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1 O2 binding to the Fe(II) heme complex of its N-terminal
2 O2 plasma etching increased the sensitivity due to incre
3 O2 plasma etching was performed by a microwave plasma sy
4 e cells adapted to a hypoxic environment (1% O2), those cultured in 5% O2 still mobilized sufficient
5 Our data support a new model in which a (1) O2 retrograde signal, generated by chlorophyll precursor
7 luorescent nanoprobe for singlet oxygen ((1) O2 ) detection in biological systems was designed, synth
8 t enables tumor-specific singlet oxygen ((1) O2 ) generation for cancer therapy, based on a Fenton-li
9 t specifically generates singlet oxygen ((1) O2 ) in mitochondria under white light irradiation that
10 atives exhibiting strong singlet oxygen ((1) O2 ) quenching (HCP2, HCP3) and another capable of dissi
11 vitro and in vivo through tumor-specific (1) O2 generation and subsequent ROS mediated mechanism.
19 molecular oxygen produces singlet oxygen ((1)O2), which reacts with the anthracene moiety yielding hi
25 d that continuously breathing normobaric 11% O2 from an early age prevents neurological disease and d
26 nally, we show that breathing normobaric 11% O2 in mice with late-stage encephalopathy reverses their
27 tion reactions carried out with labeled (18) O2 unambiguously show that the oxygen atoms present in t
28 e of an unusual (S)P species [(MeAN)2Cu(II)2(O2(2-))](2+) ((S)P(MeAN), MeAN: N-methyl-N,N-bis[3-(dime
29 similar -40 degrees C, cis-[Pd(IPr)2(eta(2)-O2)] adds a second O2 to form trans-[Pd(IPr)2(eta(1)-O2)
30 on to reaction with O2, cis-[Pd(IPr)2(eta(2)-O2)] reacts at low temperature with H2O in methanol/ethe
34 promising cathode materials, Na(Li1/3 M2/3 )O2 (M: transition metals featuring stabilized M(4+) ), f
35 tion mechanism in Li2 MnO3 , Na(Li1/3 Mn2/3 )O2 is designed as an example of a new class of promising
38 ic environment (1% O2), those cultured in 5% O2 still mobilized sufficient Ca(2+) to activate AMPK.
39 r, increased dephosphorylation of eNOS in 5% O2 was Ca(2+)-sensitive and reversed by okadaic acid or
40 brane targeting of PP2A-C was observed in 5% O2, resulting in greater interaction with eNOS in respon
44 re chopped, modified atmosphere packaged (70%O2/30%CO2) and maintained under retail conditions (4+/-0
45 device based on the model system Gd0.1 Ce0.9 O2-delta /Er2 O3 to set and tune the property of "memris
46 o CO molecules, while Ag binds and activates O2 , and Ag/Pt surface proximity disfavors poisoning by
49 of O2 with Al2O3 also activates the adsorbed O2 for receiving electrons from the photoexcited dyes.
51 and the relatively hydrophilic surface after O2 plasma etching provided better resistance to fouling
52 in-between NIV sessions, was superior to air/O2 in reducing NIV failure (25-15%) in severe hypercapni
53 he decrease in matrix [dicarboxylate] allows O2 access to reduced site IIf, thereby making electron d
54 noxygenic phototrophic bacteria use BchE, an O2-sensitive [4Fe-4S] cluster protein, whereas plants, c
55 from Toxoplasma gondii is hydroxylated by an O2-dependent prolyl-4-hydroxylase (PhyA), and the result
56 s are identical to those created when (i) an O2 molecule accepts an electron from a near-surface dopa
57 e of NO consumption by metabolizing NO in an O2-dependent manner with decreased NO consumption in phy
58 a, and some phototrophic bacteria possess an O2-dependent enzyme, the major catalytic component of wh
59 ligated (deoxy), CO-inhibited (carboxy), and O2-bound (oxy) hemes in myoglobin (MB) and hemoglobin (H
61 l example, Schonecker showed that copper and O2 promoted the hydroxylation of steroid-containing liga
63 flue gas components (SO2, NO, NO2, H2O, and O2) on vanadium at 500-600 degrees C were investigated b
66 s on electronic charge of both heme iron and O2 , resulting in increased O2 dissociation and reduced
71 uring simultaneously high CO2 resistance and O2 permeability and the exploitation of phase reactions
72 lipid peroxidation and of superoxide anion (O2(* horizontal line )) were higher in Prdx6 (-/-) than
73 etries of monochloramine (NH2Cl) and aqueous O2 consumption, derived (18)O-kinetic isotope effects ((
74 cts ((18)O-KIE) for the reactions of aqueous O2, and studied the impact of radical scavengers on NDMA
76 thology and the concentration of atmospheric O2 Future work on glaciation-weathering-carbon cycle fee
77 ither assembling into spoked wheels, 1-5 bar O2, or closely packed in parallel lines, above 2.2 bar.
78 to use our previously reported gelatin-based O2-controllable hydrogels that can provide hypoxic micro
79 hniques, reflecting a tight coupling between O2 production and consumption by aerobic processes under
82 otion of direct oxidation of palladium(0) by O2, bypassing the typical requirement for Cu salts or re
83 ddition to -C( identical withN), followed by O2 addition to -C(OH) horizontal lineN., internal H-shif
85 )E and D2:(246)M are oxidatively modified by O2(*-) formed by the reduction of O2 either by PheoD1(*-
88 alkyl halides, as well as rapid oxidation by O2, to generate detectable Ni(III) and/or Ni(IV) interme
96 uced arterial hypoxaemia (EIAH) can decrease O2 delivery and exacerbate exercise-induced quadriceps f
97 y inhibits mitochondrial complex I-dependent O2 consumption and reverse electron transfer-mediated re
98 of transition-metal complexes with dioxygen (O2 ) is important for understanding oxidation in biologi
100 eal reaction mechanism, which permits direct O2 formation in single collisions of energetic water ion
101 indow of pH and in the presence of dissolved O2, but occurs independently of this optical quenching.
102 antified the functional significance of each O2 pathway defect by calculating the improvement in exer
106 al cofactor in oxygen metabolism, especially O2 production via photosynthesis and the disposal of sup
107 ell as in situ collection of locally evolved O2 by photosystem 2 using a positioned scanning electroc
114 the development of efficient biocathodes for O2 reduction relying both on direct and mediated electro
115 ip surpass the 2008 Robeson upper bounds for O2/N2, H2/N2, CO2/N2, H2/CH4 and CO2/CH4, with the poten
116 st that the adsorption mechanisms differ for O2 and H2O adsorption on ZnO, and are governed by the su
119 ts origin was ascribed to primordial gaseous O2 incorporated into the nucleus during the comet's form
120 iO2 surface, we show that the tip-generated (O2)(-) radicals are identical to those created when (i)
126 e using nearly stoichiometric 3 % aqueous H2 O2 with a turnover frequency (TOF) of 16 000 h(-1) .
131 nal excitation, which yields a remarkable H2 O2 -NO cooperative anticancer effect with minimal advers
133 n of glucose into gluconic acid and toxic H2 O2 , a novel treatment paradigm of starving-like therapy
134 of carbonyl and dicarbonyl compounds with H2 O2 were not detected because the structural distortions
138 baseline, O1A titres were 4.6 times higher, O2 titres were 9.4 times higher, O6A titres were 4.9 tim
140 stress responses and thermogenesis, and how O2 deficiency leads to metabolic reprograming in cancer.
141 HIm)4](+), and LS-3DCHIm, [(DCHIm)F8Fe(III)-(O2(2-))-Cu(II)(DCHIm)3](+) (F8 = tetrakis(2,6-difluoroph
142 -Cu complexes, LS-4DCHIm, [(DCHIm)F8Fe(III)-(O2(2-))-Cu(II)(DCHIm)4](+), and LS-3DCHIm, [(DCHIm)F8Fe(
143 ction, as indicated by the level of impaired O2 extraction from arterial blood during peak exercise.
145 extent to which this reflects differences in O2 storage fluctuations and/or contributions from oxidat
148 the hypothesis that age-associated increased O2(*-) and resulting DNA damage mediate the increased su
149 th heme iron and O2 , resulting in increased O2 dissociation and reduced O2 affinity at high E degree
152 ncompetitive transport, the textile-based Li-O2 cathode exhibits a high discharge capacity of 8.6 mAh
153 ns of cathodic reactions in a liquid-cell Li-O2 microbattery in the presence of the redox mediator te
156 st of all battery chemistries (lower than Li/O2 and Mg/O2 but comparable to Li/S), and Mg metal allow
157 charge potentials mainly takes place at Li2 O2 /electrolyte interfaces and has obvious correspondenc
159 y chemistries based on LiOH, rather than Li2 O2 , have been recently reported in systems with added w
162 +), whereas nitrifier denitrification at low O2 levels was stimulated by NO2(-) at levels as low as 0
164 inherent CO2 resistance, typically have low O2 permeability but this can be improved via different a
167 es bacteria possibly contributed to lowering O2 levels in leaf pockets but did not release detectable
169 Enhanced current densities for mediated O2 reduction are observed with the redox nanoparticle sy
170 Best-fit rates for Citrate-Fe(II) mediated O2 to O2(-) and H2O2 to OH were 3.0 +/- 0.7 and (4.2 +/-
171 battery chemistries (lower than Li/O2 and Mg/O2 but comparable to Li/S), and Mg metal allows reversib
172 ucts stimulated significantly more microbial O2 consumption (113 +/- 4 muM) than either the dark (78
178 ELs and S3QELs, suppressors of mitochondrial O2()/H2O2 generation that do not inhibit oxidative phosp
180 of phoQ Salmonella to RNS requires molecular O2 and coincides with the nitrotyrosine formation, the o
181 ases with a precision better than 1% for N2, O2, CO2, He, Ar, 2% for Kr, 8% for Xe, and 3% for CH4, N
182 tible or easy-to-generate chemicals like N2, O2, CO2, CO, H2, or methane gas to value-added products
184 (23)Na MAS NMR spectra of sodium-oxygen (Na-O2) cathodes reveals a combination of degradation specie
185 both the presence of H2O2 and the absence of O2 Experiments show that Ccp lacks enough activity to sh
188 nic effect makes Pt favour the adsorption of O2, alleviating CO poisoning and promoting the catalysis
197 n together, we propose that the influence of O2 availability on the levels of active Fur adds a previ
198 ur results suggest that seasonal influxes of O2 and NO3(-) may cause only localized mobilization of U
199 es, high pH, the presence of H2O2 instead of O2 as the initial Fe(II) oxidant, or a combination of al
204 ations to uncover the molecular mechanism of O2 diffusion within the enzyme and its reactions at the
208 the conversion are formed in the presence of O2 and that high temperature together with prolonged act
210 ngly, the decrease of GSH, the production of O2 , and the formation of nanoDVD are shown to be synerg
212 ess of the O-O sigma bond makes reactions of O2, which eventually lead to cleavage of this bond, very
213 ions involving 1- or 2-electron reduction of O2 Although often viewed as dangerous, ROS are now recog
214 *-) appears to be formed by the reduction of O2 at either PheoD1 or QA Early oxidation of D1:(332)H,
215 ither the two- or four-electron reduction of O2 can be explained by the constraint provided by the st
216 odified by O2(*-) formed by the reduction of O2 either by PheoD1(*-) or QA(*-) The identification of
218 X4) enzyme, which catalyzes the reduction of O2 to hydrogen peroxide (H2O2), has been implicated in t
220 that serves as the main in vivo regulator of O2-dependent NO degradation in smooth muscle remains elu
222 enges imposed by the triplet ground state of O2 and the disparate electron inventories of four-electr
224 o identify residues that contribute to O1 or O2 selectivity and gating to minimize undesirable effect
226 ndrial energy metabolism (glucose oxidation, O2 consumption, and ATP production), insulin secretion w
228 ene by using a controlled low energy oxygen (O2(+)/O(+))-ion for chemical adsorption and a low energy
229 Then, using isotopically labeled oxygen (O2) as an oxidant in the presence of hydrogen peroxide (
230 -type exoplanets including molecular oxygen (O2), ozone (O3), water vapor (H2O), carbon dioxide (CO2)
231 e eighth key metabolite is molecular oxygen (O2), thermodynamically activated for reduction by one el
232 However, LCHF also increased the oxygen (O2 ) cost of race walking at velocities relevant to real
234 k cardiac power output and 69% achieved peak O2 consumption within the ranges of healthy controls.
235 ties relevant to real-life race performance: O2 uptake (expressed as a percentage of new VO2 peak ) a
236 ed a substantial fraction (70%) of gas-phase O2 More oxygenated products were formed than the amount
237 nce, photosynthetic CO2 and photorespiratory O2 fixation, and starch synthesis in response to changes
243 ave a direct link to seagrass-derived radial O2 loss and secretion of dissolved organic carbon from t
246 show that, in general, the way the released O2 is accommodated is linked to lithium-ion diffusion an
250 is was put forward after discounting several O2 production mechanisms in comets, including photolysis
254 erobic metabolism also generates superoxide (O2()) and hydrogen peroxide (H2O2) as bona fide products
255 nd maximal oxygen uptake ([Formula: see text]O2 max) were determined with the use of indirect calorim
256 MFO was explained by the [Formula: see text]O2 max, sex, and SRPAL with dietary carbohydrate (carboh
257 iability explained by the [Formula: see text]O2 max, sex, and SRPAL; dietary carbohydrate and fat int
262 ovided by the stannoxane core that makes the O2-binding to 1 an entropically unfavorable process.
263 nd pathophysiological microenvironments, the O2 concentration is not uniformly distributed but instea
267 ermore, both oxides are unstable outside the O2 atmosphere, indicating the presence of active O atoms
268 n species, which damages DNA and reduces the O2 level; (2) decreased cross-membrane proton gradient f
269 rovide direct experimental evidence that the O2 generated during the OER on some highly active oxides
270 eps of oxygen transport and utilization (the O2 pathway) in each patient with HFpEF, identifying the
271 tin complex through its interaction with the O2-sensing prolyl hydroxylase domain containing protein
272 s via their role in Fe(II) oxidation through O2 production, the capacity of their cell surfaces to so
273 ite IIf, thereby making electron donation to O2 possible, explaining the rapid increase in ROS produc
275 ), reducing CO2 into CO and oxidizing H2O to O2 with a 64% electricity-to-chemical-fuel efficiency.
276 -fit rates for Citrate-Fe(II) mediated O2 to O2(-) and H2O2 to OH were 3.0 +/- 0.7 and (4.2 +/- 1.7)
278 PFM), demonstrate differences in response to O2 and H2O, confirming that different adsorption mechani
279 We propose that the distinctive responses to O2 and H2O adsorption on ZnO could be utilized to statis
282 ion of the two unpaired electrons in triplet O2, relative to the unpaired electrons in two hydroxyl r
283 ce stabilization of the pi system of triplet O2, the weakness of the O-O sigma bond makes reactions o
284 r propane ODH after thermal activation under O2 to open a cobalt coordination site and to oxidize Co(
285 Here we combine high-resolution underway O2/Ar, which provides an estimate of net community produ
287 larly in developing systems that can utilize O2, will be required to develop a practical process that
288 reported can directly or indirectly utilize O2 as the only net coreactant based only on thermodynami
291 e-supported cobalt(I) complex L(tBu) Co with O2 gives a rare example of a side-on dioxygen complex of
294 the sensory module, undergoing reaction with O2 that leads to conversion to a [2Fe-2S] form with loss
296 chemistry at mild potentials and reacts with O2, CO2, and ethylene via formal [4+2] cycloaddition to
297 2 and CO evolved and has a relationship with O2 evolved from the TMO lattice on the first charge.
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