ライフサイエンスコーパス: thermodynamics

1 nd outer-sphere anions on their phase-change thermodynamics.

2 with the claim that it violates the laws of thermodynamics.

3 ropy appears to comply with the third law of thermodynamics.

4 l for an accurate calculation of RNA folding thermodynamics.

5 m a kinetic electric paradigm, which ignores thermodynamics.

6 echanisms, as well as converged kinetics and thermodynamics.

7 thodology for global quantitation of folding thermodynamics.

8 photons without violating the second law of thermodynamics.

9 nation, as well as ternary complex formation thermodynamics.

10 tate energy and a benchmark set by classical thermodynamics.

11 al hydrogen acceptor to overcome unfavorable thermodynamics.

12 e most important parameters that control the thermodynamics.

13 nstituents, thereby marking the breakdown of thermodynamics.

14 itrification is not explained by kinetics or thermodynamics.

15 taneously flows from hot to cold in standard thermodynamics.

16 relationship exists between information and thermodynamics.

17 lizing cosolutes to modulate protein folding thermodynamics.

18 sembly; (4) speculative links to equilibrium thermodynamics.

19 cted to deviate substantially from classical thermodynamics.

20 ure directly affected the BSA/lutein binding thermodynamics.

21 tbed to explore its molecular structures and thermodynamics.

22 ransport modeling which is based on chemical thermodynamics.

23 tationally costly, step in understanding its thermodynamics.

24 e highest sensitivity allowed by the laws of thermodynamics.

25 ental thermodynamic values using statistical thermodynamics.

26 empirical trends in solution spin-crossover thermodynamics.

27 , permit the rigorous measurement of folding thermodynamics.

28 w for efficient calculations of kinetics and thermodynamics.

29 would bring fundamental insights to quantum thermodynamics(5) and practical implications to thermal

30 is whether the laws of quantum mechanics and thermodynamics allow the existence of a coherence distil

31 oth one- and two-step pathways are driven by thermodynamics alone.

32 tion, but in this paper, we demonstrate that thermodynamics also serves a crucial role.

33 Data from activation and equilibrium thermodynamics analyses as well as pH dependence of the

34 directly measures the overall PCET reaction thermodynamics and avoids the need for a pK(a) scale in

35 horoughly reviewed, with special emphasis on thermodynamics and catalyst design considerations.

36 n two and three dimensions, constrained only thermodynamics and crystal symmetries.

37 surprisal analysis (an approach derived from thermodynamics and information theory).

38 t the subtle interplay of quantum mechanics, thermodynamics and information theory.

39 directionality and reversibility in terms of thermodynamics and kinetics and conclude that neither bi

40 that DGMs can faithfully describe molecular thermodynamics and kinetics and predict previously unobs

41 neral CPA may have been dictated by the same thermodynamics and kinetics as we observe today.

42 ollowed by discussion of how they affect the thermodynamics and kinetics involved in a synthesis of m

43 les and enables independent control over the thermodynamics and kinetics of aptamer switches.

44 The thermodynamics and kinetics of binding between human ser

45 he sequence selectivity and characterize the thermodynamics and kinetics of binding in a single assay

46 the role of the ligand corona in shaping the thermodynamics and kinetics of BNSL assembly.

47 nt FcalphaRI glycoforms and investigated the thermodynamics and kinetics of complex formation.

48 shell ultrastructures that is bounded by the thermodynamics and kinetics of crystal growth.

49 formation processes in natural environments, thermodynamics and kinetics of divalent mercury Hg(II) c

50 target engagement is a function of both the thermodynamics and kinetics of drug-target interactions,

51 Thermodynamics and kinetics of H2O splitting are largely

52 Thermodynamics and kinetics of hydrogen release in the s

53 hts into how residual structure may modulate thermodynamics and kinetics of IDP interactions.

54 The thermodynamics and kinetics of interfacial coupling are

55 ons and show that crystal packing alters the thermodynamics and kinetics of local conformational exch

56 es and associated proteins are linked to the thermodynamics and kinetics of membrane protein (MP) fol

57 m of this mutual regulation, we measured the thermodynamics and kinetics of PLC-beta3 binding to Galp

58 with radical cation formation as well as the thermodynamics and kinetics of radical cation cyclizatio

59 ver, requires a more subtle control over the thermodynamics and kinetics of reactions.

60 ed to their function, in part, by tuning the thermodynamics and kinetics of steps in this cycle.

61 henols such as RES and RESAn1 influenced the thermodynamics and kinetics of the complex formation wit

62 the structural underpinnings of the observed thermodynamics and kinetics of the conformational change

63 These findings reveal both the thermodynamics and kinetics of the ion binding sites and

64 e selectivity filter are all governed by the thermodynamics and kinetics of the ion-protein interacti

65 giving controlled gel times dictated by the thermodynamics and kinetics of the system.

66 ion box size only minimally affects both the thermodynamics and kinetics of the type of biomolecular

67 nsfer across the rim of nanospheres, and the thermodynamics and kinetics of this process are describe

68 ccurately modeled by taking into account the thermodynamics and kinetics of tile attachment and detac

69 Starting from fundamental thermodynamics and kinetics phenomenological equations,

70 standing of the influence of solvents on the thermodynamics and kinetics remains largely elusive in i

71 catalysts, explanations of their stability (thermodynamics and kinetics) are discussed, challenges f

72 tate explosive reactions are built upon both thermodynamics and kinetics, and then successfully used

73 metry (ITC) can provide quantitative binding thermodynamics and kinetics.

74 islocations are subject to the second law of thermodynamics and second, that the controlling inverse

75 We first give an overview of the relevant thermodynamics and semiconductor physics.

76 Inspired by thermodynamics and statistical mechanics in physical sys

77 We studied the thermodynamics and structures of the precursor tRNA and

78 The OHPAH adduct thermodynamics and the ALIE approaches were the most acc

79 st, at small to moderate surface areas, bulk thermodynamics and the energetics of the aqueous phase d

80 The second law of thermodynamics and the exponential sensitivity of chaos

81 st quantifiable relationship between the MOF thermodynamics and the linker structure, suggesting a ro

82 The results are discussed in terms of thermodynamics and theoretical calculations of the expec

83 s a pivotal role in determining the reaction thermodynamics and thereby catalytic mechanism and activ

84 discussion on the fundamental assumptions in thermodynamics and to engage in research activities earl

85 nal chemistry, which was used to compute the thermodynamics and, in selected cases, kinetics of an AT

86 bents and their use as separating agents via thermodynamics and/or kinetics and molecular sieving.

87 to MamM CTD in terms of their binding sites, thermodynamics, and binding-dependent conformations, bot

88 To shed light on the molecular determinants, thermodynamics, and kinetics of Na+ translocation throug

89 determine sorption capacity, reversibility, thermodynamics, and kinetics.

90 of this remarkable cation on the structure, thermodynamics, and proton transport properties of the C

91 estigated the adsorption kinetics, affinity, thermodynamics, and selectivity, as well as the effect o

92 plexes with replicable geometry, predictable thermodynamics, and tunable length.

93 ravel this complexity by applying a rigorous thermodynamics approach and performing binding measureme

94 An ab initio thermodynamics approach modelled how material morphology

95 al metamaterials, designed by transformation thermodynamics are artificial structures that can active

96 utational tools for evaluating water-centric thermodynamics are reviewed.

97 To this date, its solid-state thermodynamics are still poorly understood: a pentahydra

98 le MOFs demands control over the macroscopic thermodynamics as determined by microscopic chemical int

99 ples of the application of the Second Law of Thermodynamics as expressed in geometric entropy terms.

100 At the same time, the gating thermodynamics, as characterized by the gating charge an

101 We find the incorporation of the thermodynamics associated with protonation state changes

102 z regime, we have enabled the exploration of thermodynamics at the quantum scale and allowed interfac

103 e active sites and a decrease in kinetic and thermodynamics barriers along the reaction pathway(s).

104 In this paper, a thermodynamics-based approach is proposed for greatly en

105 ments and analyzed these using a statistical thermodynamics-based equation and electrophysiological e

106 this hypothesis, we developed a statistical-thermodynamics-based informatics framework, which allows

107 is perspective aims to provide an intuitive, thermodynamics-based interpretation of energy efficiency

108 While in line with previous thermodynamics-based models of a general RNA folding mec

109 In addition to describing the redox thermodynamics behind HET, we suggest that the correspon

110 to a paucity of experimental studies of the thermodynamics behind such interactions.

111 ity between Nitrospinae and AOA, rather than thermodynamics, biomass yield and cell size, determine t

112 the scaffold proteins will promote not only thermodynamics but also kinetics of cell signaling given

113 consistent with the results of our ab initio thermodynamics calculations.

114 gh-throughput method for measuring DNA motif thermodynamics called TEEM (Toehold Exchange Energy Meas

115 t the observed unusual spin correlations and thermodynamics can be accurately described by a transver

116 Next, we demonstrate how preorganization thermodynamics can be largely dominated by enthalpy rath

117 nt by embedding in mesoporous scaffolds, the thermodynamics can be modified to reduce the exothermici

118 It is shown here that the thermodynamics can be optimized by replacement of H in t

119 e that a deeper knowledge of RTK interactome thermodynamics can lead to a better understanding of fun

120 of phase-separation effects into activation thermodynamics can lead to a CCN number concentration th

121 ation of formalisms derived from equilibrium thermodynamics can provide insight into the basis of non

122 results indicate that kinetics, and not just thermodynamics, can significantly alter the efficiency o

123 rithms have been updated as our model of RNA thermodynamics changed and expanded.

124 how structure, conformational dynamics, and thermodynamics combine to modulate ligand-binding specif

125 e surprising that the laws of nonequilibrium thermodynamics, combined with Maxwell's equations, sugge

126 ss can be understood in terms of equilibrium thermodynamics considerations.

127 These correlations imply that thermodynamics controlled goethite and hematite reductio

128 rticle hydrodynamics (SPH) and computational thermodynamics (CT) has been developed.

129 Thermodynamics data show that a persistent RISC cofactor

130 Nonetheless, the fundamental thermodynamics dictating PCET reactivity at the MO(x)/so

131 Therefore, thermodynamics does appear to play an essential role in

132 The standard second law of thermodynamics does not hold in the presence of measurem

133 s work provides fundamental insight into the thermodynamics driving metal-ion adsorption reactions an

134 relative to the cis, dictating the cis/trans thermodynamics, driving the equilibrium product exclusiv

135 Reaction kinetics, thermodynamics, electrochemistry, EPR spectroscopy, and

136 as been argued that there is one more law of thermodynamics: entropy of microstructure decays in isol

137 es can be determined by stoichiometry and/or thermodynamics, especially in the presence of a base.

138 Can the Second Law of Thermodynamics explain why ecosystems naturally organize

139 Stochastic thermodynamics extends classical thermodynamics to small

140 digm is not restricted to eutectic alloys or thermodynamics, extends the utility of topological attri

141 environments it has been shown that classic thermodynamics favour the production of CO2 from CH4, wh

142 An experimental study of the configurational thermodynamics for a series of near-eutectic Pt(80-x) Cu

143 edox potentials that define the ground-state thermodynamics for C-H bond activation in cytochrome P45

144 ne pairs currently is limited by unfavorable thermodynamics for hydrogen release.

145 sis to quantify the kinetics and equilibrium thermodynamics for the binding of a fluorine-labeled Src

146 demonstrate the importance of nonequilibrium thermodynamics for understanding biological dynamics and

147 Then we review the statistical thermodynamics fundamentals of the model, considering va

148 fully reversible and strictly adheres to the thermodynamics governing the reactions.

149 The role of coherence in quantum thermodynamics has been extensively studied in the recen

150 Evaluation of cellular thermodynamics has recently received a high interest bec

151 the linker as the key factor determining the thermodynamics in a flexible MOF.

152 at the external electric field can alter the thermodynamics inhibiting the trans-to-cis reverse react

153 Here, we develop a thermodynamics-inspired method, "disassembly asymmetry s

154 The challenge is to unravel the binding thermodynamics into separate contributions and to interp

155 Statistical thermodynamics is a powerful, general tool for computing

156 The gate structure and thermodynamics is a result of the self-assembly of the s

157 Since relativistic thermodynamics is a topic that can be treated as part of

158 vior based on electrochemical nonequilibrium thermodynamics is presented, in which the metal-insulato

159 A fundamental problem in thermodynamics is the recovery of macroscopic equilibrat

160 nge in fundamental physics and especially in thermodynamics is to understand emergent order in far-fr

161 Markov state models (MSMs) to report on the thermodynamics, kinetics, and accessible states of BTK's

162 ghlight the impact of the environment on the thermodynamics, kinetics, and fundamental mechanisms of

163 the first case where experimentally derived thermodynamics lead to a ferric heme hydroperoxide OO-H

164 In apparent contradiction to the laws of thermodynamics, Maxwell's demon is able to cyclically ex

165 e colloids is a signature of the first-order thermodynamics nature of this phase transition.

166 for crystal growth are based on macroscopic thermodynamics, neglecting the atomistic nature of the l

167 yet been quantified, in terms of kinetics or thermodynamics, nor has the underlying molecular mechani

168 The reduction thermodynamics obtained with this method are in good agr

169 This value is compared to the thermodynamics of a hydrogen bond determined by similar

170 We carry out a detailed investigation of the thermodynamics of a series of isochoric, diffusionless s

171 Modeling the thermodynamics of a transition metal (TM) ion assembly b

172 important theoretical questions, such as the thermodynamics of active systems(13), and practical ones

173 y has the potential to directly quantify the thermodynamics of allosteric interactions, but usually f

174 the basis for understanding the kinetics and thermodynamics of amyloid nucleation and elongation of a

175 or, and (3) the determination of the folding thermodynamics of an electrode-attached, redox-reporter-

176 semble simulation approach, we determine the thermodynamics of around 2000 sequence variants represen

177 Here, we investigate in detail the thermodynamics of assembly of diphenylalanine (FF).

178 O(2) was reported to affect the kinetics and thermodynamics of biochemical conversions because CO(2)

179 ith respect to metabolite concentrations and thermodynamics of biochemical reactions.

180 oorly understood facet of the nonequilibrium thermodynamics of biomolecules.

181 detailed here indicate that the ground-state thermodynamics of C-H bond activation in P450 are best d

182 probe is an effective tool for exploring the thermodynamics of cancer cell migration and invasion.

183 e a starting point for rationally tuning the thermodynamics of catalytic intermediates broadly and fo

184 ytic effects on the kinetics and improve the thermodynamics of chemical reactions.

185 lytic effects upon both the kinetics and the thermodynamics of chemical reactions; however, the vast

186 l, no significant effects on the kinetics or thermodynamics of conformational transitions were observ

187 Here, we experimentally investigate the thermodynamics of continuous, time-delayed feedback cont

188 ze the observations based on the statistical thermodynamics of critical phenomena.

189 due in part to the fundamental difficulty in thermodynamics of designing a self-sustaining circuit th

190 ases that PEG had significant effects on the thermodynamics of detergent micellization.

191 steric properties influence the kinetics and thermodynamics of dioxygen binding versus release from s

192 ained model of DNA to study the kinetics and thermodynamics of DNA duplex and hairpin formation in cr

193 Understanding the thermodynamics of DNA motifs is important for prediction

194 tration spectra are used to characterize the thermodynamics of dUMP binding, with a focus on quantifi

195 on potential that is provided by the binding thermodynamics of each metal oxidation state.

196 ts significant influence on the kinetics and thermodynamics of electron transfer, and frequently defi

197 We find that the thermodynamics of FF assembly displays the typical chara

198 This is achieved by evaluating the thermodynamics of hybridization for full-length oligonuc

199 metry can be used to rationally modulate the thermodynamics of individual molecular binding interacti

200 tensively studied, little is known about the thermodynamics of its cofactors under catalytically rele

201 indicates that different factors control the thermodynamics of Lewis adduct formation for iodonium io

202 elopments in the nonequilibrium dynamics and thermodynamics of living systems, giving a few examples

203 uantitative insights into the size-dependent thermodynamics of metastable oxide nucleation and growth

204 lts provide a basis for understanding global thermodynamics of multi-GeV plasma accelerators, which u

205 ve the way for a deeper understanding of the thermodynamics of multicomponent intracellular phase beh

206 on State Theory to quantify the kinetics and thermodynamics of network rearrangements, enabling a mec

207 elucidate the electronic structure and redox thermodynamics of Ni-only and mixed NiFe oxyhydroxide th

208 However, the kinetics and thermodynamics of nucleic acid interactions in a crowded

209 Understanding the thermodynamics of paramagnetic transition metal hydride

210 t can be invoked to explain the kinetics and thermodynamics of photoinduced oxidation reactions at aq

211 ications in our current understanding of the thermodynamics of polyamorphic transitions in glasses an

212 The thermodynamics of protein folding in bulk solution have

213 l entropy can be an important element of the thermodynamics of protein functions such as the binding

214 water within a binding pocket can alter the thermodynamics of protein-ligand association.

215 rface of a protein is thought to mediate the thermodynamics of protein-ligand interactions.

216 a key but underexploited contributor to the thermodynamics of protein-ligand recognition, with impli

217 binding energy, binding kinetics and binding thermodynamics of protein-protein interactions is crucia

218 ned alpha3FnY DeltaE degrees 's to model the thermodynamics of radical-transfer reactions in FnY-RNRs

219 regarding the electron transfer kinetics and thermodynamics of redox-active species encapsulated into

220 Herein, the thermodynamics of RISC cofactors and targeting magnesium

221 ch range from the fundamental aspects of the thermodynamics of self-assembly through to the developme

222 raising in turn fundamental questions in the thermodynamics of separation.

223 Here, we determined the kinetics and thermodynamics of single-stranded break ligation by LIG3

224 irs, and gain insight into the mechanism and thermodynamics of target discrimination.

225 ture from 5 to 45 degrees C to determine the thermodynamics of the base pair opening for MN4.

226 Here, we describe the thermodynamics of the formation of binary and ternary co

227 Cu exchange appears to be driven by both the thermodynamics of the interactions between the proteins

228 owledge in understanding the non-equilibrium thermodynamics of the liquid-vapor interface to benefit

229 responsible for the anomalous transport and thermodynamics of the material.

230 serve the effects of Fermi statistics on the thermodynamics of the molecular gas.

231 s analyzed as a function of the kinetics and thermodynamics of the preceding and subsequent chemical

232 We report the free-energy landscape and thermodynamics of the protein-protein association respon

233 ons provide insight into the selectivity and thermodynamics of the reaction.

234 The bonding in 25 and the mechanism and thermodynamics of the reactions have been studied using

235 of any metal ligand alters the kinetics and thermodynamics of the reorganization.

236 amatic rate retardations, as well as (2) the thermodynamics of the self-sorting process, i.e., the di

237 mesoscale particle arrangement to alter the thermodynamics of the supramolecular bonding behavior.

238 ssed offering insights into the kinetics and thermodynamics of the switching process.

239 s scenario arises from a direct study of the thermodynamics of the system in the quantum regime, wher

240 re expected to play an important role in the thermodynamics of the system.

241 Both kinetics and thermodynamics of the transacylation process are governe

242 Here, we captured the thermodynamics of the triple helix unwinding by monitori

243 yered structure of the starting crystal, the thermodynamics of the two differently colored forms, and

244 sition of condensates is finely tuned by the thermodynamics of the underlying biomolecular interactio

245 nzenes can influence the isomerism-dependent thermodynamics of their dynamic covalent bonds with smal

246 cture are used in conjunction to dictate the thermodynamics of their multivalent interactions, result

247 The stoichiometry, kinetics, and thermodynamics of these bacteria are evaluated, and oppo

248 be either PCET or HAT and is governed by the thermodynamics of these intermediates involved.

249 ations in order to rigorously understand the thermodynamics of this process.

250 Structural effects on the thermodynamics of this reaction are assessed.

251 sent a detailed analysis of the kinetics and thermodynamics of this reaction, also known as the "rege

252 approaches, accurate studies describing the thermodynamics of TM ion binding are rare.

253 of TM ion-ligand coordination as well as the thermodynamics of TM ion binding to a protein active sit

254 of the individual TM ions and reproduces the thermodynamics of TM ion-ligand coordination as well as

255 and kinetics; however, determination of the thermodynamics of toxin-MOF interactions in aqueous medi

256 that determine the high-pressure macroscopic thermodynamics of two flexible pillared-layer MOFs.

257 part of an undergraduate course of classical thermodynamics or modern physics, the review and our own

258 Thermodynamics permits evaluating phosphorylation enviro

259 explained by first-order reaction kinetics, thermodynamics prevail on Au(111), underpinned by a clos

260 =Cl and I showed that in the case of iodide, thermodynamics prevents the production of benzene and fa

261 owed water has minor effects on the reaction thermodynamics, primarily attributable to intrinsic diff

262 Here, using heat transfer and thermodynamics principles, we show how Bui et al's concl

263 on the structures of DESs, the kinetics and thermodynamics properties, the interactions between the

264 The binding thermodynamics provide insight into bond enthalpies at t

265 dels, while only calibrated based on binding thermodynamics, recapitulate the observed kinetic accele

266 studies linking oxide reduction kinetics to thermodynamics remain scarce.

267 s influence on hydration-shell structure and thermodynamics remains an open question.

268 genstates is a resource independent of other thermodynamics resources, such as work.

269 Thermodynamics reveals that the low temperature of the s

270 tion is mainly due to the different compound thermodynamics stability.

271 actions play a major role in determining the thermodynamics, structure, and dynamics of condensed-pha

272 able interactions with PCSK9 as evidenced by thermodynamics, structure-activity relationship (SAR), N

273 factors (survival of the first) rather than thermodynamics (survival of the fittest).

274 a counterintuitive interplay of kinetics and thermodynamics termed the inverted region in Marcus theo

275 Passivity is a fundamental concept in thermodynamics that demands a quantum system's energy ca

276 paradox which goes against the second law of thermodynamics that states how entropy must increase.

277 y, we present some of the areas in clathrate thermodynamics that we foresee as the new frontiers in t

278 ription, reminiscent of Onsager's trajectory thermodynamics, that is based on the principle of micros

279 In terms of thermodynamics, the aqueous phase is considered as a com

280 Within the framework of linear irreversible thermodynamics, the maximum-power efficiency is obtained

281 he most accepted version of the third law of thermodynamics, the unattainability principle, states th

282 The construction of a relativistic thermodynamics theory is still controversial after more

283 to have a major contribution to the binding thermodynamics, this release remains to be confirmed thr

284 te, we reduced the problem of dissecting the thermodynamics to a comparison of the two protein-ligand

285 that we have derived by assuming the laws of Thermodynamics to be covariant.

286 spectroscopy, site-directed mutagenesis, and thermodynamics to elucidate the mechanisms of eIF2B acti

287 tial efforts have been expended in extending thermodynamics to single quantum systems.

288 Stochastic thermodynamics extends classical thermodynamics to small systems in contact with one or m

289 mational entropy could greatly influence the thermodynamics underlying membrane-protein functions, in

290 Far-from-equilibrium thermodynamics underpins the emergence of life, but how

291 Using stochastic thermodynamics, we compute the total energy cost of an a

292 the theoretical framework of nonequilibrium thermodynamics, we present a widely applicable mechanism

293 In the framework of quantum thermodynamics, we propose a method to quantitatively de

294 luid dynamical considerations and nucleation thermodynamics, we provide mechanistic understanding of

295 cross-feeding, stochastic colonization, and thermodynamics, we show that complex microbial communiti

296 es a computational model that can predict NN thermodynamics where experimental data is scarce or abse

297 extricably associated with the Second Law of Thermodynamics, which declares that entropy growth proce

298 to analysis of the interaction kinetics and thermodynamics with immobilized lectins.

299 nlightening illustration of the interplay of thermodynamics with quantum information.

300 review of the main theories of relativistic thermodynamics, with an special emphasis on the physical