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1 Al(3+) chelation increased absorbance 2-42x and lambdama
3 effects of chelation of metal ions (Mg(2+), Al(3+), Cr(3+), Fe(3+), and Ga(3+)) in factorial excesse
4 different semiconductors, Mg2Si, Si0.8Ge0.2, Al(x)Ga(1-x)As and clathrate Si46-VIII were studied, whi
5 ore the last addition of stellar-derived (26)Al has not been identified yet but may be preserved in p
7 e-crystal X-ray diffraction and show by (27) Al NMR spectroscopy, electrospray-ionization mass spectr
11 works with other Lewis acids (such as B(3+), Al(3+) and Sn(4+)) and can be applied to other 2D materi
12 ysis of the precursor complex [(HEB)Re(CO)3][Al(OR(f))4] (15) in the presence of the added alkane.
16 grain boundaries in aluminium alloy AA5083 (Al-Mg-Mn) during isothermal exposures is proposed herein
19 ield strength of the corresponding peak-aged Al alloy at ambient temperature and 14 times higher at 4
20 or Earth's most abundant mineral, (Mg,Fe,Al)(Al,Fe,Si)O3 bridgmanite (also known as silicate perovski
22 complexes of the type [(HEB)Re(CO)2(alkane)][Al(OR(f))4] (HEB = eta(6)-hexaethylbenzene; alkane = cyc
24 Al and 85Al alloys, and [am] --> [am + alpha-Al + cubic AlxMy (M = Y, Ni, Co, Fe, Pd)] --> [am + alph
25 e heating-induced reversion from [am + alpha-Al + multicomponent AlxMy] to [am + alpha-Al] for the 84
26 xMy (M = Y, Ni, Co, Fe, Pd)] --> [am + alpha-Al] --> [alpha-Al + Al3Y + Al9(Co, Ni)2 + unknown phase]
27 llization sequences are [am] --> [am + alpha-Al] --> [alpha-Al + compounds] for the 86Al and 85Al all
28 ha-Al + multicomponent AlxMy] to [am + alpha-Al] for the 84Al alloy is abnormal, not previously obser
29 is encouraging for obtaining the [am + alpha-Al] mixture over a wide range of high temperature effect
30 Co, Fe, Pd)] --> [am + alpha-Al] --> [alpha-Al + Al3Y + Al9(Co, Ni)2 + unknown phase] for the 84Al a
31 nces are [am] --> [am + alpha-Al] --> [alpha-Al + compounds] for the 86Al and 85Al alloys, and [am] -
33 he heterogeneous nucleation of primary alpha-Al crystals and reduces the undercooling needed for soli
34 terogeneous particles, the size of the alpha-Al crystals was found to be less dependent on the proces
35 w pH solubilizes root-toxic ionic aluminium (Al(3+)) species from clay minerals, driving the evolutio
36 (Co), nickel (Ni), zinc (Zn), and aluminum (Al) concentrations in atmospheric deposition, likely via
38 te the physiological importance of aluminum (Al) phytotoxicity for plants, it remained unknown if, an
39 ntity possesses trans-planar geometry and an Al-Al bond length of 2.3943(16) A, which is the shortest
40 ardening Al-Zn-Mg(-Cu) matrix composites, an Al 7075 alloy composite reinforced with B4C particles wa
41 n, we present a new approach in designing an Al-based alloy through solid state precipitation route t
42 on of a stable neutral compound featuring an Al horizontal lineAl double bond stabilized by N-heteroc
44 udy and those from similar experiments on an Al-2Cu alloy were consistent when the alloy compositions
46 A highly selective fluoride optode using an Al(III) -porphyrin ionophore is examined as an initial e
47 organometallic reagents (Mg(CH2 SiMe3 )2 and Al(TMP)iBu2 ), key intermediates in this process have be
48 ew strategy to achieve reversible Mg(2+) and Al(3+) insertion in anatase TiO2, achieved through aliov
49 rtion of multivalent ions such as Mg(2+) and Al(3+) into electrode materials remains an elusive goal.
53 s Cu-ZSM-5 is characterized by severe Cu and Al aggregation into a copper aluminate phase (CuAl2O4 sp
54 ,000 mile simulation, Cu-SSZ-13 shows Cu and Al clustering, whereas Cu-ZSM-5 is characterized by seve
57 our different metal species (Zr, Cr, Fe, and Al) were successfully functionalized with oligonucleotid
59 atory mechanisms in legumes against H(+) and Al(3+) stresses, but also casts light on their role in m
61 lubility equilibrium controls on Fe(III) and Al and a commonly reported acceleration of the abiotic F
66 ere characterized by elevated V, Fe, Si, and Al concentrations, indicating the presence of inorganic
68 nes previously shown to underlie Arabidopsis Al tolerance via root malate exudation, known as SENSITI
71 in aluminium, especially cast alloys such as Al-Si alloys, is a matter of importance in order to achi
72 A temperature gradient is induced in a Au/Al dual-layer target by proton heating, and subsequent h
73 for Al thermal conductivity and LEOS for Au/Al release equation-of-state show good agreement with da
74 olecular mechanism in which either the basic Al(I) center or the transient Al horizontal lineNTol spe
77 ith the ALD procedure, assemblies bridged by Al(III), Sn(IV), Ti(IV), or Zr(IV) metal oxide units hav
78 e surface was determined to be terminated by Al-O species, and was significantly different from the i
80 s creates two new C-C bonds as well as one C-Al bond, which can be oxidized in situ with O2 or hydrol
81 itrate, into the soil rhizosphere, chelating Al(3+) ions and thereby imparting Al-resistance based on
82 e elements and heavy metals (Cd, Cr, Cu, Co, Al, Zn, As, Pb and Fe) in 22 varieties of cooked rice us
83 nanowires in conjunction with sputter-coated Al-doped ZnO (AZO) thin films were used as a composite t
84 erformance of powder metallurgy-consolidated Al composites reinforced with either IF- or 2H-WS2 parti
87 (AlIII) and CH2 bound to a four-coordinated Al (AlIVb) are the precursors of the most active sites f
88 , favored at low values of both Si:Al and Cu:Al ratios, inhibit the material performance by being ina
89 rains in ZnO films is achieved by depositing Al at 100 degrees C with a surface roughness 9.2 nm, wh
90 us an advance in developing highly desirable Al-based BMGs, and also provides guidance for designing
91 , the dissolution method produces a discrete Al cluster on a scale suitable for studies and applicati
92 esults highlight the importance of dissolved Al for amplifying the toxicity of transition metals to h
95 butions of Cu as well as framework elements (Al, O, Si) in both fresh and aged Cu-SSZ-13 and Cu-ZSM-5
97 to the unusual 3DOM structure, which ensures Al and Mn2O3 to integrate compactly in nanoscale and gre
101 ologies, specifically for B-(18)F, Si-(18)F, Al-(18)F, and iodine (III)-mediated radiofluorination vi
102 ta for Earth's most abundant mineral, (Mg,Fe,Al)(Al,Fe,Si)O3 bridgmanite (also known as silicate pero
103 vent as early as 4.564 Ga in which the first Al-Cu-Fe alloys formed; and, second, a more recent impac
104 tion of triclusters and a 4-, 5-, and 6-fold Al-O coordination, as observed in previous studies.
105 ear working range of 0.07-100microgL(-1) for Al(III), and 0.05microgL(-1) in linear working range of
109 Further, substitution of only 1% Fe(III) for Al(III) in the structure of boehmite inhibited delaminat
112 using Purgatorio model or Sesame S27314 for Al thermal conductivity and LEOS for Au/Al release equat
114 The Al-TiO2 nanoparticles prepared from Al(NO3)39H2O exhibit the best photocatalytic activity am
116 Their emission was compared to that from Al/AlOx/Au tunnel junctions, which has been previously a
117 f boehmite (gamma-AlOOH) and gibbsite (gamma-Al(OH)3) were compared and contrasted in real time via l
118 he light absorption ratio for nanometer GeSn/Al foil heterostructures can be enhanced up to 85%.
120 g complexes 5 and 7 are stabilized by Pt-H-->Al and Pt-NH-C(Ph) = O-->Al bridging interactions, resul
121 tabilized by Pt-H-->Al and Pt-NH-C(Ph) = O-->Al bridging interactions, resulting in 5- and 7-membered
122 dianion in [{((Dep) Nacnac)Mg}2 (mu-H)]2 [H3 Al-AlH3 ] ((Dep) Nacnac=[(DepNCMe)2 CH](-) , Dep=2,6-die
123 nto precipitation phenomena in age-hardening Al-Zn-Mg(-Cu) matrix composites, an Al 7075 alloy compos
124 That deaggregation is coupled to heterolytic Al-H bond activation at the Ru-S bond, formally splittin
125 centrations were found in multifloral honey (Al, As, Be, Ca, Cr, Mn, Mo, Ni, Se, Th and U), common he
126 n through adsorption to aluminium hydroxide (Al) is a promising option, and establishing its effectiv
128 ago by the astronomer and mathematician Ibn Al-Haytham and was forcefully restated 150 years ago whe
129 ing Lewis acidity, including Ni(II), Zn(II), Al(III), Ti(IV) and Mo(VI), are anchored as metal-oxide,
130 chelating Al(3+) ions and thereby imparting Al-resistance based on excluding Al(+3) from the growing
132 f atomic-layer-deposited Al2O3 thin films in Al/Al2O3/Al trilayers can recover after the breakdown.
135 nchrotron-based hard X-ray nanotomography in Al-Cu alloys to measure kinetics of different nanoscale
136 h as tripling the critical temperature TC in Al-Al2O3 epsilon near zero (ENZ) core-shell metamaterial
137 Similar to fcc-to-hcp transformations in Al and the noble gases, the transformation is sluggish,
138 ure of 10(-10) Torr, but rather an increased Al-O occupancy occurred, which was accompanied by a larg
142 peak after the year 2100, predicted free ion Al, Fe, Cu, and Pb concentrations increase by factors of
143 K, Mg, and Na, as well as the foreign ions (Al, Cu, Fe, Mn, Zn) to the solution on the in situ atomi
144 INTERPRETATION: The lowest dose (1/10 IPV-Al) of the vaccine performed well both after two and thr
146 2), and 98.5% (n=202, type 3); and 1/10 IPV-Al: 98.5% (n=201, type 1), 94.6% (n=193, type 2), and 99
147 /5 IPV-Al], ten-times reduced dose [1/10 IPV-Al], or IPV) intramuscularly in the thigh at 6, 10, and
148 programme of immunisation schedule): 1/3 IPV-Al 98.5% (n=202, type 1), 97.6% (n=200; type 2), and 99.
149 05 were randomly assigned to receive 1/3 IPV-Al, 205 to receive 1/5 IPV-Al, 204 to receive 1/10 IPV-A
150 mulations (three-times reduced dose [1/3 IPV-Al], five-times reduced dose [1/5 IPV-Al], ten-times red
151 o receive 1/3 IPV-Al, 205 to receive 1/5 IPV-Al, 204 to receive 1/10 IPV-Al, and 206 to receive IPV.
152 type 2), and 99.5% (n=204, type 3); 1/5 IPV-Al: 99.5% (n=204, type 1), 96.1% (n=197, type 2), and 98
153 /3 IPV-Al], five-times reduced dose [1/5 IPV-Al], ten-times reduced dose [1/10 IPV-Al], or IPV) intra
156 2, and 3 was already high for the three IPV-Al vaccines after two vaccinations, but was higher after
161 ed site and these two types of extra-lattice Al-OH species, and it also reveals unexpected proton exc
164 The reduction of pH leads to much lower Al, V, and As mobility in the actively treated residue a
168 the type M[(mu-OH)2 Co(NH3 )4 ]3 (NO3 )6 (M=Al, Ga) can be synthesized using Werner's century-old cl
169 linity or impurities such as organic matter, Al or Si, persisted under suboxic-oxic conditions in the
170 e and Fe-Si metal, and oxidation of metallic Al to Al2O3, occurring where silicate melt was in contac
171 ion of twenty-seven elements (Li, Be, B, Mg, Al, P, K, Ca, Cr, Mn, Co, Ni, Cu, Zn, As, Se, Sr, Mo, Cd
176 The first reversible capacity of EG-MNPs-Al as anode material for lithium ion battery was 480 mAh
177 d less Al-chelating malate, accumulated more Al, and displayed a severe root growth reduction in resp
180 grain boundary migration in nanocrystalline Al films with the excess of O atoms at the boundaries.
181 igate the effects of aluminum nanoparticles (Al NPs) prepared by sonication of aluminum foil on the U
182 conventional s-wave superconductor (e.g. Nb, Al) and either strongly spin-polarized ferromagnetic ins
184 create a class of steels, strengthened by Ni(Al,Fe) precipitates, with a strength of up to 2.2 gigapa
187 icating the distribution of Si(-O-Si)4-n (-O-Al)n species is spatially biased as opposed to being ran
189 n only be modeled with a few combinations of Al positioning at tetrahedral sites in the crystal unit
190 he formation of anionic chelate complexes of Al(III) and Cr(VI) with o-hydroxy azo dye, at pH 6.5, an
192 on and subsequent intergranular corrosion of Al-5.3 wt.% Mg alloy has been shown to be an important f
194 ty loading at the site, and the depletion of Al mineral buffering capacity after approximately 5 year
197 successfully applied to the determination of Al and Cr in vegetables using standard addition method.
202 h temperature effective for the formation of Al-based high-strength nanostructured bulk alloys by war
205 Our study shows that the inoculation of Al-10Si braze alloy with these compounds effectively pro
208 er, is inserted between a top layer, made of Al/polydimethylsiloxane, and a bottom layer, made of Al.
210 ussed here investigate the shock response of Al microstructures comprising of grain sizes ranging fro
211 vatives on color expression and stability of Al(3+) and Fe(3+) chelates in pH 6-7 were evaluated by s
212 attempt was made to enhance the strength of Al-6wt%Si-2wt%Fe model recycled cast alloy with differen
216 urements show that the elastic behaviour of (Al,Fe)-bearing bridgmanite is markedly different from th
217 Hence, with the required combination of [Al] and [B], a highly selective hydrosilylative reductio
218 Finally, transparent conductors based on Al-doped Ag possess both a high and flat transmittance o
220 we report single-crystal elasticity data on (Al,Fe)-bearing bridgmanite (Mg0.9Fe0.1Si0.9Al0.1)O3 meas
222 ion of a Lewis acid (e.g., E(C6F5)3 E = B or Al) with a small molecule substrate and decamethylferroc
224 nsist of densely packed LixM (M = Si, Sn, or Al) nanoparticles encapsulated by large graphene sheets.
227 oduced the general patterns of salinity, pH, Al, and Fe during an uncontrolled river breach in 2011,
228 Cp*2Fe][PhSB(C6F5)3] 1 and [Cp*2Fe][(mu-PhS)(Al(C6F5)3)2] 2 and [Cp*2Fe][(mu-PhTe)(Al(C6F5)3)2] 3, re
230 cate glass cross-cutting lower melting-point Al-Cu-Fe alloys, as well as unambiguous evidence of a re
233 o Al (2Al sites) is consistent with a random Al siting in the SSZ-13 lattice subject to Lowenstein's
234 y and the tensile properties of the recycled Al-Si alloys due to the presence of the Fe containing in
235 s, that mu-methylene structures (Al-CH2-ReO3-Al) containing a Re horizontal lineO bound to a tricoord
236 n strength due to addition of Cu, in Fe-rich Al-Si alloys is promising from the alloy recyclability p
239 cant differences in the amounts of Na, K, S, Al, Mn, Ni, As and Cd were observed between conventional
244 extraction of zeolite framework cations (Si, Al) on a faujasite-type zeolite, the archetype of molecu
246 nthesis protocols applied here and across Si:Al ratios, the volumetric density of six-membered-rings
247 ites in 6r, favored at low values of both Si:Al and Cu:Al ratios, inhibit the material performance by
248 can be explained by the formation of soluble Al-F complexes and some dissolution of the Al(OH)3 preci
249 calculations, that mu-methylene structures (Al-CH2-ReO3-Al) containing a Re horizontal lineO bound t
251 Crack-free semi-polar [Formula: see text] Al x Ga1-x N epilayers with AlN contents up to x = 0.56
254 ced bioimaging methods and genetic show that Al(3+) misfolds cell membrane proteins, while Fe(2+) evo
255 cal analysis of AMZ and bacteria showed that Al, P, and transition metals (Fe, Cu, Mn, and Zn) were e
256 of membrane permeabilization, suggests that Al reacts with membrane phospholipids, enhancing intrace
259 cial role of the substrate structure and the Al(OtBu)3 additive on the kinetics and thermodynamics of
261 e through-plane thermal conductivity and the Al/TMD interface conductance depend on the modulation fr
262 ula: see text] to [Formula: see text] as the Al-concentration increased, and for Mg-Zn alloys, this d
264 P was observed at the interface between the Al matrix and eutectic Si, strongly indicating that P, i
265 ur kinds of samples, followed in turn by the Al-TiO2 nanoparticles prepared with AlCl3, Al2(SO4)318H2
266 oxygen pressure to 10(-6) Torr enriched the Al site occupancy fraction at the outermost surface from
267 cal ordering, and by selectively etching the Al and Sc atoms, we show evidence for 2D Mo1.33C sheets
269 n), may have nucleated on the surface of the Al matrix and thereby enhanced the heterogeneous nucleat
272 xperimental evidence on the influence of the Al-induced atomistic configurational change on the mecha
273 the present thermodynamic description of the Al-Si-Fe-Cu system needs finer tuning to accurately pred
276 d Fe-Si beads, aluminous spinel rinds on the Al-Cu-Fe alloys, and Al2O3 enrichment in the silicate me
278 The new evidence firmly establishes that the Al-Cu-Fe alloys (including quasicrystals) formed in oute
279 bsequent heat flow from the hotter Au to the Al rear surface is detected by two simultaneous time-res
285 ments show that this species is proximate to Al atoms, similar to the Bronsted acid site proton.
288 ansparent conducting oxide nature of the top Al:ZnO film can be tuned to facilitate the fine control
289 ther the basic Al(I) center or the transient Al horizontal lineNTol species deprotonates the methyl g
290 e horizontal lineO bound to a tricoordinated Al (AlIII) and CH2 bound to a four-coordinated Al (AlIVb
291 y of six-membered-rings (6MR) containing two Al (2Al sites) is consistent with a random Al siting in
292 rbolic metamaterials consisting of ultrathin Al-doped Ag films are attained having a homogeneous and
293 ad less root growth than the wild type under Al(3+) stress, and seedlings were chlorotic under Fe-def
294 mass and composition was investigated using Al-referenced enrichment factors (EFs) and source factor
295 based on VACNT grown on aluminum foil (VACNT-Al foil) with poly (9,9-di-(2-ethylhexyl)-fluorenyl-2,7-
296 rect interaction of the bacterial cells with Al NPs and elucidate the nanoshielding mechanism via UV
299 glass/indium tin oxide/NiO(x)/perovskite/ZnO/Al), in which the ZnO layer isolates the perovskite and
300 ll-inorganic solar cells (ITO|NiOx |BiOI|ZnO|Al) with negligible hysteresis and up to 80% external qu
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