ライフサイエンスコーパス: thermolysis

1 intramolecular loss of dinitrogen upon mild thermolysis.

2 t afford carbon-fluorine bond formation upon thermolysis.

3 tride materials that are formed via triazine thermolysis.

4 basis of spectroscopic characterization and thermolysis.

5 that 1-butene and n-butane are formed during thermolysis.

6 ely, for the aza-Wittig reaction followed by thermolysis.

7 oxhlet washing, linker hydrolysis and linker thermolysis.

8 ot close to the Si-F groups that form during thermolysis.

9 amolecular aggregates and microwave-assisted thermolysis.

10 tigated after processing, in comparison with thermolysis.

11 itions of matrix photolysis and flash vacuum thermolysis.

12 ]octan-8-ylidene (3) by either photolysis or thermolysis.

13 hanisms of the oxidations and the subsequent thermolysis.

14 to packing in the crystalline phase prior to thermolysis.

15 undergo high yielding Ar-CF(3) coupling upon thermolysis.

16 The quinolone intermediates were prepared by thermolysis (220-240 degrees C) of anilinomethylene deri

17 Thermolysis (33-65 C) of 1 in benzene-d(6) leads to anth

18 Thermolysis (60 degrees C, 16 h) of 1 in py gave ((t)Bu3

19 dation of 29 to the sulfoxide and subsequent thermolysis afforded the hexenulose 30.

20 From the solventless thermolysis and AACVD methods, either particulate or thi

21 ture and inexpensive techniques (solventless thermolysis and aerosol-assisted chemical vapor depositi

22 went intermolecular C-H bond activation upon thermolysis and exhibited hydroalkoxylation-like reactiv

23 t a portable sensor system that combines the thermolysis and paper-based NAATs to detect target RNA m

24 Thermolysis and photolysis experiments suggest that the

25 iazolyl cation (1) has been attempted by the thermolysis and photolysis of 1-(1,2,4-triazol-4-yl)-2,4

26 Furthermore, the products obtained from thermolysis and the kinetics of the thermolysis are inve

27 enes using MRR spectroscopy with an improved thermolysis apparatus that eliminates deuterium scrambli

28 t precursor pretreatments in the solventless thermolysis approach, respectively.

29 ned from thermolysis and the kinetics of the thermolysis are investigated.

30 Mechanistic studies of thermolysis at 122 degrees C reveal a dramatic reactivit

31 a6,eta5-bis(indenyl)zirconium THF compounds, thermolysis at 85 degrees C also resulted in C-O bond cl

32 based methods, many that involve solid-state thermolysis at or above 500 degrees C.

33 lso afford allenyl ketones upon flash vacuum thermolysis, but in addition, 3-ethynylcoumarins 6 are f

34 free amino acids were similar after HPH and thermolysis, but the former gave a more interesting vola

35 Following the thermolysis by NMR spectroscopy indicated that only a mi

36 Under microwave/thermolysis, carboxylic acids can couple with isonitrile

37 Under thermolysis conditions, 5-aryl-4-(alpha-diazoacyl)-1H-im

38 DPC, because it is not observed at all under thermolysis conditions, where only S1 and T0 are populat

39 omerization is reversible under flash vacuum thermolysis conditions.

40 in the production of silica nanoparticles by thermolysis, due to their structural similarities with s

41 ray of tertiary-quaternary-tertiary centers, thermolysis equilibrates a quaternary center, and the en

42 Thermolysis experiments have also been conducted on a mo

43 nerally match those observed in flash vacuum thermolysis experiments.

44 in the "reverse sense" addition, which upon thermolysis forms the metal aryl complex (L)(2)Sc(C(6)F(

45 Flash vacuum thermolysis (FVT) of 1-methyl-5-phenyltetrazole (5b), 2-

46 Flash vacuum thermolysis (FVT) of 3-methylidenefuran-2(3H)-ones 3 cau

47 In contrast, flash vacuum thermolysis (FVT) of diazoamides 1a-d, in which reaction

48 Flash vacuum thermolysis (FVT) of phenyl azide 29 as well as precurso

49 2, the nitrene was generated by flash vacuum thermolysis (FVT) of phenylazide and subsequently isolat

50 enone (1) has been generated by flash vacuum thermolysis (FVT) with Ar-matrix isolation of methyl sal

51 nzannulated enyne-carbodiimides 25, which on thermolysis gave the isoquinolino[2',1':1,2]pyrimido[4,5

52 icularly stable trialkylhydroxylamine, whose thermolysis half-life is 2.1 h at 150 degrees C.

53 Upon thermolysis, HC(SiHMe(2))(3) is formed.

54 Kinetic investigations of (i)Pr2NPA thermolysis in 1,3-cyclohexadiene and/or benzene-d6 are

55 cesium-rich suboxidometalates Cs(9)MO(4) by thermolysis in a dynamic vacuum at temperatures below 15

56 facile 1,5-hydrogen transposition upon mild thermolysis in benzene or toluene solution (80-110 degre

57 F(5))(3)]][B(C(6)F(5))(4)] (29) also undergo thermolysis in benzene to produce their respective pheny

58 )(mu-H)2W(NSi(t)Bu3)py2 (5-py2, 5%), whereas thermolysis in DME produced ((t)Bu3SiN)2WCl(OMe) (7, 30%

59 can be mixed at the molecular scale prior to thermolysis in order to produce the high entropy oxysulf

60 converted into 4-boryl-2(5H)-furanones upon thermolysis in the presence of an N-heterocyclic carbene

61 Complexes 2a,b eliminate RSiH(3) upon thermolysis in the presence of DMAP to generate {[BP(2)

62 nker synthesis, framework incorporation, and thermolysis is demonstrated using the mesoporous, terphe

63 at the rate-determining step of nitrosoamide thermolysis is made, and a mechanistic framework is prop

64 Thermolysis is shown to affect C-N bond scission while r

65 Temperature-gradient thermolysis is the key to controllably degrading PE and

66 Thermolysis is used to convert matter to H(2) and CO gas

67 t likely by a concerted mechanism, while the thermolysis is well explained by the formation of radica

68 observed forming ureate ligands, which upon thermolysis isomerize to bridging carbodiimides.

69 The thermolysis kinetics of this vicinal trisazoalkane were

70 In contrast, photolysis and thermolysis lead to the formation of unexpected products

71 2-(azidomethyl)-3-(indol-2-yl)acrylate upon thermolysis led to the expected delta-carboline.

72 trast, the c,c-C(70)O(3) isomer, which has a thermolysis lifetime of 650 min at 296 K, decays thermal

73 favors dopant incorporation by using the co-thermolysis method.

74 ectrochemical, hydrothermal, and solventless thermolysis methods in order to compare their common opt

75 grees C) or into oxazoles under noncatalytic thermolysis (o-dichlorobenzene, 170 degrees C).

76 These microcrystals have been obtained by thermolysis of (AuCl4)(-) stabilized with tetraoctylammo

77 Thermolysis of (eta(5)-Me(5)C(5))(2)LaCH(TMS)(2) in cycl

78 could be synthesized (70% isolated yield) by thermolysis of (i)Pr(2)NPA in 1,3-cyclohexadiene.

79 In the absence of a hydrogen acceptor, thermolysis of (PNP)IrH2 in t-butyl methyl ether under a

80 HCP generated by thermolysis of 1 has been observed by molecular beam mas

81 Thermolysis of 1 in the presence of H2C=CH(t)Bu and PhC

82 Complex 5 was also accessed via thermolysis of 1, and kinetics studies of this thermolyt

83 thylpyridinium tetrafluoroborate (2) and the thermolysis of 1- and 4-diazonium-1,2,4-triazoles, using

84 Inspection of the methane byproducts from thermolysis of 13, 14, 15, 25, and 29 in benzene-d(6) sh

85 Thermolysis of 15 under refluxing p-xylene furnished the

86 Extended thermolysis of 17 and 18 results in an aryl coupling pro

87 Thermolysis of 1a in C(6)D(6) at 45-55 degrees C leads t

88 Thermolysis of 1b at ~100 degrees C leads to the expulsi

89 Thermolysis of 2 gave mostly 1,2,4-triazole, together wi

90 In this work, thermolysis of 2 in an attempt to favor a monomeric kety

91 m of the formation of carbon nitrides during thermolysis of 2,4,6-triazidopyrimidine.

92 Unexpectedly, the thermolysis of 2-(azidomethyl)-3-(indol-3-yl)acrylates l

93 Thermolysis of 3 in C6D6 at 95 degrees C over 48 h gener

94 Interestingly, thermolysis of 37f bearing a 2-(methoxymethyl)phenyl sub

95 Thermolysis of 3a-g in the presence of zinc bromide indu

96 Compound 7 was independently produced via thermolysis of 4-py and DME (-MeOEt, -py), and THF and e

97 Thermolysis of 6-Me ultimately gives (PCP)Ir(CH3)(kappa(

98 Thermolysis of 7 at 50 degrees C formed carbocycles 6 in

99 Thermolysis of [(H)(BPI)Pt(CH(3))][OTf] (BPI = 1,3-bis(2

100 In addition, thermolysis of [TCT](2)(2-) yields [TCBT]*-.

101 Thermolysis of a 2'-[(16)O]-O-benzoyl-[(17)O]-5'-O-(tert

102 hologies were synthesized by the solventless thermolysis of a copper alkylthiolate molecular precurso

103 formation of an acylketene generated by the thermolysis of a m-dioxolenone.

104 Thermolysis of a pair of dibenzo-7-phosphanorbornadiene

105 following bromide abstraction and subsequent thermolysis of a Pt(IV) complex bearing both Csp(3)- and

106 and composition are synthesized by efficient thermolysis of a single source precursor of mixed metal-

107 Here we show the thermolysis of a single-source precursor (1,3-(BBr2)2C6H

108 eters wide were synthesized by a solventless thermolysis of a single-source precursor in the presence

109 ride species generated through photolysis or thermolysis of a site-isolated cobalt azide within the e

110 colloidal nanocrystals have been prepared by thermolysis of a stoichiometric Co(2+)Fe(2)(3+)-oleate c

111 20:4omega6) or peroxyl radicals generated by thermolysis of ABIP in the presence of oxygen.

112 lenes are obtained from the high temperature thermolysis of alkanes.

113 Diradical intermediates, formed by thermolysis of alkynylcyclobutenones, can display radica

114 onditions (solution versus solid-state), the thermolysis of azide precursors yielded bridging phosphi

115 Reinvestigation of the thermolysis of azido-meta-hemipinate (I) yielded, in add

116 mounts of 1-phenyl-1-buten-3-ynes from flash thermolysis of azulene has an activation energy of 360 k

117 Thermolysis of benzannulated enyne-isocyanates 13 and en

118 The thermolysis of bicyclo[3.2.0]hept-6-ene via a conrotator

119 Thermolysis of borapyramidane 2 in the presence of SMe(2

120 The lowest-energy pathway for thermolysis of both structures proceeds through the (E,Z

121 sive CQDs can be prepared by straightforward thermolysis of citric acid in a simple one-pot, multigra

122 Thermolysis of compounds 2-4 in the solid-state results

123 It was shown that thermolysis of CPs follows first-order kinetics.

124 In contrast, thermolysis of dicobalthexacarbonyl-complexed enynes und

125 Thermolysis of each of the diazonium salts in the presen

126 The thermolysis of furan-2-carbonyl azide results in a Curti

127 Subsequent thermolysis of imidazoles 14 in diphenyl ether affords 2

128 Thermolysis of isonitriles with carboxylic acids provide

129 Chemically inert F2PhEtyCbl resisted thermolysis of its Co-C bond at 100 degrees C, was stabl

130 elimination of methane occurs upon solution thermolysis of kappa(3)-Tp(Me)2Pt(IV)(CH(3))(2)H (1, Tp(

131 Mild thermolysis of Lewis base stabilized phosphinoborane mon

132 yrolysis" (FFP) technique was applied to the thermolysis of Meldrum's acid derivatives, pyrrole-2,3-d

133 on polyethylene processing temperatures, the thermolysis of Meldrum's acid to ketene provides the des

134 nitrido complexes have been prepared via the thermolysis of metastable vanadium(III)-azido precursors

135 This is the result of the very fast thermolysis of MPAN at high temperatures that affects th

136 Furthermore, thermolysis of N-(4-chloro-5H-1,2,3-dithiazol-5-ylidene)

137 d core was formed stereoselectivity from the thermolysis of N-[(2-methyl-2-cyclopentenyl)methyl]-N-(4

138 Extended thermolysis of neutral [Ph(2)BP(2)]Pt(Ph)(THF) (16) resu

139 nto the porous polymer Activated Borane, the thermolysis of nido-B(10)H(14) (1) in benzene at 200 deg

140 absence of metals have been achieved by the thermolysis of nonconjugated 2-azetidinone-tethered bis(

141 old NP core (PS-AuCoNPs) were synthesized by thermolysis of octacarbonyldicobalt [Co(2)(CO)(8)] in th

142 Thermolysis of omega-iodoalkyl-beta-siloxyalkenenitriles

143 esis of non-PGM ORR electrocatalysts through thermolysis of one-pot synthesized ZIF is demonstrated.

144 es include organic solution-phase synthesis, thermolysis of organometallic precursors, sol-gel proces

145 In contrast to the thermolysis of p-benzoquinone, which does not decompose

146 thermodynamic activation parameters for the thermolysis of P2A2 in a solution containing different a

147 in approximately 50% yield by the short-time thermolysis of Pd10(CO)12{P(p-Tolyl)3}6 in THF solution

148 re exposed to hydroxyl radicals generated by thermolysis of persulfate under basic pH conditions and

149 Thermolysis of phosphorus-based vinyl azides under solve

150 ed nine exposure units of smoke generated by thermolysis of pine woodchips (80 g).

151 The thermolysis of polyfused cyclobutanes with a cis,syn,cis

152 Thermolysis of RPA benzene-d(6) solutions leads to anthr

153 ents and thermal gravimetric analysis of the thermolysis of Ru(2)(D(3,5-Cl(2))PhF)(4)N(3), and by Arr

154 s absorb light, get heated, and induce focal thermolysis of sebaceous glands.

155 olecular beam mass spectrometry study on the thermolysis of solid P2A2 reveals the direct detection o

156 The method is based on the thermolysis of spin coated ammonium tetrathiotungstate (

157 Thermolysis of spiro[2.4]hepta-1,4,6-triene (1a) at 50 d

158 The pyrazino derivative 1c was formed upon thermolysis of sulfoxide 14c obtained from 2c.

159 Mild flash vacuum thermolysis of tetrazolo[1,5-b]pyridazines 8T generates

160 Thermolysis of the arylpalladium cyanoalkyl complexes le

161 Thermolysis of the betaines gave rise to 2-dialkylaminob

162 Thermolysis of the cobalt-imido compound induced selecti

163 Thermolysis of the complex results in N-O bond homolysis

164 Thermolysis of the crude peroxoniobium compounds (72-96

165 Controlled thermolysis of the deposited alkoxide gives the metal a

166 Thermolysis of the enyne-carbodiimide 42 having a methox

167 edirect the reaction toward 32 by conducting thermolysis of the enyne-carbodiimide 7e in the presence

168 Thermolysis of the enyne-carbodiimides 7 having the cent

169 Thermolysis of the heterobimetallic phosphinidene comple

170 ehyde, which is easily generated as a gas by thermolysis of the inexpensive and abundant paraformalde

171 Thermolysis of the iron(IV) nitride complex [PhB(tBuIm)3

172 Thermolysis of the latter mixture afforded ((t)Bu3SiNH)(

173 While thermolysis of the macrobicyclic triene lactone 12 did n

174 Thermolysis of the methyl and hydride derivatives, ((tBu

175 Thermolysis of the methyl-borylamide (NacNac(NMe2))Sc(Me

176 Thermolysis of the Pd chelates results in beta-acetate e

177 Mass spectrometry and solid state thermolysis of the precursors generated common fragments

178 Thermolysis of the pyrazolo[3,4-e][1,2,4]dithiazines 7 g

179 ido[4',3':4,5]pyrrolo[2,3-b]quinolines 8 via thermolysis of the pyridannulated enyne-carbodiimides 14

180 Thermolysis of the Rh(III)-Me complex (DPEphos)RhMeI2 (1

181 Thermolysis of the ring-opened product ICF(2)CF(2)CFIOR(

182 Thermolysis of the silver complexes in the presence of C

183 Thermolysis of the terminal azido Ru(2)(D(3,5-Cl(2))PhF)

184 Thermolysis of the titanocene TEMPO complexes in the pre

185 ed to H/D scrambling that could occur during thermolysis of the tungsten-bound cyclohexene ligand pri

186 Thermolysis of the well-defined aluminum fluoroalkoxide

187 d 8-MeOAdo(*) radicals are generated by Co-C thermolysis of their respective precursors, AdoCbl and 8

188 Flash vacuum thermolysis of these adducts leads to various isotopic i

189 Thermolysis of these complexes in the presence of PPh(3)

190 Thermolysis of these furans resulted in an intramolecula

191 Thermolysis of this complex at 80 degrees C resulted in

192 Thermolysis of this complex promotes extrusion of azoben

193 Product studies upon thermolysis of this precursor give the same products as

194 Ammonia (NH(3)) is produced in situ from thermolysis of urea and hydrolysis of isocyanic acid (HN

195 Thermolysis of {[PhBP(CH(2))(Cy)(3)]Fe}(2)(mu-eta(1):eta

196 photolysis and two possible pathways for the thermolysis, one involving proton transfer from the OOH

197 ylamine derivatives in aromatic solvents via thermolysis or acid-catalyzed decomposition may not be c

198 (*-)) formed when persulfate is activated by thermolysis or base addition during in situ chemical oxi

199 The Boc group can be removed on thermolysis or left intact during subsequent transformat

200 (mu2 -CH2 )] (2) can be cleanly prepared via thermolysis or photolysis of [(Ar'O)2 Nb(CH3 )2 Cl] (1)

201 These ozonides lose O(2) through thermolysis or photolysis to form various isomers of C(7

202 find an initiator, which is usually done by thermolysis or photolysis.

203 oxy-7H-benzo[c]carbazole-6-carboxylate under thermolysis or Rh(2)(OAc)(4) catalysis.

204 es (N-ethoxycarbonyl)carbamoyl chloride upon thermolysis, or (N-ethoxycarbonyl)isocyanate upon treatm

205 en highlighted, covering radical initiation, thermolysis, photolysis, and, more recently, photoredox

206 ndiscriminate side reactions typical of bulk thermolysis processes.

207 Slow, protracted thermolysis produces a fractionation line of shallower s

208 The thermolysis product readily reverts to active catalysts

209 The thermolysis products obtained by refluxing a series of v

210 the 26-mer), but a significant abundance of thermolysis products were also observed.

211 s and strong vertical mixing the slower MPAN thermolysis rate aloft could increase the fraction of MP

212 THF inhibits the rate of the thermolysis reaction in all three cases.

213 the chemical conversion processes during the thermolysis reaction.

214 l ether from 2,2-dimethoxypropane during the thermolysis reaction.

215 s carbon nitride networks formed by triazine thermolysis reactions.

216 Miniaturization of a thermolysis reactor using commercially available compone

217 ement of the thiophene ylide, in contrast to thermolysis results.

218 r [2 + 2] photocyclization is present in the thermolysis step, however, the result of a formally "sym

219 The microwave-assisted thermolysis strategy is simple, rapid, and robust, there

220 nd indicate the utility of gas-phase NMR for thermolysis studies of a variety of materials that relea

221 Thermolysis studies show that with complete cluster diss

222 By tuning the thermolysis temperature, we can systematically vary the

223 In their denuded state produced by gentle thermolysis, the cluster carbonylates yield nanoparticle

224 CH(2) CH(2) SiPr(i) (2) CHMeCH(2) )}] (4) by thermolysis; thereby, providing an unprecedented example

225 CH(2) CH(2) SiPr(i) (2) CHMeCH(2) )}] (4) by thermolysis; thereby, providing an unprecedented example

226 Upon thermolysis, these compounds give YbSe(x)().

227 itive C-N and C-C reductive elimination upon thermolysis to form N-methylsulfonamides and ethane, res

228 Because thermolysis to form seven stable products proceeds stepw

229 er, by using multiphoton infrared photolysis/thermolysis to initiate decarbonylation, it was shown th

230 S5 nanosheets that are formed by solventless thermolysis, utilizing Cu alkanethiolates as single-sour

231 cile synthetic approach based on solventless thermolysis was employed for the simple and tunable synt

232 rathiomolybdate ((NH4)2MoS4), and subsequent thermolysis was used to produce large area MoS2 layers.

233 that the polymer decomposes to monomer upon thermolysis, which indicates that the polymerization-dep

234 f diatomic oxygen to IPU and is subjected to thermolysis whose rate depends on temperature, pH, the p

235 The a,b-C(70)O(3) isomer dissociates through thermolysis with a decay time of 14 min at 296 K to form