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1 ylpiperidine moiety at the 3-position of the triazene.
2 scribe the synthesis of a terminal 1-alkynyl triazene.
3 mple alkynyl triazenes and tethered 1-diynyl triazenes.
4 tch reversibly the colors exhibited by these triazenes.
5 2] cyclotrimerization reactions of 1-alkynyl triazenes.
6                                          New triazenes 10a--v and 12a--f were prepared by coupling th
7 inii DHFR was the naphthylmethyl-substituted triazene 10t (IC(50): 0.053 microM), but a more substant
8 onor 1-hydroxy-2-oxo-3,3-bis(3-aminoethyl)-1-triazene (300 microM) caused a decrease in each CYP apop
9 ation of 30 to 31 also produced the bicyclic triazene 32, the result of 1,3-dipolar cycloaddition of
10 etrakis(p-iodophenyl)methane afforded, after triazene activation, a dodecaiodo-terminated first gener
11 sis of interesting organic molecules such as triazenes and azo dyes.
12        The coordination chemistry of alkynyl triazenes and Cp*RuCl was studied and led to the structu
13 ation proceeds well with both simple alkynyl triazenes and tethered 1-diynyl triazenes.
14 zides to afford diverse classes of push-pull triazenes and triazene salts.
15 able species such as diazomethane, diazenes, triazenes, and methyl azides, which further undergo exot
16 , such as ester, ketone, nitrile, nitro, and triazene are well tolerated.
17                                    1-Alkynyl triazenes are versatile reagents in synthetic organic ch
18          We describe the preparation of five triazene-arylene oligomers (3, 4, 7, 8, and 11) and inve
19 vs axial conformational constraints, and the triazene-based CBIs are also conformationally constraine
20          Furthermore, the terminal 1-alkynyl triazene can be used for the synthesis of di- and triyne
21           Densely substituted fused aromatic triazenes can be prepared by [2 + 2 + 2] cyclotrimerizat
22 ein, we report that readily accessible azoxy-triazenes can serve as nitrogen atom sources under visib
23 aled bond alteration patterns in a series of triazenes characteristic of donor-acceptor compounds.
24                              The rapid arene triazene chemistry is chemoselective for secondary amine
25        This work also unveils new aspects of triazene chemistry, i.e., the unprecedented efficient ge
26 we highlight the efficient decoupling of the triazene-conjugate to afford unmodified starting compone
27                   Importantly, the resulting triazene cyclic peptide is highly stable at neutral pH a
28                 Due to the high stability of triazene cyclic peptides, the postcyclization modificati
29            Products of the thermally induced triazene decomposition reaction were identified as molec
30 oducts that result from heating the starting triazenes depend on both the type of alkyne ortho to the
31 n donor strength order of N-alkyl indole and triazene donor groups was also established.
32 uents (derived from the azides), the acyclic triazenes exhibited intense absorptions in the visible s
33                                              Triazenes featuring electron-rich phenyl azide component
34                                 The use of a triazene function to anchor phenylalanine to a polymeric
35 pend on both the type of alkyne ortho to the triazene functionality and the temperature used.
36                                          The triazene group precisely installed on the synthesized ar
37 ible to synthesize various ortho-fluorinated triazenes in good yields via simple CH-substitution.
38  and for the preparation of (hetero)aromatic triazenes in metal-catalyzed cyclization reactions.
39  mono- and ditopic 1,3-disubstituted acyclic triazenes in moderate to excellent yields (38-92%).
40 ecting H2S by the reduction of an azide to a triazene intermediate in aqueous media is reported.
41 way has been proposed, involving a lithiated triazene intermediate resulting from the nucleophilic ad
42 y available organic azides via pi-conjugated triazene intermediates.
43 fluoromethylation of functionalized aromatic triazenes is described.
44           Novel reactivity for pi-conjugated triazenes is herein reported.
45 on to give a cinnoline from (2-ethynylphenyl)triazenes is proposed to occur through a pericyclic path
46 agged products were detagged by cleaving the triazene linkage and generating a series of aryl diazoni
47                                          The triazene linkage is formed by coupling the diazonium sal
48 e solid support through its side chain via a triazene linkage, on-resin cyclization of the peptide ch
49                       Although the resulting triazene-linkage with Kme is stable, we highlight the ef
50 ags and substrates were anchored together by triazene linkages.
51 lse (~405 nm) by means of a photo-immolating triazene linker.
52 developed an atropselective variation of the triazene mediated diaryl ether forming reaction.
53 rivative bearing a terminal alkyne and three triazene moieties.
54 tides that generates an inbuilt chromophoric triazene moiety at the site of cyclization within a minu
55      The transformation possibilities of the triazene moiety make these reactions interesting for the
56 abilizing interaction between "AgRf" and the triazene moiety, which may be responsible for the good y
57  however, may reside in its nitrosohydrazone/triazene moiety.
58 lization in MeI is that the (2-alkynylphenyl)triazene must contain a suitably electron-withdrawing su
59 -2-oxo-3-(N-3-methyl-aminopropyl)-3-methyl-1-triazene (NOC-7) markedly protected both SL NOS and (Na+
60 oxy-2-oxo-3-[(methylamino)propyl]-3-methyl-1-triazene (NOC-7), PGHS-1 enzyme activity was inhibited i
61                                              Triazenes possessing bulky N-substituents (e.g., neo-pen
62 gn approach, has various heterocyclic cores (triazenes, pyrimidines, trithianes, cyclohexanes) that m
63 the explosive hexahydro-1,3,5-trinitro-1,3,5-triazene (RDX).
64              This observed and unprecedented triazene reactivity gave access to oxidation and substit
65 he idea that the photofragmentation of azoxy-triazenes results in the generation of a free singlet ni
66 d diverse classes of push-pull triazenes and triazene salts.
67 rapid, macrocyclization strategy featuring a triazene scaffold, amenable to late-stage diversificatio
68          Here, we report a novel rapid arene triazene strategy for the macrocyclization of peptides t
69 tion is distinctly more favored for aromatic triazenes than for other aromatic substrates.
70                Using an isotopically labeled triazene, the mechanism of the decomposition reaction wa
71                                              Triazene thermal stabilities were studied using thermogr
72 tituent on the phenyl ring to deactivate the triazene toward methylation-induced decomposition to an
73 tached to Merrifield's resin through a known triazene-type linkage.
74 pects of the cyclization of (2-ethynylphenyl)triazenes under both thermal and copper-mediated conditi
75  through the cyclization of (2-alkynylphenyl)triazenes under neutral conditions is presented.
76 ering only on the replacement of the central triazene unit with a furan moiety.
77 benes and the organic azides, the respective triazenes were found to exhibit lambda(max) values rangi
78                            Bromo substituted triazenes were less reactive as starting materials towar
79             A new class of 1,3-disubstituted-triazenes were synthesized by coupling functionalized be
80  1,2-dichloroethane solution of the starting triazene with CuCl overnight at 50 degrees C.
81 generation of an azo compound by mixing of a triazene with phenol.
82 lization allows the preparation of 1-alkynyl triazenes with a range of functional groups including es