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1 N2 -fixing N. azollae, we conclude, dominated the microb
2 N2 elimination from monocyclic 1,2,3-triazoles can gener
3 N2 is the terminal cluster of the enzyme's intramolecula
4 N2 O was not detectably released from surface-sterilized
5 N2 reduction to NH3 is essential to the chemical industr
6 N2-fixing symbionts progressively outcompete isogenic no
9 nuNN up to 172 cm(-1)), decreases the Fe(0)-N2 redox potential, polarizes the N-N bond, and enables
10 nd electronic changes that occur in an Fe(0)-N2 unit (Fe(depe)2(N2); depe = 1,2-bis(diethylphosphino)
11 ge, {K(crypt)}2{[(R2N)3Sc]2[mu-eta(1):eta(1)-N2]} (crypt = 2.2.2-cryptand, R = SiMe3), has been isola
13 ur saponins, named licoricesaponins M3 (13), N2 (14), O2 (16) and P2 (18), have been characterized.
15 The application of this strategy to a (15) N2 -diazirine-containing choline derivative demonstrates
16 erivative demonstrates the potential of (15) N2 -diazirines as molecular imaging tags for biomedical
19 es that occur in an Fe(0)-N2 unit (Fe(depe)2(N2); depe = 1,2-bis(diethylphosphino)ethane) upon the ad
20 es of formula [A2Ln(THF)x]2[mu-eta(2):eta(2)-N2] (Ln = Sc, Y, and lanthanides; x = 0, 1; A = anionic
21 Horizon oil spill using a combination of (29)N2 and (30)N2 production (isotope pairing), denitrificat
22 spill using a combination of (29)N2 and (30)N2 production (isotope pairing), denitrification potenti
26 lites: 6-hydroxymelatonin (6-OHM), N1-acetyl-N2-formyl-5-methoxykynuramine (AFMK), N-acetylserotonin
27 independently affected by nutrient addition (N2-fixation), modified herbivory (sediment organic matte
29 They are responsible for up to 50% of all N2 released from marine ecosystems into the atmosphere a
30 ng magnetic exchange coupling provided by an N2(3-) radical bridging ligand results in a series of di
33 colonization, root phosphatase activity and N2 fixation increased in the N2 fixers, allowing them to
37 was minor for CO2 emissions, whereas CH4 and N2 O fluxes displayed strong and asynchronous seasonal d
40 ient cycling, including pathways for CO2 and N2 fixation, anaerobic respiration, sulfur oxidation, fe
43 EFC) that is able to produce NH3 from H2 and N2 while simultaneously producing an electrical current.
44 gh dry weather decreased NO3(-) leaching and N2 O emissions in isolation, 2-year cumulative N losses
45 ectron tomography reconstruction methods and N2 adsorption for determining the fractal dimension for
46 ource availability (via N mineralization and N2 fixation) and (ii) elevated resource use efficiency,
50 aggregated N loss (sum of NO3(-) , NH3 , and N2 O, totaling 84 kg N/ha); (ii) UI in rice-paddy system
52 growth and turnover of nitric oxide (NO) and N2 O at low cell densities of Nitrosomonas europaea (AOB
53 esis that AOB dominate ammonia oxidation and N2 O production under conditions of high inorganic ammon
54 sms in the latter, but ammonia oxidation and N2 O production were directly linked in all treatments.
55 In unamended soils, ammonia oxidation and N2 O production were lower and resulted mainly from ammo
59 ains, cell-specific rates of NO turnover and N2 O production reached maxima near O2 half-saturation c
60 ction model errors predicted both yields and N2 O emissions within experimental uncertainties for 44%
63 ional analysis show that 2'-O methylation at N2, another abundant mRNA modification, is also detrimen
64 inuously analyzing the amount of atmospheric N2 in static environmental chambers with Raman gas spect
65 the highest turnover number of any Fe-based N2 silylation catalyst to date (up to 65 equiv N(SiMe3)3
67 le analytical approach to measure biological N2 fixation rates directly without a proxy or isotopic l
69 mino acids did not significantly affect bulk N2 fixation rates, N2 fixation was enhanced by amino aci
70 of these nanocomposites are characterized by N2 adsorption-desorption isothermal analysis and thermal
73 ratios and reaction conditions, both 1D (C4 N2 H14 )SnBr4 and 0D (C4 N2 H14 Br)4 SnBr6 can be prepar
76 hey have not been shown to mediate catalytic N2-to-NH3 conversion (N2RR), nor have M-NxHy complexes b
82 degrees C and 0.15 bar), extraordinary CO2 /N2 selectivities (98-205 at 25 degrees C), and excellent
83 ions with CO2 permeance of 1,020 GPU and CO2/N2 selectivity as high as 680, demonstrating its potenti
85 es with both high CO2 permeance and high CO2/N2 selectivity, especially under wet conditions, is a ch
86 8 Robeson upper bounds for O2/N2, H2/N2, CO2/N2, H2/CH4 and CO2/CH4, with the potential for biogas pu
87 At 0.15 bar CO2 partial pressure, the CO2/N2 selectivity was 49 (corresponding to 91% purity of th
90 dry-wet sequence decreased 2-year cumulative N2 O emissions while the wet-dry sequence increased 2-ye
92 omic differences concentrated in CDR3's N1-D-N2 region, which allowed the prediction of public and pr
94 ethods can presumably also be used to detect N2 fluxes by denitrification from ecosystems to the atmo
95 targeting the amino nitrogen of guanine (dG-N2) provides direct evidence for Watson-Crick (G)N2H2...
96 ements of population abundances, dinitrogen (N2) fixation, mortality, productivity, export and transc
97 products nitrous oxide (N2O) and dinitrogen (N2) represent often-unmeasured fluxes that may close the
98 enase catalyzes the reduction of dinitrogen (N2) to two ammonia (NH3) at its active site FeMo-cofacto
99 pated to influence the growth of dinitrogen (N2)-fixing phytoplankton, which contribute a large fract
100 nzyme known to be able to reduce dinitrogen (N2) to ammonia (NH3), is irreversibly damaged upon expos
103 ed inhibitor of AOB, was used to distinguish N2 O production resulting from archaeal and bacterial am
105 FVP of 5-aryltetrazoles can result in double N2 elimination with formation of arylcarbenes or of hete
106 s and biological pathways regulating dryland N2 O emissions, and discuss how these processes will res
110 LDH nanosheets, which significantly enhances N2 chemisorption and thereby promotes NH3 formation.
113 esis and characterization of new P2(P'Ph) Fe(N2 )(H)x systems that are active for catalytic N2 -to-NH
115 es derived from the direct protonation of Fe-N2 and Fe-CN species at the terminal N atom (e.g., Fe ho
118 remarkably short Fe-N (1.859 A) and long FeN-N2 (1.246 A) distances, while the FT-IR spectra show an
120 ONALE: Estimating the probability of finding N2 or N3 (prN2/3) malignant nodal disease on endobronchi
121 row aerobically and diazotrophically (fixing N2 to grow) while containing functional nitrogenase.
122 ed gases with a precision better than 1% for N2, O2, CO2, He, Ar, 2% for Kr, 8% for Xe, and 3% for CH
123 nd Fe-CN systems are functionally active for N2-to-NH3 and CN-to-CH4/NH3 conversion, respectively, wh
125 ifics and whether the intimate mechanism for N2-to-NH3 conversion involves a distal pathway, an alter
127 phic denitrification was the main source for N2 O production, and was not impacted by the application
129 ed by N2 desorption is greater than that for N2 adsorption for each linear section of each tested sam
130 identify the relative contributions of four N2 O pathways including nitrification, nitrifier-induced
133 position plots and turned the mesocosms from N2 O sinks to N2 O sources, but had little influence on
134 We demonstrate the synthesis of NH3 from N2 and H2O at ambient conditions in a single reactor by
136 ndance and biomass) and ecosystem functions (N2-fixation, denitrification, extracellular polymeric su
137 r) = (0.094 +/- 0.002) cm(-1)/bar and gammap(N2) = (0.112 +/- 0.003) cm(-1)/bar have been determined.
140 h the nitrite pathway (NH4(+) --> NO2(-) --> N2) is favorable for wastewater treatment plants without
141 his, a charge of 60 mC was passed across H2 /N2 EFCs, which resulted in the formation of 286 nmol NH3
142 model was validated experimentally with H2, N2, Ar and CH4 on three classes of microporous materials
143 the 2008 Robeson upper bounds for O2/N2, H2/N2, CO2/N2, H2/CH4 and CO2/CH4, with the potential for b
144 the family of Prussian blue analogues (C3 H5 N2 )2 K[M(CN)6 ], where C3 H5 N2 is the imidazolium ion
145 alogues (C3 H5 N2 )2 K[M(CN)6 ], where C3 H5 N2 is the imidazolium ion and M=Fe, Co, undergo two phas
146 te collision cross sections (Omega) with He, N2, Ar, CO2, and N2O were measured for the 20 common ami
147 seedling experiment: the N2 fixer with high N2 fixation and root phosphatase activity grew best on o
148 oxidising archaea (AOA), due to their higher N2 O yield under oxic conditions and denitrification in
153 extensive study of siderophore production in N2 -fixing A. vinelandii under a variety of trace metal
154 egrades in air but leaves a tarry residue in N2 that accounts for about 12% of the initial total carb
156 e a dramatic effect on catalysis, increasing N2 solubility and the thermodynamic N2 binding affinity
158 used IP6K2 RNAi and the pan-IP6K inhibitor, N2-(m-trifluorobenzyl), N6-(p-nitrobenzyl) purine (TNP),
161 ordinated in situ metabolism of the keystone N2-fixing cyanobacterium Crocosphaera, as well as the br
162 haustible or easy-to-generate chemicals like N2, O2, CO2, CO, H2, or methane gas to value-added produ
165 mpound 2 is only stable at cryogenic (liquid N2) temperatures, and frozen solutions as well as solid
166 essing (freezing at -196 degrees C in liquid N2, FN sample; freeze-drying at -50 degrees C and 30Pa,
171 chemical implications in an important marine N2 -fixer, as well as advancing evolutionary theory exam
172 etween nifH transcript abundance and maximal N2 fixation, as well as sepF transcript abundance and ce
173 haracterized derivative, [Fe(III)S2(Me2)N(Me)N2(amide)(Pr,Pr)](-) (8), shows that oxo atom donor reac
177 anipulate the dryland microbiome to mitigate N2 O emissions in situ using emerging technologies with
178 ed a mean N2 fixation rate of 78 +/- 5 mumol N2 (g dry weight nodule)(-1) h(-1) of a Medicago sativa-
179 including an N-back task (3 task loads: N1, N2, N3; control condition: N0) inside the MR scanner.
180 CO2 mixing ratio might be needed for natural N2 fixation and only used the time interval above this m
181 sorption of several small gases (H2, D2, Ne, N2, CO, CH4, C2H6, Ar, Kr, and Xe) on the metal-organic
187 mental plasma conditions from pure nitrogen (N2) to pure oxygen (O2) in an atmospheric pressure argon
188 xhibited higher reduction of NO to nitrogen (N2) comparing to the predictions by the kinetic simulati
189 dinium) to shuttle electrons to nitrogenase, N2 reduction to NH3 can be mediated at an electrode surf
190 izing effects (e.g., exposure to 250 ppmv NO/N2 resulted in an 2.4 times increase in surface V2O5 com
191 hypothesized that dinitrogen (N2 )- and non-N2 -fixing tropical trees would have distinct phosphorus
194 (AM) colonization among two N2 - and two non-N2 -fixing seedlings, and grew them alone and in competi
195 P, whereas the poor N2 fixer and the two non-N2 fixers with high AM colonization grew best on inorgan
197 evels of tRNA-specific modified nucleosides (N2,N2-dimethylguanosine, N1-methylinosine), tricarboxyli
198 O-->B interaction through reaction with O2 , N2 O, or CO2 , and formation of silanethione borane 4 fr
199 ption measurements also reveal excellent O2 /N2 selectivity with substantial O2 reversibility at room
200 surpass the 2008 Robeson upper bounds for O2/N2, H2/N2, CO2/N2, H2/CH4 and CO2/CH4, with the potentia
204 ly implies that the metal-free activation of N2 with frustrated Lewis pairs may be achievable in the
205 from two degenerated N(+) + N(+) channels of N2, we observe an opposite angular distribution developm
206 unities on the production and consumption of N2 O, we have limited knowledge of the biological pathwa
207 2)(P4N2) complex catalyzes the conversion of N2 to N(SiR3)3 (R = Me, Et) at room temperature, represe
208 roach was taken complemented by detection of N2 O released and nitrogen isotope determinations of fer
211 I) complexes reveals that the free energy of N2 binding across three oxidation states spans more than
214 may provide means to improve the kinetics of N2 dissociation via induced resonance electronic excitat
216 enitrification were the dominant pathways of N2 O production, and application of the nitrification in
217 catalytic activity for the photoreduction of N2 to NH3 in water at 25 degrees C under visible-light i
218 The dependent variable was the presence of N2 or N3 disease (vs. N0 or N1) as assessed by EBUS-TBNA
226 adsorption capacity and high binary CO2-over-N2 and CO2-over-CH4 selectivity, suitable for CO2 captur
227 quantified by measuring soil nitrous oxide (N2 O) and methane (CH4 ) fluxes and SOC changes (DeltaSO
228 e (CO2 ), methane (CH4 ), and nitrous oxide (N2 O) are the three most important greenhouse gases (GHG
229 s to predict productivity and nitrous oxide (N2 O) emissions for wheat, maize, rice and temperate gra
233 largest contributor to global nitrous oxide (N2 O) production, which is regulated by a wide variety o
234 AOB) are thought to emit more nitrous oxide (N2 O) than ammonia oxidising archaea (AOA), due to their
235 of the potent greenhouse gas nitrous oxide (N2 O), which is generated during denitrification and, in
239 ity grew best on organic P, whereas the poor N2 fixer and the two non-N2 fixers with high AM coloniza
240 sition and pH-dependent reduction potential, N2 has long been considered a candidate for the elusive
242 angle X-ray scattering (SAXS), low-pressure N2 and CO2 adsorption (LPGA) and high-pressure methane a
243 ngle neutron scattering (SANS), low-pressure N2 physisorption (LPNP), and mercury injection capillary
244 ing bacteria (AOB) and archaea (AOA) produce N2 O, their relative activities in soil are unknown.
245 ticide and phosphor bronze, and the produced N2 might be collected and used as a protective gas or be
247 trate binding is reminiscent of the proposed N2 binding step at the FeMo cofactor of nitrogenase, sug
248 ddition, two substitutions, H274Y and R292K (N2 numbering), were introduced into each NA gene for com
249 significantly affect bulk N2 fixation rates, N2 fixation was enhanced by amino acids in individual co
251 ion resulted in low cytosolic pH and reduced N2-fixation rates despite elevated nitrogenase concentra
261 turnover required to reach 2.5% of starting N2 concentration (-0.88; 95% CI, -1.40 to -0.37; P = 0.0
262 rought frequency, which may affect symbiotic N2 fixation (SNF), a process that facilitates ecosystem
269 ed P sources in the seedling experiment: the N2 fixer with high N2 fixation and root phosphatase acti
270 se activity and N2 fixation increased in the N2 fixers, allowing them to outcompete the non-N2 fixers
271 nitrification inhibitor DMPP can inhibit the N2 O production from nitrifier-induced denitrification,
273 e phosphate (DMPP) significantly reduced the N2 O production from these pathways; this is probably du
276 Pharmacologic inhibition of IP6K by TNP [N2-(m-Trifluorobenzyl), N6-(p-nitrobenzyl)purine] recapi
277 Relative contributions of AOA and AOB to N2 O production, therefore, reflect their respective con
281 ate flux, suggesting that denitrification to N2 and not facultative nitrate reduction by Geobacter sp
285 emperature, and complete conversion of NO to N2 could be reached in the range of 700 to 800 degrees C
289 and turned the mesocosms from N2 O sinks to N2 O sources, but had little influence on CH4 emissions.
291 ular mycorrhizal (AM) colonization among two N2 - and two non-N2 -fixing seedlings, and grew them alo
293 n=Y and lanthanides) in that it occurs under N2 without formation of isolable reduced dinitrogen spec
294 logical pathways and mechanisms underpinning N2 O emissions from drylands, which are estimated to acc
296 ogenic non-fixers within root nodules, where N2-fixation occurs, even when they share the same nodule
297 at germ extract translation systems, whereas N2-methylguanosine (m2G) moderately impeded translation.
298 terocyclic carbene=C[((i) Pr)NC(Me)]2 ) with N2 O furnishes the first Si-metalated iminosilane, [Dipp
300 ctrophilic borylene such as 1 can react with N2 reversibly and with CO irreversibly under photochemic
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