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1 CH4 fluxes were measured in situ during peak growing sea
3 al stable isotopic methane records [delta(13)CH4 and deltaD(CH4)] from four Antarctic ice cores, whic
5 C emitted from the SPRUCE Bog as CH4 is <2%, CH4 represents >50% of seasonal C emissions in the highe
6 tion (100 m x 100 m) regional (10,000 km(2)) CH4 flux map of the Mackenzie Delta, Canada, based on ai
11 Org-M decreased soil N2O emission by 13% and CH4 emission by 12%, and increased soil CO2 emission by
14 tive facility-scale losses (0.09-0.34%), and CH4 emissions from both NGPPs and refineries were more s
15 validated experimentally with H2, N2, Ar and CH4 on three classes of microporous materials: trapdoor
17 strategy to fine tune the pore chemistry and CH4 -storage performance of a family of isomorphic MOFs
18 riods using satellite measurements of CO and CH4, nearly twice the decrease expected from prior estim
19 nthesized in a one-step process from CO2 and CH4 at room temperature (30 degrees C) and atmospheric p
22 ng to positive Tw-Ta, it can enhance CO2 and CH4 emissions from inland waters, thereby contributing t
24 ance measurements of whole-ecosystem CO2 and CH4 exchange to estimate GHG fluxes and associated radia
27 s revealed that the evasion rates of CO2 and CH4 in tributaries of the rivers of the plateau were hig
28 eruptions released large amounts of CO2 and CH4 into the atmosphere, causing severe global warming a
29 on in the temperature sensitivity of CO2 and CH4 production and increased peat aerobicity due to enha
32 gly negative Tw-Ta, thereby reducing CO2 and CH4 transfer velocities from inland waters into the atmo
34 n fact, the (14) C content of DOC, CO2 , and CH4 across the entire peat profile was considerably enri
35 e (<60 years), despite stream DOC, CO2 , and CH4 primarily being sourced from deep peat horizons (2-4
37 gest that parameter uncertainties in CUE and CH4 -C:CO2 -C ratios have a larger impact on long-term s
39 For each subject, we measured exhaled H2 and CH4, oro-anal transit time, and the severity of psycholo
42 sing rice biomass by 10% could reduce annual CH4 emissions from Chinese rice agriculture by 7.1%.
45 d values, but substantially smaller per-area CH4 emissions, highlighting the need for improvements in
47 quantity of C emitted from the SPRUCE Bog as CH4 is <2%, CH4 represents >50% of seasonal C emissions
48 o have significantly altered land-atmosphere CH4 emissions for this region, potentially acting as a p
49 is an important pathway for land-atmosphere CH4 emissions, but the magnitude, timing, and environmen
51 s adjacent to the trees consumed atmospheric CH4 at a rate of -4.52 +/- 0.64 mumol CH4 m(-2 ) soil h(
52 a steady but only minor role in atmospheric CH4 changes and that the glacial budget is not dominated
53 ower decadal mean growth rate in atmospheric CH4 concentrations throughout the 1980s and 1990s and to
55 he 1980s and 1990s and to stable atmospheric CH4 concentrations from 1999 to 2006, resulting in negat
57 mass balance method, we calculate an average CH4 flux of 0.54 +/- 0.20 Tgyr(-1) (1sigma), in close ag
59 mperature, composition) behaviour of binary (CH4 + C3H8) and (Ar + CO2) mixtures over the temperature
60 O2 pre-enriched inoculum enhanced biocathode CH4 production, although the archaeal communities in bot
61 Thus, ZVI may be used to increase biocathode CH4 production, assist in the start-up of an electrometh
63 ommon intermediate for the formation of both CH4 and C2H4 These results suggest that, to obtain hydro
66 Progressive enrichment of both delta(13)C-CH4 and deltaD-CH4 is observed with increasing distance
67 ces are characterised by specific delta(13)C-CH4 signatures, so high precision stable isotope analysi
69 L (n = 12) were all found to have delta(13)C-CH4 values larger than -30 per thousand, typical of a th
70 of several small gases (H2, D2, Ne, N2, CO, CH4, C2H6, Ar, Kr, and Xe) on the metal-organic framewor
71 ter diffusion and ebullition fluxes of CO2 , CH4 , and N2 O from a restored emergent marsh ecosystem.
73 f the first to incorporate stream GHGs (CO2, CH4 and N2O) concentrations and emissions in rivers of t
74 e flux of gas, the calculated fluxes of CO2, CH4 and N2O (3,452 mg-C m(2) d(-1), 26.7 mg-C m(2) d(-1)
75 rnality costs are based on emissions of CO2, CH4, N2O, PM2.5, PM10, NOx, SO2, VOC, CO, NH3, Hg, Pb, C
77 nds for O2/N2, H2/N2, CO2/N2, H2/CH4 and CO2/CH4, with the potential for biogas purification and carb
78 gh-yielding rice cultivars strongly decrease CH4 emissions from paddy soils with high organic C conte
79 sults provide insight into a way to decrease CH4 production and increase CE using FAN to control the
80 g CO2 -eq m(-2) mostly because of decreased CH4 emissions, while N deposition reduced GWP from 21.0
81 GeoChip analysis revealed that decreased CH4 production potential, rather than increased CH4 oxid
82 a displays an exceptionally high deliverable CH4 capacity of 208 v/v between 5 and 80 bar at room tem
83 high gravimetric and volumetric deliverable CH4 capacities of 0.24 g g(-1) and 163 vol/vol (298 K, 5
84 pic methane records [delta(13)CH4 and deltaD(CH4)] from four Antarctic ice cores, which provide impro
87 enrichment of both delta(13)C-CH4 and deltaD-CH4 is observed with increasing distance and decreasing
88 bes a new C-H bond activation pathway during CH4-CO2 reactions on oxophilic Ni-Co and Co clusters, un
89 ically relevant step leads to more effective CH4 turnovers and complete elimination of coke depositio
93 Both MFM-112a and MFM-115a show excellent CH4 uptakes of 236 and 256 cm(3) (STP) cm(-3) (v/v) at 8
94 negatively with microbial richness, exhaled CH4, presence of methanogens, and enterotypes enriched w
96 e nature of the silane, with PhSiH3 favoring CH4, and Ph3SiH favoring the bis(silyl)acetal, H2C(OSiPh
99 usion, possibly increasing the potential for CH4 oxidation and leading to a decrease in net CH4 fluxe
102 ersion of adsorbed formate, whereas that for CH4 formation is the hydrogenation of adsorbed carbonyl.
103 direct plasma synthesis of acetic acid from CH4 and CO2 is an ideal reaction with 100 % atom economy
104 modynamics favour the production of CO2 from CH4, while abiotic methane synthesis would require the o
105 t biomass was a strong predictor of A. fulva CH4 flux while water depth and thaw depth were copredict
109 (May-October) wetland CH4 emission of 13 g CH4 m(-2) is the dominating contribution to the landscap
111 ctic, may see increased emission of geologic CH4 in the future, in addition to enhanced microbial CH4
112 on recent air and soil temperature, geologic CH4 was produced over millions of years and can be relea
114 ubsurface environments, and we show that H2, CH4, and CO feature prominently in many of their predict
115 on upper bounds for O2/N2, H2/N2, CO2/N2, H2/CH4 and CO2/CH4, with the potential for biogas purificat
118 production would likely contribute to higher CH4 emissions, unless effective strategies to mitigate G
119 ), which has previously been used to improve CH4 production in anaerobic digesters, has not been expl
121 rease of 10% resulted in a 10.3% decrease in CH4 emissions in a soil with a high carbon (C) content.
122 re, we quantify the thaw-induced increase in CH4 emissions for a boreal forest-wetland landscape in t
124 lorophyll a] experienced larger increases in CH4 emission in response to drawdown (R(2) = 0.84, p < 0
125 that warming in boreal regions may increase CH4 emissions from peatlands and result in a positive fe
126 production potential, rather than increased CH4 oxidation potential, may lead to the reduction in ne
127 the positive radiative forcing of increasing CH4 emissions until the end of the 21st century as indic
129 ipulation on an Arctic floodplain influences CH4 -associated microorganisms, soil thermal regimes, an
130 drylands had 36% higher emission intensity (CH4 emissions/km(2) ) compared to that in nondrylands in
134 x footprint modeling, we find that landscape CH4 emissions increase with increasing wetland-to-forest
137 'bottom-up' estimates, indicating that large CH4 emissions from trees adapted to permanent or seasona
138 s likely responsible for the 3.8-fold larger CH4 production rate observed in the EHM-biocathode.
140 We show that in this model, the global LGM CH4 source was reduced by 28-46%, and the lifetime incre
144 2.9-fold higher, respectively, than the mean CH4 production in the four prior cycles without ZVI addi
150 n (DOC), carbon dioxide (CO2 ), and methane (CH4 ) exported from a boreal peatland catchment coupled
151 uring soil nitrous oxide (N2 O) and methane (CH4 ) fluxes and SOC changes (DeltaSOC) at a long-term,
153 ide (N2O), carbon dioxide (CO2) and methane (CH4) emissions to manure (Org-M) in comparison to chemic
154 tential for nitrous oxide (N2O) and methane (CH4) generation in dissolved form at the base of laborat
155 ide (CO2), nitrous oxide (N2O), and methane (CH4) requires days of integration time with largest spac
157 he substrate's electrons ends up as methane (CH4) through hydrogenotrophic methanogenesis, an outcome
159 udgets ascribe 4-10% of atmospheric methane (CH4 ) sinks to upland soils and have assumed until recen
164 yr(-1) ) on carbon dioxide (CO2 ), methane (CH4 ) and nitrous oxide (N2 O) fluxes as well as the und
167 e East Siberian Arctic Shelf (ESAS) methane (CH4) emissions, yet these factors still require assessme
171 Biogenic production and release of methane (CH4 ) from thawing permafrost has the potential to be a
173 is high uncertainty in estimates of methane (CH4) emissions from natural gas-fired power plants (NGPP
175 ncreasing rice growth can stimulate methane (CH4 ) emissions, exacerbating global climate change, as
176 estricted salt marshes, substantial methane (CH4) and CO2 emission reductions can be achieved through
178 rt carbon dioxide (CO2) directly to methane (CH4), promise to be an innovative technology for anaerob
185 issions in 2014 was 97.1 million tonnes (MT) CH4 or 2.72 Gigatonnes (Gt) CO2 -eq (1 MT = 10(12) g, 1
187 om May to September were 1.59 +/- 0.88 mumol CH4 m(-2 ) stem h(-1) (mean +/- 95% confidence interval)
191 ed wetland and landscape eddy covariance net CH4 flux measurements in combination with flux footprint
193 potential, may lead to the reduction in net CH4 emissions, and decreased nitrification potential and
195 is and methanotrophy, thereby increasing net CH4 fluxes to the atmosphere, should be a focus of futur
201 ntly underestimate the atmospheric burden of CH4 determined via remote sensing and inversion modellin
202 ep peat warming increased the delta(13) C of CH4 suggesting an increasing contribution of acetoclasti
203 we provide a 'top-down' regional estimate of CH4 emissions of 42.7 +/- 5.6 teragrams of CH4 a year fo
204 r II guidelines to quantify the evolution of CH4 emissions from ruminant livestock during 1890-2014.
205 Due to this decrease, a higher fraction of CH4 was alternatively emitted to the atmosphere by diffu
206 Total global warming potential (GWP) of CH4 and N2O emissions was 5303 kg CO2-eq in 1983 and 656
211 ducing agent, as the total reducing power of CH4 originates from the carbon and hydrogen of CH4, whic
214 is seems problematic because the reaction of CH4 and water to generate methanol and H2 is highly unfa
215 in, the largest natural geographic source of CH4 in the tropics, consistently underestimate the atmos
217 s and oil refineries may be large sources of CH4 emissions and could contribute significantly (0.61 +
218 f CH4 emissions of 42.7 +/- 5.6 teragrams of CH4 a year for the Amazon basin, based on regular vertic
219 it 15.1 +/- 1.8 to 21.2 +/- 2.5 teragrams of CH4 a year, in addition to the 20.5 +/- 5.3 teragrams a
222 4 +/- 0.6 kt CO2 -eq yr(-1) ) did not offset CH4 emission (3.7 +/- 0.03 kt CO2 -eq yr(-1) ), producin
225 ns to investigate the impacts of the ENSO on CH4 emissions in tropical wetlands for the period from 1
226 f the El Nino-Southern Oscillation (ENSO) on CH4 emissions from wetlands remains poorly quantified at
228 d investigating effects of soil hydrology on CH4 fluxes is of great importance for predicting ecosyst
230 y, we successfully built several new CH3- or CH4-based heterodimers that may prove useful for designi
234 ity and high binary CO2-over-N2 and CO2-over-CH4 selectivity, suitable for CO2 capture from flue gas
235 g cultivars can substantially mitigate paddy CH4 emission in China and other rice growing regions.
237 ach is applied to a use-case for quantifying CH4 emission from an oil field south of San Ardo, CA, an
242 -based climate change intervention, reducing CH4 emissions is an entirely distinct concept from biolo
248 orarily, greatly increase per-area reservoir CH4 fluxes to the atmosphere, and can account for more t
250 sions offset 1-6% of the growing season soil CH4 sink and may have briefly changed the forest to a ne
255 hat fossil fuels contribute between 12-19 Tg CH4 per year to the recent atmospheric methane increase,
257 ions of methane decreased by 3.7 (+/-1.4) Tg CH4 per year from the 2001-2007 to the 2008-2014 time pe
258 tory-scale experimental study confirmed that CH4 actively reduces SnO2, producing 99.34% high-purity
263 tively separated from the raw biogas and the CH4 content in the outlet reached as high as 97.0 +/- 0.
268 i 43) were prepared and we observed that the CH4 volumetric working capacity and volumetric uptake va
269 ogic emissions and their contribution to the CH4 budget in addition to recent, biogenic CH4 is uncert
273 y of the electrocatalytic reduction of CO to CH4 and C2H4 on copper electrodes prevents a straightfor
277 MPn metabolism contributes significantly to CH4 oversaturation in Yellowstone Lake and likely other
278 functionally active for N2-to-NH3 and CN-to-CH4/NH3 conversion, respectively, when subjected to prot
281 Africa, Asia and Latin America) to the total CH4 emissions had increased from 51.7% in the 1890s to 7
284 we find evidence of an increase in tropical CH4 emissions of approximately 6-9 TgCH4 yr(-1) during t
289 mediating approximately half of all wetland CH4 emissions in the Amazon floodplain, a region that re
291 use a process-based model of global wetland CH4 emissions to investigate the impacts of the ENSO on
292 esents up to one-third of the global wetland CH4 source when trees are combined with other emission s
294 ulative growing season (May-October) wetland CH4 emission of 13 g CH4 m(-2) is the dominating contri
295 me lag was detected between tropical wetland CH4 emissions and ENSO events, which was caused by the c
296 ve much stronger effects on tropical wetland CH4 emissions than the changes in precipitation during E
298 onality was minor for CO2 emissions, whereas CH4 and N2 O fluxes displayed strong and asynchronous se
299 mples were dominated by taxa affiliated with CH4 oxidizing, fermenting and SO42- reducing lineages.
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