ライフサイエンスコーパス: C6H6

1 tallographic data for Tb2@C79N x Ni(OEP) x 2 C6H6 demonstrate the presence of an 80-atom cage with id

2 , which reduces benzene to make [(C5Me5)2U]2(C6H6), a U3+ complex formally containing a (C6H6)2- liga

3 iffraction on Gd3N@Cs(39663)-C82.NiII(OEP).2(C6H6) The carbon cage has a distinct egg shape because o

4 with benzyl potassium followed by [Cu(OTf)]2(C6H6) affords a tricopper(I) complex containing a bridgi

5 the arene to form ((iPr)PDI)Mo(NH3)2(eta(2)-C6H6).

6 and 5-p, two isomers of [(Ph2PC6H4)2B(eta(5)-C6H6)RuCl] (5), along with [Mes3PH][HB(C6F5)3].

7 m eta(6)-benzene complex ((iPr)PDI)Mo(eta(6)-C6H6) ((iPr)PDI, 2,6-(2,6-iPr2C6H3N horizontal lineCMe)2

8 nium(III) compound [UN''2]2(mu-eta(6):eta(6)-C6H6) (N''=N(SiMe3)2) has been studied using variable, h

9 6)-C7H8)] (3) and [Fe{((Dipp)C:)2CH2}(eta(6)-C6H6)] (4), selectively and in good yields.

10 (C6H6), a U3+ complex formally containing a (C6H6)2- ligand.

11 ich dynamics that contain bonded C4H4(+) and C6H6(+) structures solvated with one or more neutral ace

12 nglet excited states (S1 and S2) of benzene (C6H6) and square cyclobutadiene (C4H4) are investigated

13 yer and near-monolayer coverages of benzene (C6H6) on Au[111] at 4 K.

14 ction of boronyl radicals (BO) with benzene (C6H6).

15 e chromium tricarbonyl ion, BzCr(CO)3+ (Bz = C6H6).

16 also predicted for the parent complex, C6F6-C6H6, which is in contrast to predictions based on quadr

17 For the aromatic C6H7(+)/C6H6 and C5H6/C5H5(-) systems, geometric parameters and

18 refer to the benzenium ion/benzene (C6H7(+)/C6H6), the 2,4-cyclopentadiene/cyclopentadienyl anion (C

19 y of the chemical reactivity of PAH cations (C6H6+, C10H8+ and C16H10+) in the gas phase.

20 rystal structure of [(Mes)3Si][H-CB11Me5Br6].C6H6 (where Mes is 2,4,6-trimethylphenyl).

21 A cationic ruthenium hydride complex, [(C6H6)(PCy3)(CO)RuH](+)BF4(-) (1), with a phenol ligand w

22 )12, Ru6(CO)17(micro6-C), and Ru6(CO)14(eta6-C6H6)(micro6-C) without displacement of any of the ligan

23 , n = 1 (12), n = 2 (13), and Ru6(CO)14(eta6-C6H6)(micro6-C)[Pd(PBut3)]n, n = 1 (15), n = 2 (16), hav

24 s, but reduction of Cy-[H12]2+ using Cr(eta6-C6H6)2 resulted in the isolation of Cy-[H12]+.

25 iaromatic (S0 and S2 for C4H4, T1 and S1 for C6H6).

26 n of these states as aromatic (S0 and S2 for C6H6, T1 and S1 for C4H4) or antiaromatic (S0 and S2 for

27 rdment of a range of carbon projectiles from C6H6 to C180 is studied by a coarse-grained molecular dy

28 h produces benzene and hydrogen: 6CH4(g) --> C6H6(g) + 9H2(g) DeltaG degrees (r) = +433 kJ mol(-1) De

29 ,9b-dihydro-1H-cyclopropa[l]phenanthrene, in C6H6 (or C6D6), at ambient temperature, produces (alpha-

30 he intermolecular C-H activation reaction in C6H6 vs C6D6).

31 = {(2,6-iPr2C6H3)NC(R)}2CH; R = Me, tBu) in C6H6 results in the formation of [L(R)Ni(SCPh3)] (1: R =

32 the model systems (MeMMMe, PhMMPh, (MeMMMe)(C6H6)2, Ar(S)MMAr(S), Ar (#)MMAr(#); M = Cr, Fe, Co; Ar(

33 ters with n > 3, as well as other metastable C6H6(+) isomers.

34 mesitylazide react with [(dtbpe)Ni]2(eta2-mu-C6H6) to give the eta2 organic azide adducts (dtbpe)Ni(e

35 ffects on the CH activation with mixtures of C6H6/C6D6 (KIE = 1) and with 1,3,5-C6H3D3 (KIE approxima

36 shielding distributions in the S0 states of C6H6 and C4H4 represent aromaticity and antiaromaticity

37 ge with D2O shows that the proton remains on C6H6(.+) in the observed Bz(.+)(H2O)n clusters.

38 otoelimination decrease in CH3CN, CH2Cl2, or C6H6 due to competing cyclization of 8a,b to give oxazol

39 formation of the fully dissociated products, C6H6, Cr+, and CO, the 298 K heats of formation the ioni

40 With benzene as a dopant, providing C6H6+ as reactant ion, protonated molecular ions and pro

41 s predicted to be even more aromatic than S0 C6H6.

42 S2 C6H6 is predicted to be even more aromatic than S0 C6H6.

43 rall yield synthesis) and 5 mol % (CuOTf)2 x C6H6.