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1 Ge et al. now show that skin tumors exhibit merged chrom
2 Ge-Sb-Te alloys have been widely used in optical/electri
3 H18(-) or as a large hypho-deltahedron of 18 Ge-atoms with a triangle of Pd3 inside, i.e., [Pd3@Ge18(
4 nthesis of a diphosphagermylene, [(Dipp)2P]2 Ge, in which one of the P centers is planar (Dipp=2,6-di
6 the salt [K([18]-crown-6)](2)K(2)[(MesCu)(2)Ge(4)](NH(3))(7.5) with the polyanion [(MesCu)(2)Ge(4)](
7 pped Au squares (or corner-shared Au(Au(4/2))Ge octahedra), in which the apical Au-Ge pairs in adjoin
9 rdinate germanium cation [(IDipp){(Me3Si)2CH}Ge:](+) has been synthesized, which lacks pi-donor stabi
15 igh spin polarization at the Co2FeSi0.5Al0.5/Ge interface, hence can be used as a model to study spin
18 mined new relative response ratios for a (68)Ge solid epoxy mock syringe source used in activity cali
19 pH range, enabling direct elution from a (68)Ge/(68)Ga generator into a lyophilized radiopharmaceutic
20 r averaged 80% (range, 72.0%-95.1%), and (68)Ge breakthrough was less than 0.006%, initially decreasi
21 d relative response ratios for (18)F and (68)Ge by -3.7%, allowing users of the commercial mock syrin
24 A good-manufacturing-practices (GMP) (68)Ge/(68)Ga generator that uses modified dodecyl-3,4,5-tri
25 68)Ga from coeluted metallic impurities ((68)Ge(4+), Fe(3+), Zn(2+), and Ti(4+)) on various cation-ex
26 me to 0.001% (expressed as percentage of (68)Ge activity present in the generator at the time of elut
31 rces, identical in geometry to the solid (68)Ge epoxy calibration source currently on the market, wer
35 ribution pattern and the feasibility of (69) Ge-SPION@PEG for in vivo dual-modality positron emission
38 e Zeeman splitting to the cyclotron gap in a Ge two-dimensional hole system increases with decreasing
40 ion is actually a vertical displacement of a Ge layer through a Te layer, followed by a lateral motio
41 posed crystal structures, which consist of a Ge parent crystal in which the P atoms form a third-near
43 cubic symmetry in the Fe film deposited on a Ge buffer is surprising, and we discuss possible reason
46 tobleaching (PB) and transient PD (TPD) in a-Ge(x)As(35-x)Se65 thin films as a function of network ri
48 r, we study the crystallization of amorphous Ge using atomistic simulations of critical nano-metric n
49 form-diameter Si cores, Ge onto Ge cores and Ge onto Si cores can generate diameter-modulated core-sh
51 e, anode, and cathode, based on the Li-S and Ge-S components in Li10GeP2S12 acting as the active cent
52 d electronic properties of partial C, Si and Ge decorated graphene were investigated by first-princip
55 rsification of the bulk properties of Si and Ge, in complete agreement with the available experimenta
58 Ge x alloys as a function of temperature and Ge concentration can be described by the cBOmega thermod
60 u(4/2))Ge octahedra), in which the apical Au-Ge pairs in adjoining nets are strongly interbonded in t
63 p, is exo-bonded to one of the six available Ge atoms with the Ge-C bond positioned radially to the G
64 rication of uniform diameter, direct bandgap Ge(1-x)Sn(x) alloy nanowires, with a Sn incorporation up
67 lifted within Si quantum wells clad between Ge-Si alloy barrier layers, but the magnitude of the val
68 source MBE by tuning the interaction between Ge-based P(GeH3)3 precursors and In atoms to yield nanos
71 of the equilibrium solubility of Sn in bulk Ge, through a conventional catalytic bottom-up growth pa
73 This commentary highlights the article by Ge et al, which proposes the use of methylation and expr
76 monstrate that the strong donor ability of C-Ge sigma-bonds can be used to raise the energy of the an
77 on increases conductance: for example, the C-Ge-C sequence is over 20 times more conductive than the
78 s an effective precatalyst for the catalytic Ge-H dehydrocoupling of (t)BuGeH3 to form ((t)BuGeH2)2 (
83 sized by salt-metathesis reaction of [L2 (Cl)Ge:] 1 with sodium phosphaethynolate [(dioxane)n NaOCP].
84 in toluene gives compounds [(LB)Ge(II)Cl](+)[Ge(II)Cl(3)](-) (1) and [(LB)Sn(II)Cl](+)[Sn(II)Cl(3)](-
85 alised interface structure, terminated by Co-Ge bonds, preserves the high spin polarization at the Co
87 Importantly, for a fixed Se concentration, Ge:As ratio plays the critical role in controlling the n
88 deposition conditions, leading to controlled Ge enrichment of the solid product relative to the stoic
89 epositing Si onto uniform-diameter Si cores, Ge onto Ge cores and Ge onto Si cores can generate diame
90 conduction at crystalline Si and crystalline Ge interfaces and found that more than 15% of the interf
94 esents the first three-coordinate dicationic Ge(II) species stabilized by an anionic bis(NHC) chelate
97 group 14 species Ar(iPr(4))EEAr(iPr(4)) (E = Ge, Sn), which give very different product structures.
98 II) pincer complexes with E = Si(II) and E = Ge(II) metallylene donor arms were synthesized via C-X (
100 ocytoplasmic proteins; rck/p54, Dcp1a, Edc3, Ge-1, and Xrn1 are insensitive to LMB and remain cytopla
103 a Zintl phase and thus represents the first Ge=Ge double bond under such conditions, as also suggest
104 nomena described in this Tutorial Review for Ge/Si should be relevant for other lattice-mismatched he
106 magnetic centers by diamagnetic ions [e.g., Ge(IV)] allows one to "switch off" specific spin sites i
107 tion mediated by the germylene (germanediyl) Ge(Ar(Me6))2 (Ar(Me6) = C6H3-2,6(C6H2-2,4,6-Me3)2) showe
111 is work, Mg was microalloyed with germanium (Ge), with the aim of improving corrosion resistance by r
117 exists in MC-ICPMS, e.g., Nd, Ce, W, Sr, Hf, Ge, Hg, and Pb isotopes, the nature of mass bias for Si
120 e study the dynamics of radiation defects in Ge in the temperature range of 100-160 degrees C under p
121 evious work showing site-selective doping in Ge-Si core-shell nanowires, we find both an enhancement
122 ent that can be traced with the red shift in Ge K edge energy which is also identified by the princip
123 lysts permitted a greater inclusion of Sn in Ge nanowires compared with conventional Au catalysts, wh
124 (PL) attributed to emission from individual Ge nanocrystals (nc-Ge) spatially resolved using micro-p
126 of GeSe displays a boat conformation for its Ge-Se six-membered ring ("six-ring"), while the previous
127 -digermylium-2,4-diphosphacyclobutadiene [L2 Ge(mu-P)2 GeL2 ] 4 and bis(germyliumylidenyl)-substitute
128 myliumylidenyl)-substituted diphosphene [(L2 Ge-P=P-GeL2 )] 5 could also be obtained in moderate yiel
129 the entire PCO group, the unprecedented [L2 Ge-GeL2 ] complex 3 in 54 % yields bearing the Ge2(2+) i
130 gorithm to optimize the structure of layered-Ge/Si-clad Si quantum wells to improve this splitting.
131 and SnCl(2) in toluene gives compounds [(LB)Ge(II)Cl](+)[Ge(II)Cl(3)](-) (1) and [(LB)Sn(II)Cl](+)[S
132 rangements and phase evolution of various Li-Ge alloy phases during (de)alloying reactions with lithi
134 luorination of LMNMe2 (L = PhC(N(t)Bu)2, M = Ge, Sn) using HF.pyridine in toluene leads to the format
135 ate class of iron chalcogenides, Fe2MS4 (M = Ge, Si) has been proposed as a possible alternative to p
136 n(II) hydride complexes, L(dagger)(H)M: (M = Ge or Sn, L(dagger) = -N(Ar(dagger))(SiPr(i)3), Ar(dagge
137 = Tb, Dy, Er, Ho, and X = S, Se), UMGe (M = Ge, Rh, Co), CeCoIn5, EuFe2(As(1-x)P(x))2, etc.], provid
138 se can be attributed to the unusual metallic Ge-Ge bonds which act in a similar way to organic chromo
139 dominant tunnelling from the lower moment Mn-Ge termination layers that are oppositely magnetized to
141 es of the prism interacting with one or more Ge atoms in three crystallographically different molecul
142 We identify an optimal sequence of multiple Ge/Si barrier layers that more effectively isolates the
144 emission from individual Ge nanocrystals (nc-Ge) spatially resolved using micro-photoluminescence and
145 stics and we argue that the spread of the nc-Ge peaks in the PL spectrum is due to different confinem
146 r-sharing tetrahedra units together with new Ge-O bond formation and decrease in energetically unstab
147 hollow nickel germanide nanostructures of Ni-Ge core-shell nanoparticles by solid state reactions.
150 atoms during nanowire growth by comparing nu(Ge-H) absorption bands from operando measurements (i.e.,
152 The most recent advances in the area of Ge-based nanocomposite electrode materials and electroly
153 X = N,P,As} semiconductors to a new class of Ge-III-V hybrid compounds, leading to the creation of (I
154 modynamic equilibrium, where condensation of Ge adatoms on SiO2 is disfavored due to the extremely sh
156 We use strain to increase the diffusivity of Ge and Te atoms that are confined to 5 A thick 2D planes
158 electrics and also promotes the formation of Ge vacancies to provide enough carriers for electrical t
162 eveals that there is a small outdiffusion of Ge into specific atomic planes of the Co2FeSi0.5Al0.5 fi
171 dra which are linked by a Zn atom, with one (Ge(4)) tetrahedron coordinating with a triangular face (
172 g Si onto uniform-diameter Si cores, Ge onto Ge cores and Ge onto Si cores can generate diameter-modu
175 ) of metal germanides and silicides on Si or Ge find that these vary with the facet, unlike those of
176 porous Pt anode and the deposition of Si or Ge under bias at the cathode from chloride-based gaseous
178 phosphaketenyl germyliumylidene [(L2 (O=C=P)Ge:] 2 (L2 =(p-tolyl)2 B[1-(1-adamantyl)-3-yl-2-ylidene]
180 e distance suggest a significant degree of P-Ge multiple bond character that is due to delocalization
181 his P center and the correspondingly short P-Ge distance suggest a significant degree of P-Ge multipl
182 ascinating compounds containing P-C, P-Si, P-Ge, and P-P bonds using a single step with a base-stabil
183 ied to access the analogous addition product Ge-Au-Fe3O4, allowing tuning between two distinct hetero
186 2](4-) unit is characterized by the shortest Ge-Ge distance (2.390(1) A) ever observed in a Zintl pha
189 ermal and photobehavior of XH2OO (X = C, Si, Ge, and Sn) that serve as precursors for dioxiranes, an
190 ing functionalized E=E multiple bonds (E=Si, Ge, Sn, Pb) because of their potential to exhibit novel
192 y of materials (WHM with W = Zr, Hf; H = Si, Ge, Sn; M = O, S, Se, Te) with identical band topology.
193 ions of low-bandgap semiconductors (InP, Si, Ge, PbS, InAs and Te) in an insulating composite to tail
195 ions of internal alkynes with R3M-H (M = Si, Ge, Sn) follow an unconventional trans-addition mode in
196 chalcogenolates of formula M(ChAr)2 (M = Si, Ge, Sn, Pb; Ch = O, S, or Se; Ar = bulky m-terphenyl lig
197 tal group IV compounds (carbon nanodots, Si, Ge), III-V compounds (e.g., InP, InAs), and binary and m
198 germanene and stanene (2D allotropes of Si, Ge, and Sn), lends itself as a platform to probe Dirac-l
201 agnetic half-metal compounds Co2TiX (X = Si, Ge, or Sn) with Curie temperatures higher than 350 K.
202 ional (2D) crystals termed 2D-Xenes (X = Si, Ge, Sn and so on) which, together with their ligand-func
203 (NCs) of lithiated group 14 elements (Z=Si, Ge, and Sn) is reported, which are Li4.4 Si, Li3.75 Si,
204 e substitutional incorporation of Sn into Si-Ge and yields materials with superior quality suitable f
205 which is also associated with negligible Si-Ge intermixing owing to geometric hindrance by the Si na
207 vier group 14 and 15 elements to afford Si-, Ge-, As- or Sb-decorated POV structures (heteroPOVs).
211 nanoscale size effect, silicon/germanium (Si/Ge) superlattice nanowire (SNW) can have very low therma
212 how that periodically arranged defects in Si/Ge H-SNW lead to a ~38% reduction of the already low the
214 t the already low thermal conductivity of Si/Ge SNW can be further reduced by introducing hierarchica
217 ith respect to the N atom attached to the Si/Ge center has been found to be the most effective way of
218 ty and reactivity differences between the Si/Ge hydride sources in terms of a complex interplay among
222 Previous work has demonstrated that Sn, Ge, Cu, Bi, and Sb ions could be used as alternative ion
224 raphic defect content of the resultant solid Ge films were analyzed by electron backscatter diffracti
227 he band gap and electronic structure of ST12-Ge (tP12, P43212) due to experimental limitations in sam
229 vidence for the intrinsic properties of ST12-Ge, including the first optical measurements on bulk sam
231 es, by synthesis of (29)Si-enriched starting Ge-UTL frameworks and incorporation of (17)O from (17)O-
232 ial modulation doping in coherently strained Ge-SixGe1-x core-shell nanowires and a technique to dire
233 -assembled growth of highly tensile-strained Ge/In0.52Al0.48As (InAlAs) nanocomposites by using spont
234 e, the careful control of the supersaturated Ge layer allows us to obtain perfectly site-controlled,
236 ectron chemical oxidation of the symmetrical Ge(0) compound K2[(boryl)GeGe(boryl)] and its subsequent
238 t reaction in CCl3Br(l) formed Br-terminated Ge(111), as shown by the disappearance of the Ge-H absor
239 l cations A(+) (A = K, Rb), two tetrahedral [Ge(4)](4-) Zintl anions, and one anionic heterometallic
240 ed characterization methods demonstrate that Ge islands are dislocation-free and heteroepitaxial stra
241 n a combined analysis herein, we report that Ge is potent in supressing the cathodic hydrogen evoluti
248 ribbons are self-aligning 3 degrees from the Ge<110> directions, are self-defining with predominantly
250 non-equilibrium incorporation of Sn into the Ge nanowires can be understood in terms of a kinetic tra
253 the observed high crystalline quality of the Ge islands which is also associated with negligible Si-G
254 e(111), as shown by the disappearance of the Ge-H absorption in the FTIR spectra concomitant with the
260 nd alternating current simultaneously to the Ge-based Schottky devices, where the rectification magne
261 e addition of an annealing step close to the Ge-Sn eutectic temperature (230 degrees C) during cool-d
264 ations surrounded by the pi systems of three Ge dumbbells, further underlines this interpretation.
265 nic ligand (R) that runs from T = Si through Ge to Sn and from R = methyl through phenyl and p-styryl
267 resonance is an excellent probe to follow Ti/Ge disorder, as it is sensitive to the atomic scale envi
268 ed here, PO4 units are surrounded by four Ti/Ge octahedra, and then, five different components ascrib
269 analysis of detected components, a random Ti/Ge distribution has been deduced in next nearest neighbo
270 Structural addition of only 0.95% wt Fe to Ge-imogolite not only alleviated the toxicity observed i
271 V semiconductor systems, colloidal routes to Ge NPs with uniform sizes and shapes are much less matur
273 The products contain the trifluorinated Ge(II) and Sn(II) anionic species which are stabilized b
275 -carrier density modulation in an underlying Ge(001) substrate by switching of the ferroelectric pola
276 tching on the conductivity of the underlying Ge is measured using microwave impedance microscopy, cle
277 o surface bonding are critical to understand Ge nanowire synthesis and provide new guidelines for rat
279 studies of [(HCDippN)2B]2GeGe reveal a weak Ge-Ge double bond-the pi component of which contributes
280 ntains double four-membered-ring units where Ge is preferentially located, and fluoride anions are pl
281 ed by molecular beam epitaxy growth, whereas Ge-based germanene was obtained by molecular beam epitax
286 Here we show that, self-diffusion in Si1-x Ge x alloys as a function of temperature and Ge concentr
287 n9Cl5O68.(H2O)m]n (1, X = Si, m = 35; 2, X = Ge, m = 41), and the molecular tetramer Na6[{Na(mu-OH2)(
289 e that the resultant monocrystalline (InP)(y)Ge(5-2y) alloys with y = 0.3-0.7 are tetragonally strain
291 n of photoluminescence suggests that (InP)(y)Ge(5-2y) may have important optoelectronic applications.
296 , Mg, Si, Cl, Ca, Ti, V, Cr, Fe, Ni, Cu, Zn, Ge, Se, Br, Sr, Mo, Ag, Cd, Sn, Sb, Te, Ba, W, Pt, Hg, T
297 we report a novel orange zinc germanate (Zn-Ge-O) with a chromophore-like structure, by which the ab
298 om the enhanced light harvest, the orange Zn-Ge-O demonstrates superior capacity for solar-driven hyd
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