ライフサイエンスコーパス: unsymmetrical

1 [reaction: see text] Two new unsymmetrical 1,2,4,5-tetrazines, 3-methylsulfinyl-6-met

2 be achieved keeping an ortho alkoxy group in unsymmetrical 1,2-dialkynylbenzene in the form of a cycl

3 s is achieved for the synthesis of versatile unsymmetrical 1,2-diamine derivatives.

4 nBr(2)-mediated regioselective annulation of unsymmetrical 1,2-diarylmethinedipivalates in DCM at roo

5 Little selectivity was observed in cases of unsymmetrical 1,2-diketones.

6 of terminal alkynes to give symmetrical and unsymmetrical 1,3-diynes in good to excellent yields and

7 Five new, unsymmetrical 1,4-distyryl-2,5-bisphenylethynylbenzenes

8 In addition, the reaction of unsymmetrical 16-Selena/telluratripyrranes with symmetri

9 r into both symmetrical (5a-c and 11a-c) and unsymmetrical (19a-e) bis-2,5-diketopiperazines (bis-2,5

10 A flexible route to both symmetrical and unsymmetrical 1H,8H-pyrrolo[3,2-g]indole has been develo

11 re limited, and methods for the formation of unsymmetrical 2,2'-bis-pyridines are scarce.

12 on a selective oxidative rearrangement of an unsymmetrical 2,2'-bis-tryptamine.

13 Unsymmetrical 2,2'-disubstituted 6,6'-binicotinates were

14 ribed for the preparation of symmetrical and unsymmetrical 2,4-diarylpyridines.

15 osine and 5-octadiynyl-2'-deoxycytidine with unsymmetrical 2,5-bis(azidomethyl)pyridine using copper(

16 ct arylation event furnishing symmetrical or unsymmetrical 2,5-diaryl selenophenes in good yield.

17 trate the divergent C-H functionalization of unsymmetrical 2-aryl cyclic 1,3-dicarbonyl compounds tha

18 ovel access to highly useful symmetrical and unsymmetrical 2-aryl substituted 1,4-diketone building b

19 roach was also extended for the synthesis of unsymmetrical 3,3'-bisimidazopyridinylmethanes under opt

20 With unsymmetrical 3,3-diarylacrylamides, high selectivity is

21 e I porphyrins that utilizes the reaction of unsymmetrical 3,4-difunctionalized pyrroles and sterical

22 ing this method, a series of symmetrical and unsymmetrical 3,5-diarylpyridines were synthesized with

23 3-Substituted, 6-substituted, and unsymmetrical 3,6-disubstituted 4-alkylaminopyridazines

24 e vinyl boronic acids and alkynes to provide unsymmetrical 3-boryl-1,4-diene reagents.

25 connectivity, the selective symmetrical and unsymmetrical 4,4"-functionalization (-CN, -Me, -CO2Me)

26 cient and high-yielding strategy to prepare "unsymmetrical" 4-aryl-isoxazol-3,5-dicarboxylic acid der

27 new 2,2'-bipyridine ligands, symmetrical and unsymmetrical 6,6'-binicotinates, and 2,2'-bipyridine-5-

28 DFT computations revealed formation of an unsymmetrical adduct of (TMP)Co-CH(OAc)CH3 (4) with *CH(

29 either formal hydrosilylation regioisomer of unsymmetrical aliphatic-substituted internal alkynes fro

30 The NMR data for 12a-l are consistent with unsymmetrical alkene bonding and polarization of the alk

31 The unprecedented formation of unsymmetrical alkenes from the intermolecular reductive

32 Reactions involving unsymmetrical alkenyl and alkynyl dienophiles proceed wi

33 ld and efficient method for the synthesis of unsymmetrical alkyl ketones.

34 ycloaddition with a range of symmetrical and unsymmetrical alkyne and alkene dipolarophiles to afford

35 by excellent levels of regioselectivity when unsymmetrical alkynes are used that carry an -OH or -NHR

36 ad substrate scope, and both symmetrical and unsymmetrical alkynes can be applied.

37 ad substrate scope, and both symmetrical and unsymmetrical alkynes can be harnessed.

38 cycloaddition between a variety of internal, unsymmetrical alkynes is described.

39 Alternatively, unsymmetrical alkynes of the form EtCCR (R variable) can

40 Unsymmetrical alkynes proceed with excellent regioselect

41 hine followed by regioselective insertion of unsymmetrical alkynes to afford nonracemic 1,2-dihydroqu

42 lized ylides that undergo cycloaddition with unsymmetrical alkynes to give indolizidines with good re

43 In the case of unsymmetrical alkynes, a highly regioselective product w

44 bstrate scope with different symmetrical and unsymmetrical alkynes, affording the desired product in

45 oxy-2-alkynoates, as coupling partners, form unsymmetrical alkynes, which undergo lactonization after

46 of several substituted VCPs with a range of unsymmetrical alkynes.

47 regioselectivity was achieved in the case of unsymmetrical alkynes.

48 bite angles and that nucleophilic attack on unsymmetrical allyl complexes with larger bite angle lig

49 larger bite angle ligands was faster than on unsymmetrical allyl complexes with smaller bite angle li

50 enzimidazole and imidazole nucleophiles with unsymmetrical allylic carbonates in the presence of sing

51 [Rh(CO)2Cl]2-catalyzed allylic alkylation of unsymmetrical allylic carbonates was discovered.

52 Palladium-catalyzed reaction of unsymmetrical allylic electrophiles with amines gives ri

53 The use of unsymmetrical allylic pro-nucleophiles was shown to give

54 a precursor for the convenient synthesis of unsymmetrical alpha,alpha-diarylacetates featuring indol

55 The reaction of unsymmetrical alpha,omega-diynes gave a product only wit

56 nctional groups delivering fully substituted unsymmetrical amides in high yields (up to 96%).

57 These observations are made for a class of unsymmetrical amides that exhibits two asymmetric axes--

58 ccording to a two-site binding model, 28 new unsymmetrical analogues bearing a benzyl tail group and

59 ROMP of the strained unsymmetrical and "electronically-ambiguous" cyclophaned

60 e is a need for new approaches to synthesize unsymmetrical and 3-monosubstituted tetrazines.

61 A series of unsymmetrical and symmetrical push-pull phenothiazines (

62 ny need for purification, to produce various unsymmetrical and symmetrical tetraarylethylenes in exce

63 Studies of substituted unsymmetrical and unsubstituted symmetrical model eta(3)

64 s the design, and synthesis of D-pi1-A-pi2-D unsymmetrical, and D-pi1-A-pi2-A-pi1-D symmetrical type

65 Our studies suggest that unsymmetrical aniline derivatives bearing electron withd

66 precedented ruthenium (Ru)-catalyzed twofold unsymmetrical annulation of 3-O/N-allyl benzoic acid der

67 The unsymmetrical annulation of N-methoxybenzamides with two

68 stablished for the synthesis of novel hybrid unsymmetrical aryl chalcogenides with the aid of a catal

69 to access highly functionalized arynes from unsymmetrical aryl(mesityl)iodonium tosylate salts.

70 ipso-substitution of the iodonium moiety and unsymmetrical aryl(TMP)iodonium salts are primarily empl

71 purine nucleophiles, as well as a variety of unsymmetrical aryl, heteroaryl, and aliphatic allylic ca

72 Unsymmetrical aryl-, heteroaryl-, and alkyl-substituted

73 better selectivity was also observed in the unsymmetrical aryl-aryl alkenes having an electron-withd

74 regioselectivity was achieved in the case of unsymmetrical (aryl)alkynes.

75 into regioselectivity trends in reactions of unsymmetrical arynes, which in turn has fueled advances

76 For unsymmetrical azoarenes, selective aroylation took place

77 scope and is compatible with symmetrical and unsymmetrical azobenzene derivatives, with maleimides an

78 The regioselective coupling of unsymmetrical azobenzenes was further demonstrated and l

79 rocess involves 1,3-dipolar cycloaddition of unsymmetrical azomethine ylide resulting from the therma

80 l groups and allows the synthesis of diverse unsymmetrical azophenols under mild conditions in good t

81 -x)(PMe3)x(NO)]BF4, which are electronically unsymmetrical because of the presence of a single NO(+)

82 benzofurans, xanthenes, diaryl indoles, and unsymmetrical benzophenones by novel routes without appl

83 A series of unsymmetrical bi- and tetrathiophenes have been synthesi

84 rnished highly oxygenated and functionalized unsymmetrical biaryls in good to excellent yields by the

85 facile synthetic access to a wide variety of unsymmetrical biaryls of pharmaceutical, agrochemical an

86 of arenediazonium salts in the synthesis of unsymmetrical biaryls, built around the seminal works of

87 ium metal in pure water leads to symmetrical/unsymmetrical biaryls, indicative of a net Kumada-like b

88 lerated if the ligand L is an electronically unsymmetrical bidentate ligand.

89 Unsymmetrical bifunctional antitumor agent WMC79 was fur

90 The synthesis of novel unsymmetrical bifunctional antitumor agents was accompli

91 s is unknown, but previous studies led to an unsymmetrical binding model.

92 An iron-catalyzed oxidative unsymmetrical biphenol coupling in 1,1,1,3,3,3-hexafluor

93 ns are scalable for preparing a long list of unsymmetrical biphenols assembled from a less reactive p

94 steric interactions between substituents of unsymmetrical bis(4-pyridyl)acetylene ligands dictate th

95 elimination from a series of electronically unsymmetrical bis-aryl complexes was not faster from com

96 OMe, CH(3), H, Cl, CF(3)) and electronically unsymmetrical bis-aryl platinum complexes (DPPF)Pt(C(6)H

97 ctionalized heteroarenes through challenging unsymmetrical bis-olefination process in a one-pot seque

98 A catalytic cycle involving an unsymmetrical bis-pi-allylpalladium complex as the key i

99 Unsymmetrical bis-propargyl ethers and sulfonamides cont

100 The synthesis of unsymmetrical bisalkoxysilanes containing unsaturated C-

101 In this two-step synthesis, unsymmetrical bisalkoxysilanes with groups that can be f

102 s, we made predictions on the selectivity of unsymmetrical bispropargyl sulfones, amines, methanes, a

103 Several examples of unsymmetrical BODIPYs were synthesized and characterized

104 phic analysis of [3H]BF(4) revealed a highly unsymmetrical bridging hydride, the Fe-H bond being 0.40

105 re observed, the initial product again being unsymmetrical but more stable isomers being symmetrical.

106 le more weakly donating ligands give rise to unsymmetrical (C(4)) structures; the physical properties

107 eveloped for effective synthesis of diverse, unsymmetrical CADA compounds.

108 elopment of a new method for the assembly of unsymmetrical carbazoles is reported.

109 omers of enolates generated in situ from the unsymmetrical carbonyl compounds.

110 s Hayashi's Ph-bod* ligand, as well as novel unsymmetrical chiral dienes.

111 Symmetrical and unsymmetrical chromophores of isoindigo 3-7 were designe

112 ilities of one fluid into the other are very unsymmetrical, CO2 being highly soluble in the ionic liq

113 A series of sidearm analogues, including two unsymmetrical compounds, have also been prepared by modi

114 bsolute rate constants of stepwise or highly unsymmetrical concerted cycloadditions.

115 y supported Au nanoparticles proceeds via an unsymmetrical concerted transition state in which there

116 (-))(2) x 2 CH(3)CN published previously, an unsymmetrical conformation having one PD(+) ring syn and

117 omplex in which the substrate is fixed in an unsymmetrical conformation, with the amine terminal expo

118 these hybrid systems occurs through space in unsymmetrical conformations, where the center-to-center

119 abled facile access to either symmetrical or unsymmetrical conjugated diynes through homo-coupling or

120 Unsymmetrical cyanine dyes are widely used in biomolecul

121 complementary hydroarylation reactions of an unsymmetrical cyclic olefin have been developed.

122 esent the template-directed synthesis of two unsymmetrical cyclic porphyrin hexamers with both ethyne

123 The synthesis of unsymmetrical cyclobutanes by controlled heterodimerizat

124 A strategy for the construction of unsymmetrical cyclobutanes using C-H functionalization l

125 udied as applied to diarylethenes containing unsymmetrical (cyclohexenone and cyclopentenone) and sym

126 Unsymmetrical cyclophanedienes comprising electron-donat

127 elective transformations of the newly formed unsymmetrical dendralene derivatives are demonstrated.

128 exists as two isomers: a kinetically favored unsymmetrical derivative, unsym-[1(CO)](+), and a thermo

129 d accessing a new library of symmetrical and unsymmetrical derivatives (35 examples).

130 Unsymmetrical derivatives were prepared by sequential ar

131 blem of the inability to use the enolates of unsymmetrical dialkyl ketones lacking alpha-branching fo

132 ighly chemo- and regioselective synthesis of unsymmetrical dialkyl ketones.

133 inhibitors resulted in the identification of unsymmetrical dialkyl-hydroxynaphthalenoyl-benzothiadiaz

134 C-H activation/amination reaction of various unsymmetrical dialkyl-substituted alkenes.

135 beginning an oligomerization process whereby unsymmetrical dialkylchloronium ions decompose to alkyl

136 In a second step, unsymmetrical diallylated aromatic amines are generated

137 or C-C bond formation is described to access unsymmetrical diaryl acetamides under TM-free conditions

138 thod has been developed for the synthesis of unsymmetrical diaryl chalcogenides (S, Se, and Te) from

139 rbon-chalcogen bond-forming reaction to give unsymmetrical diaryl chalcogenides in trifluoroacetic ac

140 coupling reaction with aryl bromides to give unsymmetrical diaryl ketones.

141 ading to a general route toward synthesis of unsymmetrical diaryl, aryl-alkyl, aryl-heteroaryl, and d

142 enide in PEG-600 in the second step produces unsymmetrical diaryl, diheteroaryl, or aryl-alkyl bis-se

143 lectron-rich arene or heteroarene ligands of unsymmetrical diaryl-lambda(3)-iodanes is a key step in

144 ficient, strategy has been devised to access unsymmetrical diarylacetamides with the possibility of t

145 on of this method to the direct synthesis of unsymmetrical diarylacetates featuring indoles and N-sub

146 oles were synthesized from 2-iodoaniline and unsymmetrical diarylacetylenes using the Larock heteroan

147 It was found that the unsymmetrical diarylcyclopentenone bearing at second pos

148 o-6-ethoxyphenol, respectively, with a novel unsymmetrical diaryliodonium salt, 2,3,4,5-tetrabromo-6-

149 The chemoselectivity of unsymmetrical diaryliodonium salts has been investigated

150 Notably the reaction extends well to unsymmetrical diaryliodonium salts with a number of high

151 reactions led to the construction of various unsymmetrical diarylmethane scaffolds, such as thiophene

152 mild conditions to provide a wide variety of unsymmetrical diarylmethanes and other 1,1-diarylalkane

153 tituted arenes is efficiently converted into unsymmetrical diarylmethanes with various arenes as nucl

154 vative is thermally stable, when heated, the unsymmetrical diborane(5) anion derived from 9-BBN is fo

155 With the unsymmetrical diboron reagent PinB-BDan (Dan = naphthale

156 The unsymmetrical dications allowed sensitive detection for

157 be attributed to the surface activity of the unsymmetrical dications, which results in a concurrent s

158 Reactions of unsymmetrical dienes provide good to excellent olefin se

159 eactions with several symmetrical as well as unsymmetrical dienophiles, these dendralenes afforded di

160 opodium alkaloid complanadine A, which is an unsymmetrical dimer of lycodine, was achieved by exploit

161 exacene participates as the diene to give an unsymmetrical dimer.

162 iously unreported flavomannin B (2), two new unsymmetrical dimers (3 and 4), and two new mixed dihydr

163 The lactonization of unsymmetrical diols containing two primary alcohols occu

164 activity with symmetrical diols and hindered unsymmetrical diols, whereas a Cu/TEMPO catalyst system

165 lectivity for the oxidation of less hindered unsymmetrical diols.

166 we present a cobalt-catalyzed regioselective unsymmetrical dioxygenation of gem-difluoroalkenes using

167 A new series of unsymmetrical diphenylaminofluorene-based chromophores w

168 elf-selective manner upon mixing 120 degrees unsymmetrical dipyridyl ligands with 60 degrees or 120 d

169 The effect results from the unsymmetrical distribution of the HOMO, which shows decr

170 leads to formation of (iPr2)TpCu(NO) and the unsymmetrical disulfide RS-S(t)Bu.

171 lyzed oxidative cross-coupling of alkynes to unsymmetrical diynes has been achieved for the first tim

172 Moreover, the use of unsymmetrical diynes was investigated, resulting in the

173 and excellent regioselectivity is found with unsymmetrical diynes.

174 A family of unsymmetrical donor-acceptor, ferrocenyl-substituted ben

175 A two-directional unsymmetrical double annulation and biomimetic etherific

176 ing group N-methoxyamine (NHOMe) assists the unsymmetrical double annulations of arenes [that use bot

177 roxide, reacts with a second aldehyde to the unsymmetrical E-alkenes.

178 The endo invertomer is favored, showing an unsymmetrical equilibrium in variable (1)H NMR studies.

179 mical calculations (CCSD(T)/ANO1) predict an unsymmetrical equilibrium structure for triplet MeC3Me (

180 otochromic diarylethenes (DAEs) based on the unsymmetrical ethene "bridge" bearing heterocycles of th

181 with the salen moieties being attached in an unsymmetrical, flexible, pendent manner.

182 Hence, formulation of [1-F]+ as an unsymmetrical fluoronium must also be considered.

183 e of nonsubstitution on carbazolyl-N and the unsymmetrical framework of some of the derivatives is th

184 This double-unsymmetrical functionalization of both o,o'-C-H bonds o

185 ectivities of (4 + 3) cycloadditions between unsymmetrical furans and a chiral oxazolidinone-substitu

186 UHF calculations predict a planar unsymmetrical gas-phase structure for 1,3-dinitrobenzene

187 Rather, the B-N-B array of 4 is unsymmetrical, having a 2c-2e B-N dative bond with the r

188 egioselective reaction of the in situ formed unsymmetrical (hetero)aryl-lambda(3)-iodanes with a wide

189 Two examples of highly unsymmetrical heterobenzisapphyrins containing one benze

190 on reactions with catecholborane to yield an unsymmetrical hydro(boryl)diborene and a 2,3-dihydrotetr

191 synthesis relied on the development of a new unsymmetrical IF-TTF building block by a combination of

192 th triphosgene affords highly functionalized unsymmetrical imidazo[4,5-b]pyridin-2-ones in just three

193 be Abeta binding data for bis-styrylbenzenes unsymmetrical in the outer rings.

194 istances of ca. 2.5 A, although the mu-CO is unsymmetrical in the propanedithiolate derivative.

195 of this reaction permit modular assembly of unsymmetrical indeno[1,2-b]fluorene analogues.

196 II) catalytic strategy for easy syntheses of unsymmetrical indolotriarylmethanes and new bisindolylbe

197 reaction was compatible with symmetrical and unsymmetrical internal alkenes as well as substituted su

198 nd enantioselective formal hydroamination of unsymmetrical internal alkenes catalyzed by a copper cat

199 -Cycloadditions of alkyl azides with various unsymmetrical internal alkynes in the presence of CpRuCl

200 Both the symmetrical and unsymmetrical internal alkynes were reacted smoothly to

201 A modular titanium-promoted coupling of unsymmetrical internal alkynes with Weinreb amides is de

202 Here, we report that an unsymmetrical iron P-NH-P' catalyst that was previously

203 PPh3 as the trapping ligand, we obtained an unsymmetrical isomer of Fe2(S2C2H4)(mu-CO)(CN)2(PPh3)2(C

204 udies of the photochromic characteristics of unsymmetrical isomeric 2,3-diarylcyclopent-2-en-1-ones h

205 A one-pot procedure for the synthesis of unsymmetrical ketones utilizing a pyrrole-bearing carbon

206 s been applied to the total synthesis of the unsymmetrical lignan lactone (-)-bursehernin and a medic

207 or both samples, which were found to obey an unsymmetrical log-normal distribution, typical for vapor

208 This study details syntheses of unsymmetrical magnesium(I)-adduct complexes, [((Ar)Nacna

209 nd sterically equivalent, but electronically unsymmetrical, meta- and para-substituted diarylethynyls

210 The coupling of unsymmetrical monomers allowed access to the unsymmetric

211 An unsymmetrical monomethylated cyclic unsaturated acetal l

212 The protocol allows for the synthesis of unsymmetrical N,N'-di- and N,N,N'-trisubstituted ureas i

213 In most cases, when the formation of unsymmetrical N,N'-disubstituted uracil derivatives can

214 ent and facile protocol for the synthesis of unsymmetrical N-alkyl-N'-aryl perylene diimides is repor

215 The use of challenging unsymmetrical N-allyl-N-methylglycine esters is also tol

216 eophilic addition to p-benzynes derived from unsymmetrical N-substituted cyclic enediynes proceeds wi

217 unraveled a novel pathway for the synthesis unsymmetrical naphthoquinones.

218 The unsymmetrical nature of L as well as the rotational free

219 The unsymmetrical nature of the triazole staple also allowed

220 mediates suggest that the resting states are unsymmetrical Ni(II)-biaryl and Ni(II)-bithiophene compl

221 A new and highly fluorescent family of unsymmetrical organoboron complexes containing 5-(pyridi

222 Another method to prepare unsymmetrical organoselenides was also completed by coup

223 ethodology is presented for the formation of unsymmetrical organotrisulfides in a high yield and puri

224 Compound 3, with an unsymmetrical orientation of PT heterocycles, shows subt

225 ing reactions with aryl bromides to generate unsymmetrical ortho-substituted biaryls in good to excel

226 opening reaction of various C(1)-substituted unsymmetrical oxabenzonorbornadienes (OBD) with oxime nu

227 eveloped for the site-selective synthesis of unsymmetrical oxygenated biaryls.

228 Several unsymmetrical ozonolyses were also performed to further

229 On the basis of the paradigm of unsymmetrical paired edges of aromatic rings for minor g

230 ne ligand framework through incorporation of unsymmetrical pendant groups is reported.

231 namely, the flexible oligomer backbone, the unsymmetrical pendent immobilization motif of the cataly

232 that include dewetting of the pi bond and an unsymmetrical perepoxide transition state in the hydrope

233 A number of unsymmetrical perylene diimides containing a solubilizin

234 s of selective and regiodivergent opening of unsymmetrical phenonium ions with chloride ions.

235 assisted diboration of alkynamides using the unsymmetrical pinacolato-1,8-diaminonaphthalenato diboro

236 aforementioned results, seeded growth of the unsymmetrical PLLA BCPs PLLA42-b-P2VP240 or PLLA20-b-PAG

237 A series of novel, well-defined, unsymmetrical poly(ethylene glycol) chains of the type X

238 the anticipated symmetrical hydrodimers, an unsymmetrical product derived from the two coumarins.

239 resulted in an increase in the amount of the unsymmetrical product.

240 -2X, has greatly improved performance for an unsymmetrical protonated epoxide, and we recommend this

241 nge of medicinally promising hydroxyarylated unsymmetrical pyridines in good to high chemical yields

242 nts in terms of regiochemical preferences in unsymmetrical rearrangement precursors and explained why

243 practical, one-pot synthesis of enantiopure unsymmetrical salen ligands is described, using a 1:1:1

244 more, the comparison with the mononucleating unsymmetrical salophen reference ligand H(2)carl(Cl) and

245 Prepared unsymmetrical salts (e.g., 2-RC(6)H(4)I(+)2'-R'C(6)H(4)X

246 Cyclic, acylic, symmetrical, and unsymmetrical secondary alcohols are selectively coupled

247 enient one-pot method for the preparation of unsymmetrical selenides has been developed.

248 0-porphodimethenes, whereas the process with unsymmetrical selenophene-2,5-diols/tellurophene-2,5-dio

249 porphotrimethenes, whereas the process with unsymmetrical selenophene-2,5-diols/tellurophene-2,5-dio

250 le to the bridging Nb(5+), leading to highly unsymmetrical seven-coordinated Nb(5+) sites.

251 Here we demonstrate that axially unsymmetrical silicon phthalocyanines uncage small molec

252 anediols, including naphthyl-substituted and unsymmetrical siloxanes, has been quantified and compare

253 ed upon the controlled oxidative coupling of unsymmetrical silyl bis-enol ether intermediates, formed

254 gioselectivity on the addition of indoles to unsymmetrical silyloxyallyl cations are reported.

255 alpha'-hydroxy silyl enol ethers to generate unsymmetrical silyloxyallyl cations that were subsequent

256 n dynamic, letter-shaped and compositionally unsymmetrical single rings, complex multi-ring systems,

257 Metal-free near-infrared (NIR) active unsymmetrical squaraine dyes, RSQ1 and RSQ2, with benzod

258 Because of the unsymmetrical structure of both the wheel and the axle,

259 d the COSMO solvent model also give a planar unsymmetrical structure.

260 gn and synthesis of two novel dications with unsymmetrical structures and their utilization for anion

261 d that is well suited for the preparation of unsymmetrical structures.

262 s (4 and 5, R = 2,4,6-(i)Pr(3)C(6)H(2)) with unsymmetrical substitution patterns (including Si, SiR,

263 a for 7a,b,and 8a are consistent with highly unsymmetrical substrate coordination and substantial pol

264 We extended our study to unsymmetrical substrates and compare the results with ex

265 selective and enantioselective silylation of unsymmetrical substrates was also achieved in the presen

266 ver, the regioselectivity is often poor with unsymmetrical substrates.

267 t has been accomplished yielding substituted unsymmetrical succinic acid derivatives.

268 Regioselective alkylation of an unsymmetrical succinic anhydride and a profound effect o

269 0 W) at 120 degrees C for 10 min to give the unsymmetrical sulfamides 4a-c (80-90%).

270 antioselective Ti(IV)-catalyzed oxidation of unsymmetrical sulfides to sulfoxides with high selectivi

271 ion and the dynamics of the ring flip of the unsymmetrical t-CHP ring and the observed NMR shifts and

272 A total of 13 new, unsymmetrical target compounds were synthesized, as well

273 promoted by the oxidative electrocoupling of unsymmetrical tetra(hetero)arylborates (TABs) prepared f

274 In their studies, Hoye found that unsymmetrical tetraynes selectively form a single aryne.

275 termediates were applied to the synthesis of unsymmetrical tetrazines through Pd-catalyzed cross-coup

276 an potentially be integrated into the target unsymmetrical thioether final products.

277 -free, one-pot strategy for the synthesis of unsymmetrical thioethers.

278 Nevertheless, a diverse range of unsymmetrical tri- and tetrasubstituted cyclobutane stru

279 or the success of these reactions which form unsymmetrical tri- and tetrasubstituted cyclobutanes thr

280 In the present account we describe unsymmetrical triads constructed from extended borondipy

281 so been demonstrated through construction of unsymmetrical triaroylbenzenes functionalized with only

282 lly and synthetically important indole-based unsymmetrical triarylmethanes using indoles and aldehyde

283 in the analogous methanesulfenyl cases, are unsymmetrical trigonal bipyramidal, with the nucleophile

284 The unsymmetrical tris(imidazolium) salt H3-1(Br)3, featurin

285 eagents results in formation of a completely unsymmetrical trisubstituted BODIPY.

286 (type I) transition structures (TSs), novel unsymmetrical TSs were found in which the Li is coordina

287 applied to the synthesis of (a)chiral bulky unsymmetrical unsaturated 2,6-diisopropylphenyl N-hetero

288 The unsymmetrical (unsym) arrangement of the dppv ligands is

289 ep cyclization reaction involving amino acid unsymmetrical urea A and carboxy-imidazolyl-dipeptide es

290 versatile intermediates in the synthesis of unsymmetrical urea-linked disaccharides and trisaccharid

291 apped by various amines and alcohols to make unsymmetrical ureas and carbamates, respectively.

292 rapid (1-5 min) construction of an array of unsymmetrical ureas in good to excellent yields.

293 ith amines cleanly and irreversibly and give unsymmetrical ureas in high yield and purity.

294 very convenient method for the synthesis of unsymmetrical ureas is described, based on isopropenyl c

295 ave-accelerated, one-pot tandem synthesis of unsymmetrical ureas via a Curtius rearrangement.

296 satile intermediates for the construction of unsymmetrical ureas, carbamates, thiocarbamates and amid

297 erived auxiliary is a promising component of unsymmetrical variants, yet access remains limited.

298 The Fe-H...Ni center is unsymmetrical with r(Fe-H) = 1.51(3) A and r(Ni-H) = 1.7

299 (3), X = I (4), X = NO2 (5), X = CN (6)) and unsymmetrical (X = I, Y = MeO (7), Y = PhO (8)) para-dis

300 kynes (i.e., tolan and 3-hexyne) to give the unsymmetrical ziconacyclopentadienes Cp(2)Zr[2,4,5-Ph(3)