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1 MOF-1201 shows a 100 times lower release rate compared w
2 MOFs may prove useful in the dissipation of shock wave e
3 MOFs represent the development of covalent chemistry "be
4 MOFs that have failed to be activated previously can ach
5 MOFs with widely varied fluorometric sensing properties
6 MOFs, constructed by the designed assembly of metal ions
9 methylphosphonate (DMMP), on UiO-66, UiO-67, MOF-808, and NU-1000 using synchrotron-based X-ray powde
10 0,11-hexaiminotriphenylene)2 (Ni3(HITP)2), a MOF with high electrical conductivity, can serve as the
14 res and internal diameters of 7.8 and 9.6 A (MOF-1201) and 4.6 and 5.6 A (MOF-1203), respectively.
16 higher concentration of monocarboxylic acid MOFs were isostructural but suffered from increased fwhm
17 m and constructed the first indium-based alb-MOF, In-alb-MOF, by employing trinuclear [In3(mu3-O)(O2C
18 ucted the first indium-based alb-MOF, In-alb-MOF, by employing trinuclear [In3(mu3-O)(O2C-)6] as the
23 construction of composite MOFs and amorphous MOFs, as well as providing new synthetic routes for MOF
24 n biomedical settings and the addition of an MOF coating opens the way for the sensing of volatile or
25 te metathesis and metal node extension in An-MOFs are reported, and the results of the former approac
28 lopments in the field of luminescent MOF and MOF-based photonic crystals/thin film sensory materials.
30 hree- and multi-photon absorption in CPs and MOFs is further supplemented with application-oriented p
31 onlinear optical (NLO) properties of CPs and MOFs, with a closer look at the two-photon absorption pr
33 c microporous materials such as zeolites and MOFs, a field of research that has emerged some 15 years
34 ne) acetyltransferase 8 (KAT8, also known as MOF) mediates the acetylation of histone H4 at lysine 16
35 present a mesoporous cationic thorium-based MOF (SCU-8) containing channels with a large inner diame
36 to transplant shp topology into copper-based MOFs by employing the copper paddlewheel [Cu2(O2C-)4] as
37 trakis(p-benzoic acid)pyrene; H4TBAPy)-based MOFs: ROD-7 (In2(OH)2TBAPy, frz), NU-901 (scu), and NU-1
38 chemical warfare agent simulants on Zr-based MOFs open new opportunities in rational design of new an
39 L-125, a TiO2/1,4-benzenedicarboxylate (bdc) MOF for the oxidation of benzyl alcohol to benzaldehyde
40 d H2S and NO detectors reported and the best MOF-based chemiresistive sensors for these analytes.
41 cyclo[2.2.2]octane dicarboxylic acid (BODCA)-MOF, a metal-organic framework (MOF) built with a high-s
42 he bicyclo[2.2.2]octane (BCO) group in BODCA-MOF constitutes an example where engineered rotational d
44 is similar to the mechanism behind breathing MOFs, but is unique because the deformation pattern exte
45 Zr6(mu3-O)4(mu3-OH)4(HCO2)6 nodes in Zr-BTC (MOF-808) to the [Zr6(mu3-O)4(mu3-OH)4Cl12](6-) nodes in
47 amage repair pathways that are controlled by MOF, as correlated with a significant increase in yH2AX
51 on the part of the Li(+) ions in the new CD-MOF has been confirmed by single-crystal X-ray analysis
53 e capacities of the Li(+)-ion-substituted CD-MOF have been shown to exceed the highest sorption capac
56 the Ca(2+) counterions of a preformed chiral MOF of formula Ca6(II){Cu(II)24[(S,S)-hismox]12(OH2)3}.2
57 Reported herein are two new polymorphic Co-MOFs (CTGU-5 and -6) that can be selectively crystallize
58 tructural integrity, as the parent cobaltous MOF retains its crystallinity and porosity even after th
59 n characteristics, construction of composite MOFs and amorphous MOFs, as well as providing new synthe
60 e dispersed Zr sites present in the confined MOF, and the loading of the mesoporous SiO2 , is demonst
61 the design and synthesis of highly connected MOFs based on reticulation of the sole two edge-transiti
62 hat, unlike other dithienylethene-containing MOFs, the properties of the pore can be changed via an o
64 ies the structural diversity of conventional MOFs can also be applied to the self-assembly of protein
66 mechanically robust conformed and densified MOFs for high volumetric energy storage and other indust
68 onditions to synthesize readily exfoliatable MOF nanosheets, functionalized in situ by adopting the g
70 h yielded an expanded library of 15 ferritin-MOFs with the expected body-centered (cubic or tetragona
71 attice symmetries and dimensions of ferritin-MOFs can be dictated by both the metal and linker compon
72 tablishes that the self-assembly of ferritin-MOFs is highly robust and that the synthetic modularity
73 rystalline samples reveal that some ferritin-MOFs can adopt multiple lattice conformations, suggestin
74 rthermore, the bromine pre-adsorbed flexible MOFs can be used as generic bromine sources for brominat
77 3.02; P < .05), and benzodiazepines (aHR for MOF, 1.15; 95% CI, 1.04-1.26; P < .05; aHR for hip fract
78 1.18-1.85; P < .05), antipsychotics (aHR for MOF, 1.43; 95% CI, 1.15-1.77; P < .05; aHR for hip fract
79 ctive serotonin reuptake inhibitors (aHR for MOF, 1.43; 95% CI, 1.27-1.60; P < .05; aHR for hip fract
80 ortunities and challenges are identified for MOF-enabled device functionality and technological appli
84 r, which is amongst the highest reported for MOFs under these conditions and is much higher than the
85 fraction measurements indicate that all four MOFs adsorb DMMP (introduced at atmospheric pressures th
87 e critical steps in metal-organic framework (MOF) activation involving solvent exchange and solvent e
88 ered nanopores of a metal-organic framework (MOF) are exploited to encapsulate and homogeneously disp
89 a chiral Cu(II) 3D metal-organic framework (MOF) based on the tripeptide Gly-l-His-Gly (GHG) for the
90 acid (BODCA)-MOF, a metal-organic framework (MOF) built with a high-symmetry bicyclo[2.2.2]octane dic
91 recently developed metal-organic framework (MOF) catalyst for the dimerization of ethylene has a com
92 bility underpinning metal-organic framework (MOF) confers a versatile platform to contrive next-gener
93 The aluminum-based metal-organic framework (MOF) made from 2-aminoterephthalate is a photocatalyst f
94 on the nodes of the metal-organic framework (MOF) NU-1000 are active for oxidation of methane to meth
95 Kr, and Xe) on the metal-organic framework (MOF) NU-1000, which is one of the most thermally stable
97 in a robust azolate metal-organic framework (MOF) to produce stable and safe-to-handle Co(III) materi
98 ovel Cu(II)-azolate metal-organic framework (MOF) with tubular pores undergoes a reversible single cr
99 e-functionalized Zr metal-organic framework (MOF), UiO-66-NH2 (Pt@UiO-66-NH2 ) as a multifunctional c
100 ed rare-earth-based metal-organic framework (MOF), with dual functionality for moisture control withi
101 a robust and porous metal-organic framework (MOF), Zr12-TPDC, constructed from triphenyldicarboxylic
102 microstructure of metal-organic frameworks (MOFs) after postsynthetic exchange (PSE) reveals that th
103 are a subclass of metal-organic frameworks (MOFs) amenable to significant property tuning by alterin
104 , the potential of metal-organic frameworks (MOFs) and covalent organic frameworks (COFs) as platform
107 cs, titanium based metal-organic frameworks (MOFs) are one of the most appealing classes of MOFs repo
112 The influence of metal-organic frameworks (MOFs) as additives is herein described for the reaction
113 cal feasibility of metal-organic frameworks (MOFs) as novel delivery systems for encapsulation and co
114 niversity of Oslo) metal-organic frameworks (MOFs) can be transformed into self-propelled micromotors
115 able properties of metal-organic frameworks (MOFs) can be tuned by chemical functionalization of the
117 ification (PSM) of metal-organic frameworks (MOFs) has attracted much attention due to the possibilit
118 urface tunability, Metal-Organic Frameworks (MOFs) have been gaining popularity as candidates for enz
124 o-dimensional (2D) metal-organic frameworks (MOFs) into fabrics through direct solution-phase self-as
125 rol of porosity of metal-organic frameworks (MOFs) is of critical importance to their materials funct
126 compounds, called metal-organic frameworks (MOFs) or coordination polymers, has been investigated in
128 polymers (CPs) and metal-organic frameworks (MOFs) results not only in a plethora of materials that c
129 or applications of metal-organic frameworks (MOFs) such as gas storage and separation, flexibility is
130 n this manuscript, metal-organic frameworks (MOFs) were investigated as a model system for engineerin
132 is the subclass of metal-organic frameworks (MOFs) with pore aperture sizes below 5-7 A, namely ultra
133 Two porous, chiral metal-organic frameworks (MOFs), Ca14(l-lactate)20(acetate)8(C2H5OH)(H2O) (MOF-120
135 (metallo)porphyrin metal-organic frameworks (MOFs), ZrPP-n (n = 1, 2), featuring infinite Zr(IV) -oxo
136 aviour of flexible metal-organic frameworks (MOFs)-porous crystalline materials that undergo a struct
141 ctricity in chiral metal-organic frameworks (MOFs): following a single-crystal to single-crystal cati
142 y exhibit effective selectivity derived from MOF cavities, but also enhanced catalytic activity due t
143 ged as a versatile approach to functionalize MOF surfaces with a wide variety of catalytic metal-oxo
145 linkers presented by the topology of a given MOF that are primed to form such an excited state comple
150 OF-1201) and Ca6(l-lactate)3(acetate)9(H2O) (MOF-1203), are constructed from Ca(2+) ions and l-lactat
151 ), Ca14(l-lactate)20(acetate)8(C2H5OH)(H2O) (MOF-1201) and Ca6(l-lactate)3(acetate)9(H2O) (MOF-1203),
152 of a series of 14 interpenetrated Zr and Hf MOFs linked by functionalized 4,4'-[1,4-phenylene-bis(et
155 n control of the chemistry of CO2 capture in MOF materials and one that highlights the importance of
157 Notably, atomic layer deposition (ALD) in MOFs has recently emerged as a versatile approach to fun
158 The uniform catalytic sites available in MOFs provide a unique opportunity to directly study reac
160 hese studies demonstrate that metal nodes in MOFs mimic homogeneous catalysts not just functionally,
162 servation, 5750 (8.4%) sustained an incident MOF, 1579 (2.3%) sustained an incident hip fracture, and
164 easure the mechanical behavior of individual MOF nanocrystals under compression within a transmission
165 gy that enables MNPs to be encapsulated into MOFs with controllable spatial localization by using met
168 cal developments in the field of luminescent MOF and MOF-based photonic crystals/thin film sensory ma
169 moderate solvothermal conditions could make MOFs an exceptionally powerful tool to address fundament
171 the latest developments in ultra-microporous MOF adsorbents and their use as separating agents via th
173 sizes below 5-7 A, namely ultra-microporous MOFs, which in contrast to conventional zeolites and act
174 r to the surface of MOFs, the resultant MNPs@MOF composites not only exhibit effective selectivity de
175 Nanoindentation tests on the monolithic MOF showed robust mechanical properties, with hardness a
176 of a supercapacitor made entirely from neat MOFs as active materials, without conductive additives o
178 ylene rings, we construct moisture-stable Ni-MOF-74 members with adjustable pore apertures, which exh
179 ighlights the opportunity in designing novel MOF-supported single-site solid catalysts by tuning the
182 for a series of isoreticular octacarboxylate MOFs, denoted MFM-180 to MFM-185, via a strategy of sele
183 al conditions were as follows: the amount of MOF-545, 10mg; pH of sample, 7; adsorption and elution t
187 his review summarizes recent developments of MOF-enzyme composites with special emphasis on preparati
191 ain its position as the definitive method of MOF structure determination, these issues must be addres
192 er-resolution microscopy reveals movement of MOF particles when located outside of the cell boundary,
193 ments with catalytically inactive mutants of MOF showed that its enzymatic activity was required to m
195 tionalization of the external metal nodes of MOF nanoparticles with terminal phosphate-modified oligo
196 It also underestimated the 10-year risk of MOF by 36% for use of selective serotonin reuptake inhib
197 s is attributed to the chemical stability of MOF in low pH environment and to the protease resistance
200 nits can be anchored on the outer surface of MOF NPs in a self-assembly process generating multifunct
201 esult, we demonstrated that the tailoring of MOF electronic properties could be performed as a functi
203 ts herein aid in the efficient activation of MOFs in both laboratory and industrial settings and prov
204 sing the myriad of potential applications of MOFs by enabling larger scale production and hence real-
205 terest in and many potential applications of MOFs, such as in gas storage, catalysis, sensing and dru
206 ecifically we bring together many aspects of MOFs that underpin their stability, reactivity and dynam
209 ll critically depend on the compatibility of MOFs with existing fabrication protocols and predominant
210 ity and endothermicity during deformation of MOFs shows a surprising potential for absorption and dis
212 to be overcome to enable the integration of MOFs with technologies where these promising traits can
219 play an important role in the properties of MOFs and can significantly change the pore architecture.
220 standing of the distinguishing properties of MOFs and eliminating fabrication-related obstacles for i
221 or transforming the electronic properties of MOFs from insulating to semiconducting, as well as provi
222 ns we also target the photonic properties of MOFs that benefit from their porosity, and resulting fro
226 ptical band gap, varies across the series of MOFs and is a function of the relative orientation of th
227 framework topology give rise to a series of MOFs with a remarkable range of physical properties that
228 e encapsulated MNPs closer to the surface of MOFs, the resultant MNPs@MOF composites not only exhibit
230 the inherent structural features/topology of MOFs and the associated gas/vapour separation performanc
231 d structural and compositional tunability of MOFs, these results herald the advent of a new generatio
234 nced signal transduction by devices based on MOF photonic crystals and thin films have been developed
236 hese are the unusual examples of Zr-MOFs (or MOFs in general) based on phenolic porphyrins, instead o
237 d conditions, suggesting that defect-ordered MOFs could be a productive route to porous two-dimension
243 e DNA damage, offering a rationale to pursue MOF inhibitors as a targeted approach to treat MLL-rearr
247 ation to the amino groups, and the resulting MOF is an efficient photocatalyst for overall water spli
255 ble hierarchical porous structures in stable MOFs, which facilitates the diffusion and adsorption pro
267 ntradicts any notion that degradation of the MOF at grain boundaries is enabling the observed conduct
269 strates that amination of all linkers of the MOF is not required to obtain the maximum photocatalytic
270 al isotherms indicate similar filling of the MOF surface by the different gases, starting with strong
271 t, further demonstrating the capacity of the MOF to contain a high concentration of active sites nece
272 es positioned on the external surface of the MOF, the construct shows a high catalytic activity for h
274 species and how they are tethered within the MOF is critical to understanding how these components co
277 the release of AITC molecules from all these MOFs was triggered under high RH (95-100%) conditions.
279 and GC headspace analyses showed that these MOFs could encapsulate and retain AITC molecules within
280 d NU-901, while taking care to utilize these MOFs' large pore volume and size to achieve exceptional
288 Using spray drying, we show the PSM of two MOFs, the amine-terminated UiO-66-NH2 and the aldehyde-t
289 nickel isonicotinate based ultramicroporous MOF, 1 [Ni-(4PyC)2.DMF], that has the lowest PE for post
290 terials through utilization of unprecedented MOF modularity, which cannot be replicated in any other
291 n applications, but also for instances where MOFs serve as components of functional nanodevices.
292 r FRAX score, depression was associated with MOF (adjusted hazard ratio [aHR], 1.39; 95% CI, 1.27-1.5
293 e and fabrication of electronic devices with MOF-based components has not been widely explored, despi
296 lled spatial distribution of the MNPs within MOFs remains a challenge for addressing key issues in ca
297 Mx-yM'y-MOFs, MxM'y-MOFs, and Mx(ligand-M'y)-MOFs, in which the second metal (M') incorporation occur
298 s of bimetallic systems, Mx-yM'y-MOFs, MxM'y-MOFs, and Mx(ligand-M'y)-MOFs, in which the second metal
299 tinct classes of bimetallic systems, Mx-yM'y-MOFs, MxM'y-MOFs, and Mx(ligand-M'y)-MOFs, in which the
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