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1 sticizer syntheses, with high yield and TON (turnover number).
2 for erythrose and their catalytic capacity (turnover number).
3 dependent ATPase activity, albeit with a low turnover number.
4 ot catalysis (E111F), exhibits a decrease in turnover number.
5 ydroxychalcones and dienes in high yield and turnover number.
6 position 512 critically affects transporter turnover number.
7 ), combine to yield the overall observed low turnover number.
8 , still more than a 100-fold slower than the turnover number.
9 in high yield at rates that exceed the BZDOS turnover number.
10 more fully reduce the enzyme do not slow its turnover number.
11 oxidation reactions, in some cases with high turnover numbers.
12 rbon monoxide from CO2 selectively with high turnover numbers.
13 defluorinated with high conversions and high turnover numbers.
14 s giving a longer-lived catalyst with higher turnover numbers.
15 es C, which agree well with the experimental turnover numbers.
16 cular sieves, manifested by higher catalytic turnover numbers.
17 is kinetically competent with the enzymatic turnover numbers.
18 detection window ranging from single to high turnover numbers.
19 age to the protein, and produce higher total turnover numbers.
20 ciency hydroxychlorination with thousands of turnover numbers.
21 ees C, and at room temperature it exhibits a turnover number (0.07 s(-1)) comparable to bacterial DHN
24 merization of acetylenes and exhibits a high turnover number (4371), activity (1.05 x 10(6) g(PPA) mo
26 lipoyl protein domain had a 2-3-fold higher turnover number, a lower K(I) for NADH, and a higher K(I
29 al properties of D454C, i.e., a reduction in turnover number and a loss of voltage sensitivity, altho
31 reductase (Frd) is notable both for its high turnover number and for its production of substantial O2
32 rve, is established between oxygen-reduction turnover number and the Lewis basicity of graphitic carb
33 o the wildtype (WT) Km value but had a lower turnover number and transfructosylation/hydrolysis ratio
35 methylstyrene (20 bar H2, 40 degrees C) with turnover number and turnover frequency of ca. 540 and 1.
36 hol substrates and the immobilized catalyst, turnover numbers and frequencies approach 2 000 and 4 00
37 ate and camphorsulfonic acid, gives the best turnover numbers and reactivity with the broadest range
38 h high selectivity and activity and achieves turnover numbers and turnover frequencies reaching 98,00
39 formation of CH3OBR2 or (CH3OBO)3 with TON (turnover numbers) and TOF (turnover frequencies) reachin
41 s of P450BM-3 due to its high affinity, high turnover number, and increased solubility as compared to
45 ned their ability to mediate enzymatic total turnover numbers approaching or exceeding that of the na
46 with O(2) is decreased >or=100-fold and the turnover number approximately 1000-fold thus verifying t
47 utA(Hh) and PutA(Hp) exhibit 100-fold-higher turnover numbers (approximately 30 min(-1)) than PutA(Ec
48 ratio and an order of magnitude increase in turnover number are achieved by simply altering the fram
50 the relative k(cat)/K(m) values, the maximum turnover numbers are similar, suggesting that the 2'-pho
51 It introduces the notion of the limiting turnover number as a second key element of catalyst benc
52 nge depending on the source of the IgMs, and turnover numbers as great as 2.1/min were observed, sugg
55 essive decreases in the maximum steady-state turnover number, as well as lower apparent rate constant
56 hylidene species and provide good yields and turnover numbers at relatively low catalyst loading (<50
57 o alkynes and cycloisomerizations, with high turnover numbers at room temperature or slightly elevate
60 um in absence of substrate and, in turn, the turnover number can be modulated with mutational- and os
62 r) or greater, a number that agrees with the turnover number derived from steady-state kinetic method
67 generated CO with high selectivity, and its turnover number for CO formation reached 32 based on the
68 thiol-modified AuNPs by the enzyme, (iii) a turnover number for CtCDH immobilised on thiol-modified
74 tion is 20-fold slower than the steady-state turnover number for the overall reaction, implying that
77 elatively stable GS-CH(2)F intermediate, the turnover numbers for a series of dihalomethanes fall in
80 Even under non-optimised conditions, high turnover numbers for coupled FOx/peroxygenase catalysis
81 iments, in conjunction with the steady-state turnover numbers for dCDP formation of 2-14 s(-1) at RNR
83 ecule levels demonstrate increased substrate turnover numbers for DNA nanocage-encapsulated enzymes.
85 erial enzymes, the diiron hydrogenases, have turnover numbers for hydrogen production from water as l
86 , are found to give extremely high rates and turnover numbers for n-alkane dehydrogenation, and yield
89 up to 92% ee and a 4-fold increase in total turnover number) for the production of (S)-salsolidine.
91 on was sustained for more than one week with turnover numbers greater than 6x10(5) and 3x10(6), respe
96 boxylic acids has been developed with a high turnover number (>99 000) and turnover frequency (>2000
99 ed the catalytic nature of the process, with turnover numbers in excess of 5 and essentially quantita
104 dingly, we establish the following trend for turnover number (k(cat)) and catalytic efficiency (k(cat
110 respectively, values that corresponded to a turnover number (k(cat)) of 0.66 min(-1) and a catalytic
112 mM, with a V(max) of 7.9 +/- 0.3 mM min(-1), turnover number (k(cat)) of 6.7 x 10(-2) s(-1), and a ca
113 The Michaelis-Menten constant (k(m)) and turnover number (k(cat)) of purified total GSTs toward p
116 ization exchange, revealed that the enzyme's turnover number (k(cat)) was strongly correlated with pr
124 excellent transport substrate with apparent turnover number, K(m) and K(i) values of 5.8 s(-1), 4 mi
125 he key kinetic constants of these proteases, turnover number kcat and catalytic efficiency kcat/KM, a
128 schii AdoMetDC has a Km of 95 microm and the turnover number (kcat) of 0.0075 s(-1) at pH 7.5 and 22
129 outside-out orientation yielded a catalytic turnover number (kcat) of about 1 s(-1), a value that is
130 l findings that the impact is largely on the turnover number (kcat), with less substantial effects on
132 e compared these with the observed catalytic turnover numbers measured under steady-state conditions.
136 dendrimer with 12 phenylseleno groups has a turnover number of >60 000 mol of H2O2 consumed per mole
137 conversion to hydrogen gas of ~4.0% (with a turnover number of >7,000 over 5 h, a frequency of >1,40
140 H(2) by methanolysis of phenylsilane, with a turnover number of 10(5) and a turnover frequency surpas
141 f H(2) production for up to 4 h with a total turnover number of 10(6) before photocatalytic activity
142 rk lifetime of more than 5 days and a record turnover number of 1094+/-61 molH2 (molNi )(-1) for a de
144 We demonstrated that syngas with a benchmark turnover number of 1330 and a desirable CO/H2 ratio of 1
147 Tn oligomers, NTP hydrolysis occurred with a turnover number of 20-25 min(-1) and the observed S0.5 v
148 length, NTP hydrolysis still occurred with a turnover number of 20-25 min(-1), but the observed S0.5
149 e active in vitro, with the fastest having a turnover number of 22 +/- 1 s(-1) -sixfold faster than t
150 lly, allylation proceeded efficiently with a turnover number of 2200 at room temperature, which is un
156 E. coli pyrophosphatase was found to have a turnover number of 570 s(-1) under the same conditions.
159 ction proceeds at a low driving force with a turnover number of 9 x 10(9) cell(-1) and turnover frequ
162 from Pseudomonas aeruginosa has the highest turnover number of all characterized IGPS enzymes, provi
163 t room temperature, representing the highest turnover number of any Fe-based N2 silylation catalyst t
167 While TPX2 binding has no effect on the turnover number of AurA and does not change the reaction
170 state and is predicted to enhance the kinase turnover number of PKCalpha during a single membrane doc
175 gh level of expression and a relatively high turnover number of the efflux pumps in gram-negative bac
179 resent in excess is a key determinant of the turnover number of the G-quadruplex DNAzyme; decompositi
182 Mutations at position 179 also affected the turnover number of the ornithine carrier severely, imply
184 of the hydroxyl group of A621 inhibited the turnover number of the ribozyme significantly, this acti
186 ze the HDF of C(6)F(5)H with Et(3)SiH with a turnover number of up to 200 and a turnover frequency of
188 ng the catalyst-substrate interaction times, turnover numbers of (0.6-1.2) x 10(4) and (3.0-5.0) x 10
192 sterol 14alpha-demethylation with respective turnover numbers of 1.7 min(-1), 5.6 min(-1) and 3.4 min
193 scal pressure led to yields as high as ~52%, turnover numbers of 100, and improved chemoselectivity f
194 - 2 microM, respectively, with corresponding turnover numbers of 2.08, 1.65, and 1.32 s(-1), respecti
198 e 6 h experiment, MOF-1992/CB cathodes reach turnover numbers of 5800 with turnover frequencies of 0.
200 e screening of the catalytic system, maximum turnover numbers of 786 for dimethoxymethane and 1290 fo
201 ethers, amines, and unactivated alkanes with turnover numbers of 930, 790, and 950, respectively.
202 iven hydroxylation of lauric acid with total turnover numbers of 935 and initial reaction rate of 125
204 al groups and displayed unprecedentedly high turnover numbers of approximately 2.5 x 10(6) and turnov
206 st activity, generating approximately 40,000 turnover numbers of H2 over 12 d (with respect to dye).
207 the bottleneck for determining the specific turnover numbers of individual whole-cell biocatalysts.
209 ng determination of the remarkable intrinsic turnover numbers of O2 (*-) to O2 by PEG-HCCs at >20,000
212 ns revealed a 15-20-fold decrease in overall turnover numbers of the hybrid modules as compared to th
213 e kinetic data were employed to simulate the turnover numbers of the various CBS-catalyzed reactions
215 Impressively, sal-Fe-MOF displayed very high turnover numbers of up to 145000 and was recycled and re
217 etoxifying a chlorinated model compound with turnover numbers of up to 200, but it can also be employ
218 Q240A variant biocatalysts displaying total turnover numbers of up to 32,000 and space time yields u
219 catalyst loadings as low as 0.002 mol %, and turnover numbers of up to 43,000 were achieved without r
220 d 3-alkylindoles and bisindolylmethanes with turnover numbers of up to 500 and 460, respectively, ill
221 he Mg-functionalized MOF displayed very high turnover numbers of up to 8.4 x 10(4) for ketone hydrobo
223 bstrates with low micromolar K(m) values and turnover numbers on the order of hundreds per second.
225 ding nor catalysis (H112Q) exhibits the same turnover number per active subunit as wild-type IDE.
226 oduction of PPC polyols, outstanding yields (turnover numbers), quantitative carbon dioxide uptake (>
228 ction of hydrogen from neutral water, with a turnover number reaching 5.5 x 10(4) mol of H(2) per mol
230 often feature high catalyst loading and low turnover numbers relative to non-oxidative cross-couplin
234 E showed comparable kinetic parameters, with turnover number similar to that of carboxypeptidase and
235 dissociation constants of less than 8 nM and turnover numbers similar to palmitic acid and N-palmitoy
236 (>5 days) than the protein-film (<6 h), with turnover numbers surpassing those of the protein-film af
237 her known substrate and reacts with a higher turnover number than palmitic acid but with unaltered re
238 ith blue light produces oxygen with a higher turnover number than the analogous intermolecular compon
241 igh tolerance of functional groups, and with turnover numbers that exceed those of previous catalysts
242 ein, but the FhuA constructs functioned with turnover numbers that were equivalent to wild type.
243 capable of carrying out more than a million turnover numbers (TNs) at pH 7 with an Eapp =1.45 V vs.
244 ith a maximum rate of 941 mumol h(-1) g(-1), turnover number TON(Ni) > 103, and total projected TON(N
245 demonstrates a more-than-3-fold increase in turnover number (TON(CO) = 100 +/- 4) and quantum yield
247 of saturated N-heterocycles with the highest turnover number (TON) (1 mol% of 1, 12 h, TON = 62; 0.1
248 xtends catalyst lifetime to increase the Met turnover number (TON) 3-fold compared with H2O2, highlig
249 t loadings down to 500 ppm and the catalytic turnover number (TON) and turnover frequency (TOF) regis
257 zes H2 production over 1 week and achieves a turnover number (TON) of as high as 6500 with almost no
258 nstrate alpha-alkylation of aldehydes with a turnover number (TON) of over 52,000 under visible light
260 nduced air-water-CO(2) reduction with a high turnover number (TON) of ~10(6)-10(8) (mols of product p
261 electively oxidized to glyceraldehyde with a turnover number (TON) of ~1000 and Faradaic efficiency (
262 egrees C for oxidation of NH(3), the highest turnover number (TON) reported to date for a molecular c
264 alladacycles have been used to generate high turnover numbers (TON's) and turnover frequencies (TOF's
266 onate) formed was in the range of 92-99% and turnover numbers (TON) were close to 500; in the case of
267 degrees C, 1 bar N(2)O), together with high turnover numbers (TON, up to 6700) and turnover frequenc
268 ong-lived and remarkably efficient with high turnover numbers (TONs) and turnover frequencies (TOFs)
270 ting S or Se for O in the xanthene ring give turnover numbers (TONs) as high as 9000 for the generati
271 3030COA:3030TBE:1p-XPCPIrHCl (4):1.1NaOtBu, turnover numbers (TONs) between 1400 and 2200 (up to 72%
273 activity during solar light irradiation with turnover numbers (TONs) of more than 50,000 mol H2(mol H
274 enorhodamine dye generate more hydrogen [181 turnover numbers (TONs) with respect to chromophore] tha
277 binding affinities and steady-state kinetic turnover numbers toward native (K(d)(S6K1) = 1.2 microm
278 ethers with excellent mass balance and high turnover numbers under 1 atm of O2 with no need for any
279 hloroperbenzoic acid (mCPBA) occur with high turnover numbers under mild conditions, but the mechanis
281 faradaic efficiency of 96 %, an exceptional turnover number up to 320 000, and a long-term turnover
283 ve olefin metathesis catalysts, allowing for turnover numbers up to 10,000 in various olefin metathes
290 beta-lactones, catalyst 1 exhibits excellent turnover numbers (up to 10,000) and turnover frequencies
292 s exhibit high Faradaic efficiency (90%) and turnover numbers (up to 290,000, with initial turnover f
294 At 37 degrees C, the enzyme shows a maximal turnover number (V(max)) of 670 s(-1) and K(m) values fo
299 CrPGK1 oxidation was found to affect the turnover number without altering the affinity for substr