ライフサイエンスコーパス: trans-

1 enediamine, 1,2-pn; isobutylenediamine, ibn; trans-(+/-)-1,2-diaminocyclohexane, dach; 1,3-propylened

2 A healthy man was given an oral dose of all-trans [10,10',11,11'-(14)C]-beta-carotene (1.01 nmol; 10

3 Following photoaffinity labeling with all-trans-[11,12-(3)H]retinoic acid, the most abundant label

4 Automerization in tri-trans-[12]annulene (1) was investigated by DFT, MP2, and

5 anar, bond-equalized radical anion of 1,7-di-trans-[12]annulene (4a(*-)) is lowest in energy; several

6 l anion, [16]annulene radical anion, and tri-trans-[12]annulene radical anion indicate that electron

7 to a highly twisted structure for the 1,7-di-trans-[12]annulene radical anion.

8 the formation of the anion radical of 1,5-di-trans-[12]annulene, which loses hydrogen and undergoes r

9 A third isomer (3,9-di-trans-[12]annulyne) was generated via the complete dehyd

10 -(+)-MR200], cis-(-)-1a [cis-(-)-MR201], and trans-(+/-)-1a [trans-(+/-)-MR204], have been identified

11 wer-energy s-trans,s-trans (1tt) and s-cis,s-trans (1ct) product conformers at cryogenic temperatures

12 hese data clearly demonstrated that compound trans-(+)-1d, due to its sigma1 agonist activity and fav

13 An in vivo evaluation evidenced that trans-(+)-1d, in contrast to trans-(-)-1d, cis-(+)-1d, o

14 The most promising compound, trans-(+)-1d, showed remarkable selectivity over a panel

15 evidenced that trans-(+)-1d, in contrast to trans-(-)-1d, cis-(+)-1d, or cis-(-)-1d, which behave as

16 to 1-carboxy-2-aryl-cyclopropanes with high trans-(1R,2R) selectivity and catalytic activity.

17 DPE (100 nmol), but not by the kappa agonist trans-(1S,2S)-3,4-dichloro-N-mathyl-N-[2-(1-pyrrolidinyl

18 propanation biocatalysts complements that of trans-(1S,2S)-selective variants developed here and prev

19 The metabotropic agonist, trans-(1S,3R)-1-amino-1,3-cyclopentanedicarboxylic acid

20 (+)-2-Cyano-1-{[trans-(1S,3S)-3-(1H-imidazol-4-yl)cyclopentyl]methyl}-3-

21 cid, isolation of the lower-energy s-trans,s-trans (1tt) and s-cis,s-trans (1ct) product conformers a

22 opropane-1-carboxylic acid], and trans-DCCA [trans-(2,2-dichlorovinyl)-2,2-dimethylcyclopropane-1-car

23 .68%), d-allose (3.67%) and 5-Caranol, trans,trans-(+)- (2.14%) were identified from Halodule pinifol

24 MAPA are mostly close to statistical (gauche/trans = 2/1) in other protic solvents, e.g., alcohols.

25 ioavailability of cis (24.5% +/- 6%) and all-trans (23.2% +/- 8%) isomers did not differ, endogenous

26 We have located six minima: two doubly trans (26, 27), one triply trans (28), one singly trans

27 inima: two doubly trans (26, 27), one triply trans (28), one singly trans (29), one quintuply trans (

28 (26, 27), one triply trans (28), one singly trans (29), one quintuply trans (trannulene-type, 33), a

29 synthesis of a C-activated N-Fmoc-protected trans-(2S,3S)-3-aminotetrahydrofuran-2-carboxylic acid a

30 it 2, resulting in identification of racemic-trans-(3-((4-(aminomethyl)-6-(trifluoromethyl)pyridin-2-

31 (DAMGO), [D-Ala2,D-Leu5]-enkephalin (DADLE), trans-(+/-)-3,4-dichloro-N-methyl-N-(2-[1-pyrrolidinyl]c

32 y for cyano(6-methoxy-naphthalen-2-yl)methyl trans-[(3-phenyloxiran-2-yl)methyl] carbonate.

33 The conversion of all-trans-[3H]retinol to 11-cis-[3H]retinol was used as the

34 ectric field showed a significant release of trans-(4.01+/-0.48) and cis-(5.04+/-0.26mug/g) lycopene,

35 enriched not naturally occurring isomers of trans-(-)-(4R,5S)-4b or cis-(+)-(4R,5R)-4a were formed p

36 idiella resinae KCH50 afforded a mixtures of trans-(+)-(4S,5R)-4b with enantiomeric excess ee=99% and

37 Trans-(+)-(4S,5R)-isomer (ee=99%) of whisky lactone 4b w

38 egioselectively at the 15-position to give a trans-(5,15)-AB-bacteriochlorin building block.

39 y established by X-ray analysis of precursor trans-(+)-5a as camphorsulfonyl derivative 9.

40 esion exists as a mixture of cis-(5R,6S) and trans-(5R,6R) epimers; these modulate base excision repa

41 We examine the 7:3 cis-(5R,6S):trans-(5R,6R) mixture of epimers paired opposite adenine

42 hat over three-quarters of these eQTL act in trans (78%) and that 86% of these differentially regulat

43 3.1.0(2,7)]dodecane moiety having either the trans (8a-e) or cis (9a-e) relative configuration of the

44 w specificity: many aldehydes, including all-trans-, 9-cis-, 11-cis-, and 13-cis-retinals and even be

45 bulkier Phe enhances stereoselectivity (cis:trans ~99:1), whereas the Leu120Phe substitution in the

46 ,O = kappa2-O,O-acetylacetonate, -Ir- is the trans-(acac-O,O)2Ir(III) motif, R = CH3, C2H5, Ph, PhCH2

47 f libraries to provide a prediction of which trans -acting factors binding sites are disrupted/create

48 sters at cell-cell contacts through cis- and trans- (adhesive) interactions.

49 ffinity of r(K57D)K3 for the lysine analogue trans-(aminomethyl)cyclohexanecarboxylic acid (AMCHA) wa

50 B-DNA complex formation was similar with (+)-trans- and (+)-cis-BPDE-adducted substrates, suggesting

51 study, we have measured the effects of all -trans- and 11- cis-retinals and -retinols on the opsin's

52 that RDH12 utilizes the unbound forms of all-trans- and 11-cis-retinoids.

53 mitoyl coenzyme A-dependent synthesis of all-trans- and 11-cis-retinyl esters.

54 ocols for the high-yielding synthesis of 2,3-trans- and 2,3-cis-6-methoxy-3-substituted morpholine-2-

55 sis and the stereoselective synthesis of 2,5-trans- and 2,6-trans-piperazines.

56 A4 is not only required for the formation of trans- and 9'-cis-neoxanthin from trans-violaxanthin, bu

57 The vitamin A metabolites all-trans- and 9-cis-retinoic acid regulate gene expression

58 weak acid to give the 1,2-difurylethylenes, trans- and cis-1,2 di(2-(5-phenylfuryl))ethene (trans-1

59 uction" protocol was successfully applied to trans- and cis-2-methyl-N-(pyridin-2-yl)-6-undecylpiperi

60 the locus, demonstrating cell type-specific trans- and cis-acting roles of this lncRNA.

61 573 K, and the relative epoxidation rates of trans- and cis-alkenes showed that calixarene ligands di

62 ed cis- and trans-epoxides can be reduced to trans- and cis-alkenes, respectively, in >99:1 stereospe

63 owever, we have successfully docked both the trans- and cis-amide isomers of the benzoquinone ansamyc

64 oxidoreductase 1 (NQO1) in the metabolism of trans- and cis-amide isomers of the benzoquinone ansamyc

65 results of these studies indicate that both trans- and cis-amide isomers of the hydroquinone ansamyc

66 trans- and cis-beta-Carotenes were analyzed by reversed-

67 arietal difference in carotenoids as well as trans- and cis-beta-carotenes were noted in both the raw

68 ports the analysis of total carotenoids, and trans- and cis-beta-carotenes, in different varieties of

69 product distributions from the reactions of trans- and cis-beta-methylstyrene reveal that the reacti

70 d for alpha, beta, and gamma isomers of HCH, trans- and cis-chlordane, oxychlordane, or SigmaCHB.

71 pounds determined in both air and water were trans- and cis-chlordanes (TC, CC), trans- and cis-nonac

72 obviating the usual requirement for both the trans- and cis-cinnamylsilanes.

73 The PL2 protease possessed both trans- and cis-cleavage activities, which were distingui

74 eparation of the n -> pai* bands between the trans- and cis-conformations, which allows for the gener

75 difference between the responses of Notch to trans- and cis-Delta: whereas the response to trans-Delt

76 The synthesis of both trans- and cis-diastereomers of pyrrolidinine-thioxotetr

77 ilized aryldibromoborane yields a mixture of trans- and cis-diborenes in which the aryl groups are co

78 emonstrated here would be useful to evaluate trans- and cis-elements that affect rate of the translat

79 The trans- and cis-epoxides lead to opposite ( syn and anti)

80 The main phenolic acids in WF were trans- and cis-ferulic acids (257 and 165.57mg/100g dw,

81 type 1 (HIV-1) to CD4(+) T cells through the trans- and cis-infection pathways; however, little is kn

82 n elaborately designed process in which both trans- and cis-interactions are fine-tuned collectively

83 uces intercellular adhesion clusters through trans- and cis-intercadherin bonds, and the intracellula

84 band separation of n-pai* transitions of its trans- and cis-isomers.

85 a convenient reaction sequence for both the trans- and cis-isomers.

86 the aqueous ozonolysis reaction products as trans- and cis-lactols [4-(5-hydroxy-2,2-dimethyltetrahy

87 Two mutants that lack trans- and cis-neoxanthin, tomato (Solanum lycopersicum)

88 ter were trans- and cis-chlordanes (TC, CC), trans- and cis-nonachlors (TN, CN), heptachlor exo-epoxi

89 Although the influence of trans- and cis-regulatory mutations is well known, the g

90 One key question concerns the extent of trans- and cis-regulatory variation in how co-expressed

91 RH transcription factors, but vary widely in trans- and cis-requirements for these inputs and their b

92 ulfide cross-links provide clear readouts on trans- and cis-SNARE arrangements during this fusion eve

93 ficant differences in total UCA content, and trans- and cis-UCA contents between the two samples.

94 s study, the amino acid, biogenic amine, and trans- and cis-urocanic acid (UCA) contents of fifteen c

95 re and the stability of the edge surfaces of trans- and cis-vacant montmorillonites.

96 nactivation of GRASP55-KR first affected the trans- and not the cis-Golgi.

97 ter of seven OR genes has been proposed as a trans- and pan-enhancer for OR gene expression.

98 in the transition structures determines high trans- and syn-diastereoselectivities for aldol reaction

99 Computational studies suggest that the trans- and the gem-pathway have similar barriers, but po

100 The reaction is highly selective for trans- and trisubstituted alkenes and can be selective f

101 etone catalyst for asymmetric epoxidation of trans- and trisubstituted olefins was efficiently prepar

102 died catalysts, is an effective catalyst for trans- and trisubstituted olefins, and up to 97% ee has

103 e esters are highly photostable due to a cis-trans (and vice versa) photoisomerization, the cis-isome

104 nantioselectivity for hydroboration of cis-, trans-, and gem-disubstituted alkenes in excellent agree

105 eQTL) mapping by jointly utilizing cis-, cis-trans-, and trans-regulation.

106 in the highest quartile of trans-zeaxanthin, trans -anhydro-lutein, and trans-, cis-, and total beta-

107 [ a]pyrene-derived N (2)-dG adduct, 10 S(+)- trans- anti-[BP]- N (2)-dG ([BP]G*), reveal that an inco

108 he RPTPmu ectodomain that forms a homophilic trans (antiparallel) dimer with an extended and rigid ar

109 YP26A1, which catalyzes the oxidation of all-trans (at)-retinoic acid (RA), is induced moderately by

110 induced receptor dimerization and consequent trans- auto-phosphorylation are among the earliest event

111 n cell signaling revealed that expression of trans- but not cis-null JAM-A mutants decreased Rap2 act

112 cular docking simulations indicated that the trans- but not the cis-amide isomers of the benzoquinone

113 ts the disassembly of SNARE complexes in the trans-, but not in the cis-, configuration.

114 hat consist of flavan-3-ol units such as 2,3-trans-(+)-catechin and 2,3-cis-(-)-epicatechin.

115 C. polonica revealed that the levels of 2,3-trans-(+)-catechin and PAs that are produced in the tree

116 orescence anisotropy analysis, for which the trans (cis) isomer in DOPC (DPPC) presents a fast decay

117 e variety of substituted styrenes, including trans-, cis-, and beta,beta-disubstituted styrenes, to y

118 ction was further studied by the reaction of trans-, cis-, and gem-ethylene-d2 upon activation of Cr(

119 trans-zeaxanthin, trans -anhydro-lutein, and trans-, cis-, and total beta-carotene had significant 43

120 nd Ac-NDP-gamma-MSH-NH(2) replaced by Pro or trans-/cis-4-guanidinyl-Pro derivatives were designed an

121 2))][PF(6)](2), 2[PF(6)](2), a derivative of trans-[Cl(dppe)(2)Ru(C triple bond C)(6)Ru(dppe)(2)Cl] f

122 MCl2; cagelike adducts of the in,in isomer, trans- Cl2(P((CH2)14)3 P) (M = 2/Pt, 3/Pd, 4/Ni), then f

123 ariants were identified that were encoded in trans (compound heterozygosity).

124 cts of both long-range intra-chromosomal and trans (cross-chromosomal) regulation, we observe modular

125 ost stable in vacuo, while the cis-trans-cis-trans (ctct) or trans-cis-trans-cis (tctc) amide conform

126 somerized from the cis,cis (ccMA) to the cis,trans (ctMA) isomer.

127 ts have been achieved using compounds with a trans-[CuX(4)Y(2)] coordination sphere, which seems to a

128 on as well as the cis (vesicle membrane) and trans (cytoplasmic membrane) binding of its two C2 domai

129 ssay in yeast to measure cis (same site) vs. trans (different site) repair for the majority process o

130 al programs that can drive the division and (trans-)differentiation of non-beta cells to produce insu

131 species could be attributed to both cis- and trans- DNA sequence changes during evolution, but it is

132 ngle configurational isomer, assigned to the trans (E) configuration.

133 rotary motors that harness photoinduced cis-trans (E-Z) isomerization are promising tools for the co

134 atory evolution in both cis (e.g., Creb) and trans (e.g., fork head) for nearly 2000 genes, many of w

135 As we expected, both significant cis- and trans- effects are responsible for the expression diverg

136 expression markers, by integrating cis- and trans- effects from many genomic loci, may overcome limi

137 trans-(-)-epsilon-Viniferin (viniferin), a natural produ

138 A series of trans-(FcC(2n))Ru(2)(Y-DMBA)(4)(C(2m)Fc) with n, m = 1 a

139 , CH2Cl2, reflux) give the cage-like trienes trans- Fe(CO)3(P((CH2)mCH horizontal lineCH(CH2)m)3 P) (

140 , 60-80 degrees C) yield the title compounds trans- Fe(CO)3(P((CH2)n)3 P) (4a-c,e, 74-86%; n = 2m + 2

141 )2)4) afford the metal hydride complexes mer,trans-[ Fe(CO)3(H)(P((CH2)n)3 P)](+)BArf(-) (6a-c,e(+)BA

142 n alcohol, new iron dicarbonyl complexes mer-trans-[Fe(Br)(CO)2(P-CH horizontal lineN-P')][BF4] (wher

143 atmosphere to produce the complexes cis- and trans-[Fe(Br)2(CO)(P-CH horizontal lineN-P')]; (2) the r

144 active system generated from the precatalyst trans-[Fe(CO)(Br)(Ph(2)PCH(2)CH horizontal lineN-((S,S)-

145 he mechanism of transfer hydrogenation using trans-[Fe(NCMe)CO(PPh(2)C(6)H(4)CH horizontal lineNCHR-)

146 s, leading to the formation of catechin [2,3-trans-(+)-flavan-3-ol] and epicatechin [2,3-cis-(-)-flav

147 e with their role in the biosynthesis of 2,3-trans-(+)-flavan-3-ols, transcript abundance of Norway s

148 t enzyme involved in the biosynthesis of 2,3-trans-(+)-flavan-3-ols, were identified and functionally

149 -handed all-cis (Form I) and left-handed all-trans (Form II), were determined in the crystalline stat

150 Baseline separation of the cis- and trans- forms of both hydroxyproline and fluoroproline wa

151 Importantly, expression of gB and gH/gL in trans (gB-expressing cells mixed with other gH/gL-expres

152 nd targeting it for sequestration within the trans- Golgi network (TGN).

153 erence for the second most activating gauche,trans (gt) conformation to avoid the energy penalty that

154 Azobenzene undergoes trans-->cis isomerization when irradiated with light tun

155 ups ortho to the azo group, exhibits minimal trans-->cis photoisomerization and extremely rapid cis--

156 structure of the retinal chromophore and all-trans --> 13-cis isomerization.

157 xhibit a high photochemical conversion rate (trans --> cis > 98%) and no measurable fatigue over a la

158 Pro-238 trans --> cis isomerization is not a simple on/off switc

159 contractions up to 13 A in the backbone upon trans --> cis photoisomerization.

160 and 19-20 kcal/mol for the cis --> trans and trans --> cis processes, respectively.

161 all isomeric states of an azobenzene moiety (trans --> cis-(M) --> cis-(P)) are passed step by step.

162 2 elimination the chlorostannylidene complex trans-[H(dmpe)2Mn horizontal lineSn(Cl)(C6H3-2,6-Mes2)]

163 tatively into the stannylidyne complex salts trans-[H(dmpe)2Mn identical withSn(C6H3-2,6-Mes2)]A [A =

164 trans-[(H(2)NCH(2)CH(2)C triple bond N)(dppe)(2)Ru(C tri

165 rmation of endo (4a) and exo (4b) isomers of trans-[HFe(PNHP)(dmpm)(CH(3)CN)](BPh(4))(2).

166 The complex trans-[HFe(PNP)(dmpm)(CH(3)CN)]BPh(4), 3, (where PNP is

167 hen be easily engineered for applications in trans (i.e., in an intermolecular setup).

168 eplication, some of which can be provided in trans (i.e., via expression from a separate RNA molecule

169 mechanistic study of the reaction of O2 with trans-(IMes) 2Pd(H)(OBz), 1 (IMes = 1,3-dimesitylimidazo

170 3-dimesitylimidazol-2-ylidene), which yields trans-(IMes) 2Pd(OOH)(OBz), 2.

171 plicable for large-scale mapping of cis- and trans- interaction networks of genomic elements and for

172 To prove this concept, trans-/intramucosal and lymph-node delivery of PLGA-PEG

173 th both C-F and P-C bond activation to yield trans-[Ir(C6F5)(PEt3)2(PEt2F)], C2H4, and CH4.

174 onditions in CH3CN/TEOA, a common reactive C-trans-[Ir(tpy)(ppy)](0) species, irrespective of the sta

175 Only one isomer, C-trans-[Ir(tpy)(ppy)H](+), reacts with CO2 to generate th

176 Using a model species, trans-[IrMe(PH3)2(PH2Et)], a low-energy mechanism involv

177 d with the more electron-rich model reactant trans-[IrMe(PMe3)2(PMe2Et)] and the higher barriers foun

178 s were modeled using HCCR as weak acids, and trans-{kappaC,N-(3,4,5-(F)3-C6H2)CH2N horizontal lineCH(

179 Asymmetric reductions in the trans [KCl] produced noticeable asymmetric shifts in the

180 As cis or trans [KCl] was reduced by 25%, 50%, or 75% relative to

181 To examine this question, cis or trans [KCl] was systematically lowered and the equilibri

182 ged from 0.61 at 25% cis [KCl] to 1.4 at 25% trans [KCl], with a Hill coefficient of 1.0.

183 he Lewis acid stabilized hyponitrite dianion trans-[LA-O-N=N-O-LA](2-) [LA=B(C(6) F(5) )(3) ], which

184 of the secondary phosphine oxides (SPOs) PHR(trans-(+)-Lim-OH)(O), which could be separated by chroma

185 separation of the commercially available cis/trans-(+)-limonene oxide mixture by ring opening with pr

186 racterization of the heteroleptic complexes, trans-[M(IV) F(4) (CN)(2) ](2-) (M=Re, Os), obtained fro

187 2)(PhCN)(2)] afforded the Group 10 complexes trans-[MCl(2)(1)(2)] (3a-c, M = Ni, Pd, and Pt, respecti

188 crystal structures of a family of compounds trans-[MCl(2)(NC(5)H(4)X-3)(2)] (M = Pd(II), Pt(II); X =

189 DFT calculations on the model dimers {trans-[MCl(2)(NH(3))(NC(5)H(4)X-3)]}(2) show association

190 = N,N,N',N'-tetramethylethylenediamine) with trans-[MCl(2)(Pn-Bu(3))(2)] [M = Ni (trans-6a) and Pd (t

191 actors as mega transcription factor-bound in trans (MegaTrans) enhancers.

192 fies the collective effects of both cis- and trans- methylations on gene expression.

193 of its components, suggest that for G:C W:W Trans , Mg(2+) binding can fine tune the basepair geomet

194 -(-)-1a [cis-(-)-MR201], and trans-(+/-)-1a [trans-(+/-)-MR204], have been identified as new potent s

195 l effects on CHGA expression, and that a cis:trans (mRNA:miR) interaction regulates the association o

196 on the use of catalytic copper(I) iodide and trans- N, N'-dimethylcyclohexane-1,2-diamine and promote

197 -tetramethylethylenediamine (TMEDA), ( R,R)- trans- N,N,N',N'-tetramethylcyclohexanediamine [( R,R)-T

198 e activates the kinase domain of Stt7 on the trans (negative) side, leading to phosphorylation and re

199 ion of O2 into the palladium-hydride bond of trans-(NHC)2Pd(H)OAc (NHC = N-heterocyclic carbene).

200 n investigated for both mono- and bimetallic trans-(NHC)PtX2(amine) complexes.

201 heterocyclic carbene (NHC) complexes of type trans-{(NHC)PdCl(2)L} (L = C(5)H(5)N, 3-ClC(5)H(4)N, and

202 omplexes featuring a single fluoride ligand (trans-[Ni(F)(2-C5NF4)(PR3)2], R = Et 1a, Cy 1b, trans-[P

203 The synthesis of trans-[Ni(F){2-C5NF3(NH2)}(PEt3)2], which exhibits an ex

204 expression by acting in cis (locally) or in trans (non-locally).

205 or interaction with both cis (same cell) and trans (opposite cell) ligands.

206 -bp oligonucleotides containing a single (+)-trans- or (+)-cis-BPDE adduct.

207 ls and cell membrane were incubated with all-trans- or 11-cis-retinol to study retinyl ester synthesi

208 ng a saturated alpha-isoprene to unsaturated trans- or cis- alpha-isoprene units.

209 The stereoselective synthesis of either trans- or cis-3,5-disubstituted pyrazolidines is accompl

210 Treatment of either trans- or cis-4-N,N-dibenzylaminocyclohex-2-en-1-ol with

211 Treatment of either trans- or cis-4-N-benzylaminocyclohex-2-en-1-ol with Cl3

212 Trans- or cis-disubstituted alkenes can be used; alkyl-

213 the precursor alkene (i.e., monosubstituted, trans- or cis-disubstituted and cyclic alkenes).

214 c dihydroxylation is converted into either a trans- or cis-epoxide, and these are subsequently conver

215 onditions for maintenance of and invasion by trans- or cis-plus-trans-controlled hotspots are broader

216 Amino acid-dependent selectivity for either trans- or cis-substituted piperazinone products has been

217 at it represents an intermediate step in the trans- or dedifferentiation of neurons into astrocytes.

218 SR events occur between chromosome homologs (trans- or interallele CSR), suggesting that the homologo

219 chromosome kissing" between two DNA sites in trans (or in cis) is known to facilitate three-dimension

220 THFA shows a strong preference for the trans- over the cis-COOH configuration.

221 ization of the air-stable nickel(II) complex trans-(PCy(2)Ph)(2)Ni(o-tolyl)Cl is described in conjunc

222 ns-[Ni(F)(2-C5NF4)(PR3)2], R = Et 1a, Cy 1b, trans-[Pd(F)(4-C5NF4)(PCy3)2] 2, trans-[Pt(F){2-C5NF2H(C

223 on that kinetic factors inhibit formation of trans-[Pd(IMes)2(eta(1)-O2)2] at the low temperatures at

224 tion diagram is constructed for formation of trans-[Pd(IPr)2(eta(1)-O2)2] and leads to the conclusion

225 d(IPr)2(eta(2)-O2)] adds a second O2 to form trans-[Pd(IPr)2(eta(1)-O2)2].

226 with H2O in methanol/ether solution to form trans-[Pd(IPr)2(OH)(OOH)].

227 The crystal structure of trans-[Pd(IPr)2(OOH)(OH)] is reported.

228 o detect the predicted T-shaped intermediate trans-[Pd(NHC)2(eta(1)-O2)] for either NHC = IMes or IPr

229 ic potential distributions for the compounds trans-[PdCl(2)(NC(5)H(4)X-3)(2)] (X = F, Cl, Br, I) demo

230 nsmetalation from 2 to [NiCl(2)(PPh(3))(2)], trans-[PdCl(2)(PhCN)(2)], or trans-[PtCl(2)(PhCN)(2)] af

231 cinchona alkaloid derivatives; surprisingly, trans-(Ph(3)P)(2)PdCl(2) was found to afford the most dr

232 3)Rh(F)] reacts with CF(3)SiMe(3) to produce trans-[(Ph(3)P)(2)Rh(CF(2))(F)] (1; X-ray), which is equ

233 conditions (3 h at 80 degrees C) to produce trans-[(Ph(3)P)(2)Rh(Ph(2)PF)(Cl)] (2) and ArPh as a res

234 the thermodynamics of addition of methane to trans-(PH3)2IrX are generally strongly disfavored by inc

235 disfavors oxidative addition of N-H bonds to trans-(PH3)2IrX.

236 ons were performed on an extensive series of trans-(PH3)2IrXL complexes (L = NH3 and CO; X = various

237 Thus cis-(PMe(3))Cr(CO)(4)(H(2)) (3) and trans-(PMe(3))Cr(CO)(4)(H(2)) (4) were prepared and char

238 C(5)H(4)N)(2)-p-C(2)B(10)H(10) (1) and 1,12-(trans-(Pt(PEt(3))(2)I)CC)(2)-p-C(2)B(10)H(10) (2), are r

239 1a, Cy 1b, trans-[Pd(F)(4-C5NF4)(PCy3)2] 2, trans-[Pt(F){2-C5NF2H(CF3)}(PCy3)2] 3 and of group 4 dif

240 The octahedral Pt(IV) complex trans,trans,trans-[Pt(N(3))(2)(OH)(2)(py)(2)] (1) is potently cytoto

241 anticancer platinum(IV) complex trans,trans,trans-[Pt(N3 )2 (OH)2 (MA)(Py)] (MA=methylamine, Py=pyri

242 d, consequently, the cytotoxicity of cis,cis,trans-[Pt(NH3)2Cl2(O2CCH2CH2COOH)(OCONHR)], 4, where R i

243 ands (and carboxylate ligands in general) in trans-[Pt(OAc)(2)(L)(L')] results in significantly enhan

244 By use of XANES spectroscopy, trans-[Pt(OAc)2(ox)(en)] and trans-[PtCl2(OAc)2(en)] wer

245 )OH)(2)], trans-[PtCl(2)(s-PhobPBu)(2)], and trans-[PtCl(2)(a(7)-PhobPBu)(2)] are reported.

246 bPBu)(2)], (iii) (1)J(PtP) for the PEt(3) in trans-[PtCl(2)(PEt(3))(PhobPBu)].

247 2)(PPh(3))(2)], trans-[PdCl(2)(PhCN)(2)], or trans-[PtCl(2)(PhCN)(2)] afforded the Group 10 complexes

248 ]Cl(2), cis-[PtCl(2)(a(5)-PhobPCH(2)OH)(2)], trans-[PtCl(2)(s-PhobPBu)(2)], and trans-[PtCl(2)(a(7)-P

249 S spectroscopy, trans-[Pt(OAc)2(ox)(en)] and trans-[PtCl2(OAc)2(en)] were observed to be reduced at a

250 oduced instead, along with novel difluorides trans-[(Py)(2)Pd(F)(2)] (3) and trans-[(t-BuPy)(2)Pd(F)(

251 Complexes trans-[(Py)(2)Pd(Ph)(F)] (1; Py = pyridine) and trans-[(

252 Direct and selective mono-N-pyridylation of trans-(R,R)-cyclohexane-1,2-diamine is described here.

253 Our data support a mechanism in which trans- rather than cis-amide forms of benzoquinone ansam

254 An S = 3/2, high-anisotropy building unit, trans-[ReCl(4)(CN)(2)](2-), representing the first param

255 arked increase in the magnetic anisotropy of trans-[ReF(4) (CN)(2) ](2-) as compared to [ReF(6) ](2-)

256 urces of information, we identified putative trans- regulators for a variety of metabolic pathways.

257 ion, but the relative importance of cis- and trans- regulatory mechanisms in the early stages of adap

258 ated carbon powder with one of the complexes trans-[ReO(2)(py-X)(4)](+) (py-X = 4-substituted pyridin

259 ) (1)J(PSe) for PhobP(Se)Bu; (ii) nu(CO) for trans-[RhCl(CO)(PhobPBu)(2)], (iii) (1)J(PtP) for the PE

260 mers (PAOs) with the general structure trans,trans-[(RO)3Ph-C[triple bond]C-Pt(PMe3)2-C[triple bond]C

261 u((R,R)-Me-DuPHOS)(2)(eta(2)-C(2)H(4))], and trans-[Ru((R,R)-Me-DuPHOS)(2)(C(6)F(5))(H)].

262 fac-[Ru(II)Cl(2)(DMSO)(3)(CTZ)] (1), cis,cis,trans-[Ru(II)Cl(2)(DMSO)(2)(CTZ)(2)] (2), Na[Ru(III)Cl(4

263 I analogs of a general structure [4-R-pyH](+)trans-[Ru(III)Cl4(DMSO)(4-R-py)](-), where 4-R-py stands

264 odefluorination (HDF) of fluoroarenes by the trans-[Ru(IMe4 )4 H2 ] catalyst, 3, is reported.

265 ammatory activity of ruthenium(II) complexes trans-[Ru(NO(+))(NH3)4(L)](BF4)3 and [Ru(NH3)5(L)](BF4)3

266 ld (Phi(S)(-->)(O) = 0.25), isomerization of trans-[Ru(tpy)(pic)(dmso)](+) occurs with a time constan

267 For trans-[Ru(tpy)(pic)(dmso)](+), global analysis of the tr

268 xes [Ru(tpy)(bpy)(dmso)](OSO(2)CF(3))(2) and trans-[Ru(tpy)(pic)(dmso)](PF(6)) (tpy is 2,2':6',2' '-t

269 nation of acetophenone by the chiral complex trans-[RuCl2{(S)-binap}{(S,S)-dpen}] and KO-t-C4H9 in pr

270 CHPh)2NH2}] and the 18e(-) Ru alkoxo complex trans-[RuH{OCH(CH3)(R)}{(S)-binap}{(S,S)-dpen}] (R = CH3

271 of the Noyori ketone hydrogenation catalyst trans-[RuH2((R)-BINAP)((R,R)-dpen)] (1a) yields trans-M[

272 -[RuH2{(S)-binap}{(S,S)-N(K)H(CHPh)2NH2}] or trans-[RuH2{(S)-binap}{(S,S)-N(K)H(CHPh)2NH(K)}].

273 formation of the potassium amidato complexes trans-[RuH2{(S)-binap}{(S,S)-N(K)H(CHPh)2NH2}] or trans-

274 connections and neural circuits by acting in trans (spanning cellular junctions) and/or in cis (at th

275 Resveratrol (3,5,4'-trihydroxy-trans -stilbene) is a well-known polyphenolic compound o

276 e example is the 1:1 charge-transfer complex trans--stilbene-2,3,5,6-tetrafluoro-7,7,8,8-tetracyanoqu

277 on reaction and the ratio of trans,cis/trans,trans (t,c/t,t)-conjugated diene oxidation products form

278 difluorides trans-[(Py)(2)Pd(F)(2)] (3) and trans-[(t-BuPy)(2)Pd(F)(2)] (4).

279 ns-[(Py)(2)Pd(Ph)(F)] (1; Py = pyridine) and trans-[(t-BuPy)(2)Pd(Ph)(F)] (2; t-BuPy = 4-tert-butylpy

280 ticancer agents, especially NKP-1339 (sodium trans-[tetrachloridobis(1H-indazole)ruthenate(III)]), wh

281 Indazolium trans-[tetrachlorobis(1H-indazole)ruthenate(III)] (1, KP

282 te(III)] (1, KP1019) and its analogue sodium trans-[tetrachlorobis(1H-indazole)ruthenate(III)] (2, KP

283 especially the clinically studied indazolium trans-[tetrachlorobis(1H-indazole)ruthenate(III)] (KP101

284 enate(III)] (KP1019) and its analogue sodium trans-[tetrachlorobis(1H-indazole)ruthenate(III)] (NKP-1

285 The anticancer ruthenium complex trans-[tetrachlorobis(1H-indazole)ruthenate(III)], other

286 The organometallic compound trans-(tetrafluoropyrid-2-yl)bis(triethylphosphine)-fluo

287 Our results show that both the trans- TF features and the cis- motif features are predi

288 cis (the GlnRS N-terminal Yqey domain) or in trans (the Arc1p protein associating with GluRS).

289 mains of both the cis (GS(m)-bound ring) and trans (the opposite substrate-free ring) show counterclo

290 ly transformed to the corresponding cis- and trans- title compounds, respectively.

291 ate, the quantum yield of isomerization from trans- to cis-azobenzene is halved.

292 th the low thermal activation barrier of the trans- to cis-isomerization typical for imine derivative

293 -12)) and one variant regulating 53 genes in trans (top trans interaction: ZNF423, rs3851570, p = 8.2

294 s (28), one singly trans (29), one quintuply trans (trannulene-type, 33), and one all-cis (31).

295 This study revealed the preferential all-trans (TTT) conformation of the three ethylenedioxy link

296 ry that two aspects of lectin functionality (trans- versus cis-activity) respond non-uniformly to a s

297 Here, we examine how trans- versus cis-silenced genes in a somatic cell type

298 s N1 cyclization) and the stereoselectivity (trans- vs cis-fused ring system) of the cyclization proc

299 pecific Slc34a2-deficient mice, and analysed trans- vs. paracellular routes of phosphate absorption.

300 he form H(2)[pz(A(4-n);C(n))], n = 1, and 2 (trans-), where "A" represents peripheral heteroatom (S-