ライフサイエンスコーパス: sulfuryl

1 through the fine-tuning of the reactivity of sulfuryl chloride (SO(2)Cl(2)) by organocatalysts.

2 glycosyl chlorides from thioglycosides using sulfuryl chloride at rt.

3 ical olefin-addition reactions with bromine, sulfuryl chloride, m-chloroperbenzoic acid, dioxygen, an

4 nly used S(VI) electrophiles, and the parent sulfuryl chloride, O2 S(VI) Cl2 , has also been relied o

5 hair exposed to chlorine, hypochlorite, and sulfuryl chloride.

6 lpha-haloketones, a silyl chloride, acyl and sulfuryl chlorides, and a nitroarene.

7 heteroarenes in good yield by treatment with sulfuryl diimidazole in nonpolar solvents at elevated te

8 PAPS serves as the sulfuryl donor for the biosynthesis of all sulfate ester

9 CoA that was competitive with respect to the sulfuryl donor substrate, 3'-phosphoadenosine-5'-phospho

10 constants for hydrolysis of a wide range of sulfuryl esters, ArOSO(2)X(-), are shown to be correlate

11 aration of this reagent relies on the use of sulfuryl fluoride (SO(2)F(2)), which is difficult to obt

12 Sulfuryl fluoride (SO(2)F(2), SF) is an effective and in

13 od for the deoxyfluorination of phenols with sulfuryl fluoride (SO2F2) and tetramethylammonium fluori

14 etramethylammonium 2,6-dimethylphenoxide and sulfuryl fluoride (SO2F2) serves as a particularly pract

15 imple to perform, as recently exemplified by sulfuryl fluoride exchange chemistry.

16 Sulfuryl fluoride is a valuable reagent for the one-pot

17 This enzyme transfers the sulfuryl group (SO(3)) from 3'-phosphoadenosine 5'-phosp

18 density of this oxygen atom on a transferred sulfuryl group accounts for a large fraction of the decr

19 The universal sulfuryl group donor for SULT-catalyzed sulfation is ade

20 The universal sulfuryl group donor for SULTcatalyzed sulfation is aden

21 In mammals, the universal sulfuryl group donor molecule 3'-phosphoadenosine 5'-pho

22 gi enzymes that catalyze the transfer of the sulfuryl group from 3'-phosphoadenosine 5'-phosphosulfat

23 nsferase (EST) catalyzes the transfer of the sulfuryl group from 3'-phosphoadenosine 5'-phosphosulfat

24 roup of enzymes catalysing the transfer of a sulfuryl group from 3'-phosphoadenosine 5'-phosphosulpha

25 Sulfotransferases catalyze the transfer of a sulfuryl group from the eukaryotic sulfate donor 3'-phos

26 phoadenosine 5'-phosphosulfate (PAPS), whose sulfuryl group is reduced or transferred to other metabo

27 ansferase (EST) catalyzes transfer of the 5'-sulfuryl group of adenosine 3'-phosphate 5'-phosphosulfa

28 S/MS) analysis under conditions in which the sulfuryl group of sulfotyrosine is labile.

29 Receipt of the sulfuryl group often radically alters acceptor-target in

30 isotope effects support the notion that the sulfuryl group resembles SO(3) in the transition state.

31 s of enzymes that catalyze the transfer of a sulfuryl group to a hydroxyl or amine moiety on various

32 -3), a key sulfotransferase that transfers a sulfuryl group to a specific glucosamine in HS generatin

33 directions indicates that the transfer of a sulfuryl group to an aryl hydroxyl group catalyzed by be

34 NodST catalyzes the sulfuryl group transfer from 3'-phosphoadenosine 5'-phos

35 ohydrate sulfotransferase Stf0 catalyzes the sulfuryl group transfer from 3'-phosphoadenosine-5'-phos

36 measured, and the catalytic mechanism of the sulfuryl group transfer reaction was investigated in ini

37 Arg78 is in close proximity to the site of sulfuryl group transfer.

38 tem since no shift in absorption accompanies sulfuryl group transfer.

39 catalytic histidine residue, (2) an in-line sulfuryl-group transfer mechanism, and (3) constraints i

40 rases in liver and catalyzes transfer of the sulfuryl moiety (-SO(3)) from activated sulfate (PAPS, 3

41 solic sulfotransferases (SULTs) transfer the sulfuryl moiety (-SO(3)) from activated sulfate [3'-phos

42 ysiological relevance by the transfer of the sulfuryl moiety (-SO(3)) from PAPS (3'-phosphoadenosine

43 ignaling small molecules via transfer of the sulfuryl moiety (-SO3) from 3'-phosphoadenosine 5'-phosp

44 of signaling metabolites via transfer of the sulfuryl moiety (-SO3) from activated sulfate (3'-phosph

45 s and other xenobiotics--by transferring the sulfuryl moiety (SO3) from 3'-phosphoadenosine 5'-phosph

46 ults show that while the interactions of the sulfuryl moiety and the phenyl ring with the YopH active

47 network with the hydroxyl group ortho to the sulfuryl moiety, which may be exploited to design more p

48 switched "on" and "off" via transfer of the sulfuryl-moiety (-SO3) from PAPS (3'-phosphoadenosine 5'

49 ll kinetic isotope effect in the nonbridging sulfuryl oxygen atoms suggests no significant change in

50 for the estrogen sulfotransferase-catalyzed sulfuryl (SO3) transfer from p-nitrophenyl sulfate to th

51 faster than the aqueous reaction, while the sulfuryl transfer from the pNPS anion is some 40-fold sl

52 Understanding phosphoryl and sulfuryl transfer is central to many biochemical process

53 istic of the transition state for an in-line sulfuryl transfer reaction from PAPS to E2.

54 in position to play a catalytic role in the sulfuryl transfer reaction of EST.

55 Sulfuryl transfer reactions of sulfate diesters (RO-SO(2

56 on of the data for enzymatic and uncatalyzed sulfuryl transfer reactions suggests that both proceed t

57 del systems for understanding phosphoryl and sulfuryl transfer reactions, respectively.

58 ups are aryl groups the hydrolysis reaction (sulfuryl transfer to water) occurs by way of attack at s

59 PAPS and K(I) values for PAP, the product of sulfuryl transfer.

60 at can be used to regulate specific areas of sulfuryl-transfer metabolism.

61 echanistic similarities, the phosphoryl- and sulfuryl-transfer reactions differ markedly in their res

62 ts and medium effects have been measured for sulfuryl-transfer reactions of the sulfate ester p-nitro