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1 N2O isotope and isotopomer signatures, as well as molecu
2 N2O production by hydroxylamine oxidation was further st
3 N2O represents approximately 6% of the global greenhouse
4 4:1 showed significantly higher (p = 0.028) N2O accumulation (8.5.3 +/- 0.9% of the total nitrogen a
5 r findings question the assumptions that (1) N2O is an intermediate required for N2 formation, (2) pr
9 water column and, together with a strong (45)N2O signature indicated neither canonical nor nitrifier-
13 tration (0.8 mug L(-1)), EF5r (0.00016), and N2O-N flux (2.6 kg ha(-1) a(-1)), regardless of bedrock
14 tration (0.7 mug L(-1)), EF5r (0.00020), and N2O-N flux (2.0 kg ha(-1) a(-1)) on lower permeability u
16 f gas, the calculated fluxes of CO2, CH4 and N2O (3,452 mg-C m(2) d(-1), 26.7 mg-C m(2) d(-1) and 0.1
19 tural log (lnR) of response ratio of CH4 and N2O emissions under NT correlated positively (enhancing
20 al global warming potential (GWP) of CH4 and N2O emissions was 5303 kg CO2-eq in 1983 and 6561 kg CO2
23 rst to incorporate stream GHGs (CO2, CH4 and N2O) concentrations and emissions in rivers of the Tibet
25 ffect the greenhouse gas (GHG; CO2, CH4, and N2O) sink capacity of grasslands as well as other terres
27 sphere Watch (GAW) Program for CO2, CH4, and N2O, since NOAA serves as the WMO Central Calibration La
30 +/-0.06% of the certified values for CO2 and N2O and <0.2% for CH4, which represents the smallest rel
31 At the tip of salt wedge, average CO2 and N2O concentrations were approximately five and three tim
32 the combined cumulative emissions of CO2 and N2O from a simulated no-tillage (NT) system to the same
33 f greenhouse gases (the sum of CH4, CO2, and N2O in CO2 equivalents) emitted from a shallow productiv
34 s sections (Omega) with He, N2, Ar, CO2, and N2O were measured for the 20 common amino acids using lo
36 ity composition of actively denitrifying and N2O-reducing microbial communities, we collected RNA sam
37 haracteristic 15N and 18O fractionation, and N2O site preference may be used in combination to qualit
40 d for N2 formation, (2) production of N2 and N2O requires anaerobiosis, and (3) hybrid N2 is evidence
44 ing nitrate, nitrite, nitric oxide (NO), and N2O consecutively by denitrifying polyphosphate accumula
45 ific and Indian Oceans, dissolved oxygen and N2O concentrations in the Atlantic OMZ are relatively hi
49 findings highlight that in reporting annual N2O emissions and estimating N2O-EFs, particular attenti
50 emissions to estimate tropic-specific annual N2O emission factors (N2O-EFs) using a Generalized Addit
51 il N was high due to fertilizer application, N2O emissions were higher during daytime than during the
54 3.3 +/- 0.57% of the total nitrogen added as N2O and large pools of tricarboxylic acid cycle intermed
55 sulfate, 0.6% of the added N was emitted as N2O, while for vinasse, this ranged from 1.0 to 2.2%.
58 nondenitrifying N2O reducers, which could be N2O sinks without major contribution to N2O formation.
59 However, the underlying processes that cause N2O emission suppression in biochar-amended soils are st
60 ty costs are based on emissions of CO2, CH4, N2O, PM2.5, PM10, NOx, SO2, VOC, CO, NH3, Hg, Pb, Cd, Cr
62 w oxygen eddies for bulk, upper water column N2O at the regional scale, and point out the possible ne
67 mathematical model is developed to describe N2O dynamics and the key role of PHA consumption on N2O
69 published in peer-review journals on direct N2O emissions from agricultural systems in tropical and
75 ish between abiotic and biogenically emitted N2O--a finding important for determining N2O sources in
77 ficantly higher quantities of soil-entrapped N2O and N2 in biochar microcosms and a biochar-induced i
78 This study applied a previously established N2O model incorporating two currently known N2O producti
79 eporting annual N2O emissions and estimating N2O-EFs, particular attention should be paid in modellin
82 tropic-specific annual N2O emission factors (N2O-EFs) using a Generalized Additive Mixed Model (GAMM)
83 enitrifying microorganisms with capacity for N2O reduction was recently shown to be greater than prev
87 r unit are employed in a subsequent step for N2O reduction to N2, for an overall (partial) conversion
89 the laser source made it the ideal tool for N2O analyses of the off-gas of a wastewater treatment pl
98 setups for the online-measurement of gaseous N2O, employing semiconductor lasers at 2.9 and 4.5 mum,
100 ntrasting bedrock and superficial geologies, N2O and nitrate (NO3(-)) concentrations were analyzed in
107 where groundwater is unconfined, with a high N2O yield from high permeability chalk contrasting with
108 ical meta-analysis indicated that the higher N2O emission could be mitigated by adopting NT within al
112 ted a substantial role of PHA consumption in N2O accumulation due to the relatively low N2O reduction
117 We characterized an exponential response in N2O production to decreasing oxygen between 1 and 30 mum
118 Most subsurface exchange will not result in N2O emissions; only specific, intermediate, residence ti
119 , whereas the reaction with azide results in N2O formation; these products derive from attack of the
120 substantial, yet widely overlooked, role in N2O fluxes, especially in redox-dynamic sediments of coa
122 declining organic carbon reactivity increase N2O production, highlighting the importance of associate
123 lurry CH4 emissions for Europe and increased N2O emissions from solid piles and lagoons in the United
126 cosystem consequences that include increased N2O production, NO2(-) toxicity, and shifts in phytoplan
127 incubations with elevated nitrate, increased N2O fluxes are not mediated by direct bacterial activity
128 eiving increased attention due to increasing N2O emissions (and our need to mitigate climate change)
131 oils have been widely investigated, indirect N2O emissions from nitrogen (N) enriched surface water a
132 Our findings suggest that biochar-induced N2O emission mitigation is based on the entrapment of N2
133 ards a potential coupling of biochar-induced N2O emission reduction and an increase in microbial N2O
134 mately 90%) but did not prevent thaw-induced N2O release, whereas waterlogged conditions suppressed t
136 sions from anaerobic lagoons (0.9 +/- 0.5 kg N2O hd(-1) yr(-1)) and barns (10 +/- 6 kg N2O hd(-1) yr(
139 N2O model incorporating two currently known N2O production pathways by ammonia-oxidizing bacteria (A
140 issolved oxygen (DO) levels of 2.5-3.0 mg/L, N2O emission from the nitritation stage was 76% lower th
141 en the DO level was reduced to 0.3-0.8 mg/L, N2O emission from the nitritation stage was still 40% lo
144 The presence of vegetation, known to limit N2O emissions in tundra, did decrease (by approximately
146 n N2O accumulation due to the relatively low N2O reduction rate by using PHA during denitrifying phos
150 We used isotope tracers to directly measure N2O reduction rates in the eastern tropical North Pacifi
151 k bedrock regions yielded the highest median N2O-N concentration (3.0 mug L(-1)), EF5r (0.00036), and
152 contrasting with significantly lower median N2O-N concentration (0.7 mug L(-1)), EF5r (0.00020), and
153 deposits yielded significantly lower median N2O-N concentration (0.8 mug L(-1)), EF5r (0.00016), and
155 ssion reduction and an increase in microbial N2O reduction activity among specific groups of typical
156 trix and concurrent stimulation of microbial N2O reduction resulting in an overall decrease of the N2
159 ow organic carbon and nitrite loads modulate N2O accumulation in denitrification, which may contribut
162 tration exerted the strongest control on net N2O production with both production pathways stimulated
166 include a large fraction of nondenitrifying N2O reducers, which could be N2O sinks without major con
168 n enzymes contributed 20, 13, 43, and 62% of N2O that accumulated in 48 h incubations of soil collect
173 highly variable, but peak concentrations of N2O accounted for <1.5% of the incoming total nitrogen l
175 lied to investigate pathways and controls of N2O production by biomass taken from a full-scale nitrit
176 comparing simulation results with 40 days of N2O emission monitoring data as well as other water qual
177 veloped from observations of the dynamics of N2O production and reduction in soil incubation experime
178 of the genomics, physiology, and ecology of N2O reducers and the importance of these findings for cu
179 ion mitigation is based on the entrapment of N2O in water-saturated pores of the soil matrix and conc
180 ch revision would halve current estimates of N2O emissions associated with nitrogen leaching and runo
181 th Bronsted acids leads to the generation of N2O, demonstrating the viability of the hyponitrite comp
182 Differences in the overall magnitude of N2O production were accounted for by archaeal functional
185 termediate yields insight into the nature of N2O binding and reduction, specifying a molecular mechan
187 through the detection and quantification of N2O ( approximately 70% yield), a byproduct of the estab
188 useful approach for direct quantification of N2O production pathways applicable to diverse environmen
189 ess was based on the biological reduction of N2O by Paracoccus denitrificans using methanol as a carb
190 l denitrification, two-electron reduction of N2O occurs at a [Cu4(mu4-S)] catalytic site (CuZ*) embed
191 ns, the potential for substantial release of N2O or CH4 in biofilter effluent appears relatively low.
198 d possible factors underlying variability of N2O fluxes, driven in part by fungal respiration and/or
199 nsights into the large spatial variations of N2O fluxes in a step-feed full-scale activated sludge pl
200 amics and the key role of PHA consumption on N2O accumulation during the denitrifying phosphorus remo
201 evated nitrogen, we investigated controls on N2O production mechanisms in intertidal sediments using
202 ly applied to reproduce experimental data on N2O production obtained from four independent denitrifyi
205 investigate the modulation of nitrous oxide (N2O) accumulation by intracellular metabolites in denitr
206 ped to improve predictions of nitrous oxide (N2O) accumulations in soil and emissions from the surfac
207 The denitrification products nitrous oxide (N2O) and dinitrogen (N2) represent often-unmeasured flux
208 This study aimed to quantify nitrous oxide (N2O) and methane (CH4) emission/sink response from sugar
209 ure treatment effects on NH3, nitrous oxide (N2O) and methane (CH4) emissions from manure management
210 nvestigated the potential for nitrous oxide (N2O) and methane (CH4) generation in dissolved form at t
212 ect and indirect agricultural nitrous oxide (N2O) emissions in developing countries and in particular
214 major source of anthropogenic nitrous oxide (N2O) emissions, especially under alternate wetting-dryin
216 though increasing atmospheric nitrous oxide (N2O) has been linked to nitrogen loading, predicting emi
217 ide (CO2), methane (CH4), and nitrous oxide (N2O) in a dry-natural air balance at ambient mole fracti
221 ction of nitric oxide (NO) to nitrous oxide (N2O) is a process relevant to biological chemistry as we
225 rally recognized to stimulate nitrous oxide (N2O) production by ammonia-oxidizing bacteria (AOB).
227 e magnitude and mechanisms of nitrous oxide (N2O) release from rivers and streams are actively debate
228 to reduce the greenhouse gas nitrous oxide (N2O) to harmless dinitrogen gas are receiving increased
231 (H2O), carbon dioxide (CO2), nitrous oxide (N2O), and methane (CH4) requires days of integration tim
232 ammonia (NH3), methane (CH4), nitrous oxide (N2O), and other trace gas emissions were measured from f
233 xide (CO2), methane (CH4) and nitrous oxide (N2O), and therefore has an important role in regulating
234 unts of nitric oxide (NO) and nitrous oxide (N2O), both of which contribute to the harmful environmen
235 ntified the responses of soil nitrous oxide (N2O), carbon dioxide (CO2) and methane (CH4) emissions t
240 denitrification of nitrite to nitrous oxide (N2O); and (3) N2O conversion to N2 with energy generatio
241 cle summarizes efforts to use nitrous oxide (N2O, 'laughing gas') as a reagent in synthetic chemistry
243 ate allocation to the grain can reduce paddy N2O emissions through decreasing belowground C input and
244 en into account for describing all potential N2O accumulation steps in the denitrifying phosphorus re
245 d we report the first evidence for potential N2O cycling via the denitrification pathway in the open
247 n tropical North Atlantic (ETNA) can produce N2O concentrations much higher (up to 115 nmol L(-1)) th
248 iciently long (and fast reacting) to produce N2O by nitrate reduction but also sufficiently short (or
250 ved exponential terms, accurately reproduces N2O profiles in the top 350 m of water column and, toget
253 mount of total N input, Org-M decreased soil N2O emission by 13% and CH4 emission by 12%, and increas
255 FNA treatment decreased the biomass-specific N2O production rate, suggesting that the enzymes relevan
257 our laser-based analysers, we show here that N2O exchange exhibits contrasting diurnal behaviour depe
258 It was found in this study, however, that N2O emission from a mainstream nitritation system (cycli
261 s by in situ infrared spectroscopy show that N2O is formed in sp(3)-C-H acetoxylation reactions at 80
265 tion and the hydroxylamine pathways) and the N2O production pathway by heterotrophic denitrifiers to
269 lts, also point towards a major shift in the N2O cycling pathway in the core of the low oxygen eddy d
271 S(2-) bridged tetranuclear copper cluster to N2O via a single Cu atom to accomplish N-O bond cleavage
273 e maximum proportions of NH4(+) converted to N2O via extracellular NH2OH during incubation, estimated
274 aneous biological N and P removal coupled to N2O generation in a second generation CANDO process, CAN
280 oxidation to NO2(-), (2) NO2(-) reduction to N2O, and (3) N2O conversion to N2 with energy production
284 denitrification contributed substantially to N2O accumulation across a wide range of conditions with
285 icated mobile sampling device, and the total N2O emissions were analyzed in the gastight headspace of
289 ined, these observations help constrain when N2O release will occur, providing a predictive link betw
291 n, specifying a molecular mechanism in which N2O coordinates in a mu-1,3 fashion to the fully reduced
294 orded under N limiting conditions along with N2O-REs of approximately 57% and approximately 84% in th
299 asibility of combining high-rate, high-yield N2O production for bioenergy production with combined N
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