ライフサイエンスコーパス: supramolecular

1 ments in two-dimensional self-assembly, most supramolecular 2D materials are assembled by tedious met

2 usters do not coalesce into a stable central supramolecular activation cluster (cSMAC).

3 he localization of dyneins in the peripheral supramolecular activation cluster facilitates their inte

4 The molecular assembler is a supramolecular aggregate of bifunctional surfactants pro

5 ng dynamic shortening of chain length in the supramolecular aggregates.

6 embler starts to produce polymers instead of supramolecular aggregates.

7 ll as alteration of molecular geometries and supramolecular aggregation.

8 addition (CuAAC), providing interpenetrating supramolecular and covalent networks.

9 ethodology relies on a concept that combines supramolecular and macromolecular chemistry and differs

10 ng blocks, which are valuable precursors for supramolecular and materials chemistry to illustrate the

11 est of BN-doped polyaromatic hydrocarbons in supramolecular and materials chemistry, it is expected t

12 OMs in biological, medical, electrochemical, supramolecular and nanochemistry fields, or as homogeneo

13 ctivity, relies on hydrophobic, hydrophilic, supramolecular, and ionic interactions, which are common

14 Supramolecular anion receptors can be used to study the

15 Here we present a modular supramolecular approach to relay the photoinduced geomet

16 surface of natural killer (NK) cells with a supramolecular aptamer-based polyvalent antibody mimic (

17 ets set a clear distinction between this new supramolecular architecture and previously reported 2D n

18 We are reporting an original supramolecular architecture based on a rationally design

19 Structural studies have revealed the supramolecular architecture of a variety of disease-asso

20 ribe the design and synthesis of crystalline supramolecular architectures from charge-complementary h

21 Efficient long-range energy transport along supramolecular architectures of functional organic molec

22 for the efficient and reliable discovery of supramolecular architectures through the exploration of

23 Designing supramolecular architectures with uncommon geometries em

24 w approach to construct highly sophisticated supramolecular architectures.

25 modified by the hierarchical level of H-type supramolecular architectures.

26 onlike fibrous morphology that resembles the supramolecular arrangement of 1 in its crystalline state

27 rt capabilities using metalloporphyrin-based supramolecular arrays.

28 small-angle X-ray scattering) that differing supramolecular assemblies are accessed, controlled by TM

29 e report the implementation of DNA-decorated supramolecular assemblies as dynamic and responsive nano

30 process involves the use of ordered peptide supramolecular assemblies as templates to direct the fol

31 constitutes aberrantly stable, GTP-resistant supramolecular assemblies both in vitro and in vivo, nei

32 rt that incubation of aqueous dispersions of supramolecular assemblies formed by synthetic alkyl tria

33 Supramolecular assemblies have gained tremendous attenti

34 mation of elegant helical superstructures or supramolecular assemblies in chiral environments.

35 ving long-range order with surface-supported supramolecular assemblies is one of the pressing challen

36 One of the most appealing features of supramolecular assemblies is their ability to respond to

37 Supramolecular assemblies of enamel matrix proteins (EMP

38 ed that full-length AMELX forms higher-order supramolecular assemblies that regulate ordered minerali

39 However, for supramolecular assemblies to be considered a standard re

40 nthesis of such a nanotopology using fibrous supramolecular assemblies with intrinsic curvature.

41 edically relevant ABC transporters and their supramolecular assemblies, including the ATP-sensitive p

42 ckbone and open up ways to design programmed supramolecular assemblies.

43 examples of new nonequilibrium materials and supramolecular assemblies.

44 ts and electrocatalytic applications of such supramolecular assemblies.

45 hus, will have implications in catalysis and supramolecular assemblies.

46 cs of redox-active species encapsulated into supramolecular assemblies.

47 l as in the construction of redox-controlled supramolecular assemblies.

48 ic peptides and proteins are rich sources of supramolecular assemblies.

49 between stacked lipid bilayers, visualizing supramolecular assembly at the myelin major dense line.

50 ]paracyclophane bridge results in a weakened supramolecular assembly for [3.3]pCpTA compared to [2.2]

51 'Smart' supramolecular assembly of catalysts offers precise reco

52 The supramolecular assembly of medin, a 50-amino acid peptid

53 ecular-weight polyethyleneimime (CP) through supramolecular assembly to generate CP/Ad-SS-GD.

54 We combined synthetic biology and supramolecular assembly to prepare elastin-like protein

55 A nanoring-rotaxane supramolecular assembly with a Cy7 cyanine dye (hexameth

56 ic protein, the network yields a cooperative supramolecular assembly with a hybridization architectur

57 ng" event results from collision of a single supramolecular assembly with the LC interface.

58 catalytic three-component coupling within a supramolecular assembly, providing a supramolecular solu

59 Their properties can be further tuned by supramolecular assembly.

60 of cytotoxic multiprotein complexes, called supramolecular attack particles (SMAPs), from CTLs to ta

61 n-1 (TSP-1) in specialized structures termed supramolecular attack particles (SMAPs).

62 amic, and functional characterization of the supramolecular BCPs.

63 te to explore the applications of functional supramolecular BCPs.

64 rnate supramolecular copolymer, or a complex supramolecular block copolymer can occur, determined by

65 Herein, we report the cooperative supramolecular block copolymerization of fluorescent mon

66 a detailed spectroscopic probing during the supramolecular block copolymerization process to unravel

67 However, the synthesis of supramolecular block copolymers (BCPs) constitutes a sig

68 Supramolecular block copolymerzation with optically or e

69 ally, we demonstrate that alterations to the supramolecular bond strength between particles can alter

70 ing block to assemble the permanently porous supramolecular cage Co-PB-1(6) bearing six Co-TPP subuni

71 n confined spaces, such as those provided by supramolecular cages, is quickly gaining momentum.

72 nities in the design of catalytically active supramolecular cages.

73 Supramolecular cages/vesicles in biology display sophist

74 identify the origin of the catalysis by the supramolecular capsule Ga(4)L(6)(12-) on the reductive e

75 t biomaterials will have applications beyond supramolecular catalysis for copper-catalyzed cycloaddit

76 have emerged as one of the popular topics in supramolecular catalysis.

77 ioenriched product (90% ee) is produced by a supramolecular catalyst operating with ppm levels of chi

78 organogels formed by the glycoconjugates as supramolecular catalysts, efficient catalysis was demons

79 eractions of a series of biologically-active supramolecular cationic metallohelices with human telome

80 n in several areas of research, ranging from supramolecular chemistry and colloidal science to roboti

81 espread applications in material science and supramolecular chemistry due to their aggregation-induce

82 Supramolecular chemistry exploits weak, yet effective, i

83 Although solvent effects in supramolecular chemistry have been recognized for a long

84 nteractions has been sparked in the field of supramolecular chemistry in general and that of supramol

85 bled nanomaterials and provide evidence that supramolecular chemistry is an effective tool in control

86 The development of the supramolecular chemistry of anion-anion dimers has led t

87 ns enhance our understanding of the specific supramolecular chemistry of Z1 that is essential for the

88 Synthetic supramolecular chemistry pursues not only the constructi

89 rred on by significant developments in anion supramolecular chemistry, electrochemical anion sensing

90 -inorganic framework via coordination-driven supramolecular chemistry, for efficient remediation of t

91 nisms involving reversible covalent bonding, supramolecular chemistry, or polymers with phase-separat

92 lso a glimpse to his vision of the future of supramolecular chemistry.

93 ore applicable as a complementary synthon in supramolecular chemistry.

94 pidly growing area of dynamic and switchable supramolecular chemistry.

95 ons is gaining momentum in biochemistry and (supramolecular) chemistry.

96 While it has been studied and exploited by supramolecular chemists for many years, most of this wor

97 ireview, the focus is on the strategies that supramolecular chemists use to emulate the efficiency of

98 es are important but challenging targets for supramolecular chemists.

99 ystems and are of significant interest among supramolecular chemists.

100 ion determination, as well as a range of new supramolecular clusters discovered in solution using hig

101 Herein, we report a supramolecular co-assembly based on lower-rim dodecyl-mo

102 Here, we disclose a series of supramolecular (co)polymers based on water-soluble benze

103 mics and DFT calculation demonstrated that a supramolecular complex of saccharide-fullerene was forme

104 r systems using six-membered hydrogen-bonded supramolecular complexes (rosettes).

105 n to preorganize noncovalently polymerizable supramolecular complexes is a characteristic process of

106 Inflammasomes are supramolecular complexes that play key roles in immune s

107 7,8]uril (CB[7,8]) hosts in water; resulting supramolecular complexes were characterized by NMR, ESI-

108 dynamic radius of small molecules, proteins, supramolecular complexes, macromolecules, nanoparticles

109 in aqueous solution for the Ga(4)L(6) (12-) supramolecular construct.

110 Nature has developed supramolecular constructs to deliver outstanding charge-

111 of bis-aza[60]fullerene (C(59)N)(2) within a supramolecular coordination capsule has been studied for

112 t, we present a new water-soluble Pd(12)L(6) supramolecular coordination nanocage (1) that was synthe

113 lecular homopolymers, a random (statistical) supramolecular copolymer, an alternate supramolecular co

114 ical) supramolecular copolymer, an alternate supramolecular copolymer, or a complex supramolecular bl

115 recedented two-component sequence controlled supramolecular copolymerization by manipulating thermody

116 in the context of the temperature-controlled supramolecular copolymerization of chiral and achiral bi

117 The water incorporated in the supramolecular DES complex stabilizes the transition sta

118 al review will discuss recent efforts to use supramolecular design to leverage the non-covalent force

119 best obtained by dimer formation, promoting supramolecular double helices.

120 induced electron transfer in a TBPCExBox(4+) supramolecular dyad.

121 This works opens to supramolecular electronics, a concept already exploited

122 Supramolecular energy materials also hold great potentia

123 rm objectives of the field described here as supramolecular energy materials is to learn how to desig

124 an idea about the most probable microporous supramolecular environment in the gel state, gelator mol

125 10 ternary assemblies via two processes: (1) supramolecular exchanges (i.e., the egression and ingres

126 do not significantly affect the rate of the supramolecular exchanges, they were found to control (1)

127 igand exchanges are consistently slower than supramolecular exchanges.

128 framework (MOF), Fe-HAF-1, constructed from supramolecular, Fe(3+)-hydroxamate-based polyhedra with

129 Supramolecular fibers in water, micrometers long and sev

130 Tyr-Tyr (KYY) with strong propensity to form supramolecular fibers, is utilized.

131 PT prodrug can be steadily released from its supramolecular filament hydrogel, effectively killing pr

132 ned CPT prodrug spontaneously assembles into supramolecular filaments with a 100% CPT loading.

133 f the indicators by hexylcreatinine produced supramolecular fluorescence turn-on sensors that work at

134 lity of the observed anionic bases and their supramolecular formations and hydrates has also been exa

135 Furthermore, microporous supramolecular framework of PTC-1(2H) is able to promote

136 CT cocrystals were found to display a rigid supramolecular framework while weakly bound CT complexes

137 gn of inorganic systems can result in potent supramolecular functionality, beyond that observed for o

138 k demonstrates the operation of a reversible supramolecular gate, i.e., an ensemble of various compon

139 The rotational dynamics of dirhodium supramolecular gears, formed with four 9-triptycene carb

140 sulated and released from a nucleoside-based supramolecular gel and sets the basis for the design of

141 Here, we use a novel nucleoside-based supramolecular gel as a drug delivery system for protein

142 ell-structured gel beads-a rare example of a supramolecular gel formulated inside discrete gel sphere

143 Erosion of a supramolecular gel has not yet been reported to contribu

144 are stable until re-oxidation to Cu(II) and supramolecular gelation.

145 lent gelation properties and can function as supramolecular gelators.

146 ts the basis for the design of more tailored supramolecular gels for drug delivery applications.

147 Supramolecular gels have recently emerged as promising b

148 hind the release of bioactive molecules from supramolecular gels, this work provides mechanistic insi

149 the goal of imposing shape and structure on supramolecular gels, we combine a low-molecular-weight g

150 strong, cross-linkers in the fabrication of supramolecular gels, which exhibited excellent viscoelas

151 mechanisms for the release of molecules from supramolecular gels.

152 We focus our investigation on supramolecular helices composed of an achiral benzene-1,

153 lecule to suppress conformational defects in supramolecular helices, thus leading to the emergence of

154 report the construction of a series of giant supramolecular hexagonal grids, with diameters on the or

155 etween macrocycle and diphosphate produces a supramolecular homopolymer of general formula (A)(n) com

156 arious possible outcomes such as self-sorted supramolecular homopolymers, a random (statistical) supr

157 generates N-phenylaziridines, catalyzed by a supramolecular host, that provides the stereoisomer oppo

158 this tutorial review, we present the use of supramolecular hosts (cyclodextrins, calixarenes, (acycl

159 al and molecular recognition features of the supramolecular hosts and some of the principles used in

160 The structural simplicity of synthetic supramolecular hosts imbues them with considerable poten

161 icipates future research efforts in applying supramolecular hosts in catalysis.

162 d G4/Adv into a biocompatible and injectable supramolecular hydrogel (SH) made of alpha-cyclodextrin

163 ptothecin) that self-assemble in situ into a supramolecular hydrogel.

164 trogen coordinate bonding into preorganized, supramolecular hydrogen-bonded cyanuric acid-melamine (C

165 ls with switchable properties based on their supramolecular interactions by establishing clear SOFT-p

166 The importance of supramolecular interactions in COFs to their mechanisms

167 sport behaviors, nanoscale self-assembly via supramolecular interactions is also a potentially desira

168 in we incorporate simple, naturally inspired supramolecular interactions via the axial complexation o

169 nected together via covalent or non-covalent/supramolecular interactions, are arguably the most versa

170 Enzymatic reactions and noncovalent (i.e., supramolecular) interactions are two fundamental nongene

171 propose terminology more appropriate to the supramolecular interpretation of surface typology: the p

172 try change, from flat to conic, can generate supramolecular landscapes where different self-assembled

173 lso prepared, which forms a highly stable 3D supramolecular lattice via strong intermolecular interac

174 At the supramolecular level, the proliferation of invasive duct

175 egulated behaviour from the molecular to the supramolecular level.

176 responsible for the remarkable efficiency of supramolecular light-harvesting assemblies within photos

177 ation barriers through composition of stable supramolecular light-harvesting nanotubes enabled by tun

178 The dynamic character of supramolecular links present challenges to sequence defi

179 provides a convenient approach to preparing supramolecular luminescent liquid crystals, which will s

180 The incorporation of supramolecular macrocycles into porous organic polymers

181 hallenges to sequence definition in extended supramolecular macromolecules, and design principles rem

182 ther-directed covalent functionalization and supramolecular masks-the control of regioselectivity req

183 Here we describe a supramolecular material set and patterning approach wher

184 a connection between chemical reactivity and supramolecular material structure.

185 t nanosheets represent one of the largest 2D supramolecular materials ever made, with potential appli

186 se of functionalized PAs and their assembled supramolecular materials in the field of catalysis.

187 hesis of a free-standing, macroscopic robust supramolecular membrane by introducing silver-nitrogen c

188 In this work, we investigate supramolecular mimics of these systems by mixing one-dim

189 uilding blocks reversibly self-assemble into supramolecular model network hydrogels and facilitate th

190 Here, we show that the supramolecular modification of insulin and pramlintide w

191 Herein, we introduce a bifunctional supramolecular modulator, 1,2,4,5-tetrafluoro-3,6-diiodo

192 tides influences molecular-level packing and supramolecular morphology.

193 The most striking supramolecular motif among them, which emerged from the

194 a cell by encoding carbohydrate activity via supramolecular multivalency.

195 Supramolecular nanoassemblies of an AIEE-ICT-active pyra

196 on pico- to nanosecond time scales in single supramolecular nanofibers and bundles of nanofibers.

197 In particular, we find that single supramolecular nanofibers exhibit the highest diffusivit

198 A supramolecular nanogel is now used as an artificial neut

199 ssembly of peptide-based building units into supramolecular nanostructures creates an important class

200 e substrates, the effect of water on the DES supramolecular network and its physicochemical propertie

201 drogen bonds results in the expansion of the supramolecular network into undulating 2D sheets, which

202 poly(N-isopropylacrylamide) (PNIPAAM)-based supramolecular networks crosslinked by emissive hexagona

203 ructures and topologies of the crosslinks in supramolecular networks play a crucial role in their pro

204 n the isoelectric point of the protein-based supramolecular object.

205 bilized magnetic pertriflated pillar[5]arene supramolecular-organic framework (magOTfP5SOF-Ga(3+)) wa

206 s into the role of the beta3-subunit and the supramolecular organization of sodium channels, in an im

207 l proximity correlation map that defines the supramolecular packing of alpha-synuclein within the fib

208 , and pai-pai stacking, resulting in unusual supramolecular patterns.

209 trates a means for controlling the length of supramolecular peptide nanofibers to modulate their immu

210 artificial light-harvesting systems based on supramolecular peptide nanotubes in water.

211 rins, have been proposed as a model to study supramolecular photoresponsive systems in aqueous enviro

212 Supramolecular plant cellulose synthase complexes organi

213 that water increases the flexibility of the supramolecular polymer and decreases the polymer length.

214 ther demonstrate that covalently tethering a supramolecular polymer built from PBI subunits enables t

215 trolling self-assembly in a single-component supramolecular polymer by the rational monomer design an

216 The supramolecular polymer ensures the efficient intracellul

217 intermolecular interactions in the resultant supramolecular polymer structures.

218 tform to monitor the assembly and jamming of supramolecular polymer surfactants (SPSs) at the liquid/

219 This supramolecular polymer system is prepared by complexing

220 mbly/disassembly processes within artificial supramolecular polymer systems using six-membered hydrog

221 Herein, we describe a supramolecular polymer that can mediate efficient contro

222 However, it has not been exemplified with a supramolecular polymer that features multiple helical st

223 thering of a perylene bisimide (PBI)-derived supramolecular polymer with a molecular locker enables t

224 t of water on the molecular structure of the supramolecular polymer, light scattering and atomic forc

225 he reaction do not affect or destabilize the supramolecular polymer, whereas in ambient or wet condit

226 , a microfluidic-regulated tandem process of supramolecular polymerization and droplet encapsulation

227 e synthesis, characterization, and isodesmic supramolecular polymerization of [3.3]paracyclophane-5,8

228 Additionally, this spatially organized supramolecular polymerization of peptide nanotubes was a

229 r molecular machines, the spatial control of supramolecular polymerization with synthetic monomers ha

230 ing that water may play a ubiquitous role in supramolecular polymerizations in oils.

231 ications in hierarchical assemblies, such as supramolecular polymers and hydrogen bonded organic fram

232 These supramolecular polymers are formed through a spontaneous

233 This study offers new insight into supramolecular polymers composed of custom-designed anio

234 ramolecular chemistry in general and that of supramolecular polymers in particular.

235 The self-assembly of chiral supramolecular polymers is an intricate process that spa

236 ical studies of the self-assembly of helical supramolecular polymers of (S)-triarylamine tris-amides

237 Sequence-controlled supramolecular polymers offer new design paradigms for g

238 r a long time, the unique opportunities that supramolecular polymers offer to gain insight into solut

239 stitution in squaramide synthons resulted in supramolecular polymers with increased fiber flexibility

240 lexes is a characteristic process of natural supramolecular polymers, and such recognition processes

241 ors that drive monomer self-assembly to form supramolecular polymers, the effects of aromaticity gain

242 sical organic chemistry can be studied using supramolecular polymers.

243 be widely applicable to dynamic covalent and supramolecular polymers.

244 yield overall neutral, internally ion-paired supramolecular polymers.

245 ally impact the structure of hydrogen-bonded supramolecular polymers.

246 yll sodium copper salt into a melamine-based supramolecular precursor followed by controlled pyrolysi

247 report the self-assembly of giant pentagonal supramolecular prisms (molecular weight >50 kDa) with te

248 but necessary for not only developing future supramolecular probes for HCh(-) binding and detection,

249 and reaction cycles in vital non-equilibrium supramolecular processes.

250 In supramolecular reaction center models, the lifetime of t

251 into motif design for future anion-selective supramolecular receptors and highlight the importance of

252 s the feasibility of integrating a wealth of supramolecular receptors and sensors into higher-order m

253 emains challenging, as is the development of supramolecular receptors that have adequate sensitivity

254 thod offered simultaneous advantages of high supramolecular recognition and enrichment capability of

255 [4]resorcinarene cavitands commonly serve as supramolecular scaffolds for construction of coordinatio

256 these transport processes on a molecular and supramolecular scale is a long-standing goal.

257 nity with many breakthroughs in the field of supramolecular self-assembly.

258 structure-directing unit for H-bond-directed supramolecular self-assembly.

259 nds were used as receptors for the design of supramolecular sensors for creatinine and its lipophilic

260 ts with transmembrane receptors organised in supramolecular signalling arrays.

261 ithin a supramolecular assembly, providing a supramolecular solution to a synthetically challenging t

262 anganese ethylene-bisdithiocarbamate) with a supramolecular solvent liquid phase microextraction meth

263 Mn(2+) content of maneb was extracted in the supramolecular solvent phase as 1-(2-pyridylazo)-2-napht

264 meat and chicken products by vortex-assisted supramolecular solvent-based liquid phase microextractio

265 tic nanoparticles combined with 1-octanol as supramolecular solvents (SUPRASs) presenting new ferrofl

266 We report a supramolecular strategy for promoting the selective redu

267 Herein, we report supramolecular strategy-based linkage engineering to fab

268 This combination of supramolecular structure and function paves the way for

269 segments of protofilaments in directing the supramolecular structure and nanoscale morphology remain

270 NMR techniques were used to analyse both the supramolecular structure and the role of water and to ca

271 les that interact with GJ channels make up a supramolecular structure known as the GJ Nexus.

272 In particular, the relevance of the supramolecular structure of polyols has a fundamental im

273 ts revealed the presence of water within the supramolecular structure of XoCH, but CiCH is a "DES-in-

274 e emitters into 2D rectangular columnar-like supramolecular structure stabilized by intermolecular H-

275 f the individual molecules but also by their supramolecular structures and intermolecular interaction

276 ttachments to surfaces, their insertion into supramolecular structures and photomodulating materials,

277 While many different size and shape supramolecular structures are now readily accessible, on

278 The discovery of PBIs with supramolecular structures beyond layers and columns may

279 e ability to control reaction selectivity in supramolecular structures beyond traditional host-guest

280 x H-bonded networks most probably leading to supramolecular structures or non-specific intermolecular

281 ces has been limited by the fragility of the supramolecular structures used and the delicate nature o

282 t and they regulate the access of molecules, supramolecular structures, particulate matter, and patho

283 Comparison of thermal steps in solution and supramolecular surface inclusions revealed that switchin

284 Herein, we design and synthesize a supramolecular switch based on a host-guest complex cont

285 ss this formidable challenge, we developed a supramolecular-synthon-driven approach to fabricate Borr

286 anic polymers paves the avenue to expand the supramolecular-synthon-driven approach to other building

287 The catalyst is a supramolecular system consisting of nanometer-sized inor

288 An octapodal corannulene-based supramolecular system has been prepared by introducing e

289 However, the design of supramolecular systems able to respond to multiple stimu

290 Advances in anion transport by synthetic supramolecular systems are discussed in this article.

291 Supramolecular systems are intrinsically dynamic and sen

292 the analysis of various chiral molecular and supramolecular systems in solution.

293 The synthesis of metallo-supramolecular systems with well-defined shapes and size

294 a new direction for the design of functional supramolecular systems.

295 understanding of solvents in multicomponent supramolecular systems.

296 interactions in the design of robust aqueous supramolecular systems.

297 t encapsulation and interactions in numerous supramolecular systems.

298 investigated the ambient water confined in a supramolecular tetrahedral assembly, and determined that

299 The supramolecular tubisomes pave an alternative way for fab

300 A supramolecular two-dimensional kagome weave(15) and a si