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1 COD was also consumed during the process, but heterotrop
2 cular nucleation" in which 2(COD)Ir(+) and 1(COD)Ir.POM(8-) yield the transition state of the rate-de
3 rs catalyzed by the combination of Ni(COD)2 (COD = 1,5-cyclooctadiene) and an N-heterocyclic carbene
4 le ligands and Ru3(CO)12 or Ru(methylallyl)2(COD) direct hydroformylation and hydrogenation of alkene
5 ernative termolecular nucleation" in which 2(COD)Ir(+) and 1(COD)Ir.POM(8-) yield the transition stat
7 e dimeric complexes 1, [R(3)Si(mu-Cl)(eta(2)-COD)Pt](2) [R(3)Si = Et(3)Si, MeCl(2)Si, Me(2)ClSi, "(Et
9 low isomerization to 1,3-cyclooctadiene (1,3-COD), along with the formation of a new complex that inc
10 he catalytic isomerization of 1,5-COD to 1,3-COD, only in the case of the zinc species is the cyclooc
11 ansfer from [2,5-Ph(2)-3,4-Tol(2)(eta(5)-C(4)COD)]Ru(CO)(2)D to N-aryl imines to give amine complexes
12 ene], and the bis-silyl complexes 2, (eta(4)-COD)Pt(SiR(3))(2) (R(3)Si = Cl(3)Si, MeCl(2)Si, Me(2)ClS
13 etent for the catalytic isomerization of 1,5-COD to 1,3-COD, only in the case of the zinc species is
14 etallic complex with 1,5-cyclooctadiene (1,5-COD) results in slow isomerization to 1,3-cyclooctadiene
15 n reveals closely analogous, solution Ir(1,5-COD)(+) or Ir(1,5-COD)Cl-mediated, mechanisms of nanopar
16 lly and mechanistically well-studied, Ir(1,5-COD).P(2)W(15)Nb(3)O(62)(8-) to Ir(0)(~300).(P(2)W(15)Nb
18 cle formation mechanism consisting of Ir(1,5-COD)Cl(solvent) dissociation from the gamma-Al(2)O(3) su
19 ased nucleation from that dissociated Ir(1,5-COD)Cl(solvent) species, fast Ir(0)(n) nanoparticle capt
20 rom Ir(0)(n)/gamma-Al(2)O(3) and with Ir(1,5-COD)Cl(solvent), the first kinetically documented mechan
21 analogous, solution Ir(1,5-COD)(+) or Ir(1,5-COD)Cl-mediated, mechanisms of nanoparticle formation.
22 e system explored is the precatalyst, Ir(1,5-COD)Cl/gamma-Al(2)O(3) (characterized via ICP, CO adsorp
24 ion and growth pathway involving only Ir(1,5-COD)Cl/gamma-Al(2)O(3) and also disprove a solution-base
25 x 10(4) h(-1) M(-1)), where A is the Ir(1,5-COD)Cl/gamma-Al(2)O(3) precatalyst and B is the resultan
26 formation kinetics, starting from the Ir(1,5-COD)Cl/gamma-Al(2)O(3) precatalyst, are closely fit by t
27 e development of a well-characterized Ir(1,5-COD)Cl/gamma-Al(2)O(3) precatalyst, which, when in conta
29 stic studies allow comparisons of the Ir(1,5-COD)Cl/gamma-Al(2)O(3) to Ir(0)(~900)/gamma-Al(2)O(3) su
30 is central question for the prototype Ir(1,5-COD)Cl/gamma-Al(2)O(3) to Ir(0)(~900)/gamma-Al(2)O(3) sy
31 e gamma-Al(2)O(3) support (i.e., from Ir(1,5-COD)Cl/gamma-Al(2)O(3)), solution-based nucleation from
32 onstant k4), where A is nominally the Ir(1,5-COD)Cl/gamma-Al2O3 precursor, B the growing Ir(0) partic
35 le catalyst precursor, [A] = [(Bu4N)5Na3(1,5-COD)Ir(I).P2W15Nb3O62], forming soluble/dispersible, B =
36 ately 300 nanoparticles from (Bu4N)5Na3[(1,5-COD)Ir.P2W15Nb3O62] (abbreviated hereafter as (COD)Ir.PO
39 of 39%, a n-butyrate yield of 23% (both on a COD basis), a maximum total fermentation production rate
40 in, we describe the implementation of such a COD platform to perform high precision nanoliter assays.
41 parent second-order in the precatalyst, A = (COD)Ir.POM(8-), not the higher order implied by classic
43 ely offset annual freshwater consumption and COD discharge driven by per capita GDP growth, but that
44 ge percent error of Coulombic efficiency and COD removal rate predictions were 1.77 +/- 0.57% and 4.0
45 olid samples, with high suspended solids and COD concentrations, using an optimized closed reflux col
46 l oxygen demand (COD)/L (16% of total SMP as COD) because many SMPs have considerably higher MWs.
47 D)Ir.P2W15Nb3O62] (abbreviated hereafter as (COD)Ir.POM(8-), where POM(9-) = the polyoxometalate, P2W
48 near molecular level, for poorer adhesion at COD crystal faces, which explains the benign character o
49 Metabolic modeling analysis shows that at COD:N of 4:1 the denitrifying cells slowly generate elec
50 study was 0.82 mg CH(3)OH COD/mg AOB biomass COD-d, which is 1.5 times the highest value reported wit
54 H-transfer rather than Si-transfer to bound COD provides experimental support for the sequence of in
55 catalyst, (dfmpe)Ni(COD) and (dfmpe)Ni(bpy), COD = 1,5-cyclooctadiene and bpy = 2,2'-bipyridine, were
56 used in place of Ni(COD)2/SIPr.HBF4/KO(t)Bu (COD = 1,5-cyclooctadiene) as a more robust catalyst for
57 l rate of cholesterol oxidation catalyzed by COD was investigated at 37 degrees C using cholesterol/1
58 The initial rate of cholesterol oxidation by COD in fluid state 1-palmitoyl-2-oleoyl-phosphatidyletha
59 cyclochiral conformers of the Ir(I) chelated COD was 5 kcal mol(-1) higher as an included organometal
60 iral twisted-boat conformers of the chelated COD included in the already chiral cavity of the contain
61 lude the structurally characterized complex (COD)Pt(OTf)2 (1) and the known dimer [PtCl2(C2H4)]2, act
64 oxygen demand) in effluent water, cumulative COD and dilution water requirements for cumulative pollu
65 or heteroleptic L2.Ir(I).1,5-cyclooctadiene (COD) complexes included in the aromatic cavity of Rebek'
66 An inhibitory role of 1,5-cyclooctadiene (COD) in nickel-catalyzed C-H functionalization processes
68 ination of bulk catastrophic optical damage (COD) due to locally high energy densities, heliotropic C
69 Network (SGN) is a clade-oriented database (COD) containing biological data for species in the Solan
70 Network (SGN) is a clade-oriented database (COD), which provides a more scalable and comparative fra
72 scan with lung cancer as the cause of death (COD) documented by the NLST endpoint verification proces
74 ting such droplets in compartment-on-demand (COD) platforms is the basis for rapid, automated screeni
75 es of chemical and biological oxygen demand (COD and BOD) in the aquatic systems into which they are
76 l elimination rates (chemical oxygen demand (COD) 90-95%, biological oxygen demand (BOD5) 94-98%, tot
77 reatment efficiency (chemical oxygen demand (COD) and ammonia removal), Ag dissolution measurements,
79 7-day Pb toxicity to chemical oxygen demand (COD) and NH3-N removal, bacterial viability, and communi
80 only 10% of influent chemical oxygen demand (COD) and recovered up to 55% of incoming organic matter
81 MFCs removed 65-70% chemical oxygen demand (COD) at a hydraulic retention time (HRT) of 11 h and red
82 determination of the chemical oxygen demand (COD) in heterogeneous solid or semisolid samples, with h
88 anic carbon (TOC) or chemical oxygen demand (COD), though these parameters do not provide information
89 d for only 2.1 mg of chemical oxygen demand (COD)/L (16% of total SMP as COD) because many SMPs have
90 ubilization (0.16 mg chemical oxygen demand (COD)/mg volatile solids (VS), at 2.13 mg HNO2-N/L) being
93 aic (PV) panel, which was shown to eliminate COD and total coliform bacteria in less than 4 h of trea
95 l explained by chosen environmental factors (COD, nitrite-N, nitrate-N, dissolved inorganic phosphoru
98 -1) and n-butyrate production rate of 0.47 g COD l(-1) d(-1) in bioreactors that were fed with dilute
99 total fermentation production rate of 0.74 g COD l(-1) d(-1) and n-butyrate production rate of 0.47 g
100 3.38 +/- 0.42 g L(-1) d(-1) (7.52 +/- 0.94 g COD L(-1) d(-1)) with an n-caproate yield of 70.3 +/- 8.
101 H2 yield varied from 0.26 to 0.42 g H2-COD/g COD removed in the anode, and the bioanode volume-normal
102 ciency in the two-phase system were 228 mL/g COD added and 77.8%, respectively, which were 1.6 and 2.
103 The H2 yield varied from 0.26 to 0.42 g H2-COD/g COD removed in the anode, and the bioanode volume-
104 o locally high energy densities, heliotropic COD growth, solid-liquid-gas phase transformations, stro
105 afluoropentan-2,4-dionatocopper(I) (Cu(hfac)(COD)) to yield 1,1,1,5,5,5-hexafluoropentan-2,4-dione (H
107 e type Rh(I)(NHC)(COD)X (where X is Cl or I, COD is cyclooctadiene, and NHC is a dimethylbenzimidazol
109 Subsequent stepwise reduction of influent COD caused a decrease in total polysaccharide and protei
110 The NO2(-) spiked cultures with an initial COD:N = 11:1 accumulated 3.3 +/- 0.57% of the total nitr
111 atch cultures under four conditions: initial COD:N ratios of 11:1 and 4:1 with and without nitrite sp
112 trates and 1 as the catalyst, intermediate [(COD)Pt(norbornene)2][OTf]2 (3) was identified and charac
114 2) (COD = 1,5-cyclooctadiene) afforded 1-[Ir(COD)Cl], a complex with bond lengths and angles that wer
115 n of B(2)pin(2) with arenes catalyzed by [Ir(COD)(OMe)](2) and dtbpy occur faster with electron-poor
116 ion of complex 4a with the metal complex [Ir(COD)Cl]2 affords a heterobimetallic Zr/Ir product 14.
119 the active catalyst to be generated from [Ir(COD)Cl]2 and P(OPh)3 by cyclometalation of the phenyl gr
120 zed by an iridium complex generated from [Ir(COD)OMe]2 and chiral dinitrogen ligands that we recently
121 hydrogenation of 20 with the complex of [Ir(COD)2BArF] (26) and Taniaphos ligand P afforded the (3R,
123 he combination of (eta(6)-mes)IrBpin3 or [Ir(COD)OMe]2 and a phenanthroline derivative is reported.
124 tsynthetic metalation of these MOFs with [Ir(COD)(OMe)]2 provided Ir-functionalized MOFs (BPV-MOF-Ir,
126 arbene adducts with [M(COD)Cl]2 (M = Rh, Ir; COD = 1,5-cyclooctadiene) afforded zwitterionic rhodium(
133 ve a minimum energy consumption of 62 kWh/kg COD, reduced foam formation due to less gas bubble produ
134 ns of ML4 (M = Pt, Pd, L = PPh3; M = Ni, L2= COD) and 2,2,2-crypt to give M@Pb12(2-) cluster anions (
135 iridium(I) complexes of the type [(WCA-NHC)M(COD)], in which the metal atoms exhibit an intramolecula
136 he resulting lithium-carbene adducts with [M(COD)Cl]2 (M = Rh, Ir; COD = 1,5-cyclooctadiene) afforded
138 ntinuous bioreactor, up to 59.89 +/- 1.12 mg COD/L of CH(3)OH was produced within an incubation time
139 showed a biodegradation capacity of 1.45 mg COD/gramwet-day at a TDS concentration of 91,351 mg/L.
141 itudinal phonon cooling effect on the molten COD wave front, and the formation of patterns due to las
146 As20]3- ion was prepared from As7(3-) and Ni(COD)2 in ethylenediamine solutions and isolated as the B
148 tive cleavage of C-OMe bonds catalyzed by Ni(COD)(2)/PCy(3) with silanes as reducing agents is report
149 By using optimized reaction conditions, Ni(COD)(2)/PCy(3) was shown to be a versatile catalyst for
151 ated with nickel bis(1,5-cyclooctadiene) (Ni(COD)(2)), 2a and 2b are capable of polymerizing ethylene
153 Two candidates for a precatalyst, (dfmpe)Ni(COD) and (dfmpe)Ni(bpy), COD = 1,5-cyclooctadiene and bp
155 ysts showed that the combination of DPPF, Ni(COD)(2), and acid is a highly active catalyst system for
156 or C-aryl glycosides, reactions employing Ni(COD)2/(t)Bu-Terpy in N,N-dimethylformamide (DMF) were ty
157 l-silicide colloids were synthesized from Ni(COD)(2) and octylsilane at low temperature; they were su
159 to 99% ee catalyzed by the combination of Ni(COD)(2) and (R)-BINAP and the coupling of ketones with a
161 the first time using catalytic amounts of Ni(COD)(2), an N-heterocyclic carbene ligand, and PPh(3).
163 yl ethers catalyzed by the combination of Ni(COD)2 (COD = 1,5-cyclooctadiene) and an N-heterocyclic c
165 idazolidin-2-ylidene) is used in place of Ni(COD)2/SIPr.HBF4/KO(t)Bu (COD = 1,5-cyclooctadiene) as a
167 the well-defined soluble nickel precursor Ni(COD)(2) or Ni(CH(2)TMS)(2)(TMEDA) in the presence of a b
168 Ar(Mes2)]2, and the d(10) Ni(0) precursor Ni(COD)2, produces a porous metal-organic material featurin
169 In the presence of a phosphine scavenger, Ni(COD)2, the phosphine-ligated syn-dinickel complexes copo
171 Results from a mechanistic study on the Ni(COD)2-bipy-catalyzed alkylation of anhydrides are consis
173 lyst can be utilized as an alternative to Ni(COD)(2)/PCy(3) to provide an inexpensive, robust, and co
174 om deltahedral clusters of germanium with Ni(COD)2 and/or Ni(PPh3)2(CO)2 in ethylenediamine yielded t
177 mol % cholesterol), the initial activity of COD changed with cholesterol mole fraction in a biphasic
178 These results indicate that the activity of COD is regulated by the extent of sterol superlattice fo
179 aces, which explains the benign character of COD and has implications for resolving one of the myster
180 cation of this approach for the detection of COD online and in continuous mode, the CuO/AgO-based nan
182 hat is, freshwater consumption, discharge of COD (chemical oxygen demand) in effluent water, cumulati
184 A), which were 239 +/- 74 and 89 +/- 7 mg of COD per gram of active biomass (Xa) per hour, respective
185 ow 2-D lipid composition window, an onset of COD activity at X(CHOL) approximately 0.40 and the elimi
187 indicating its potential for the sensing of COD in clinical samples and pharmaceutical formulations.
188 trocatalytic response towards the sensing of COD with a wide linear response range of 2.0 x 10(-8)-2.
189 Between 1992 and 2007, 225 million tones of COD accumulated in Chinese water bodies, which would req
190 tained during this study was 0.82 mg CH(3)OH COD/mg AOB biomass COD-d, which is 1.5 times the highest
191 he methane yield was 2.40 +/- 0.52% based on COD and was limited by the availability of carbon dioxid
195 Storage played a minor role in the overall COD removal, which was likely dominated by aerobic bioma
199 ed at 37 degrees C by a cholesterol oxidase (COD) reaction rate assay and by optical microscopy.
201 e sensitive and selective codeine phosphate (COD) determination in the presence of paracetamol (PAR)
203 H)2, 1, was obtained from the reaction of Pt(COD)2 and Bu(t)3SnH, followed by addition of CNBu(t).
206 sponding hydrosilanes, respectively, with Pt(COD)Cl(2) in the presence of a small excess of COD.
210 key step in the sequence was the Burk's [Rh(COD)(2R,5R)-Et-DuPhos]BF4-catalyzed asymmetric hydrogena
211 +) BF(4)(-)) followed by reaction with Rh(+)(COD)(2) BF(4)(-) gave precatalysts with limited aqueous
212 um catalysts such as [RhCl(PPh3)3] or [[RhCl(COD)]2] with PiPr2(OAr) or P(NMe2)3 co-catalysts allows
213 for substrates without 2-substitution [[RhCl(COD)]2]/P(NMe2)3 mixtures tend to give better results.
214 utility and selectivity of the catalyst [Ru(COD)(L(1))Br2] (1) bearing a fused pi-conjugated imidazo
215 complexes, such as Cp*RuCl(PPh 3) 2, Cp*RuCl(COD), and Cp*RuCl(NBD), were among the most effective ca
216 nce of catalytic Cp*RuCl(PPh 3) 2 or Cp*RuCl(COD), primary and secondary azides react with a broad ra
217 tO)(3)Si", PhMe(2)Si, and (Me(3)SiO)Me(2)Si; COD = cycloocta-1,5-diene], and the bis-silyl complexes
218 he cumulative methane production and soluble COD (SCOD) removal efficiency in the two-phase system we
225 by an acoustic phonon bouncing model and the COD velocity is extrapolated to be exponentially decreas
226 A (n = 12) were cases of lung cancer as the COD because of adenocarcinoma, and group B (n = 15) were
229 nsfer rate increased by almost 5-fold as the COD loading increased from 0.39 to 1.1 kg COD/m(3)-d.
231 likely that patients with lung cancer as the COD occurred with solitary or dominant NSN as long as an
233 d (DI) water included reduction to below the COD detection limit after 60 min heating (90()C) with ad
234 in 16:0,18:1-PC and di18:1-PC bilayers, the COD initial-reaction rate displays a series of distinct
237 of total methane increased linearly with the COD loading rate, the concentration of dissolved methane
238 Although free radical species contribute to COD removal, anodes designed to enhance reactive chlorin
240 activity of reactive chlorine species toward COD with an increasing chloride ion concentration under
241 rating at peak power, the rate of wastewater COD removal, normalized to reactor volume, was 30-50 tim
244 comparison, the NO2(-) spiked cultures with COD:N = 4:1 showed significantly higher (p = 0.028) N2O
245 hen the substrate is a sterol, as it is with COD, the enzyme activity reaches a local maximum at C(r)
248 -1,3-bis(trimethylsilyl)propene reacts with (COD)2Ni to produce the dimeric purple complex {[1,3-(SiM
249 2,4,6-trimethylphenyl), imidazole-2-ylidene; COD=cyclooctadiene] catalyst onto silica particles modif
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