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   1                                              Mo concentrations ranged from <1 to 149 mug/L.          
     2 9m)Tc-NaTcO4 was produced from enriched (100)Mo (99.815%) with a cyclotron (24 MeV; 2 h of irradiatio
     3 ; OHMT = 2,6-dimesitylphenoxide) to give 14e Mo(NAr)(CHCMe2Ph)(OHMT)Cl in solution as a mixture of sy
     4 nd to be especially reactive because the 14e Mo(NR)(CHR')(OR'')Cl core is accessible through dissocia
     5   Herein, reductive pathways of MoO(S2)2bpy (Mo-bpy) (bpy = 2,2'-bipyridine) are presented from both 
     6 ctra that reveal (NEt4)[MoO(S2)2picolinate] (Mo-pic) is stable in a d6-DMSO solution after heating at
  
     8 nt uncertainties and requires the (92)Nb/(92)Mo ratio in the early solar system to be at least 50% lo
  
  
    11 y measuring both the perturbation of the (95)Mo/(96)Mo and (97)Mo/(96)Mo isotopic ratios and the tota
    12 ring both the perturbation of the (95)Mo/(96)Mo and (97)Mo/(96)Mo isotopic ratios and the total amoun
    13 urbation of the (95)Mo/(96)Mo and (97)Mo/(96)Mo isotopic ratios and the total amount of molybdenum in
    14 he perturbation of the (95)Mo/(96)Mo and (97)Mo/(96)Mo isotopic ratios and the total amount of molybd
  
  
  
    18  We report results for the production of (99)Mo from the accelerator-driven subcritical fission of an
    19  We report results for the production of (99)Mo from the accelerator-driven subcritical fission of an
    20 eparation, recovery, and purification of (99)Mo were demonstrated using a recycled uranyl sulfate sol
  
  
  
  
    25 lectrocatalyst is described, which employs a Mo-coating on a metal surface to achieve selective H2 ev
    26 S), we have determined the active state of a Mo-promoted Pt/C catalyst (NanoSelect) for the liquid-ph
  
    28 ,6-tri-tert-butylphenoxyl radical to yield a Mo-alkylimido ([Mo horizontal lineNR](+)) complex (R = 2
    29 tride complex upon N-C bond cleavage, and a [Mo horizontal lineNH](+) complex is formed by protonatio
    30 olytic cleavage of all three H atoms from a [Mo-NH3](+) complex using the 2,4,6-tri-tert-butylphenoxy
  
    32 lphenoxyl radical to yield a Mo-alkylimido ([Mo horizontal lineNR](+)) complex (R = 2,4,6-tri-tert-bu
  
    34 ox center is of broad interest for amorphous Mo-S (a-MoSx) electrocatalytic materials and anion-redox
  
  
  
    38 tion underestimates reactive Cu, Cr, As, and Mo, that is, elements with a particularly high affinity 
    39 of sites at the interface between the Co and Mo atoms on the MoS2 basal surface and we ascribe the hi
  
  
  
  
  
    45 ncluding Ni(II), Zn(II), Al(III), Ti(IV) and Mo(VI), are anchored as metal-oxide,hydroxide clusters t
    46 lybdenum center, Mo(6+) horizontal lineS and Mo(4+)-SH, are suggested to be the direct hydride accept
    47 tween the formal Mo(VI) horizontal lineS and Mo(IV)-SH states, and by modeling chronoamperometry data
  
    49 Ti and Nd, moderately siderophile Cr, Ni and Mo, and highly siderophile Ru record different stages of
    50  metals (Ag, Cd, Sb, Tl, but also V, Ni, and Mo which are enriched in bitumen) has been declining in 
  
    52 ively determine the extent to which N, P and Mo stimulate or suppress N fixation, and if environmenta
  
    54 OF of 27-34 s-1 and 42-48 s-1 for Mo-pic and Mo-pym and onset potentials of 240 mV and 175 mV for Mo-
    55 tentials of 240 mV and 175 mV for Mo-pic and Mo-pym respectively reveal these complexes as promising 
  
  
  
  
  
    61 aminants, including SO4, Ca, Mn, Fe, Se, As, Mo, and V above background levels, were also identified 
  
  
  
    65 r main classes of materials, i.e., Rh-based, Mo-based, modified Fischer-Tropsch and modified methanol
    66 he miR-34a expression varied greatly between Mo from different tissues, correlating inversely with th
  
  
  
    70 ndence of inhibitor-binding affinity on both Mo oxidation state and inhibitor electron-donor strength
  
  
    73 ver, regulation of siderophore production by Mo- and V-limitation has been difficult to confirm and k
  
  
    76 nd (NEt4)[MoO(S2)2pyrimidine-2-carboxylate] (Mo-pym) are shown to be homogenous electrocatalysts for 
  
  
    79  monocytic myeloid-derived suppressor cells (Mo-MDSC) in psoriasis patients and examine the implicati
    80  monocytic myeloid-derived suppressor cells (Mo-MDSCs) have been shown to suppress T-cell activation 
    81  the oxidized and reduced molybdenum center, Mo(6+) horizontal lineS and Mo(4+)-SH, are suggested to 
    82 ed an increased CCR2 expression on classical Mo (CD14/CD16), which was paralleled by greater chemokin
  
    84 alizing Weyl physics in the layered compound Mo(x)W(1-x)Te2, where non-saturating magneto-resistance 
    85 oriasis being a hyperinflammatory condition, Mo-MDSCs were elevated in psoriatic patient peripheral b
    86 hile the prismatic Mo2O8 dimers only contain Mo(3+) (d(3)), a result directly confirmed by density fu
  
    88 also demonstrated that psoriatic and control Mo-MDSCs both induce regulatory T-cell conversion from n
  
    90 RNAs for NOX5 indicated that NOX5 controlled Mo-DC differentiation by regulating the JAK/STAT/MAPK an
    91 e results show the importance of controlling Mo speciation to achieve the desired product formation, 
  
    93 l amidinate (CPAM) bis(carbonyl) complex [Cp*Mo{N(iPr)C(Ph)N(iPr)}(CO)2] (Cp*=eta(5)-C5Me5) serves as
    94 , with the exception of multifloral (Ca, Cr, Mo, Se), common heather (Mg, Na), bearberry (Ba, Fe, Pb)
    95 l carbonyl complexes ([M(bpy)(CO)4], M = Cr, Mo, W) are potentially promising CO2 reduction electroca
    96 ucted for six different elements (C, Al, Cu, Mo, Gd, and W) using 40 fs, 800 nm Ti: Sapphire laser.  
    97 pendent monocytes into monocyte-derived DCs (Mo-DCs) in the lungs after F. tularensis LVS pulmonary i
  
    99 oss of Mo species thus causes deactivation), Mo-SIM demonstrated no loss in the metal loading before 
   100 phobic environment for a molybdenum diamine (Mo-diamine) precursor solution, enabling direct growth o
   101 n state in La2MoO5 is 4+, the very different Mo-Mo distances reflect the fact that the Mo2O10 dimers 
  
   103 nstrate that the NOX5-p22phox complex drives Mo-DC differentiation, and thus could be critical for im
   104 OX5 expression was strongly increased during Mo-DC differentiation, but not during Mo-macrophage diff
  
  
  
  
   109 mido complex, (eta(5)-C5Me5)[N(Et)C(Ph)N(Et)]Mo(NSiMe3) (3), with a 1:2 mixture of iPrOH and Me3SiCl 
  
  
   112 cide with a dramatic increase of metals (Fe, Mo, Pb, Mn and As) in the fossils and their host rocks. 
   113 he Mo2Fe6S8(SPh)3 is capable of N2 fixation, Mo itself is not necessary to carry out this process.   
  
  
  
   117 m known CCR disposal sites, and analyzed for Mo and inorganic geochemistry indicators, including boro
  
   119 nd onset potentials of 240 mV and 175 mV for Mo-pic and Mo-pym respectively reveal these complexes as
   120  highest value of delta(iso) is observed for Mo and the lowest for Ta, the values for W and Re being 
   121 of molybdate precursors are reduced to form {Mo(V)2(acetate)} structures under the coordination effec
   122 sis, the Mo center cycles between the formal Mo(VI) horizontal lineS and Mo(IV)-SH states, and by mod
   123 olybdenum complexes with the general formula Mo(NR)(CHR')(OR'')(Cl)(MeCN) (R = t-Bu or 1-adamantyl; O
   124 molybdenum oxide cluster, {Mo132} (formula: [Mo(VI)72Mo(V)60O372(CH3COO)30(H2O)72](42-)), with system
   125     Pivalonitrile can be removed (>95%) from Mo(NAr)(CHCMe2Ph)(OHMT)(Cl)(t-BuCN) (Ar = 2,6-diisopropy
  
   127 es, PdCl2, and CO gas, released ex situ from Mo(CO)6, were assembled to generate sulfonyl isocyanates
   128  the stepwise removal of three H atoms from [Mo-NH3](+) and formation of [Mo horizontal lineNR](+).  
   129 the interaction between initially generated [Mo(bpy)(CO)4](*-) and the electrode is critical in enabl
   130  The products of heterolytic cleavage of H2, Mo hydride complexes bearing protonated amines, [CpMo(H)
   131 ce elements (As, Ba, Cu, Fe, Mn, Cd, Cr, Hg, Mo, Ni, Pb, Se, Sb, Sn, and Zn) in three different pulse
  
   133 ore than 300 years for groundwater with high Mo concentrations support a geogenic source of Mo to the
   134 d back to tetrahedral coordination at higher Mo loadings, indicated by Mo K-edge X-ray absorption spe
   135 ppressive capabilities compared to DC-HIL(+) Mo-MDSC found in melanoma patients, suggesting contextua
  
   137 ort the identification of Late Triassic HREE-Mo-rich carbonatites in the northernmost Qinling orogen.
  
   139 l combustion residues (CCRs) are enriched in Mo, and thus present a potential anthropogenic contamina
   140 bly mechanisms of the two metalloclusters in Mo-nitrogenase and giving a brief account of the possibl
  
  
   143     Here, we propose a tunable Weyl state in Mo(x)W(1-x)Te2 where Weyl nodes are formed by touching p
   144 icates that the enhanced PL due to increased Mo-O bonding leads to p-type compensation doping, and is
   145 ility of efferocytosis to polarize ingesting Mo uniquely and to reduce their host-defense functions, 
   146 icrobial ClO4(-) reductase, which integrates Mo(MGD)2 complex (MGD = molybdopterin guanine dinucleoti
   147 ed a defect in monocyte differentiation into Mo-DCs that was phenotypically similar to MR1(-/-) mice.
  
   149    During the reaction, the initial isolated Mo oxide species agglomerate and convert into carbided M
  
   151 rons to the well-characterized "as-isolated" Mo(V) oxidation state is needed to initiate the catalyti
   152 nance signal of the molybdenum center in its Mo(V) state and demonstrated the direct transfer of the 
  
   154 is procedure leads to the formation of large Mo-blue ring-shaped anion {Mo154}, which contains the su
  
   156 comb complex proto-oncogene BMI1 [B lymphoma Mo-MLV insertion region 1 homolog (mouse)] is essential 
  
  
   159 ormula M(NR)(CHR')(OR'')(Cl)(L) in which M = Mo or W, NR = N-2,6-diisopropylphenyl or NC6F5, and L is
  
  
  
   163 n multifloral honey (Al, As, Be, Ca, Cr, Mn, Mo, Ni, Se, Th and U), common heather (Co, K, Mg, Na, V)
   164  Ce, Co, Cs, Cu, Eu, Fe, Ga, Gd, La, Lu, Mn, Mo, Nb, Nd, Ni, Pr, Rb, Sm, Te, Ti, Tl, Tm, U, V, Y, Zn 
   165 ations of Ag, As, Ba, Cu, Co, Fe, K, Mg, Mn, Mo, Na, Ni, Se, Sb, U and Th (p<0.05, all) among honeys.
   166 found for Ba, Ca, Cd, Co, Cu, K, Li, Mg, Mn, Mo, P, Pb, Se, Sr, Tl and Zn; and high dialyzability rat
  
   168 ortance of N, phosphorus (P) and molybdenum (Mo) availability in controlling free-living N fixation r
   169  millisecond laser on a pristine molybdenum (Mo) surface to measure surface melting and mass loss.   
  
  
   172 y DCs is derived from circulating monocytes (Mo) and has a key role in inflammation and infection.   
   173 to investigate the alterations in monocytes (Mo) and dendritic cells (DCs) in septic burned patients 
   174 sperse, porous heterogeneous catalyst, named Mo-SIM, and its structure on the node was elucidated bot
  
   176 5 P4 , Co2 P), and their base metals (W, Ni, Mo, Co); their activity, stability, and degradation beha
  
  
  
  
  
   182  for samples containing different amounts of Mo indicate that interfacial sites are an order of magni
  
  
   185 phase, contain significant concentrations of Mo (~17 ppm), reinforcing the inference that these carbo
   186     Further, this delayed differentiation of Mo-DCs in MR1(-/-) mice was responsible for the delayed 
   187 e report that the equation of state (EOS) of Mo is obtained by an integrated technique of laser-heate
   188 he cold compression and thermal expansion of Mo have been measured up to 80 GPa at 300 K, and 92 GPa 
   189 i arc length can be changed as a function of Mo concentration, thus tuning the topological strength. 
   190 is observation motivated an investigation of Mo(NMe2 )4 as a volatile precursor for the atomic layer 
  
   192 upported molybdenum catalysts (i.e., loss of Mo species thus causes deactivation), Mo-SIM demonstrate
   193 gen abstraction and oxygenation mechanism of Mo-MnLOX by controlling oxygen access to the pentadiene 
  
   195 creening reveals the very high reactivity of Mo(NMe2 )4 with H2 S for the low-temperature synthesis o
  
  
   198   However, little is known about the role of Mo-MDSCs and their functional relationship to T-cell sup
   199 Our group has recently described a series of Mo-S molecular HER catalysts based on a MoO(S2)2L2 struc
   200  concentrations support a geogenic source of Mo to the groundwater, rather than CCR-induced contamina
   201 ime indicators to investigate the sources of Mo in drinking-water wells from shallow aquifers in a re
  
  
  
  
  
  
  
  
  
   211 nd decrease in human leukocyte antigen-DR on Mo and DCs in burned patients with sepsis compared with 
   212  Mo and DCs, particularly CCR2 expression on Mo, are not fully explored in severely burned patients w
  
   214 the fact that the Mo2O10 dimers contain only Mo(5+) (d(1)), while the prismatic Mo2O8 dimers only con
   215  fixation depends on soil nutrients (N, P or Mo), but recent evidence shows that fixation may also di
  
  
   218 gen, the rice blast fungusMagnaporthe oryzae(Mo), was expressed inPichia pastoris.Mo-MnLOX was deglyc
  
  
  
   222  starts with a lag phase period when partial Mo(VI) centers of molybdate precursors are reduced to fo
   223  oryzae(Mo), was expressed inPichia pastoris.Mo-MnLOX was deglycosylated, purified to homogeneity, an
   224  molybdenum eta(6)-benzene complex ((iPr)PDI)Mo(eta(6)-C6H6) ((iPr)PDI, 2,6-(2,6-iPr2C6H3N horizontal
   225 icantly, the weakened N-H bonds in ((iPr)PDI)Mo(NH3)2(eta(2)-C2H4) enabled hydrogen atom abstraction 
  
   227 mately 10 equiv of ammonia can be formed per Mo with a maximum efficiency in electrons of approximate
  
   229 eterminant of fixation, with P (and possibly Mo) only influencing fixation following tree-fall distur
   230 rently under debate, and whether the primary Mo coordination sphere remains saturated or one of the l
  
   232  the regulatory T cells induced by psoriatic Mo-MDSCs displayed decreased suppressive functionality. 
   233 nt previous research demonstrating psoriatic Mo-MDSC are unable to suppress autologous and heterologo
  
   235 esults suggest that aberrations in psoriatic Mo-MDSCs prevent proper suppression of effector T-cell e
  
  
   238 plane of s-MoSx contains chemically reactive Mo-rich sites that can undergo dynamic dissociative adso
   239 ot on gp91phox/NOX2, as shown by the reduced Mo-DC differentiation observed in chronic granulomatous 
  
  
  
  
   244 fractal arrays at the atomic scale for the S-Mo-S(Co) 2D- layers that conform the spherically shaped 
  
   246 ments (Na, K, V, Ni, Co, Cu, Zn, Ga, As, Se, Mo, Cd, Sn, Sb, Ba, W, and Pb), including air toxics wer
   247 bbon growth is narrowly defined by proper Se:Mo ratios, as corroborated experimentally using differen
  
  
   250 rmation of the catalytically active species [Mo(bpy)(CO)3](2-) via a second pathway at more positive 
   251 , K, Ca, Cr, Mn, Co, Ni, Cu, Zn, As, Se, Sr, Mo, Cd, Sn, Sb, Ba, Hg, Pb, Bi, Th, and U) in green coff
   252 rystalline and amorphous molybdenum sulfide (Mo-S) catalysts are leaders as earth abundant materials 
  
   254 o horizontal lineNR](+) generates a terminal Mo identical withN nitride complex upon N-C bond cleavag
  
   256 onstrating that the multiple bonded terminal Mo identical withC moiety is an intermediate on the path
  
  
   259 cid with an applied potential confirmed that Mo-bpy maintains its structure during catalytic cycling.
   260 NaNpth) as the reducing agent and found that Mo-bpy undergoes anionic persulfide reduction to form th
  
  
  
  
  
  
  
  
  
   270 n involves formal addition of HCl across the Mo horizontal lineN imido bond through initial hydrogen-
  
   272 ite oxidases, the electrons generated at the Mo center are transferred to an external electron accept
   273 lopment of a molecular motif inspired by the Mo-S catalytic materials and their active sites is of in
  
  
   276     Prostaglandin (PG) E2 is involved in the Mo/Mp-mediated inflammatory response, however, the role 
   277  detailed new insight into the nature of the Mo species on zeolite ZSM-5 during methane dehydroaromat
   278 3SiCl resulted in the rapid formation of the Mo(IV) dichloride, (eta(5)-C5Me5)[N(Et)C(Ph)N(Et)]MoCl2 
  
  
  
  
  
  
   285 ntial differences between cultures using the Mo- as opposed to the less efficient V-nitrogenase.     
  
  
  
  
   290 by miR-34a provides one means of fine-tuning Mo behavior toward AC in specific tissue environments wi
   291 e cyanobacterium Anabaena variabilis has two Mo-nitrogenases that function under different environmen
  
   293 n of all siderophores increases, while under Mo-limitation only catechol siderophore production is in
  
   295 6-norbornene skeleton, can be prepared using Mo(N-2,6-Me2C6H3)(CHCMe2Ph)(OHMT)(pyrrolide) (1) as the 
  
   297 3 are generally within a factor three, while Mo is underestimated and Co, Ni and Zn in soils with pH 
  
  
  
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