ライフサイエンスコーパス: ROMP

1 ROMP of N-trimethylsilyl norbornenes rendered the prepar

2 ROMP reactions could be stopped using MIM (1-5 equiv) an

3 ROMP reactions in neat COE and NBD could be inhibited fo

4 rdinated complexes in representative RCM and ROMP reactions.

5 s as alternatives to traditional metal-based ROMP initiators to allow the preparation of polymers wit

6 (ROMP) reactions of cyclooctene (COE), bulk-ROMP reactions of COE and norbornadiene (NBD), and ring

7 c approach and the length control offered by ROMP, we assemble block copolymers capable of traversing

8 repare pure, high MW bottlebrush polymers by ROMP grafting-through.

9 variety of polymers that may be prepared by ROMP and be of general use with norbornyl oligopeptides

10 density oligopeptide polymers synthesized by ROMP is dramatically improved upon addition of LiCl to r

11 ning triazolylbiferrocene are synthesized by ROMP or radical chain reactions and react with HAuCl4 to

12 s-ring-opening metathesis polymerization (CM-ROMP) strategy that affords functionalized Grubbs-II ini

13 e of endo-dicyclopentadiene (DCPD), a common ROMP monomer, to form linear polyDCPD and copolymers wit

14 s the first metal-free method for controlled ROMP.

15 3 was successfully demonstrated in a couple-ROMP-filter protocol utilizing in situ polymerization, a

16 monomers that can be utilized for metal-free ROMP.

17 The hydrogenated ROMP (H-ROMP) resin was found to be highly resistant to acidic,

18 similar results were obtained for both the H-ROMP and PS-DVB resins.

19 The H-ROMP resin was found to have superior performance compar

20 The hydrogenated ROMP (H-ROMP) resin was found to be highly resistant to

21 ere isolated, characterized, and employed in ROMP and RCM experiments where they exhibited very low c

22 In the first instance, ROMP of 5-acetyloxycyclooct-1-ene (ACOE) followed by eff

23 development of a rate law describing living ROMP initiated by a Grubbs third-generation catalyst tha

24 se traditionally obtained via metal-mediated ROMP.

25 ndergo ring-opening metathesis (ROM) but not ROMP.

26 Because numerous ROMP and NCA monomers are widely available, this novel p

27 polymerizable norbornene-on the kinetics of ROMP of polystyrene and poly(lactic acid) MMs initiated

28 PA-ROMP is a unique polymerization method that employs a sy

29 Additionally, PA-ROMP was used to prepare nearly perfect block copolymers

30 is-4-octene as a CTA, the capabilities of PA-ROMP were investigated with a Symyx robotic system, whic

31 n ring-opening metathesis polymerization (PA-ROMP).

32 ed to design several experiments in which PA-ROMP was performed from one to ten cycles.

33 ring-opening metathesis (co)polymerization (ROMP) of various macromonomers (MMs) using the highly ac

34 heir ring-opening metathesis polymerization (ROMP) and deprotection provide several series of SMAMPs.

35 s in ring-opening metathesis polymerization (ROMP) and ring-closing metathesis (RCM) have been invest

36 n of ring-opening metathesis polymerization (ROMP) and ring-opening polymerization of the amino acid

37 d in ring-opening metathesis polymerization (ROMP) and ring-opening/cross-metathesis (ROCM) processes

38 sion ring-opening metathesis polymerization (ROMP) and used as polymeric supports for organic synthes

39 nium ring-opening metathesis polymerization (ROMP) catalyst under synthetically relevant conditions (

40 sing ring-opening metathesis polymerization (ROMP) for use as efficient alkylating reagents is report

41 the ring-opening metathesis polymerization (ROMP) in aqueous solution were evaluated toward hydrolys

42 and ring opening metathesis polymerization (ROMP) in good to excellent conversion.

43 the ring-opening metathesis polymerization (ROMP) intramolecular backbiting process with the commerc

44 The ring-opening metathesis polymerization (ROMP) is an especially valuable reaction for block copol

45 from ring-opening metathesis polymerization (ROMP) is reported as an effective coupling reagent, scav

46 ieve ring-opening metathesis polymerization (ROMP) mediated by oxidation of organic initiators in the

47 The ring-opening metathesis polymerization (ROMP) of 1,3,5,7-cyclooctatetraene (COT) in the presence

48 Ring-opening metathesis polymerization (ROMP) of dicarbomethoxynorbornadiene (DCMNBD) with 2% 2a

49 s by ring-opening metathesis polymerization (ROMP) of macromonomers (MMs) is highly dependent on the

50 ving ring-opening metathesis polymerization (ROMP) of N-hexyl-exo-norbornene-5,6-dicarboximide initia

51 The ring-opening metathesis polymerization (ROMP) reaction is extraordinarily useful for the prepara

52 Ring opening metathesis polymerization (ROMP) reactions of cyclooctene (COE), bulk-ROMP reaction

53 via ring-opening metathesis polymerization (ROMP) through the employment of a Hamilton receptor-func

54 the ring-opening metathesis polymerization (ROMP) to generate block copolymers that are covalently a

55 ng-opening olefin metathesis polymerization (ROMP) to provide a polypseudorotaxane.

56 Ring-opening metathesis polymerization (ROMP) using Ru==CHPh(Cl)(2)(PCy(3))(DHIMes) (1) as an in

57 free ring-opening metathesis polymerization (ROMP) utilizes organic photoredox mediators as alternati

58 for ring-opening metathesis polymerization (ROMP) with [(H(2)IMes)(3-Br-pyridine)(2)(Cl)(2)Ru=CHPh].

59 e by ring-opening metathesis polymerization (ROMP) with controllable selectivity, ranging from approx

60 d by ring-opening metathesis polymerization (ROMP) with cyclometalated Ru-carbene metathesis catalyst

61 ough ring-opening metathesis polymerization (ROMP) with Mo(NR)(CHCMe2Ph)[OCMe(CF3)2]2 initiators (R =

62 via ring-opening metathesis polymerization (ROMP) with the initiator, (IMesH2)(C5H5N)2(Cl)2RuCHPh.1

63 via ring-opening metathesis polymerization (ROMP), and nitroxide radicals were incorporated at three

64 ore, ring-opening metathesis polymerization (ROMP)-derived monoliths show equivalent preconcentration

65 ving ring-opening metathesis polymerization (ROMP).

66 ) or ring-opening metathesis polymerization (ROMP).

67 ough ring-opening metathesis polymerization (ROMP).

68 e by ring opening metathesis polymerization (ROMP).

69 d by ring-opening metathesis polymerization (ROMP).

70 the ring-opening metathesis polymerization (ROMP).

71 d by ring opening metathesis polymerization (ROMP).

72 via ring-opening metathesis polymerization (ROMP).

73 yzed ring-opening metathesis polymerization (ROMP).

74 polymerization techniques (e.g. ATRP, RAFT, ROMP) that are leading to the creation of sophisticated

75 d bromination reactions to produce saturated ROMP resins with different chemical and physical propert

76 than one type of multivalent ligand and that ROMP is a useful method to synthesize such well-defined

77 To this end, we demonstrate that ROMP can be used to synthesize a block copolymer scaffol

78 ch additionally acts as an inhibitor for the ROMP reaction.

79 ively, the insights provided herein into the ROMP mechanism, monomer design, and homo- and copolymeri

80 The performance of the ROMP-derived monolithic precolumns was constant over at

81 ap a living polymer chain and regenerate the ROMP initiator with high fidelity.

82 methodology was subsequently extended to the ROMP of 5-bromocyclooct-1-ene and 1,5-cyclooctadiene to

83 The addition of trifluoroacetic acid to the ROMP reaction substantially increased the propagation ra

84 regio- and stereochemical outcomes of these ROMP and ROM reactions were analyzed at the B3LYP/6-31G*

85 Unlike traditional ROMP with chain transfer, the CTA reacts only with the l

86 The resulting unsaturated ROMP (U-ROMP) resins containing olefin repeat units were chemica

87 The U-ROMP resin was also shown to be effective in the solid-p

88 The resulting unsaturated ROMP (U-ROMP) resins containing olefin repeat units were

89 nene imide) were synthesized either also via ROMP by terminating the polymerization of norbornene oct

90 is and >99% syndiotactic poly(DCMNBD), while ROMP of cyclooctene and 1,5-cyclooctadiene (300 equiv) w