituting sulfuric acid for citric acid and achieving >52% heat re
140 strength to at least that of 100% anhydrous sulfuric acid for various acid-catalyzed organic transfo
141 ic aerosols by reacting with condensed phase sulfuric acid, forming low-volatility organosulfate comp
142 potassium contents because the production of sulfuric acid from protein metabolism and bicarbonate fr
143 rvations of dimethylsulfide, sulfur dioxide, sulfuric acid (gas), hydroxide, ozone, temperature, rela
147 ouds of Venus are believed to be composed of sulfuric acid (H(2)SO(4)) and minor constituents includi
148 using manganese dioxide (MnO(2)) as oxidant, sulfuric acid (H(2)SO(4)) as solvent, and bromine (Br(2)
150 e two key intermediates in the production of sulfuric acid (H(2)SO(4)) on Earth's atmosphere, one of
151 y in the literature regarding the effects of sulfuric acid (H(2)SO(4)) on elemental Hg uptake by acti
152 ing vapor in the atmosphere is thought to be sulfuric acid (H(2)SO(4)), stabilized by ammonia (NH(3))
153 r and a key intermediate in the formation of sulfuric acid (H(2)SO(4), SA) in the Earth's atmosphere.
154 We report on the intermolecular transfer of sulfuric acid (H2SO4) and sulfur trioxide (SO3) from an
156 ate aerosol layer led to the suggestion that sulfuric acid (H2SO4) must photolyze at high altitudes.
160 e- and dextran VPA esters were modified with sulfuric acid half ester moieties to improve intracellul
161 ospheric aging, internal mixing of soot with sulfuric acid has profound implications on visibility, h
163 d that sulfur content (S %) was very low for sulfuric acid hydrolyzed samples, and X-ray results did
164 oxidized biogenic vapours in the absence of sulfuric acid in a large chamber under atmospheric condi
166 oxoacid particle formation can compete with sulfuric acid in pristine regions of the atmosphere.
172 estigation show that the catalytic effect of sulfuric acid in the SO(3) hydrolysis can be important i
173 d bases purine and pyrimidine, are stable in sulfuric acid in the Venus cloud temperature and sulfuri
175 will convert hydrogen halides and nitric and sulfuric acids into stable salts to enable stratospheric
176 for genetic polymers stable in concentrated sulfuric acid is a necessary first step to establish tha
178 boratory experiments show that nucleation of sulfuric acid is considerably enhanced in the presence o
180 e dipeptides studied in 98% w/w concentrated sulfuric acid is different from the standard acid-cataly
182 ra with Galileo data indicates that hydrated sulfuric acid is present and is a major component of Eur
185 ad and forms particles more efficiently than sulfuric acid, its gas-phase formation mechanism remains
186 y dextran sulfate sodium and trinitrobenzene sulfuric acid, KO mice were more tolerant than wild-type
188 g a hydrothermal reaction, we have converted sulfuric acid lignin (SAL) into a water-soluble hydrothe
190 carbonyl groups is observed in concentrated sulfuric acid media that also produces a previously unob
191 its separation and crystallization, even in sulfuric acid media where protactinium is relatively sta
192 0.1 M sulfuric acid and from soil with 0.1 M sulfuric acid methanol after adjusting soil acidity with
193 ethods for carbohydrate analysis, the phenol-sulfuric acid method is the easiest and most reliable me
195 ly utilized oxidation media, via nitric acid/sulfuric acid mixtures, are too corrosive and oxidizing
197 f monoterpenes, cluster directly with single sulfuric acid molecules and then form growing clusters o
198 simulations to show that the presence of two sulfuric acid molecules in (H2SO4)m x base x (H2O)6 clus
199 With one cis-pinonic acid and three to five sulfuric acid molecules in the critical nucleus, the hyd
200 d then form growing clusters of one to three sulfuric acid molecules plus one to four oxidized organi
202 ces of nutrients of aeolian origin including sulfuric acid, nitric acid, methanosulfonic acid (MSA),
204 ide, and the condensation of OOMs along with sulfuric acid onto new particles is sufficient to explai
206 reserved by widespread cooling from volcanic sulfuric acid or by burial under dust or pyroclasts.
208 100-fold by extremely low concentrations of sulfuric acid or iodine oxoacids above 10(5) cm(-3), rea
209 in atmospheric field conditions that involve sulfuric acid, organic or iodine oxide vapours have yet
211 ades could cause up to half of stratospheric sulfuric acid particles to contain metals from reentry.
216 Results Al(2)O(3) sandblasting followed by sulfuric acid pretreatment significantly enhanced the bo
217 O(3)) sandblasting in conjunction with a 98% sulfuric acid pretreatment, exhibits improved bond stren
225 ply that the interaction between organic and sulfuric acids promotes efficient formation of organic a
226 alues were compared to those calculated by a sulfuric acid proxy that considers solar radiation and S
227 tion the neutral gaseous species ammonia and sulfuric acid react to form ammonium and sulfate ions.
229 ons of gaseous formic acid with concentrated sulfuric acid show that impinging monomers (HCOOH and DC
230 ic acid) with the increased concentration of sulfuric acid solution in water in both modes; (iii) the
231 rodes, Deltaphi(sol), immersed in an aqueous sulfuric acid solution was monitored while performing co
235 cy generation (SFG) spectra of adlayers from sulfuric acid solutions on Pt(111) surfaces and reveal s
236 of operation can collect the entire range of sulfuric acid solutions; (ii) the collection efficiency
237 ich utilizes (bpym)Pt(II)Cl2 in concentrated sulfuric acid solvent at 200 degrees C, is a highly stab
238 on is possible through the use of an aqueous sulfuric acid solvent, in an aqueous biphasic reaction m
242 tinuously cycles sulfur between three forms: sulfuric acid, sulfur dioxide, and sulfur polymers, with
243 nce on fossil fuels for sulfur and therefore sulfuric acid supply(8,9), our technology may represent
245 C-H activation between methane and Sb(V) in sulfuric acid that could potentially outcompete superaci
246 The key step is a Prins reaction in 60% sulfuric acid that gave the key tricyclic intermediate w
247 res only air, water, electricity, and dilute sulfuric acid, the bulk of the latter being recycled.
248 f the clusters containing three molecules of sulfuric acid, the clusters grow at a similar speed, ind
250 often one thousand times more abundant than sulfuric acid, the resulting particle growth rates can b
251 demonstrate that ferric iron can react with sulfuric acid to form two mineral phases: rhomboclase [(
252 s treated in the second-stage leaching using sulfuric acid to further concentrate precious metals, wh
253 = 1,3,5-benzenetricarboxylate] with aqueous sulfuric acid to generate its sulfated analogue, MOF-808
255 he cesium hexafluosilicate with concentrated sulfuric acid to generate silicon tetrafluoride gas.
257 xtractable metal complex, we used iodide and sulfuric acid to neutralize the charge on Cd(2+) to form
259 0% aqueous hydrogen peroxide in concentrated sulfuric acid to provide 2-(5-oxo-3-(pentafluorosulfanyl
260 se gas (GHG) emissions was the production of sulfuric acid to regenerate resins, rather than transpor
263 y surface is water-depleted and must support sulfuric acid transiently in liquid phase to dissolve or
265 Assay parameters for lipid sample volume, sulfuric acid, vanillin/phosphoric acid, post-reaction i
267 del predicts that nucleation rates equal the sulfuric acid vapor collision rate times a prefactor tha
268 ted nucleation rates and their dependence on sulfuric acid vapor concentrations are in reasonable agr
274 ric method constituted of p-anisaldehyde and sulfuric acid was developed and avoids all of the above
275 ls (>25.0%, w/w) reaction with diphenylamine-sulfuric acid was found adequate to indicate the presenc
277 nanotubes (SWNTs) in a mixture of nitric and sulfuric acids was carried out to synthesize highly wate
278 ammonia gas is stripped and passed into the sulfuric acid where ammonium sulfate and hydrogen triamm
279 sformations are conducted in the presence of sulfuric acid, which reacts with the amine substrates in
280 the multiphase oxidation of SO(2) to produce sulfuric acid, while the increase in acidity had a posit
281 trations and is capable of detecting gaseous sulfuric acid with a detection limit of less than 10(5)
282 emical oxidation of graphite in a mixture of sulfuric acid with a strong oxidizer, such as potassium
283 method was developed using methanol with 2 M sulfuric acid with incubation at 65 degrees C for 60 min
284 s to experimentally examine this reaction in sulfuric acid with oleum, which has never been reported
285 rcent for water to over 40% for concentrated sulfuric acid) with the increased concentration of sulfu
286 H2O hydrogens and a nearby S=O oxygen on the sulfuric acid, with an O...H distance of 2.05(1) A and a
289 te porphyrins on treatment with concentrated sulfuric acid yielded the free-base cyanobenzochlorins i