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1 nucleophiles to conjugate acceptor systems (Michael reaction).
2 on, which relies on an omega-TA-mediated aza-Michael reaction.
3 of the individual steps of a tandem Michael/Michael reaction.
4 through Trost's domino ene-yne coupling/oxa-Michael reaction.
5 T study of bicyclic guanidine-catalyzed thio-Michael reaction.
6 ed early in the sequence using an asymmetric Michael reaction.
7 a Diels-Alder like transition state for the Michael reaction.
8 nd formation through palladium-catalyzed aza-Michael reaction.
9 ted pyrrolidine 15 by way of a tandem Wittig-Michael reaction.
10 assembled rapidly via Baylis-Hillman and aza-Michael reactions.
11 kaiyama-Michael reactions and tandem Michael-Michael reactions.
12 the stereochemical course of intramolecular Michael reactions.
13 conditions has not been well established for Michael reactions.
14 ave substantially broadened the scope of oxa-Michael reactions.
17 ts of thiol groups), and two closely related Michael reaction acceptors [bis(2- and 4-hydroxybenzylid
18 enzylidene-alkanones and -cycloalkanones are Michael reaction acceptors whose inducer potency is prof
19 ways: as a donor in a highly selective anti-Michael reaction and as an acceptor in a consecutive Hen
20 ated by screening potential catalysts of the Michael reaction and in solvent optimization experiments
21 tions that characterize the current standard Michael reaction and used for facile preparation of orga
22 systems are also applicable in the Mukaiyama-Michael reactions and tandem Michael-Michael reactions.
23 were added to omega-keto alkynyl esters in a Michael reaction, and the incipient vinyl anions were tr
24 hed via a TBSOTf-mediated intramolecular aza-Michael reaction, and the relative stereochemistry of th
25 n only be achieved when base-initiated thiol-Michael reactions are carried out first, as radical-medi
26 has been demonstrated for various asymmetric Michael reactions at 5 mol % catalyst loading and afford
28 e tertiary amine that is able to promote the Michael reaction between enolizable carbonyl compounds a
29 xanols was achieved by using a tandem Henry--Michael reaction between nitromethane and 7-oxo-hept-5-e
31 e carbonyl group of 2-OP which facilitates a Michael reaction between Pro-1 and the acetylene compoun
32 amine the two key processes of the catalytic Michael reaction between propanal and beta-nitrostyrene
33 s of reversible intramolecular Michael-retro-Michael reactions between adjacent amine groups that mov
34 tereochemical outcome of the organocatalytic Michael reactions between benzylic aldehydes and nitrost
35 We systematically explored a transannular Michael reaction cascade for stereoselective synthesis o
36 verse-electron-demand hetero-Diels-Alder/oxa-Michael reaction catalyzed by modularly designed organoc
37 be released by sequential retro-aldol/retro-Michael reactions catalyzed by aldolase antibody 38C2.
39 xpression) of a series of triterpenoids with Michael reaction centers were closely correlated with th
41 mmation depends on the presence of activated Michael reaction (enone) functions at critical positions
42 In these reactions, a catalyst-controlled Michael reaction followed by a substrate-controlled Henr
43 lementary strategies: (i) an organocatalyzed Michael reaction followed by a tandem Robinson-aza-Micha
44 heterocyclic systems is initiated by an aza-Michael reaction followed by intramolecular cyclization.
46 emestane is an extended system of conjugated Michael reaction functions, which is also characteristic
48 ue, biomimetic asymmetric intramolecular oxa-Michael reaction/hydrogenation sequence that allows dias
52 formations including aldol, retro-aldol, and Michael reactions in aqueous buffer via an enamine mecha
53 ivity of base- or nucleophile-promoted thiol-Michael reactions in complex mixtures of multiple thiols
54 vations on catalytic aqueous Diels-Alder and Michael reactions in heterogeneous fashion employing a d
55 lder, [1,3]-H shift, [1,3]-trityl migration, Michael reaction) leading to architecturally complex mol
56 elements specific for 3C protease undergo a Michael reaction mediated by nucleophilic addition of th
57 The fluoride-promoted vinylogous Mukaiyama-Michael reaction of 2-[(trimethylsilyl)oxy]furan with di
58 ylamino)cyclopropenimine catalyzes the rapid Michael reaction of a glycine imine substrate with high
59 been found to be efficient catalysts for the Michael reaction of alkenones and alkynones with malonat
61 ue complexes have been shown to catalyze the Michael reaction of dibenzyl malonate and cyclohexenone
63 er (49) was prepared by the enantioselective Michael reaction of ethyl 2-nitropropionate (51) and met
64 lpha-amino acids can be prepared by a double Michael reaction of p-anisyl ethynyl ketone and a tether
65 The stereochemical outcome of the asymmetric Michael reaction of pseudoephedrine amide enolates chang
68 to a bis enone followed by an intramolecular Michael reaction of the enolate to the other enone, aldo
69 efficient and selective lipase-catalyzed aza-Michael reaction of various amines (primary and secondar
70 n effective hydrogen-bond-donor catalyst for Michael reactions of a series of water-insoluble nitro-o
72 emote stereocenters in the direct vinylogous Michael reactions of beta, gamma-unsaturated butenolides
73 yzed enantioselective and diastereoselective Michael reactions of cyclic ketoesters and enones to ins
74 II) salts as highly active catalysts for the Michael reactions of traditionally unreactive beta,beta'
75 nce for the formally disfavoured 5-endo-trig Michael reaction over the formally favoured 5-exo-trig D
76 gulation of phase 2 enzymes may involve both Michael reaction reactivity and radical quenching mechan
77 ynine, employing a proline-catalyzed Mannich-Michael reaction sequence as the key transformation.
78 ones via a K-enolate mediated domino Michael-Michael reaction sequence with moderate to good yield an
79 covered a rare duumvirate stereocontrol: the Michael reaction sets the enantioselectivity, but both t
80 two alpha,beta unsaturated carbonyl groups (Michael reaction sites) in the side chain of the avicin
81 ehyde, diastereoselective Cu(OTf)2-catalyzed Michael reaction/tandem aldol cyclizations, and one-pot
82 in a simple and reliable way through a sulfa-Michael reaction that proceeds with high yield and chemo
83 g on the Trost's domino ene-yne coupling/oxa-Michael reaction that we choose for its ability to contr
84 insights into the design of selective thiol-Michael reactions that can be used for the synthesis and
85 undamental study of the selectivity of thiol-Michael reactions through a series of 270 ternary reacti
86 ing the intrinsic reversibility of the thiol-Michael reaction to be tuned in a predictable manner.
87 positions, respectively, a Pd-catalyzed oxa-Michael reaction to construct the tetrahydropyran ring,
88 antibody 38C2 efficiently catalyzed a retro-Michael reaction to convert a novel, cell-permeable fluo
89 reoselective (dr >/=96:4) acid-catalyzed aza-Michael reaction to give trans-2,5-disubstituted pyrroli
90 leoside analogues were synthesized using the Michael reaction to introduce the 4'-substituent and Pd-
92 These approaches employ thiol-ene and thiol-Michael reactions to form homopolymers of a single nucle
95 o-3-methyl-2-butenoate underwent the phospha-Michael reaction upon simple trituration of the reagents
98 reagents for a sequential Ugi/6-exo-trig aza-Michael reaction, water as a solvent, and microwave irra
99 -pot quaternary, and sequential senary thiol-Michael reactions were designed and their selectivities
100 elimination of the maleimide through a retro-Michael reaction, which results in loss of drug-linker f
101 s favored by glutathione, indicating a retro-Michael reaction, which unveils new implications of cyPG
105 beta-diketones undergo facile domino Michael-Michael reaction with nitro-olefins to afford the corres
106 ding and affords up to 99% ee for asymmetric Michael reactions with aldehydes and nitro-olefins.
107 talyst enables highly enantioselective nitro-Michael reactions with oxazol-4(5H)-ones as nucleophilic
108 framework was generated by an intramolecular Michael reaction within precursor 16a involving the carb
109 ntoxic, easily hydrolyzed HMPT catalyzes the Michael reaction within seconds at room temperature in t
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