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1 , thus requiring a second source that may be tropospheric.
2 ng that processes controlling the background tropospheric abundance of nitrogen oxides are likely res
4 ganic compounds comprise a major fraction of tropospheric aerosol and understanding their chemical co
7 is shorter than that associated with either tropospheric aerosol loadings or previous characterizati
8 ory mass calibrations, IEPOX added > 0.4% to tropospheric aerosol mass in the remote tropics and up t
9 matter constitutes a significant fraction of tropospheric aerosol mass, and can influence CCN activit
10 decrease of the global optical thickness of tropospheric aerosols by as much as 0.03 during the peri
11 e identified organosulfate compounds in free tropospheric aerosols by single particle mass spectromet
12 into polyfunctional species widely found in tropospheric aerosols with light-absorbing brown carbon.
13 e atmosphere as Mount Bachelor received free tropospheric air masses on certain nights during the sam
14 The range suggests that dehydration of upper tropospheric air occurs both by convective dehydration a
15 4 that shows GOM* and RM* levels in dry free tropospheric air of 198 +/- 57 and 229 +/- 58 pg m(-3) w
16 recent deep convective outflow and aged free tropospheric air, suggesting a widespread abundance in t
17 ted upon the ERA-40 reanalysis, report polar tropospheric amplification of surface warming and attemp
19 orine isotope fractionation observed between tropospheric and bacterial degradation of CH(3)Cl provid
20 We test the hypothesis that this has reduced tropospheric and ground-level air pollution concentratio
21 (2-)) are among the most abundant species in tropospheric and stratospheric aerosols due to high leve
26 and range [Formula: see text], computed for tropospheric and stratospheric temperatures over 1979 to
27 observed circulation changes and associated tropospheric and surface warming over northeastern Canad
30 sustains autoignition and are implicated in tropospheric autoxidation that can form low-volatility,
32 try and climate models, since it impacts the tropospheric burden of sulfate aerosol, a major climate-
33 1, temperatures observed globally by the mid-tropospheric channel of the satellite-borne Microwave So
34 tile organic compound emissions, and impacts tropospheric chemistry by influencing oxidants and aeros
38 also suggest that a significant fraction of tropospheric chlorine atoms may arise directly from anth
40 ean Western Boundary Currents (OWBCs) on the tropospheric circulation has recently been studied in de
41 Such a linkage is interpreted to be due to tropospheric circulation patterns in which positive PNA
42 t near-surface trends in Southern Hemisphere tropospheric circulation towards the end of the twentiet
43 ills and then swept over the SWTP by the mid-tropospheric circulation, rather than by upslope flow ov
45 g Spectrometer reveal the presence of a vast tropospheric cloud on Titan at latitudes 51 degrees to 6
48 vial features and occasional rainstorms; and tropospheric clouds mainly (so far) in southern middle l
50 t in the formation and optical properties of tropospheric clouds over the ocean, a positive relations
51 been paid to low, high and vertically thick tropospheric clouds such as stratus, cirrus and deep con
52 y affect the "anomalous" oxygen signature in tropospheric CO(2) that should reflect the gross carbon
54 eoclimate applications of (17)O anomalies in tropospheric CO2, O2, mineral sulfates, and fossil bones
56 ompound emitted to the atmosphere and shapes tropospheric composition and biogeochemistry through its
58 coefficient remains poorly determined under tropospheric conditions because of difficulties in makin
66 om BL to free atmosphere and increases lower tropospheric diabatic heating by shallow and congestus c
69 e quasi-annular hemispheric structure in the tropospheric eddy-driven jetstreams and NAM variability.
70 sition of tropospheric water vapour from the Tropospheric Emission Spectrometer (TES) aboard the Aura
71 loy recent space-based observations from the Tropospheric Emission Spectrometer with the GEOS-Chem at
73 can be linked to a long-term trend in upper tropospheric equatorial westerly wind and subtropical je
74 cers of atmospheric deposition, we show that tropospheric fluxes of Hg and Pb are higher by a factor
80 acterized by large increases in mid-latitude tropospheric humidity and enhanced cycling of carbon thr
81 tionship between CAPE and a measure of lower-tropospheric humidity in simulations and in observations
82 heric mixing ratios, we demonstrate that the tropospheric hydroxyl contribution from this source can
83 tosphere-to-troposphere O(3) flux, increased tropospheric hydroxyl radical concentration, and finally
85 ht into isoprene ozonolysis, which has broad tropospheric implications due to its critical role as a
87 for a distinction between stratospheric and tropospheric influences at remote East Antarctic sites.
88 analyses suggest that advection processes or tropospheric influences were unlikely to explain the str
90 ical circulation and a poleward shift of the tropospheric jet streams and their associated subtropica
91 atitudes, generating a poleward shift of the tropospheric jet, thereby relocating the main division b
93 e influence of convective entrainment on the tropospheric lapse rate, and we demonstrate the importan
95 oughout the remote troposphere (up to 70% of tropospheric mass) over the first two ATom missions (Aug
97 Its feasibility was demonstrated by making tropospheric measurements in flights aboard the Departme
100 gued that in the tropics, the upper bound on tropospheric mixing and clouds is constrained by the rap
101 le in constraining the vertical structure of tropospheric mixing, tropopause temperature, and cloud-t
103 ight a distinct radiative signature of upper tropospheric moistening over the period 1982 to 2004.
105 resent new measurements from the space-based TROPOspheric Monitoring Instrument (TROPOMI) launched in
106 part of wet season, using SIF data from the Tropospheric Monitoring Instrument (TROPOMI), which has
111 sources over the contiguous United States on tropospheric NO(x) and O(3) levels by using a global 3D
112 tion of ground-level NO2 concentrations from tropospheric NO2 columns retrieved from the Ozone Monito
113 C concentrations and satellite-retrieved CO, tropospheric NO2, and aerosol optical depth (AOD) (R(2)
114 stimate both the magnitude of tropical upper tropospheric NPF and the subsequent growth of new partic
115 ogen oxide (NO(x)) emissions, which increase tropospheric O(3) (warming) but also increase aerosols a
116 ment (OMI) sensor enabled detection of lower tropospheric O(3) and its legitimacy has been validated.
117 ness of such satellite analyses on the lower tropospheric O(3) and its perturbations due to the precu
119 ls typically predict(4-7) an increase in the tropospheric O(3) burden of between 25 and 50 per cent s
120 the exposure response of soybean to elevated tropospheric O(3) by measuring the agronomic, biochemica
122 ow its 1590-1958 AD mean, which implies that tropospheric O(3) increased by less than 40 per cent dur
123 cance for the OMI sensor to detect the lower tropospheric O(3) responses to the future emission reduc
124 also estimate that the radiative forcing of tropospheric O(3) since 1850 AD is probably less than +0
127 ion, a small (approximately 20%) increase in tropospheric [O(3)] did not significantly alter photosyn
131 ate response of oxidants, resulting in lower tropospheric O3 in cold climates while HOx (= OH + HO2 +
134 hane (CH4 ), an important greenhouse gas and tropospheric O3 precursor that has not yet been targeted
135 ught that temperature-dependent emissions of tropospheric O3 precursors and water vapour abundance de
140 raphy (ATom) mission demonstrate that remote tropospheric OH is tightly coupled to the production and
141 ts the earth from harmful ultraviolet light, tropospheric or ground-level ozone is toxic and can dama
142 de emissions could increase the formation of tropospheric oxidants and secondary atmospheric aerosols
143 tures, with implications for the response of tropospheric oxidants and stratospheric thermal and mass
148 RO2) radicals are important intermediates in tropospheric oxidation of hydrocarbons, and their accura
149 Carbonyl oxide species play a key role in tropospheric oxidation of organic molecules and in low-t
150 intermediates," have long been implicated in tropospheric oxidation, there have been few direct measu
151 t atmospheric oxidant, capable of perturbing tropospheric oxidative cycles normally controlled by the
152 ors in calculations of global ozone budgets, tropospheric oxidizing capacity and methane oxidation ra
153 ving simple CIs can significantly impact the tropospheric oxidizing capacity, enhance particulate for
154 read and recurrent, and has implications for tropospheric oxidizing capacity, stratospheric compositi
156 e growing global background concentration of tropospheric ozone (O(3)), an air pollutant associated w
157 l pollutants such as carbon dioxide (CO(2)), tropospheric ozone (O(3)), and particulate matter (PM) c
159 e global mean temperatures leading to higher tropospheric ozone (O3) concentrations in already pollut
160 ring atmospheric chemistry and causing sharp tropospheric ozone (O3) depletion in polar regions and s
165 al cycling of nitrogen oxides (NOx) produces tropospheric ozone (O3), and NOx is traditionally consid
166 ibute to fine particulate matter (PM2.5) and tropospheric ozone air pollution, affecting human health
171 led that the short-term associations between tropospheric ozone and daily mortality rate were stronge
173 stion sources of oxides of nitrogen altering tropospheric ozone and methane concentrations and enhanc
176 compounds (BVOCs) plays an important role in tropospheric ozone and secondary organic aerosol product
178 e ozone refers to observed concentrations of tropospheric ozone at sites that have a negligible influ
179 s to peroxy acetyl nitrate (PAN), affect the tropospheric ozone budget, and in the remote marine envi
186 cted to approximately double the global mean tropospheric ozone concentration, and further increases
187 udy has found a significant increase in free tropospheric ozone concentrations above the western USA
190 sted that the interannual variability of the tropospheric ozone distribution over the central-eastern
192 g marine aerosol formation and modification, tropospheric ozone formation and destruction, photooxida
193 y, atmospheric heating from black carbon and tropospheric ozone has occurred at the mid-latitudes, ge
200 addition to reducing productivity, increased tropospheric ozone levels could alter terrestrial carbon
208 storage could be enhanced through minimizing tropospheric ozone pollution and improving nitrogen fert
209 cing per unit of emission due to aerosol and tropospheric ozone precursor emissions in a coupled comp
211 w global supply chain relocates emissions of tropospheric ozone precursors and its impacts in shaping
213 d isoprene emissions include higher rates of tropospheric ozone production, increases in the lifetime
214 hough many studies have linked elevations in tropospheric ozone to adverse health outcomes, the effec
215 urbation; the prediction of future trends in tropospheric ozone will require a full understanding of
216 cycles that catalytically destroy or produce tropospheric ozone, a greenhouse gas potentially toxic t
220 eeds further investigation, black carbon and tropospheric ozone, both of which are strongly influence
223 onmental factors (climate, atmospheric CO2 , tropospheric ozone, nitrogen deposition, and land cover/
224 While El Nino leads to enhancements of upper tropospheric ozone, we find this influence does not reac
225 ant atmospheric pollutants and precursors of tropospheric ozone, while the Middle East is a global em
226 agents--including black carbon aerosols and tropospheric ozone--are noticeably better than greenhous
232 gh studies that simulate a range of expected tropospheric particulate matter (PM) lifetimes, in order
234 eric particulate matter aid understanding of tropospheric photochemistry and are required for estimat
235 ensor technologies (e.g., TROPOMI), study on tropospheric photochemistry will be rapidly advanced in
236 relative effects of atmospheric particles on tropospheric photochemistry, as well as possible inaccur
237 te observations of hydrogen cyanide (HCN), a tropospheric pollutant produced in biomass burning.
238 contrail cirrus clouds that can alter upper tropospheric radiation and water budgets, and therefore
240 mate sensitivity, based on variations in mid-tropospheric relative humidity (RH) and their impact on
241 atmospheric moisture divergence and reduces tropospheric relative humidity in the tropics and subtro
242 bal dryness (suppressed rainfall and reduced tropospheric relative humidity) under CO2 warming from C
247 and diverges deeper in the record revealing tropospheric signals for some previously assigned bipola
249 tion of sea-surface temperature patterns and tropospheric stability will be necessary for constrainin
250 is consistent with the effect of a change in tropospheric stability, as has recently been hypothesize
251 ing the troposphere and increasing the upper-tropospheric stability, the clustering of deep convectio
253 greater role of carbonyl oxides in models of tropospheric sulfate and nitrate chemistry than previous
254 of the Ozone Monitoring Instrument (OMI) for tropospheric sulfur dioxide (SO(2)) and formaldehyde (HC
256 cies between model predictions and satellite tropospheric temperature data (and between the latter an
258 this correction in the calculation of lower tropospheric temperature from satellite microwave measur
260 sufficient magnitude to reconcile radiosonde tropospheric temperature trends and surface trends durin
261 ll remain large differences between observed tropospheric temperature trends and those simulated by a
262 hat stratospheric water vapor increases with tropospheric temperature, implying the existence of a st
265 c and natural factors project an increase in tropospheric temperatures that is somewhat larger than t
269 nstrument experiment to study the effects of tropospheric thunderstorms on the mesopause region and t
272 tes with the satellite observations of NO(2) tropospheric vertical column densities (TVCDs) from four
273 ver an area of intensive surface mining, NO2 tropospheric vertical column densities (VCDs) are seen t
274 certainty [Formula: see text] is greater for tropospheric warming (8 to 15 y) than for stratospheric
276 , both hemispheres have experienced enhanced tropospheric warming and stratospheric cooling in the 15
280 out of three recent satellite datasets, the tropospheric warming from 1979 to 2016 is unprecedented
281 t the most prominent annual mean surface and tropospheric warming in the Arctic since 1979 has occurr
283 low anthropogenic aerosol forcing, simulated tropospheric warming is larger than observed; detection
285 is larger than observed; detection times for tropospheric warming signals in satellite data are withi
295 ropical continents the isotopic signature of tropospheric water vapour differs significantly from tha
296 measurements of the isotopic composition of tropospheric water vapour from the Tropospheric Emission
297 tospheric processes, which in turn influence tropospheric weather and climate patterns on various spa
298 century, the CCMVal models predict that the tropospheric westerlies in Southern Hemisphere summer wi