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1 y between triaryl and dialkyl aryl phosphate triesters.
2 lexed diester and resembles the reactions of triesters.
3 s while slowing the rates of diesters and of triesters.
4 stability (tricarboxylate salt 1-CO(2)()Na > triester 1-CO(2)()Et > diester 2-CO(2)()Et > monoester 3
5                              The AZT prodrug triesters, 1 and 2, underwent much more rapid hydrolysis
6 cines (+)-22 and (-)-23 and the cyclopropane triester (-)-26.
7 nderwent much more rapid hydrolysis than the triester 3, most probably due to the formation of an acy
8                         Methylenation of the triester 3a and subsequent triple RCM reaction was follo
9 ing with an excess of olefin alcohol 1a gave triester 3a in excellent yield.
10  6:2 fluorotelomer phosphate mono-, di-, and triesters (6:2 mono-, di-, and triPAPs) and 6:2 FT dipyr
11                             The synthesis of triester 7 involved reaction of alpha-(chloroacetyl)sali
12                   However, potential prodrug triester 70 did induce enhancements in 2-deoxyglucose up
13 products (~40%) followed by diesters (~33%), triesters (~9%) and trace amounts of tetra- and pentaest
14                                Pyromellitate triesters afforded the ortho diester anhydrides upon dis
15                            The nature of the triester alkyl group dictates the success of solid-phase
16 te specificity for synthetic organophosphate triesters and phosphorofluoridates, which are common con
17 ein, we examine the propensities of PQQ, PQQ triester, and its various isomers, and certain PQQ tries
18 for the nonenzymatic hydrolysis of phosphate triesters, and is the inverse of that observed for the n
19                              Organophosphate triesters are high production volume additive flame reta
20 class of phospholipids, alkyl phosphocholine triesters, are described.
21 ate degradation (opd) island, hydrolyzes the triester bond found in a variety of organophosphate inse
22 s and found that a pentafluorophenol benzene triester (BTE) enabled effective desymmetrization and cr
23 er linkages are stable, and large numbers of triesters can be incorporated.
24 imized for the hydrolysis of organophosphate triesters can be made to catalyze the hydrolysis of orga
25 bonucleotide ('lariat') 25 by solution phase triester chemistry involving both H-phosphonate and conv
26 ingly high nucleophilic activity toward both triester DEDNPP and diester EDNPP.
27 er, and its various isomers, and certain PQQ triester derivatives, to catalyze glycine-fueled redox c
28 HA shows extraordinary reactivity toward the triester diethyl 2,4-dinitrophenyl phosphate (DEDNPP) an
29 thyl p-nitrophenyl phosphorothioate, and the triesters, diethyl p-nitrophenyl phosphate and diethyl p
30 n of pNPPT, the diester ethyl pNPPT, and the triester dimethyl pNPPT was probed using heavy atom kine
31 cerophospholipids via opening of a phosphate triester epoxide with carboxylic acids catalyzed by Jaco
32 drolysis of the phosphorothioate diester and triester exhibits somewhat less advanced bond fission th
33 nker-derived amino group on the 3'-phosphate triester, followed by elimination of the desired product
34  beta-glycosyl phosphate and dithiophosphate triesters from glycals via 1,2-anhydrosugars.
35 ith a series of enantiomeric organophosphate triesters have shown that the wild type PTE generally pr
36  have rapidly evolved to hydrolyze phosphate triesters in response to this challenge, converging onto
37                     The vulnerable phosphite triester intermediate is bypassed entirely, making the m
38 alkaline phosphatase (AP) is associative, or triester-like, because phosphorothioate monoesters are h
39 functional groups were incorporated into the triester linkages, including 2-butyl, 2-hexyl, 3-octyl,
40 n rate strongly supporting the less accepted triester mechanism.
41                                            A triester method for the synthesis of deoxynucleoside pho
42 sters, symmetrical 6,6'-diesters, and 2,6,6'-triesters of fatty acids were calculated from the values
43  the corresponding dimethyl long-chain alkyl triesters of PFA.
44 zation in the presence of sorbitan mono- and triesters or canola oil was investigated.
45                The occurrence and fate of 14 triester organophosphate flame retardants (OPFRs) and pl
46 ction of O,O-diethyl 4-nitrophenyl phosphate triester (Paraxon, 1) with piperidine in ionic liquids (
47  five triaryl and two dialkyl aryl phosphate triesters, previously studied experimentally, is examine
48  of free nucleotides by the masked phosphate triester prodrugs.
49                        Importantly, [3H]BZDC-triester-PtdIns(3,4,5)P3, the lipid with the same phosph
50 tion, consisting of perchlorotriphenylmethyl triester radical dissolved in hexafluorobenzene, for in
51  analogous phosphate monoester, diester, and triester reactions.
52 ing prevents accommodation of the additional triester substituent.
53  directly to the general base resulting in a triester (substrate as base) AN + DN mechanism with a mo
54 ajor effect on the corresponding reaction of triesters: though protonation of one nitrogen of DPP(-)
55 itions that maintain the delicate l-mannitol triester-triol array.
56                                    Phosphate triesters, used as pesticides, have only recently been i
57 nosubstituted glucose residues in the 2,6,6'-triesters was altered considerably to favor the gt rotam
58 philicity of the methyl-substituted cycloSal triesters was performed based on the retention times obt
59 eight phthalates and several organophosphate triesters were excreted predominantly in feces.
60                       Refluxing orthoformate triesters were found to effect quantitative esterificati
61                                   The alkyne triesters were functionalized with carbohydrates, amino
62                   Thus, different lipophilic triesters were prepared and characterized in oily soluti
63                                The requisite triesters were prepared by selective saponification or b
64         Concentrations and patterns of 16 OP triesters were presently screened for and/or determined
65  the rate of hydrolysis of neutral phosphate triesters, where a methyl group has replaced a proton.
66 ansition states, in contrast to reactions of triesters, which have tight, associative transition stat
67                              Reaction of the triesters with phosphorous pentachloride, followed by co
68 lective removal of one methyl group from the triesters with sodium iodide yielded monosodium salts, w
69 ucleotides rely on the reaction of phosphite triesters with sulfurizing reagents such as tetraethylth