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1 (PAH) luminophores and boron dipyrromethene (BODIPY).
2 ith the fluorescent dyes Alexa-Fluor 488 and Bodipy.
3 of a completely unsymmetrical trisubstituted BODIPY.
4 hearts were examined for presence of NPs and BODIPY.
5 ttached to the aryl at the meso positions of BODIPY.
6 t impact on J-aggregates and fluorescence of BODIPYs.
7 -S) cross-coupling reaction of the Biellmann BODIPYs (1a,b) and aryl- and heteroarylboronic acids in
12 The tetraphenylethylene (TPE) substituted BODIPY 2a, and 2,3,3-triphenylacrylonitrile (TPAN) subst
17 ,3-triphenylacrylonitrile (TPAN) substituted BODIPYs 2b and 2c were designed and synthesized by the P
19 various analytes revealed that the azido-aza-BODIPY 3a selectively interacts with hydrogen sulfide (H
22 interactions, meso-(4-pyridinyl)-substituted BODIPY (4,4-difluoro-4-bora-3a,4a-diaza-s-indacene) dyes
26 tivation, staining intracellular lipids with BODIPY(505/515), and FACS-based isolation of top 0.5% li
31 o-glycolic acid) (PLGA) NPs were loaded with BODIPY, a fluorophore, and percutaneously administered i
32 ensitizers derived from thieno-pyrrole-fused BODIPY (abbreviated as SBDPiR) and fullerene, C60 have b
33 le light where the two dye molecules (Ru and Bodipy) absorb with equal probability leads to the coope
34 l transformation shifts bathochromically the BODIPY absorption and permits the selective excitation o
35 lectrophiles, we have designed a fluorogenic BODIPY-acrolein probe, AcroB, that undergoes a >350-fold
41 in the literature that describes the use of BODIPY analogs for detecting alkaline phosphatase (ALP)
44 n the L-S reaction to give the corresponding BODIPY analogues in short reaction times and also with g
47 their corresponding BF2-chelated derivatives BODIPY and aza-BODIPY, respectively, are well known for
48 udies indicated a weak interaction among the BODIPY and azaBODIPY moieties and the moieties retain th
49 mphiphilic arrays containing PEG-substituted BODIPY and chlorins or bacteriochlorins were prepared an
50 gid structural conformation of the precursor BODIPY and the high reactivity of its 1,7-bromo groups.
51 are the sum of the individual chromophores (Bodipy and the PtN2S2 moieties), indicating little elect
52 l-2,6-diethyl-4-bora-3a,4a-diaza-s-indacene (Bodipy) and a Ru(II)(bipyridine)3 (Ru) derivative-which
53 ed fluorophore such as boron-dipyrromethene (BODIPY) and BF2-smaragdyrin under mild Pd(0) coupling co
54 t, IYIY-diiodo-boron-dipyrromethene (IYIY-I2-BODIPY) and its scrambled counterpart YIYI-I2-BODIPY hav
56 regioselectively from 2,3,5,6,8-pentachloro-BODIPY, and characterized by NMR spectroscopy, HRMS, and
58 pression analysis, dihydroethidium staining, BODIPY, and quantification of intracellular triglyceride
59 observed for all the aforementioned PAHs and BODIPY, and the rubrene and BODIPY emulsion systems show
60 complexes, A3-, A2B- and AB2-type corroles, BODIPYs, and their dipyrrane precursors was studied util
61 d antioxidant (chromanol) and prooxidant (Br-BODIPY) antagonistic chemical activities of the two-segm
67 For both series of arrays, excitation of BODIPY at 500 nm results in efficient energy transfer to
70 he Fe(III)-induced fluorescence quenching of BODIPY-ATP can be paired with its ALP-mediated dephospho
74 of BODIPY-conjugated adenosine triphosphate (BODIPY-ATP) was quenched by Fe(III) ions through photoin
76 fluorescence quantum yields and lifetimes of BODIPY attached to the two S16 homologs decreased gradua
77 of the fluorescence quenching efficiency of BODIPY-AuNPs in the presence of thiols can achieve a lar
79 vatives, with absorption between 500-700 nm, BODIPY-bacteriochlorin arrays should allow for construct
81 physicochemical properties of a new class of BODIPY-based donor-acceptor pi-conjugated polymers are p
83 , we report synthesis and application of new BODIPY-based hydrophobic sensors (HPsensors) that are st
85 nt charge-transport improvement (>10000x) in BODIPY-based polymeric semiconductors, demonstrating its
86 We have designed a low fluorescent azido-BODIPY-based probe AzBOCEt (Az10) that undergoes copper(
89 c substitution and led to the isolation of F-BODIPYs bearing terminal bromovinyl and enol substituent
91 ctron donating group at the meso position of BODIPY blue shifts the absorption and emission with decr
92 th alcohols and phenols can be tagged with a BODIPY (borondipyrromethene) moiety to yield highly fluo
93 aterials bear close structural similarity to BODIPYs but differ significantly in electronic configura
94 me imaging microscopy of the molecular rotor BODIPY C10 in the membranes of live Escherichia coli bac
95 ppressive conventional chemotherapy, IYIY-I2-BODIPY can act as an immune-stimulatory chemotherapeutic
96 72 nm, Phi(F) = 19% for 7) from those of the BODIPY-carboxaldehydes 2b (lambda(abs) = 643 nm and lamb
97 reaction is an interesting synthetic tool in BODIPY chemistry, mainly because it allows a valuable re
98 t here the synthesis and characterization of BODIPY-chlorin arrays containing a chlorin subunit, with
99 t the difference in lateral diffusion of the BODIPY-cholesterol probes was not caused by anomalous su
100 ce of thiols, meso-(4-pyridinyl)-substituted BODIPY chromophore were displaced and released from the
103 ive compounds combine a borondipyrromethene (BODIPY) chromophore and a photocleavable oxazine within
104 carbon monoxide-releasing molecules based on BODIPY chromophores (COR-BDPs) activatable by visible-to
105 ylbutadiene-conjugated or styrene-conjugated BODIPY chromophores (PBD-BODIPY or STY-BODIPY, respectiv
106 s were instead observed between at least two BODIPY chromophores along the edges of the cages, arisin
107 ultrafast dynamics of electronically excited BODIPY chromophores could lead to further advances in th
108 e report a set of Fe(II)4L6 cages containing BODIPY chromophores having tuneable photosensitizing pro
109 ompare the ultrafast dynamics of halogenated BODIPY chromophores through applying two-dimensional ele
110 able regioselective postfunctionalization of BODIPY chromophores with different functional groups.
115 ht-activated release of bioactive compounds (BODIPY, colchicine, paclitaxel, and methotrexate) from m
117 BODIPY-maleimide provided a dye-labeled pOEG-BODIPY conjugate with a lower critical solution temperat
118 is study discovered that the fluorescence of BODIPY-conjugated adenosine triphosphate (BODIPY-ATP) wa
122 DIPY (weak response) at 10 mg/kg, but not I2-BODIPY control, increased the levels of IL-2, IL-4, IL-6
125 l planar N atoms which are coplanar with the BODIPY core; 4 exhibits a very significant distortion th
126 based on a ring-fused boron-dipyrromethene (BODIPY) core that is conjugated to a polyglycerol dendri
128 aration of the labeled antimicrobial peptide BODIPY-cPAF26 by solid-phase synthesis (6-7 d) and its s
129 an example, we include a procedure for using BODIPY-cPAF26 for wash-free imaging of fungal pathogens,
133 ready precursors of ortho-substituted 8-aryl BODIPY derivatives by reaction with borontrifluoride eth
134 t synthesis of a new class of conjugated aza-BODIPY derivatives from readily available precursors has
135 absorbing and emitting bacteriochlorin, and BODIPY derivatives with different absorption bands in th
136 we synthesized three novel NIR absorbing aza-BODIPY derivatives, 3a-3c, and have systematically tuned
140 A and pore-network development and increased BODIPY diffusion coefficient, resulting in faster releas
141 he masking strategy was used to synthesize a BODIPY dimer by McMurry coupling of a formyl Et2B-BODIPY
142 New dyads consisting of a strongly absorbing Bodipy (dipyrromethene-BF2) dye and a platinum diimine d
143 ants exhibited a decrease in the average Trp-BODIPY distance at up to 100 mg/mL dextran 20, whereas t
144 ermo mutants did not show any changes in Trp-BODIPY distances upon increase of dextran 20 concentrati
145 he different regions of the heart influenced BODIPY distribution, with fluorophore penetrating more r
150 metric photoacoustic imaging by using an aza-BODIPY dye scaffold exhibiting two spectrally resolved N
151 applies to a maleimide derivative carrying a BODIPY dye which was chosen for its fluorescence to be o
152 t example of the use of a molecular rotor, a BODIPY dye, to quantitatively visualize the viscosity of
155 study on donor/acceptor borondipyrromethene (BODIPY) dye-labeled cavitands present in the vase and ki
159 ith the outstanding absorption properties of BODIPY dyes lead to photocages with uncaging cross secti
160 tecting groups derived from meso-substituted BODIPY dyes release acetic acid with green wavelengths >
161 -PMHC and related bromo and iodo-substituted BODIPY dyes show that the trap segment provides a total
162 ugh the judicious functionalization, the aza-BODIPY dyes thus synthesized can be utilized for the sen
165 sorption and fluorescence spectra of the aza-BODIPY dyes with the change in substitution from azido (
166 lified by the preparation of a series of new BODIPY dyes with unprecedented substitution patterns all
167 lectron deficient backbones, the BF2 unit of BODIPY dyes, and AlF or GaF3 units coordinated to multid
169 Fluorescent dithienyl-borondipyrromethene (BODIPY) dyes formylated in the beta'-position (2b, 2c) h
170 nstructed from extended borondipyrromethene (BODIPY) dyes, diketopyrrolopyrrole (DPP) dyes, and elect
171 helated tetraarylazadipyrromethene dyes (aza-BODIPYs) dyes physically entrapped in polyurethane hydro
172 ntioned PAHs and BODIPY, and the rubrene and BODIPY emulsion systems showed adequate light to record
177 ysis kinetics and were active in hydrolysing BODIPY-FL casein to varying extents at postmortem aging
179 reduction to the hydroquinone form, B-VKQH2, BODIPY fluorescence is restored, with emission quantum y
180 n thinner sheet packages which still exhibit BODIPY fluorescence right at the rim of these packages.
181 ting principles allow the photoactivation of BODIPY fluorescence with large brightness and infinite c
182 py)(H2O)3][O2CCH3] (1), which incorporates a bodipy fluorescent tag, was prepared and studied by conf
184 a spacer-free C-C linkage between Trp and a BODIPY fluorogen, which shows remarkable fluorescence en
186 curring lipid soluble antioxidant, while the BODIPY fluorophore and TPP ensure partitioning within th
187 apabilities of this system introduction of a BODIPY fluorophore as a secondary functionality was perf
189 an alpha-tocopherol-like chromanol moiety, a BODIPY fluorophore, and a triphenylphosphonium cation (T
191 ne redox center), to a boron-dipyrromethene (BODIPY) fluorophore (a lipophilic reporter segment).
192 oquinone, coupled to a boron-dipyrromethene (BODIPY) fluorophore segment that both imparts lipophilic
193 es can guide future design of functionalized BODIPYs for various applications, including bioimaging a
194 g cleaves irreversibly to bring the adjacent BODIPY fragment in conjugation with an indole heterocycl
196 ar weight (Mw), water uptake, mass loss, and BODIPY (green-fluorescent dye) diffusion coefficient in
199 lar cycloaddition yielding the first corrole-BODIPY heterodimer involving the pentafluorosulfanyl gro
200 that the 2,2'-bipyridine spacer of each bpy-BODIPY homologue does not facilitate efficient electroni
203 led distinct tyrosine quenching behaviors of BODIPY in the three variants, suggesting a dynamic local
204 action was employed to synthesize conjugated BODIPYs in high yields by treating formylated BODIPYs wi
206 efficiently, and we prepared 12 substituted BODIPYs including cholesterol-substituted BODIPYs to dem
207 monstrated on the basis of selected starting BODIPYs, including polyhalogenated and/or asymmetrical s
209 cedures (e.g., asymmetrically functionalized BODIPYs involving halogenated positions) can now be made
211 ositions of chlorin, and a second type where BODIPY is attached at the 10-position of chlorin through
212 ontrast to this, some of the arrays in which BODIPY is attached at the 3- or at both 3,13-positons of
214 this work, the energy donor moiety (distyryl-BODIPY) is connected to a photosensitizer (i.e., diiodo-
217 stances between an intrinsic Trp residue and BODIPY-labeled S16Meso depend on the level of the crowdi
220 bioconjugates brought clear evidence that Tb-Bodipy localized in the endoplasmic reticulum (ER) of va
222 frared (NIR) thanks to delocalisation of the BODIPY low-lying lowest unoccupied molecular orbital (LU
223 new emissive species is formed from the bpy-BODIPY luminophores during the annihilation process.
224 End-group modification with fluorescent BODIPY-maleimide provided a dye-labeled pOEG-BODIPY conj
226 Two types of arrays were examined: one where BODIPY moieties are attached through a phenylacetylene l
228 containing one or the other of two distinct BODIPY moieties, as well as mixed cages that contain bot
229 4,4-difluoro-4-bora-3a,4a-diaza-s-indacene (BODIPY) moieties, which we symmetrically conjugate with
231 ies higher than that in the reference dyads (Bodipy-NDI and TAPD-Ru), leading to the energy efficienc
232 tude compared to that in the reference dyads Bodipy-NDI and TAPD-Ru, as it passes from about 3 ns in
234 is of the fluorogenic amino acid Fmoc-Trp(C2-BODIPY)-OH (3-4 d), the preparation of the labeled antim
235 rp)-based fluorogenic amino acid Fmoc-Trp(C2-BODIPY)-OH and its incorporation into peptides for live-
237 styrene-conjugated BODIPY chromophores (PBD-BODIPY or STY-BODIPY, respectively) as signal carriers t
240 ditive, for example, a 2,6-diiodo-B-dimethyl BODIPY photocage features quantum yields of 28% for the
241 and photochemical reactivity of meso-methyl BODIPY photoremovable protecting groups was accomplished
242 on that breaks the planarity of the extended BODIPY pi system due to the steric impact of the two eth
243 attempt to develop photostable and efficient BODIPY (PM) dyes for use in liquid dye lasers, three new
244 d AzG-1, a cyclooctyne- and azide-containing BODIPY probe, respectively, which specifically label int
245 4'-di fl uoro-4-bora-3a,4a-diaza-s-indacene (BODIPY) probes is systematically investigated to demonst
247 th a variety of azido derivatives, including Bodipy, pyrene and ferrocene, was carried out first.
248 the origin of this decrease, we studied the BODIPY quantum yield in three protein variants in the pr
249 imple (small, nonaggregated, nonpolymeric) O-BODIPYs (R)-1 and (S)-1 by irradiation with visible ligh
250 on withdrawing group at the meso position of BODIPY red shifts the absorption and emission with enhan
251 f the final charge-separated state (oxidized Bodipy/reduced Ru) in the tetrad lies higher than that i
252 gated BODIPY chromophores (PBD-BODIPY or STY-BODIPY, respectively) as signal carriers that co-autoxid
253 ding BF2-chelated derivatives BODIPY and aza-BODIPY, respectively, are well known for fluorescence-ba
257 is is caused by intensity borrowing from the BODIPY states, which increases the squared transition mo
262 atment with BF3.Et2O gives a 3,5,8-trichloro-BODIPY that readily undergoes regioselective Stille coup
263 ed large functional groups including biotin, BODIPY, thiazole orange, and Cy7 through a polyethylene
266 methane-tetramethylrhodamine-(+/-)CGP 12177 (BODIPY-TMR-CGP)] at the human beta1-adrenoceptor express
267 an efficient (>/=0.80) energy transfer from BODIPY to the chlorin moiety in both toluene and DMF and
268 ed BODIPYs including cholesterol-substituted BODIPYs to demonstrate the versatility of the reaction.
269 nd chemoselective route for transforming BF2-BODIPYs to Et2B-BODIPYs (masking) was developed using Et
271 f a lipophilic fluorogenic antioxidant (Mito-Bodipy-TOH) that targets the inner mitochondrial lipid m
273 optive transfer of immune cells from IYIY-I2-BODIPY-treated survivor mice that were photoirradiated g
274 the fluorescent-dye conjugate, [S14R, W50Pra(Bodipy)]Ts1, we confirmed its binding to Nav1.4 through
275 ional groups was approached with a dual-mode BODIPY-type fluorescence label, which allows quantificat
277 supported an efficient energy transfer from BODIPY unit(s) to azaBODIPY unit in dyads and triads.
278 BODIPY-(BODIPY)2 triad revealed that the two BODIPY units were in perpendicular orientation with azaB
279 stepwise methodology for polychlorination of BODIPY using trichloroisocyanuric acid (TCCA) in acetic
282 as further reacted with an azido-substituted BODIPY via the copper(I)-catalyzed 1,3-dipolar cycloaddi
284 s were mostly confined to epicardial layers, BODIPY was capable of penetrating into the myocardium, r
287 chelated tetraarylazadipyrromethene dye (aza-BODIPY) was incorporated into the polyvinylpyrrolidone s
288 IYIY-I2-BODIPY (strong response) and YIYI-I2-BODIPY (weak response) at 10 mg/kg, but not I2-BODIPY co
289 diphenylanthracene, pyrene, or perylene) and BODIPY were trapped in a toluene and tri-n-propylamine m
290 w fluorescence quantum yields, the push-pull BODIPYS were effective for cell imaging, readily accumul
293 xisome abundance using the small probe Nitro-BODIPY, which in vivo fluoresces selectively inside pero
294 Y dimer by McMurry coupling of a formyl Et2B-BODIPY, while a new BODIPY with an asymmetrically substi
295 oupling of a formyl Et2B-BODIPY, while a new BODIPY with an asymmetrically substituted B-center was s
296 -diformyl BODIPYs or alpha-formyl 3-pyrrolyl BODIPY with different alkyl/aryl ylides in CH2Cl2 at roo
298 ODIPYs in high yields by treating formylated BODIPYs with alkyl/aryl ylides under simple room tempera
300 Three furan fused boron dipyrromethenes (BODIPYs) with a CF3 group on the meso-carbon are synthes
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