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1 to oxidative addition, rendering the system unreactive.
2 Hexafluorobenzene proves unreactive.
3 Aliphatic amines were unreactive.
4 ronates for reaction that would otherwise be unreactive.
5 t gas phase basicities being, in large part, unreactive.
6 eas more substituted secondary alcohols were unreactive.
7 d probe based on a warhead so far considered unreactive.
8 aromatic structure and are stable in air and unreactive.
9 ty, with the Mn(IV)(3)CaO(4) OEC model being unreactive.
10 ental P resides, is relatively insoluble and unreactive.
11 ation was attained, while anhydrite remained unreactive.
12 ive, whereas the beta-anomer was found to be unreactive.
13 of DTT thiol groups are protonated and thus unreactive.
14 ht that the interior surface of nanotubes is unreactive.
15 , which are dominant in marine systems, were unreactive.
16 alpha,beta-Unsaturated esters were unreactive.
17 ly functionalized ceramides were found to be unreactive.
18 e unable to adopt the S-cis conformation are unreactive.
19 ophiles, whereas constrained nucleotides are unreactive.
20 e spin transfer cannot occur, the species is unreactive.
21 onyl functionalities at nitrogen, are rather unreactive.
22 Esters were unfortunately found to be unreactive.
23 The other altered state is unreactive.
24 reduced form of Cys 266, which is otherwise unreactive.
25 like, acceptors were found to be essentially unreactive.
26 ntal phospholipids and alcohol analogues are unreactive.
27 e reactive than TCEP, and DTT is essentially unreactive.
28 Disulfides (cystine) are unreactive.
29 Cystine and histidine derivatives are unreactive.
30 is constrained trans to the 2'-amine is also unreactive.
31 isubstituted and trisubstituted alkenes were unreactive.
32 in, whereas the anti-beta-silyl alkoxide was unreactive.
33 lkylidenes that bear a boron substituent are unreactive.
34 ethane, and-similar to methane-is chemically unreactive.
35 n the C-H bonds, previously considered to be unreactive.
36 enging because C-C sigma-bonds are typically unreactive.
37 Of the 268 OFSs, 266 were unreactive.
38 consequence of which renders both chemically unreactive.
39 s, which in its oxidized state is relatively unreactive.
40 owed by the 3,5-positions, while the 2,6 are unreactive.
41 4.9 x 10(4) M(-1) x s(-1)) of the relatively unreactive (1)HNO into the extremely reactive (3)NO(-).
44 iously reported Mn(2) -peroxides, which were unreactive, 2 proved to be a capable oxidant in aldehyde
45 tructures of these mutants complexed with an unreactive abasic site in DNA reveal these residues to a
50 unction because it prevents the formation of unreactive acyl-enzyme intermediates, which has been a l
55 e the substitution of sulfur for hydrogen at unreactive aliphatic or electron-rich aromatic carbon at
56 his metal-free C(sp(3))-H borylation enables unreactive alkanes to be transformed into valuable organ
57 for the alkylation of amides with relatively unreactive alkyl halides (i.e., poor substrates for SN2
58 te that N-alkylation activates the otherwise unreactive amide bond towards sigma N-C cleavage by swit
59 in the presence of dihydroNADPH (NADPH3, an unreactive analogue lacking the 5,6-double bond in the n
60 nding experiments with dGCVIA peptide and an unreactive analogue of FPP, (E,E)-2-[2-oxo-2-[[(3,7,11-t
63 ed, engineered pure-magnetite was relatively unreactive and contributed minimally to the generation o
64 and as a result, the molecule is relatively unreactive and even displays reversible electrochemical
65 resulting Au99(SPh)42 compound, however, is unreactive and highly stable in the presence of excess a
68 hydrogen bonds to the O2' atom, rendering it unreactive and thus explaining the specificity for 2'-de
69 ydrogen (C-H) bonds are typically considered unreactive and unavailable for chemical manipulation.
70 ch have been thought to be relatively inert (unreactive) and thus leach small amounts of polyaromatic
71 on paths associated with other h-e pairs are unreactive, and the moderate experimental efficiency is
72 literature but whose protons were considered unreactive are also shown for the first time to react wi
73 may be synthetically useful when relatively unreactive arene substrates such as benzene, toluene, an
74 this approach to monofluorobenzenes, highly unreactive arenes, which upon complexation become nearly
76 tramethylpiperidine (TEMPO-Me) is relatively unreactive at ambient temperature in the absence of an e
77 iously difficult glycosylation with the most unreactive axial 4-OH of the rare disaccharide, and the
78 ages in [4 + 2] cycloadditions with normally unreactive azadienophiles including unactivated cyano gr
79 s the most favored one thermodynamically, is unreactive because of a high propensity for charge recom
80 tive of MDH.PQQ(NH2(+).methanol structure is unreactive because of the nonproductive means of methano
81 s for the Michael reactions of traditionally unreactive beta,beta'-enones and substituted beta,beta'-
82 also the subsequent functionalization of the unreactive beta-methylene group in an unprecedented tand
83 a powerful tool with which to convert these unreactive bonds into carbon-carbon and carbon-heteroato
86 one step, and in the process transforms the unreactive C-3 position to the reactive C-5 position.
87 ) may be a general strategy for cleaving the unreactive C-C bonds between adjacent sp(2)-hybridized c
88 is regard, transformation of a traditionally unreactive C-H bond, proximal to the nitrogen atom, into
89 r of synthetic challenges: the activation of unreactive C-H bonds and the need for regio- and stereos
90 nctionalize molecules directly at ostensibly unreactive C-H bonds, chemists have discovered reaction
91 t catalytic methods to cleave the relatively unreactive C-O bonds of ethers remains an important chal
92 e reaction is based on the activation of the unreactive C-OMe bond by the proximate amide directing g
93 diates capable of abstracting a hydride from unreactive carbon centers, including benzyl-, allyl-, an
94 f methane through the cleavage of the highly unreactive carbon-phosphorus bond in methyl phosphonate
97 at could allow delineation of the active and unreactive clones, the sequences identified in five of t
98 entadiene isomer may be regarded as a rather unreactive closed-shell singlet species with one localiz
101 predominates in the presence of practically unreactive compounds (acetone, butanol, propionic, and b
102 ion: selective preservation of biochemically unreactive compounds(4,5) and protection resulting from
103 f the triphosphate of GTP, destabilizing the unreactive conformation and thereby allowing thermal flu
104 rate processes, (b) alternative reactive and unreactive conformations, and (c) mutations within the c
109 efin coupling partners, including previously unreactive disubstituted terminal olefins and internal o
113 a new capacity, to incorporate two otherwise unreactive elements, Re and Zn, in the same structure wh
115 FTSs can form as transient intermediates or unreactive end-products via e(aq)(-) reactions with prec
119 ys265 is absent in the homologous but oxygen-unreactive FAD site in heterotetrameric sarcosine oxidas
121 cases, catalyze oxidation of the thiol to an unreactive form such as a sulfinic or sulfonic acid.
125 ctions is particularly pronounced in case of unreactive glycosyl donors and/or glycosyl acceptors.
127 cture of RtcB in complex with Mn(II) and the unreactive GTP analogue guanosine 5'-(alpha-thio)triphos
129 generally thermodynamically and kinetically unreactive; however, we recently discovered that the tri
132 the formation of covalent bonds by oxidizing unreactive hydroquinone moieties in LHA to reactive, ele
133 plexation of an activator species to form an unreactive, immobile complex reduces the effective diffu
134 and excels at the introduction of relatively unreactive impurity ions that have not been previously a
142 eplacement for Asn245, which is inaccessible/unreactive in WT LacY, alkylates readily in the Gly-->Tr
144 products occurs due to the epimerization of unreactive intermediates from the other two pathways, as
146 ssary recognition elements into an otherwise unreactive junction resulted in specific strand scission
148 the chemoselective reduction of an extremely unreactive lactam in the presence of a readily reduced l
149 ppears to be critical for inhibition because unreactive lipids, e.g. PGB1, PGE2, PGF2alpha, and TxB2,
153 revealed that fungi recruit and redistribute unreactive Mn(2+) provided by fresh plant litter to prod
154 on reveals that absorption by high-frequency unreactive modes (e.g., C[double bond]C stretches) incre
155 heated in the presence of a noble gas or an unreactive molecule at 650 degrees C and 3000 atm pressu
157 ds to accelerate C-H activation of otherwise unreactive monodentate substrates is crucial for outcomp
158 er reactions for a number of substituted and unreactive N-allyl-2-furfurylamines under biomimetic con
160 cess to reactive sites, promote formation of unreactive NH4(+), and reduce oxidant levels due to high
161 t methanol and dimethyl ether are apparently unreactive on the two most important methanol-to-hydroca
163 s were also easily obtained but showed to be unreactive or rearranged under these cyclization conditi
167 re treated soils were dominated by dissolved unreactive P (DUP), mainly originating from manure.
174 interesting biofunctionalization approach of unreactive polymers with applications in immunosensing a
175 this radical can abstract hydrogen atoms at unreactive positions, facilitating the introduction of a
177 of the water adduction reaction rate or the unreactive ratio provides two separate methods for confi
180 ted: three Ag variants and one Au used as an unreactive reference to separate mechanical from chemica
181 F3)4](-) and [(bpy)Cu(CF3)3], are stable and unreactive, remaining dead-end spectators throughout the
185 both catalyzing mineralization in otherwise unreactive solution and of templating nanocrystal growth
186 be fit to a model that assumed a protonated unreactive species A, a major reactive species B, and a
187 , like those obtained from biomass or highly unreactive species, such as CO2 should be transformed in
189 the open conformation possibly represents an unreactive state with Glu-288 positioned away from the c
191 le the racemization of traditionally static, unreactive stereocenters through the intermediacy of pro
192 ure of its complex with three Mg(2+) and the unreactive substrate analogue dimethylallyl-S-thiolodiph
193 ase complexed with three Mg(2+) ions and the unreactive substrate analogue farnesyl-S-thiolodiphospha
194 mide displacement reactions, carba-NAD is an unreactive substrate analogue for NAD-consuming enzymes.
196 ohol dehydrogenase complexed with NAD(+) and unreactive substrate analogues, 2,2,2-trifluoroethanol o
201 d to a protein target, changing an initially unreactive terminus into one that could be modified in h
202 of the approaching SO2 and makes a normally unreactive tertiary carbenium carbon susceptible to addi
205 illar inclusion pathology was diminished and unreactive to antibodies specific for the C terminus of
208 free drug, yet remain essentially stable and unreactive to in vitro DNA alkylation conditions (<0.1-0
209 cids and esters, the chromophore of pnGFP is unreactive to millimolar concentrations of hydrogen pero
210 in the presence of B(C6 F5 )3 , a Lewis acid unreactive to O2 , to generate bis(borane) peroxide.
213 ctional state, in which the active sites are unreactive, to the functional proteolytic conformation.
214 s-DNA treated in buffer or buffer containing unreactive toluene resulted in no significant changes in
218 es containing polar functionality, which are unreactive toward C-H borylation under neat conditions.
220 ibenzofuran analogue of 1b, compound 1c, was unreactive toward CO due to the longer distance between
221 In contrast, [Zn3(OH)3L] (4) was found to be unreactive toward CO2 over the course of several days at
222 F; R = H, 1-H) were prepared and shown to be unreactive toward D(2) and alpha-olefins, leading to the
227 n CHCl3 and other nonpolar solvents, OsO4 is unreactive toward H2 over a week at ambient temperatures
229 stigations reveal that hydroxyl radicals are unreactive toward HFPO-DA, while electrochemically activ
230 lates that form on warming the solutions are unreactive toward isobutyraldehyde and undergo retroaldo
231 However, the silicon reagent is completely unreactive toward many sulfones, the tin reagent typical
233 Moreover, the CDO active site is essentially unreactive toward NO in the absence of substrate, sugges
236 l changes that render the trinuclear cluster unreactive toward O(2), demonstrating a structural role
237 (4), was prepared and found to be completely unreactive toward O(2), suggesting a critical role for F
238 rimary N-oxides, and secondary N-oxides, are unreactive toward or react predominantly by proton trans
240 e semiquinone is highly stabilized making it unreactive toward oxygen; and 3) the Q(o) site catalyzes
241 ol(2)(eta(4)-C(4)CO)Ru(CO)(2)H](-) (13) were unreactive toward PhCHO under conditions where facile Ph
242 ive coordinate amide iodine(V) complexes are unreactive toward redox reactions due to the fact that i
243 hough B(C(6)F(5))(3) has been reported to be unreactive toward silica in the absence of a Bronsted ba
245 otonation renders basic sites (nucleophiles) unreactive toward the N-hydroxysuccinimide ester reagent
247 alts, including those substrates that remain unreactive toward the Zincke salt, which is the reagent
250 odeled after the p53 acetylation site but is unreactive toward trypsin because all other lysine and a
253 LS-3DCHIm is resistant to reduction, is unreactive toward weakly acidic 4-NO2-phenol, and strong
254 ular terminal metal-nitrides are notoriously unreactive towards dihydrogen, and only a few electron-r
260 eful for separation of microliter amounts of unreactive trace volatile compounds from large-volume ga
261 ithin a series of g-C3N4, the yield of these unreactive trapped electrons correlates inversely with H
263 c acid, a compound previously reported to be unreactive under Dakin-West conditions, forms 4-phenyl-2
265 hindered alpha-quaternary lactams which are unreactive under known conditions for similar transforma
267 erization into alpha-bromide that is totally unreactive under the established reaction conditions.
270 Although 1,5-dienes with this skeleton were unreactive under thermal conditions, they were photochem
271 ethyl, and isopropyl esters are essentially unreactive under these conditions, allowing for the sele
272 atic aldehydes, as an aliphatic aldehyde was unreactive under these conditions, and other reactive fu
275 were found in occluded positions, while some unreactive uracils were found in exposed positions.
277 In this series, sulfanyl derivatives were unreactive, while sulfoxide and sulfone analogues provid
279 Lycopene has previously been reported to be unreactive with BCO1, and our findings warrant a fresh l
280 are mutually reactive with one another, but unreactive with biopolymers and water, is challenging.
281 xy analog of the natural substrate, normally unreactive with cAOS, was thereby epoxidized stereospeci
282 Other hedgehog point mutants at D303, also unreactive with cholesterol, accepted 3HPC as a substrat
284 4-Hydroxyphenyl isopropyl sulfone (6) is unreactive with either CCl4 or CBrCl3 in KOH-t-BuOH, its
285 ere we show that antithrombin is essentially unreactive with factor IXa in the absence of heparin (k(
287 o methylates the cap analog m(7)GpppA but is unreactive with GTP, GDP, GpppA, m2,2,7GTP, m2,2,7GDP, A
289 enide (TOPSe)) were surprisingly found to be unreactive with metal carboxylates and incapable of yiel
292 d that while carboxylated SWCNTs were rather unreactive with respect to direct solar photolysis, they
294 rapidly with carbon-centered radicals but is unreactive with superoxide and lipid peroxidation produc
295 ated iron(II)-SciOPP species was found to be unreactive with the cycloheptyl bromide electrophile ove
296 d analogue of 1, [(bppppa)Ni](ClO4)2 (2), is unreactive with the hemithioacetal, thus indicating the
297 omplete V(H) and V(L )germline revertant was unreactive with the human ILD and didomain, the Escheric
300 ata demonstrate that 19-substituted BQAs are unreactive with thiols, display reduced hepatotoxicity,