ライフサイエンスコーパス: Diels-Alder reaction

1 acylation step followed by an intramolecular Diels-Alder reaction.

2 used for an asymmetric Lewis acid catalyzed Diels-Alder reaction.

3 regioselectivity of the noncatalyzed nitroso-Diels-Alder reaction.

4 ibutes to the enhancement of the rate of the Diels-Alder reaction.

5 ax were synthesized using the first ynindole Diels-Alder reaction.

6 clable heterogeneous catalyst for the hetero-Diels-Alder reaction.

7 med diazaheptacene from dimerization through Diels-Alder reaction.

8 ethyl nitrosoacrylate, which proceeds via a Diels-Alder reaction.

9 cetylenediols as potential catalysts for the Diels-Alder reaction.

10 heterocycles by an asymmetric catalytic thio-Diels-Alder reaction.

11 ation of these complexes does not hinder the Diels-Alder reaction.

12 heterocyclic carbene catalysts in the hetero-Diels-Alder reaction.

13 iyaura cross-coupling, and an intramolecular Diels-Alder reaction.

14 sfer complexes, [XSty, oCA], followed by the Diels-Alder reaction.

15 catalyst complexes in a Lewis acid catalyzed Diels-Alder reaction.

16 of a domino oxidation/intermolecular hetero Diels-Alder reaction.

17 rbazoles were synthesized using a key double Diels-Alder reaction.

18 uld have been possible from a trans-directed Diels-Alder reaction.

19 interesting 1,5-hydride shift followed by a Diels-Alder reaction.

20 rmed through an intramolecular photochemical Diels-Alder reaction.

21 zines by means of an inverse-electron-demand Diels-Alder reaction.

22 s likely arise from an intramolecular hetero Diels-Alder reaction.

23 esis of spinosyn A, catalyzes a transannular Diels-Alder reaction.

24 process sometimes dominates over the allowed Diels-Alder reaction.

25 te centered upon a late-stage regioselective Diels-Alder reaction.

26 ners with alkenes in inverse-electron-demand Diels-Alder reactions.

27 atalytic enantioselective intramolecular aza-Diels-Alder reactions.

28 for yne-enone cyclizations via formal hetero-Diels-Alder reactions.

29 at for models proposed for related catalyzed Diels-Alder reactions.

30 es of them frequently feature intramolecular Diels-Alder reactions.

31 estigate type 2 intramolecular N-acylnitroso Diels-Alder reactions.

32 ising from (2 + 2) cycloadditions and hetero-Diels-Alder reactions.

33 ng syntheses involving type 2 intramolecular Diels-Alder reactions.

34 , Suzuki, Sonogashira, cross-metathesis, and Diels-Alder reactions.

35 dihydrocatechol in inter- or intra-molecular Diels-Alder reactions.

36 annular cyclization process and transannular Diels-Alder reactions.

37 suggested by examination of organocatalytic Diels-Alder reactions.

38 valuable family of dienophiles for servicing Diels-Alder reactions.

39 ion of the heterocyclic core segments by two Diels-Alder reactions.

40 ymes have been shown to catalyze bimolecular Diels-Alder reactions.

41 are otherwise difficultly obtained by direct Diels-Alder reactions.

42 luable for the fusion of additional rings by Diels-Alder reactions.

43 d kidamycinone were achieved by means of two Diels-Alder reactions.

44 ous esters and amides are classic dienes for Diels-Alder reactions.

45 at generated by the NIR light induce reverse Diels-Alder reactions.

46 d highly atom-economic processes such as the Diels-Alder reaction, [2 + 2 + 2] cycloaddition, Suzuki-

47 In the hexadehydro-Diels-Alder reaction, a 1,3-diyne is engaged in a [4+2]

48 The Diels-Alder reaction, a [4 + 2] cycloaddition of a conju

49 lective, susbtrate-controlled intramolecular Diels-Alder reaction, a transannular enolate alkylation,

50 n-deficient dienophiles undergo irreversible Diels-Alder reactions, a reversible Diels-Alder reaction

51 gy involving the hemiaminal formation/hetero-Diels-Alder reaction affords the bicyclic products in a

52 of high pressure as activating method of the Diels-Alder reactions allows efficient and regioselectiv

53 Thermal asymmetric aza-Diels-Alder reactions also proceeded in good yields and

54 Using a Diels-Alder reaction, an anthracene unit with four funct

55 is of wickerol A (1) that is based on a Jung Diels-Alder reaction, an intramolecular alkylation to co

56 ormed through a one-pot sequence of a hetero-Diels-Alder reaction, an oxidative carbon-hydrogen bond

57 tions quantitatively reproduce the KIEs in a Diels-Alder reaction and a catalytic glycosylation.

58 Additional key steps include a pyrone Diels-Alder reaction and a radical cyclization/Keck ally

59 revealed two competing pathways, a concerted Diels-Alder reaction and a stepwise Michael addition, fo

60 The reaction mechanism involves a Diels-Alder reaction and an intermolecular nucleophilic

61 It involves the sequential Diels-Alder reaction and oxidative aromatization with th

62 seful chiral diene ligands, was realized via Diels-Alder reaction and resolution of an enol acetate d

63 rol the facial selectivity of the initiating Diels-Alder reaction and set the absolute stereochemistr

64 ols the facial selectivity of the initiating Diels-Alder reaction and sets absolute stereochemistry o

65 ce of a natural enzyme evolved to catalyze a Diels-Alder reaction and shows how catalysis is achieved

66 ating it for participation in the initiating Diels-Alder reaction and stabilizing the intermediate 1,

67 the power of the cobalt-catalyzed asymmetric Diels-Alder reaction and the one-pot reductive rearrange

68 ht (>435 nm) "gate" the reversibility of the Diels-Alder reaction and turn the self-healing propertie

69 he presence of light with suitable enes in a Diels-Alder reaction and undergoes a transformation into

70 ough an iterative reaction sequence, wherein Diels-Alder reactions and a subsequent aromatization aff

71 urated N-acyl iminium ions as dienophiles in Diels-Alder reactions and electrophilic alkylating agent

72 ons unique to their structure, such as retro-Diels-Alder reactions and nucleophilic addition of water

73 ltiple [2 + 2] reactions, [4 + 4] reactions, Diels-Alder reactions and polymerization reactions of ac

74 ere used to affect highly diastereoselective Diels-Alder reactions and then the silicon-substituted D

75 sphine-catalyzed annulation, Tebbe reaction, Diels-Alder reaction, and in some cases, hydrolysis.

76 lkyne cycloaddition, inverse electron demand Diels-Alder reaction, and other types of bioorthogonal c

77 d first via an intramolecular ester-tethered Diels-Alder reaction, and the A-ring was annulated to th

78 sting enzymatic examples (the intramolecular Diels-Alder reaction, and the Cope and the Claisen rearr

79 anic reactions of several arenes with C(60), Diels-Alder reactions, and barriers to [4 + 3] cycloaddi

80 via a very hindered inverse electron demand Diels-Alder reaction are described.

81 At 298 K, most Diels-Alder reactions are concerted and stereospecific,

82 with the distortion of the reactants in the Diels-Alder reactions are nearly identical and that the

83 Proton-catalyzed Diels-Alder reactions are not well-documented in the lit

84 from (+)-citronellal using an intramolecular Diels-Alder reaction as the key step.

85 gy predicated on the inverse electron demand Diels-Alder reaction as well as the use of this approach

86 onstructed using catalytic asymmetric hetero Diels-Alder reactions as the key steps.

87 ucts of which undergo fragmentation by retro-Diels-Alder reaction at rates that vary with the substit

88 The Diels-Alder reaction between 1 and 6 occurs under the se

89 d thermodynamic parameters of the reversible Diels-Alder reaction between 1,2-azaborines and methyl a

90 The Diels-Alder reaction between 2-methylfuran and 3-bromobe

91 argets is established by an enantioselective Diels-Alder reaction between 5-(trimethylsilyl)cyclopent

92 A microwave-promoted aza-Diels-Alder reaction between 6-[2-(dimethylamino)vinyl]-

93 d, in which the key step is a regioselective Diels-Alder reaction between a pyranobenzoquinone dienop

94 le regiocontrol element in an intramolecular Diels-Alder reaction between a substituted naphthyne and

95 ntheses employed an identical inverse demand Diels-Alder reaction between a surrogate for an extended

96 fully closed complex are able to catalyze a Diels-Alder reaction between cyclopentadiene and methyl

97 ly remendable polymer was synthesized by the Diels-Alder reaction between dithienylfuran and maleimid

98 ctam complex structure is not attained via a Diels-Alder reaction between pyrazinium-3-olate and MMA.

99 proach is a powerful inverse electron demand Diels-Alder reaction between substituted electron-defici

100 The mechanisms of Diels-Alder reactions between 1,2,3-triazines and enamin

101 The Diels-Alder reactions between 2 equiv of (E,E)-1,4-bis(4

102 Enantioselective (formal) aza-Diels-Alder reactions between acylhydrazones and non-Dan

103 ond formations (e.g. inverse electron demand Diels-Alder reaction) between the tumour bound antibody

104 a transient acylketene and an intramolecular Diels-Alder reaction, both of which occur in tandem thro

105 For example, in the classic Diels-Alder reaction, butadiene and ethylene combine to

106 It appears that intramolecular Diels-Alder reactions can be modeled accurately by today

107 ,beta-radical coupling/intramolecular hetero Diels-Alder reaction, can be efficiently catalyzed by la

108 are illustrated in an allylic C-H alkylation/Diels-Alder reaction cascade: a reactive diene is genera

109 g material, highly complex retro Diels-Alder/Diels-Alder reaction cascades, an unconventional protect

110 A highly diastereo- and enantioselective exo-Diels-Alder reaction catalyzed by a bis-oxazoline Cu(II)

111 anding of the observed selectivities for the Diels-Alder reaction catalyzed by Lewis acids.

112 The low-temperature Diels-Alder reactions catalyzed by our ferrocene-stabili

113 Mild Magic: A mild, enantioselective Diels-Alder reaction, catalyzed by a chiral magnesium ph

114 lerate and control organic reactions, namely Diels-Alder reaction, Claisen rearrangement, and Cope-ty

115 diate of the solution-phase cobalt-catalyzed Diels-Alder reaction, [Co(I)(dppe)(isoprene)(phenylacety

116 these products with a dienophile through the Diels-Alder reaction confirmed the formation of vitamin

117 The activation energy of Diels-Alder reactions correlates very well with reaction

118 o synthetic gain in a cascade cross-coupling/Diels-Alder reaction, delivering borylated or non-boryla

119 enging heterodienophiles in enantioselective Diels-Alder reactions, due to their inherent high reacti

120 Diels-Alder reactions employing 1,2-azaborine heterocycl

121 The Diels-Alder reaction enables introduction of new functio

122 celerate disfavored enolate addition and exo Diels-Alder reactions enantioselectively.

123 ble participation in inverse electron demand Diels-Alder reactions, extending the number of complemen

124 A second Diels-Alder reaction features the first use of an azepin

125 ntramolecular inverse electron-demand hetero-Diels-Alder reaction followed by air oxidation to furnis

126 are presumably formed through an initial oxa-Diels-Alder reaction, followed by an elimination of amin

127 h was employed in an inverse-electron-demand Diels-Alder reaction for heterobiaryl synthesis.

128 he utility of photochemically induced hetero-Diels-Alder reaction for the light-directed surface deri

129 te that cucurbit[7]uril (CB[7]) can catalyse Diels-Alder reactions for a number of substituted and un

130 lakotenin was achieved via an intramolecular Diels-Alder reaction from a (E,E,Z,E)-tetraene as linear

131 The aza-Diels Alder reaction has become one of the most widely u

132 The intramolecular Diels-Alder reaction has been used as a powerful method

133 An approach to the intramolecular Diels-Alder reaction has led to a cascade synthesis of c

134 Although the Diels-Alder reaction has long been utilized for the prep

135 alpha-ketothioesters participating in hetero-Diels-Alder reaction has remained unexplored.

136 Their reactivity in Diels-Alder reactions has been examined and the boron su

137 Few examples of oximino ether Diels-Alder reactions have been reported previously, and

138 The time-resolved mechanisms for eight Diels-Alder reactions have been studied by quasiclassica

139 ee-step mechanism that involves ene reaction-Diels-Alder reaction-hydrogen transfer.

140 An inverse-electron demand Diels-Alder reaction (IEDDA) was observed with R1 = CF3,

141 Inverse electron demand Diels-Alder reactions (iEDDA) between 1,2,4,5-tetrazines

142 this chemistry include a diastereoselective Diels-Alder reaction in the rapid synthesis of the tricy

143 s via a benzoxazine ring formation through a Diels-Alder reaction in water and a genetically encoded

144 ; two molecules of the azahexacene undergo a Diels-Alder reaction in which an alkyne substituent in t

145 nic species which can be used to effect many Diels-Alder reactions in >95% yield and >95% ee using ca

146 f water-soluble molecules that undergo retro-Diels-Alder reactions in aqueous environment releasing o

147 ith those for bimolecular and intramolecular Diels-Alder reactions in order to investigate the contro

148 bicyclic gamma-butyrolactones via the retro-Diels-Alder reaction/intramolecular conjugate ene cascad

149 igh catalytic activity in the base-catalyzed Diels-Alder reactions investigated.

150 e reactivity and endo/exo selectivity of the Diels-Alder reactions involving 1,2-azaborines have been

151 The Diels-Alder reaction is a [4+2] cycloaddition reaction i

152 The Diels-Alder reaction is a cornerstone in organic synthes

153 The Diels-Alder reaction is a cornerstone of modern organic

154 anic chemist engaged in total synthesis, the Diels-Alder reaction is among the most powerful and well

155 d enantioselective catalytic decarboxylative Diels-Alder reaction is developed using readily availabl

156 azadiene in metal-free base-assisted hetero-Diels-Alder reaction is exploited to quickly assemble an

157 The silylium ion-catalyzed Diels-Alder reaction is general with regard to the oxida

158 The Diels-Alder reaction is not limited to 1,3-dienes.

159 The Diels-Alder reaction is one of the most common methods t

160 d catalytic formal [3 + 2] cycloaddition and Diels-Alder reaction is outlined in detail.

161 Thus, calculations predict that the Diels-Alder reaction is privileged in the case of ethyl

162 h catalytic asymmetric aziridination and aza Diels-Alder reactions is described and the information g

163 clobutene as a building block for sequential Diels-Alder reactions is described.

164 of using cyclopropenyl ketones to facilitate Diels-Alder reactions is not limited to products that co

165 m salts and their use as diene precursors in Diels-Alder reactions is reported.

166 whose key-step consists of an intramolecular Diels-Alder reaction, is described.

167 iotransformations that are consistent with a Diels-Alder reaction, namely solanapyrone synthase, LovB

168 w that a concerted, but highly asynchronous, Diels-Alder reaction occurs rather than the stepwise Mic

169 ver-catalyzed formal inverse electron-demand Diels-Alder reaction of 1,2-diazines and siloxy alkynes

170 ver-mediated [3,3]-sigmatropic rearrangement/Diels-Alder reaction of 1,9-dien-4-yne esters is describ

171 type 5; (2) intramolecular Diels-Alder/retro-Diels-Alder reaction of 5 followed by tautomerization an

172 ring a scalable, catalytic, enantioselective Diels-Alder reaction of a 1-siloxydiene is outlined in d

173 Further highly diastereoselective Diels-Alder reaction of a 5,5,7-tricyclic compound with

174 We demonstrate a C-F bond driven Diels-Alder reaction of a fluorinated dienophile and a b

175 ohydrate-templated asymmetric intramolecular Diels-Alder reaction of a masked o-benzoquinone (MOB) 9

176 The second approach involves the Diels-Alder reaction of a series of new, ester-containin

177 a highly diastereoselective, intramolecular Diels-Alder reaction of a silicon-tethered acrylate; an

178 ough this study is a highly enantioselective Diels-Alder reaction of a versatile cyclic carbamate sil

179 atures an enantio- and regioselective pyrone Diels-Alder reaction of a vinyl sulfone to construct the

180 ective Bronsted acid catalysts of the hetero-Diels-Alder reaction of a wide variety of aldehydes and

181 cursors assembled in a modular fashion via a Diels-Alder reaction of acetylenic dienophiles with subs

182 Significant rate enhancements in the Diels-Alder reaction of alkynes and 2-pyrones bearing a

183 stmann in the amine-catalyzed intramolecular Diels-Alder reaction of alpha,beta-unsaturated carbonyli

184 ereoselective inverse electron demand hetero-Diels-Alder reaction of beta,gamma-unsaturated alpha-ket

185 nthesis of 2,2'-bis(naphthoquinones) using a Diels-Alder reaction of conjugated ketene silyl acetals

186 ds has been developed through the formal aza-Diels-Alder reaction of enones with cyclic imines.

187 retro-Diels-Alder reaction of its adduct with N-benzylpyrrole

188 The Diels-Alder reaction of juglone with various styrenes in

189 carbohydrate template in the intramolecular Diels-Alder reaction of MOBs were revised.

190 lished through the one-pot oxidative nitroso-Diels-Alder reaction of N-arylhydroxylamines with diene

191 phosphoric acid-catalyzed asymmetric nitroso-Diels-Alder reaction of nitrosoarenes with carbamate-die

192 Herein, we review the application of the Diels-Alder reaction of quinones in the total synthesis

193 d using a microwave-assisted dehydrogenative Diels-Alder reaction of styrene, followed by a palladium

194 ex environments: the inverse electron-demand Diels-Alder reaction of tetrazines with 1,3-disubstitute

195 was achieved in four steps through a hetero Diels-Alder reaction of the 5-alkoxyoxazole and acrylic

196 ized via a highly regio- and stereoselective Diels-Alder reaction of the diene 4 and the novel dienop

197 d a highly diastereoselective intramolecular Diels-Alder reaction of the formed ene-diene to generate

198 ntioselective inverse-electron-demand hetero-Diels-Alder reaction of the remote olefin functionality

199 lectivity using as the key step the stepwise Diels-Alder reaction of the very hindered dienone 3 and

200 cedure for the mild, practical, and scalable Diels-Alder reaction of tropones with arynes is reported

201 ted the origins of regioselectivities in the Diels-Alder reaction of vinylindene with a 1,4-quinone m

202 tematic study of the inverse electron demand Diels-Alder reactions of 1,2,3-triazines is disclosed, i

203 tepwise mechanism of inverse electron-demand Diels-Alder reactions of 1,2,3-triazines, and that these

204 In inverse-electron-demand Diels-Alder reactions of 3,6-dimethyltetrazine and 3,6-b

205 ne catalysis, asymmetric three-component aza-Diels-Alder reactions of 5-, 6-, and 7-membered cyclic k

206 cture a perfect molecular vessel to catalyze Diels-Alder reactions of 9-hydroxymethylanthracene with

207 Diels-Alder reactions of a range of 1-(alkoxy/alkyl/halo

208 Thermal Diels-Alder reactions of alpha-amido acrylates with N-Cb

209 bene (NHC)-catalyzed redox asymmetric hetero-Diels-Alder reactions of alpha-aroyloxyaldehydes with be

210 ms of recently reported Lewis acid-catalyzed Diels-Alder reactions of arylallenes and acrylates were

211 The previously observed Diels-Alder reactions of arynes with arene were not obse

212 Thermal Diels-Alder reactions of chiral 9-methoxyethyl and 9-hyd

213 The activation free energies for the Diels-Alder reactions of cyclic 1-azadienes are 10-14 kc

214 The Diels-Alder reactions of cyclic linear and cross-conjuga

215 The intramolecular Diels-Alder reactions of cycloalkenones and terminal die

216 Intramolecular Diels-Alder reactions of cyclobutenone and larger cycloa

217 and molecular mechanics calculations for the Diels-Alder reactions of cyclopentadiene with 1,4-naphth

218 The Diels-Alder reactions of cyclopentadiene, cyclohexadiene

219 Diels-Alder reactions of cyclopentadienones, to afford s

220 The synthesis and Diels-Alder reactions of cyclopropenyl ketones are descr

221 dicate that the barriers associated with the Diels-Alder reactions of ethyl nitrosoacrylate are over

222 An examination of Diels-Alder reactions of furan-containing analogues of d

223 istry on the rate of force-accelerated retro-Diels-Alder reactions of furan/maleimide adducts.

224 to catalysis of the inverse electron demand Diels-Alder reactions of heterocyclic azadienes has been

225 degree of correlation with relative rates in Diels-Alder reactions of methyl vinyl ketone and cyclope

226 rk can be constructed through intramolecular Diels-Alder reactions of propiolate-derived enynes follo

227 astereoselective inverse electron demand oxa-Diels-Alder reactions of resorcinarene ortho-quinone met

228 The Diels-Alder reactions of seven 1,2,4,5-tetrazines with u

229 reactivities and stereoselectivities in the Diels-Alder reactions of substituted cyclopropenes with

230 The Diels-Alder reactions of the cycloalkenes, cyclohexene t

231 n the absence of significant steric effects, Diels-Alder reactions of the title quinone generally tak

232 These inverse electron-demand Diels-Alder reactions of triazines have wide application

233 ifferent cobalt(I) species in regioselective Diels-Alder reactions of unactivated substrates and iden

234 act as efficient catalysts in regioselective Diels-Alder reactions of unactivated substrates such as

235 rough a common biomimetic strategy involving Diels-Alder reactions of unusual double diene containing

236 equence consisting of a Lewis acid-catalyzed Diels-Alder reaction on a 2-halocyclohexenone, followed

237 Sequential Diels-Alder reactions on a tautomerized naphthazarin cor

238 It is observed that the Diels-Alder reaction only displays high diastereoselecti

239 tone, which may proceed as a concerted [4+2] Diels-Alder reaction or a stepwise [6+4] cycloaddition f

240 lallene exhibits exceptional reactivity as a Diels-Alder reaction partner and engages in [4 + 2] cycl

241 The Diels-Alder reaction presents a number of positive attri

242 utational investigations revealed that these Diels-Alder reactions proceed via transition state struc

243 nd several Lewis acid induced intramolecular Diels-Alder reactions remained fruitless, dialkylaluminu

244 The Diels-Alder reaction represents one of the most thorough

245 molecular versions of this tridehydro (-3H2) Diels-Alder reaction support a concerted mechanism for t

246 In addition to Diels-Alder and hetero-Diels-Alder reactions, tetrafluoro-o-benzoquinone (o-flu

247 t molecule featured a novel bis-transannular Diels-Alder reaction that casted stereoselectively the d

248 As expected for the inverse-electron-demand Diels-Alder reaction, the rate constants of the cycloadd

249 Although in most stepwise Diels-Alder reactions, the subsequent ring closure has u

250 is compared with our silylium ion-catalyzed Diels-Alder reactions, thereby clearly corroborating tha

251 ding a chiral amine-catalyzed intramolecular Diels-Alder reaction to afford 22 in excellent diastereo

252 d stereocontrolled strategy that relies on a Diels-Alder reaction to construct the cis-fused 6,5-carb

253 y a highly diastereoselective intramolecular Diels-Alder reaction to fashion the fused tricyclic hydr

254 e cycloetherification, and an intermolecular Diels-Alder reaction to forge the carbocyclic core in a

255 Cycloadditions, such as the [4+2] Diels-Alder reaction to form six-membered rings, are amo

256 ridge in one step, and a stereoselective exo-Diels-Alder reaction to form the 6-membered ring.

257 raints on the organocatalyzed intramolecular Diels-Alder reaction to form the isobenzofuran core of t

258 the polyol chain, a Ti-catalyzed asymmetric Diels-Alder reaction to generate the cis-decalin skeleto

259 dravine, respectively, were found to undergo Diels-Alder reactions to afford mixtures of regioisomeri

260 ared and subsequently used as dienophiles in Diels-Alder reactions to form building blocks for the sy

261 a significant enhancement for application of Diels-Alder reactions to many synthetic targets.

262 The distortion energy of the Diels-Alder reaction transition states mostly arises fro

263 and synthetic procedures involving multiple Diels-Alder reactions under harsh extended reaction cond

264 We further report that double Diels-Alder reactions under solvent-free condition provi

265 nthetic sequence features a highly effective Diels-Alder reaction using a carbamate-substituted silox

266 The origins of chirality transfer in the Diels-Alder reaction using chiral arylallenes are uncove

267 oevenagel condensation/intramolecular hetero Diels-Alder reaction using O-(arylpropynyloxy)-salicylal

268 The exo-selective asymmetric Diels-Alder reactions using Evans' oxazolidinone chiral

269 The regioselectivities of several Diels-Alder reactions utilized en route to bisanthraquin

270 tions: intramolecular Diels-Alder and hetero-Diels-Alder reactions via a single ambimodal transition

271 additions through enamine intermediates, in Diels-Alder reactions via trienamine catalysis, and in a

272 The reactivity of macrocyclic bis-enones in Diels-Alder reactions was examined using quantum chemica

273 By taking advantage of an intramolecular Diels-Alder reaction, we have developed a prodrug strate

274 Computational results for these Diels-Alder reactions were consistent with the experimen

275 acenes are attached to this module using the Diels-Alder reaction, which also forms one of the acene

276 -1,2,4-triazoline-3,5-dione undergo a formal Diels-Alder reaction, which following an S(N)2' solvolys

277 vergent course of the central intramolecular Diels-Alder reaction, which is dependent on the nature o

278 em process involving a highly regioselective Diels-Alder reaction with alkynes, quinones or nitriles

279 h then reacts in an inter- or intramolecular Diels-Alder reaction with an alkenyl or alkynyl dienophi

280 of ethylene) to 2,4-hexadiene followed by a Diels-Alder reaction with ethylene to form 3,6-dimethylc

281 rization of enzymes catalyzing a bimolecular Diels-Alder reaction with high stereoselectivity and sub

282 versible Diels-Alder reactions, a reversible Diels-Alder reaction with the less electron-deficient me

283 an-containing CPP precursor was used for the Diels-Alder reaction with the parent benzyne or 3,6-dime

284 lopentadiene and the inverse electron-demand Diels-Alder reactions with 3,6-bis(trifluoromethyl)tetra

285 e examined to determine the mechanism of the Diels-Alder reactions with an allene dienophile.

286 ocyclic carbene (NHC)-catalyzed redox hetero-Diels-Alder reactions with azolium enolates generated fr

287 ere is an opposite regiochemical outcome for Diels-Alder reactions with beta-aryl substituted juglone

288 In normal Diels-Alder reactions with cycloalkenes, the electron-ri

289 The normal electron-demand Diels-Alder reactions with cyclopentadiene and the inver

290 The products participated in Diels-Alder reactions with electron-deficient alkenes an

291 These routes involve Diels-Alder reactions with ethylene and avoid the hydrog

292 e, and their 1-aza- and 2-aza-derivatives in Diels-Alder reactions with ethylene and fumaronitrile we

293 Several simple-looking but challenging Diels-Alder reactions with exceptionally rare dienophile

294 with a cyclopropene moiety were designed for Diels-Alder reactions with inverse electron demand, and

295 Upon tandem Diels-Alder reactions with several symmetrical as well a

296 Nitrofurans undergo intramolecular Diels-Alder reactions with tethered electron-poor dienop

297 vities of alkenes compared to alkynes in the Diels-Alder reactions with tetrazines arise from the dif

298 eraction energies in inverse-electron-demand Diels-Alder reactions with tetrazines.

299 generation of benzynes-through a hexadehydro-Diels-Alder reaction-with their in situ elaboration into

300 lysts capable of unlocking new and efficient Diels-Alder reactions would have major impact.