ライフサイエンスコーパス: NMR spectrum

1 ete consumption of 1-hexene before the first NMR spectrum.

2 ual dipolar coupling constants from a single NMR spectrum.

3 ized xenon leads to the effects on the xenon NMR spectrum.

4 which was confirmed by its characteristic 1H NMR spectrum.

5 C-9 hydroxyl group, on the basis of its (1)H NMR spectrum.

6 t exhibits some loss of dispersion in the 1H-NMR spectrum.

7 ntense H8/H8 ROE cross-peaks in the 2D ROESY NMR spectrum.

8 e at all accessible temperatures in the (1)H NMR spectrum.

9 ative thermal unfolding and a well-dispersed NMR spectrum.

10 tationary phase displayed an amorphous CPMAS NMR spectrum.

11 its protease sensitivity and (1)H-(15)N HSQC NMR spectrum.

12 midpoint potential and (for plastocyanin) 1H-NMR spectrum.

13 sine and histidine chemical shifts in the 1H NMR spectrum.

14 lucono-delta-lactone was observed in the 13C NMR spectrum.

15 leads to a 10-fold enhancement in the (11)B NMR spectrum.

16 cing a small chemical shift change in the Xe NMR spectrum.

17 m for the coordinated CH3 group in the (13)C NMR spectrum.

18 e cytosol and yields a well-resolved in-cell NMR spectrum.

19 ur peaks were observed in the direct (113)Cd NMR spectrum.

20 ded state of wild-type IscU and assigned its NMR spectrum.

21 nd observable in a variable-temperature (1)H NMR spectrum.

22 that ranged from 0.5 to 4.3 ppm in the (1)H NMR spectrum.

23 h a large 7Li hyperfine shift in the 7Li MAS NMR spectrum.

24 (II) environments, as confirmed by a (113)Cd NMR spectrum.

25 ay cause the broadened peaks of the C-RING1B NMR spectrum.

26 egular isotropic nuclear magnetic resonance (NMR) spectrum.

27 peak in the 175-212 ppm region of the (31)P NMR spectrum ((2)J(PH) ~14 Hz).

28 lable comprising compound annotation, a (1)H NMR spectrum, 2D and 3D structure with correct stereoche

29 ) the upfield shift of methyl groups in a 1D NMR spectrum, a 2D- HSQC NMR spectrum of ImmE1 in the mi

30 Finally, changes in the (87)Sr NMR spectrum after immersion of the glass in simulated b

31 IR spectra, (1)H-NMR spectrum and elemental analysis were evaluated for t

32 (calculation of the first derivative of the NMR spectrum and Gaussian shaping of the free-induction

33 amagnetically shifted resonances in the (1)H NMR spectrum and has been characterized by IR spectrosco

34 dged by titration calorimetry, by changes in NMR spectrum and intrinsic tryptophan fluorescence, and

35 Comparison of the (1)H NMR spectrum and NICS(1) zz of 5(2-) with those of 5(2+)

36 and radius of gyration and was supported by NMR spectrum and nuclease assays.

37 f the effects of Co(III) hexammine on the 1H NMR spectrum and results of automatic docking into the I

38 e unsupported bridge (inferred from the (1)H NMR spectrum), and 21 has one unsupported Fe-(mu(2)-SR)-

39 Populations were determined from the (13)C NMR spectrum, and assignments were based on the (13)C sp

40 re observed in a number of resonances in the NMR spectrum, and both chemical shifts and NOEs provide

41 alcium phosphate (OCP), reassigned its (31)P NMR spectrum, and identified an extended hydrogen-bondin

42 wn, we observed dynamic behavior in the (1)H NMR spectrum, and using VTNMR were able to measure a Del

43 ial chemical shift dispersion evident in the NMR spectrum are consistent with the highly structured d

44 at the peak ratios for any metabolite in the NMR spectrum are fixed and proportional to the relative

45 This is demonstrated using 13C NMR spectrum as readily obtainable information.

46 rcular dichroism, intrinsic fluorescence and NMR spectrum as the protein denatured at high concentrat

47 ved deuterium 2 and 3 resonances in its (2)H NMR spectrum at 14.1 T.

48 The solid-state (13)C CPMAS NMR spectrum at 20 degrees C shows three chemically ineq

49 AAF-12-mer, d(CTTCTTG[FAAF]ACCTC), whose 19F NMR spectrum at 22 degrees C and pH 7.0 gave only two si

50 act human low-density lipoprotein (LDL) (1)H NMR spectrum at 600 MHz enabled the investigation of LDL

51 Broadening of a subset of resonances in the NMR spectrum at low temperature, anomalous temperature d

52 ements, it is shown that the visible gelator NMR spectrum below the liquid-gel transition temperature

53 This rate was calculated from the 1D NMR spectrum by measuring the reappearance of biotin's u

54 Peak suppression in the NMR spectrum by sorption of the paramagnetic relaxation

55 , ClFe(III)(meso-NH(2)-OEP) displays an (1)H NMR spectrum characteristic of a high-spin, five-coordin

56 The proton NMR spectrum confirms the presence of a strong diamagnet

57 uble in dry CDCl(3) and gave an ill-resolved NMR spectrum, consistent with its nonspecific aggregatio

58 thioate 5' to A7 results in a distinct (31)P NMR spectrum, consistent with thermodynamic studies repo

59 es in its UV spectrum (lambdamax 236 nm) and NMR spectrum (defining a 9,10-epoxy-octadec-10,12Z-dieno

60 The (13)C NMR spectrum (delta = 127.8 ppm at pH 13 vs dioxane at 6

61 -(t)Bu(2)bpy derivative 1a has a useful (1)H NMR spectrum, despite being paramagnetic.

62 ents from DO spectra are projected onto a 1D NMR spectrum (diffusion-ordered projection spectroscopy,

63 inogen activator inhibitor-1, since the (1)H NMR spectrum, electrophoretic mobility, and proteolytic

64 ion causes strong upfield shifts in the (1)H NMR spectrum even in the presence of only 5 mol % of 3.

65 prisingly, at ambient temperature, the (13)C NMR spectrum exhibits isotropic motional averaging yield

66 erized complexes for which no measured (9)Be NMR spectrum exists, and to investigate a literature com

67 rresponding area under the peaks in the (1)H NMR spectrum, explains the unusual regioselectivity of h

68 The (2)H NMR spectrum for equimolar [3 alpha-(2)H(1)]cholesterol

69 diphosphate 7b, with no evidence in the 31P NMR spectrum for pentacoordinate chlorooxyanionic phosph

70 In the proton NMR spectrum for the dication, the internal CH was shift

71 The NMR spectrum for the monoadduct 2b is consistent with re

72 dependence of the chemical shift in the 13C NMR spectrum for the N5-methyl resonance indicates that

73 ies, characterized by J(SeH) coupling in the NMR spectrum for the P(V)-seleno compounds and a bathoch

74 The proton NMR spectrum for this complex also shows the retention o

75 The (13)C NMR spectrum for Y3N@C2-C78 exhibits strongly deshielded

76 also report and analyze the solid-state (2)H NMR spectrum from these spores.

77 ly diatropic characteristics, and the proton NMR spectrum gave resonances at -5.74 and -6.24 ppm for

78 k positions and intensities from a reference NMR spectrum generally serves as the identifying signatu

79 s 8-10 min for a simple one-dimensional (1)H NMR spectrum, giving access to metabolite information wh

80 downfield resonance at 556 ppm in the (13)C NMR spectrum has been assigned to the carbide carbon.

81 s there is no change in the (1)H- (15)N HSQC NMR spectrum in comparison to wild-type CaM.

82 On the basis of the downfield 1H NMR spectrum in solution, His 57 is not protonated at Ne

83 iple broad peaks and gave a poorly dispersed NMR spectrum in the presence of calcium.

84 The (1)H NMR spectrum indicates that this minor product contains

85 metric bound conformation observed in the 1H NMR spectrum, indicating that the DNA duplex retains its

86 ox domain, there is a striking change to the NMR spectrum indicative of conformational tightening.

87 The single low-field line in the 1H NMR spectrum is assigned by site-directed mutagenesis: T

88 The anomeric (H1) region of the 1H NMR spectrum is band-selected in the F1 dimension.

89 ed in the cytosol, and the resulting in-cell NMR spectrum is broadened.

90 29Si NMR spectrum is consistent with phase pure type I clathr

91 At pH* 4.6, the 1H NMR spectrum is sensitive to complexation of the proteas

92 by thermal and by chemical denaturation, its NMR spectrum is significantly broader than that of the w

93 kappaBalpha, the resonance dispersion in the NMR spectrum is significantly greater, providing definit

94 The 1H-15N TROSY NMR spectrum is well dispersed and contains signals from

95 eatly altered, paramagnetically shifted (1)H NMR spectrum observed for this species.

96 The broadened 1H NMR spectrum of 2 indicates the presence of a triplet, b

97 The (13)C NMR spectrum of 2-butyl-1,2-(13)C(2) cation (1) is uncha

98 In particular, analysis of the NMR spectrum of 27AQS2 bound to a specially designed syn

99 The (19)F NMR spectrum of 6-(19)F-Trp-labeled mADA reveals four di

100 The (1)H NMR spectrum of 9 using the lanthanide shift reagent Eu(

101 Similar to previous reports, the (31)P NMR spectrum of a 12-nucleotide stem-loop sequence 5'-GG

102 The 13C NMR spectrum of a 13C-labeled version of the latter spec

103 a (31)P refocused INADEQUATE solid-state MAS NMR spectrum of a cadmium phosphate glass, 0.575CdO-0.42

104 onsiderably overlapped cross peaks in the 1H-NMR spectrum of a DNA trinucleotide repeat sequence.

105 The impact of specific binding on the NMR spectrum of a membrane protein can be difficult to d

106 A decreased SMR intensity in the 1H NMR spectrum of a protein mixture compared to the added

107 We also acquire a NMR spectrum of a single C. elegans worm at 23.5 T.

108 ppears with PPACK, which is absent in the 1H NMR spectrum of a solution of the enzyme between pH 5.3

109 First, the de-HETCOR NMR spectrum of a ten-site (15)N-labeled sample of p1 al

110 ion was demonstrated by changes in the (31)P NMR spectrum of ATP.

111 The NMR spectrum of bacterially expressed CD2d1, assigned in

112 We now show specific differences between the NMR spectrum of bacterially expressed full-length tail a

113 demonstrated effects of dimerization on the NMR spectrum of bovine neurophysin-I, and preliminary in

114 ith C(3) symmetry as determined by the (13)C NMR spectrum of C(60)H(36) and the (3)He NMR spectrum of

115 Additionally, the line shape of the 2H NMR spectrum of CD3-Ala24 reveals more side chain dynami

116 ic spectrum of CuAbeta, hyperfine-shifted 1H NMR spectrum of CoAbeta, and molecular mechanics calcula

117 The paramagnetic (1)H NMR spectrum of Cu(II) pseudoazurin [PACu(II)] contains

118 CXCR4 induced chemical shift changes in the NMR spectrum of CXCR4 in membranes, disturbed the associ

119 The 1H-NMR spectrum of cyanide-ligated D245N CIP, assigned usin

120 inimizes the effects of Pdx titration on the NMR spectrum of CYP-S-CO, but is competent to replace K+

121 In the (1)H NMR spectrum of D. crassirhizoma PCu(I), there is no sig

122 The 19F NMR spectrum of dG-C8-FAAF [N-(deoxyguanosin-8-yl)-N-ace

123 (31)P NMR data to the chlorides 2, the (1)H NMR spectrum of each features a triplet ((3)JHP = 3.8 Hz

124 Upon DNA binding, the NMR spectrum of each isoform changed to indicate greater

125 The downfield region of the (1)H NMR spectrum of free BChE at pH 7.5 showed a broad, weak

126 matic Ge(II) porphyrin complex, while the 1H NMR spectrum of Ge(TPP)(py)2 clearly indicates the prese

127 The (13)C NMR spectrum of guanine bound to Leuko-PNP, its fluoresc

128 plexes was investigated by obtaining the 19F NMR spectrum of H93G(3-FPyr)CO, whose 19F signal can be

129 A high quality heteronuclear NMR spectrum of HCV NS5B(Delta21) has been obtained and

130 The (1)H-(15)N TROSY NMR spectrum of HO-2 reveals specific residues, includin

131 tions where CPR affects the (1)H-(15)N TROSY NMR spectrum of HO-2, BVR has no effect.

132 While the NMR spectrum of honey and its classical metabonomic anal

133 Changes in the NMR spectrum of HscB upon addition of IscU mapped to the

134 thyl groups in a 1D NMR spectrum, a 2D- HSQC NMR spectrum of ImmE1 in the mixed polarity solvent mixt

135 o a pH-dependent line broadening in the (1)H NMR spectrum of iPrNHN(O)=NOMe, suggesting a complex flu

136 The (1)H NMR spectrum of Lu[CH(SiMe3)2]3 shows that the -SiMe3 gr

137 e glucose (MAG), and a single (2)H and (13)C NMR spectrum of MAG provided the following metabolic dat

138 The 31P NMR spectrum of native enzyme exhibits resonances due to

139 The assigned paramagnetic (1)H NMR spectrum of Ni(II) UMC demonstrates that the axial G

140 The temperature-dependent imino proton NMR spectrum of oxoG modified DNA confirms the destabili

141 For the first time, the 13C NMR spectrum of p-QDM 1 was observed.

142 inal (N) domain of Hsp90 does not affect the NMR spectrum of p23 either in the presence or absence of

143 arison, the oriented-sample (OS) solid-state NMR spectrum of Pf1 coat protein in aligned phospholipid

144 by measuring a diffusion-edited 1H-1H TOCSY NMR spectrum of plasma, it is possible to obtain signals

145 complete assignment of the resonances of the NMR spectrum of proteins for the evaluation of the foldi

146 ntense H8/H8 ROE cross-peaks in the 2D ROESY NMR spectrum of Rh(2)(OAc)(2)[d(GpG)] indicate head-to-h

147 eters from the diamond surface to detect the NMR spectrum of roughly 1 pl of fluid lying within adjac

148 tion) method, which deconvolutes the average NMR spectrum of small flexible molecules into individual

149 The (1)H NMR spectrum of synthetic 5 correlated closely with that

150 The (15)N NMR spectrum of the 1((15)N) (50% Fe identical with(15)N

151 At lower temperatures, the proton NMR spectrum of the asymmetrically substituted carbaporp

152 The proton NMR spectrum of the bipyridyl ferrous cyanoheme complex

153 some N-terminal residues to appear in the 1D NMR spectrum of the carboxylated form.

154 In addition, the aromatic 1H NMR spectrum of the cold denatured state at 0 degree C i

155 extremely well resolved imino protons in the NMR spectrum of the complex.

156 eta-pinene for benzene and evaluating the 2D NMR spectrum of the corresponding beta-pinene complex.

157 3)C NMR spectrum of C(60)H(36) and the (3)He NMR spectrum of the corresponding sample of (3)He@C(60)H

158 In contrast, the HSQC NMR spectrum of the covalent complex showed that the rea

159 The NMR spectrum of the cross-linked peptide has been fully

160 The NMR spectrum of the Cu(II) protein does not exhibit any

161 A (13)C NMR spectrum of the enzyme complex with 4-nitrobenzo[(13

162 The (19)F NMR spectrum of the F93A ADH-NAD(+)-pentafluorobenzyl al

163 The (1)H NMR spectrum of the gamma-picoline/trifluoroacetic acid

164 ted resonances (<4%) were found in the (31)P NMR spectrum of the GDP product.

165 and accurate method for calculating the 13C NMR spectrum of the generated structures exists.

166 ading to an unequivocal assignment of the 1H NMR spectrum of the hexasaccharide.

167 The 15N-1H HSQC NMR spectrum of the human alpha-lactalbumin (alpha-LA) m

168 bin with the inhibitors, but in a 600 MHz 1H NMR spectrum of the inhibition adduct at pH 6.7 and 30 d

169 with input of the molecular formula and 13C NMR spectrum of the isolated compound.

170 rization (DNP) at 90 K, we observe the first NMR spectrum of the K intermediate in the ion-motive pho

171 The (1)H NMR spectrum of the Mg-IRE complex revealed, in contrast

172 The 188-MHz 19F NMR spectrum of the microcrystalline, double-labeled enz

173 The WISE NMR spectrum of the native silk exhibits (1)H line width

174 f its (1)H NMR spectrum to the obtained (1)H NMR spectrum of the natural product, as well as matching

175 onstants was obtained by analysis of the ABX NMR spectrum of the new glycine-derived N-p-toluenesulfo

176 ngle quantum correlation spectroscopy (HSQC) NMR spectrum of the non-covalent complex showed that the

177 a few minutes that registration of the (1)H NMR spectrum of the oil takes, in addition to the rest o

178 e EPR spectrum of the oxidized state and the NMR spectrum of the paramagnetically shifted resonances

179 The uniquely well-resolved (99)Tc NMR spectrum of the pertechnetate ion in liquid water po

180 Free ethene is detected in the NMR spectrum of the products, and insoluble rhenium prod

181 of the His-72 Cepsilon1H resonance in the 1H NMR spectrum of the protein, consistent with a structura

182 tter resolution than the equivalent solution NMR spectrum of the same protein in micelles.

183 The NMR spectrum of the substituted 2-methylfurans shows an

184 strate mixtures causes upfield shifts in the NMR spectrum of the substrate and often enhances the ena

185 The proton NMR spectrum of the transition-state analogue complex of

186 The (51)V NMR spectrum of this compound in CD(3)CN exhibits multip

187 utyl group chemical shift observed in the 1H NMR spectrum of this enantiomer measured in the presence

188 The 19F NMR spectrum of this enzyme showed five sharp resonances

189 As a typical example, the NMR spectrum of trimethyl derivative Me(2)NN(O)=NOMe rev

190 ppm at pH 6.40 and 42 degrees C) in the 15N NMR spectrum of uniformly 15N-labeled 4-OT.

191 evidence of monohydrogen phosphate in a (1)H NMR spectrum of unmodified bone is presented for the fir

192 The trimethoxy complex (III), the (1)H NMR spectrum of which was observed earlier by Servis, th

193 The (67)Zn NMR spectrum of WT LpxC at pH 6 (prepared at 0 degrees C

194 The 15N-1H HSQC NMR spectrum of WT PI-PLC is also reported at 600 MHz.

195 e changes in the nuclear magnetic resonance (NMR) spectrum of a protein upon binding a set of quasi-d

196 identity for many unknown metabolites in the NMR spectrum, offer new avenues for human serum/plasma-b

197 ning of ethyl and aromatic signals in the 1H-NMR spectrum on the addition of the paramagnetic probe 4

198 It is generally accepted that a single 1D NMR spectrum or mass spectrum is usually not sufficient

199 A technique is proposed in which an NMR spectrum or MRI is encoded and stored as spin polari

200 es, addition of calcium had no effect on the NMR spectrum or on the pH-induced changes.

201 The effect of pH on the (1)H NMR spectrum, reduction potential, and self-exchange rat

202 Remarkably, the native NMR spectrum returns with this slower time constant of c

203 The (113)Cd NMR spectrum reveals a single resonance of delta = 622 p

204 Surprisingly, the first NMR spectrum reveals, aside from uninitiated catalyst, Z

205 In principle, this region of the NMR spectrum should be amenable to detailed analysis, be

206 id (AE-CWI) contained 95% GalA and its (13)C NMR spectrum showed signals at delta 98.9, 78.0, 71.4, 6

207 le bands in the Soret region, and the proton NMR spectrum showed that it has a reduced diamagnetic ri

208 The proton NMR spectrum showed that the carbachlorin is highly diat

209 The 1H NMR spectrum shows a pattern consistent with mobile hydr

210 The one-dimensional exchangeable proton NMR spectrum shows resonances expected for imino protons

211 the fluorinated benzene ring, and the (19)F NMR spectrum shows three resonances for the two bound fl

212 The (29)Si CPMAS NMR spectrum shows two chemically inequivalent resonance

213 First, localized (31)P NMR spectrum signals of pHi and pHe reporter molecules [

214 In the present paper, we review the major NMR spectrum simulation techniques with regard to chemic

215 The effects detected by the NMR spectrum suggest a biphasic process, involving stron

216 The (13)C NMR spectrum suggested a C(2)-symmetrical structure.

217 avior during Edman sequence analysis and its NMR spectrum suggested that sublancin is a dehydroalanin

218 appear as one equivalent signal in the (1)H NMR spectrum, suggesting that even methane can rotate in

219 henanthryl protons shift upfield in the (1)H NMR spectrum, suggesting that the phenanthrenes pi-stack

220 The (1)H NMR spectrum supports proper folding of the K1 component

221 The ROESY NMR spectrum, tandem MS/MS analysis, and methylation ana

222 mplex results in changes in the IkappaBalpha NMR spectrum that are consistent with dissociation of th

223 traces in a constant-time (13)C-(13)C TOCSY NMR spectrum that are unique for individual mixture comp

224 produces a high-resolution, single-scan (1)H NMR spectrum that can be recorded after a pump-probe del

225 pectra) to generate a pseudo-two-dimensional NMR spectrum that displays the correlation among the int

226 arkable and complicated solvent-dependent 1H NMR spectrum that suggests the existence of hydrogen bon

227 tained from a two-dimensional, heteronuclear NMR spectrum), the inverse mode of SPARIA calculates all

228 hese required a careful analysis of the (1)H NMR spectrum to identify the stereoisomers, particularly

229 remely close match in appearance of its (1)H NMR spectrum to the obtained (1)H NMR spectrum of the na

230 ical shift perturbations in a 2D 1H-15N HSQC NMR spectrum to verify specific interactions of the comp

231 ), was isolated at -15 degrees C, and its 1H NMR spectrum was recorded at that temperature.

232 al heteronuclear nuclear magnetic resonance (NMR) spectrum was recorded after the rapid initiation of

233 However, the (15)N NMR spectrum we measure (delta = -80.6 ppm at pH 13 vs N

234 obtain a protease construct with a resolved NMR spectrum, we expressed and purified an unlinked prot

235 Based upon perturbations to the NMR spectrum, we propose that the binding site of the C-

236 Two upfield-shifted signals in the (1)H NMR spectrum were used as sensitive probes of the vWF-A

237 t comes from the (31)P splitting of the (1)H NMR spectrum, where additional coupling indicates unusua

238 by the H8/H8 NOE cross-peaks in the 2D ROESY NMR spectrum, whereas the formamidinate bridging groups

239 L550, a new SB signal is detected in the 15N NMR spectrum which disappears upon thermal relaxation.

240 nce of broad macromolecule peaks in the (1)H NMR spectrum, which can severely limit the amount of obt

241 The NMR spectrum will display signals from all species in th

242 ion of the apoenzyme with OMP yields a (31)P NMR spectrum with peaks for both free and enzyme-bound O

243 wo-dimensional (2D) [(13)C-(1)H] correlation NMR spectrum without the need for identification and ass

244 The (11)B NMR spectrum, X-ray diffraction analysis and computation

245 The (11)B NMR spectrum, X-ray diffraction analysis, and computatio