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1 Xe exposure enhanced Bcl-2 and HSP-70 expression in huma
2 Xe in the Fe4L6 cage has an unusual chemical shift downf
3 Xe is only produced by cryogenic distillation of air, an
5 Here we show that excesses of (124)Xe, (126)Xe and (128)Xe in the Timmins mine fluids can be linked
6 w that excesses of (124)Xe, (126)Xe and (128)Xe in the Timmins mine fluids can be linked to xenon iso
8 d characterization of a rotaxane-based (129) Xe hyperCEST NMR contrast agent that can be turned on in
10 otein reporter for hyperpolarized (HP) (129) Xe NMR, with significant saturation contrast at 0.1 mum.
16 -selective, which is understood using (129) Xe, (1) H, and pulsed-field gradient NMR spectroscopy.
21 by (129)Xe polarizations less than 1%, (129)Xe NMR signals smaller than 20 nT, and transport of hype
22 obtained with hyperpolarized xenon 129 ((129)Xe) magnetic resonance (MR) imaging to quantitative comp
23 ow model with hyperpolarized xenon 129 ((129)Xe) MRI (hereafter, (129)Xe MRI) and technetium 99m-diet
28 microfabricated platform that achieves (129)Xe polarizations reaching 7%, NMR signals exceeding 1 mu
29 ized and characterized for Xe affinity, (129)Xe NMR signal, and aggregation state at varying AFCA and
31 volumes of interest between the FAN and (129)Xe MRI and FAN and V-SPECT were 0.16 +/- 0.08 and 0.28 +
35 l as hyperpolarized noble gases such as (129)Xe, (3)He, and inhaled O2 and (19)F) can be used to dire
38 chieved with one BT treatment guided by (129)Xe MRI when compared with standard three-treatment-sessi
40 +/- 0.15) x 10(-2) min(-1)] and in-cell (129)Xe spin-lattice relaxation time (T1 = 2.19 +/- 0.06 h) f
41 everity is often difficult in children, (129)Xe MRI may be an important biomarker for severity, with
42 re adapted from protocols from clinical (129)Xe MRI to enable preclinical imaging of rat models of pu
44 the chemical shift of AFCA-encapsulated (129)Xe after beta-CD binding to the adamantyl moiety and a c
46 ates of batch-mode (i.e., stopped-flow) (129)Xe hyperpolarizers, which is particularly beneficial for
51 were linearly correlated to images from (129)Xe MRI (rho = 0.67; P < .001) and V-SPECT (rho = 0.59; P
52 g positive correlation with images from (129)Xe MRI (rho = 0.67; P < .001) and V-SPECT (rho = 0.65; P
53 in-human MRI using HP noble gas (e.g., (129)Xe) produced via a spin exchange optical pumping (SEOP)
54 rce" large-scale ( approximately 1 L/h) (129)Xe polarizer for clinical, preclinical, and materials NM
56 zed xenon 129 ((129)Xe) MRI (hereafter, (129)Xe MRI) and technetium 99m-diethylenetriaminepentaacetic
57 ies of HP(129)Xe with sufficiently high (129)Xe nuclear spin polarization (P(Xe)) remains a significa
58 e combustion process will facilitate hp (129)Xe production and should allow for on-demand continuous
59 vant fields for clinical imaging and HP (129)Xe production of 3 T and 4 mT, respectively); moreover,
61 tic resonance applications; moreover, HP(129)Xe embodies an alternative to rare and nonrenewable (3)H
63 pensively produce large quantities of HP(129)Xe with sufficiently high (129)Xe nuclear spin polarizat
64 activity of hyperpolarized xenon-129 (HP(129)Xe) make it attractive for a number of magnetic resonanc
66 hat can be reliably used to dissolve hp-(129)Xe into viscous aqueous and organic samples without bubb
67 Studies of hyperpolarized xenon-129 (hp-(129)Xe) in media such as liquid crystals and cell suspension
69 e NMR technique known as hyperpolarized (129)Xe chemical exchange saturation transfer (hyper-CEST).
74 ) laser irradiation, and hyperpolarized (129)Xe gas is delivered without the need for a cryocollectio
75 , and (iii) "cool"-where hyperpolarized (129)Xe gas is transferred into a Tedlar bag with low Rb cont
76 al lung ventilation with hyperpolarized (129)Xe magnetic resonance imaging ((129)Xe MRI) in pediatric
78 R ventilation images and hyperpolarized (129)Xe MR diffusion-weighted images after coregistration to
80 ADC values obtained from hyperpolarized (129)Xe MR imaging demonstrated correlation with quantitative
82 entation of multisection hyperpolarized (129)Xe MR ventilation images and hyperpolarized (129)Xe MR d
83 dy has demonstrated that hyperpolarized (129)Xe MRI has strong potential to be used to non-invasively
85 Combining the use of hyperpolarized (129)Xe NMR and of a cage-molecule functionalized by a ligand
88 zed (129)Xe magnetic resonance imaging ((129)Xe MRI) in pediatric asthma is poised to advance our und
89 ing (129)Xe magnetic resonance imaging ((129)Xe MRI) to prioritize the most involved airways for guid
90 of an ancient fluid system is found in (129)Xe excesses that, owing to the absence of any identifiab
92 tilated volume and average ADC at lobar (129)Xe MR imaging showed correlation with percentage emphyse
93 These observations show that the lower (129)Xe/(130)Xe ratios in OIBs are due to a lower I/Xe ratio
95 an automated high-throughput batch-mode (129)Xe hyperpolarizer utilizing three key temperature regime
97 rating at 84 kHz (Larmor frequencies of (129)Xe and (1)H nuclear spins), (ii) <0.3 nm narrowed 200 W
99 mented without sacrificing the level of (129)Xe hyperpolarization or the experimental stability for a
100 This study is the first application of (129)Xe MRI to the monocrotaline rat model of pulmonary hyper
102 ersatile detection schemes, and flow of (129)Xe over larger distances are desirable for wider applica
103 Coupled with the distinct ratio of (129)Xe to primordial Xe isotopes in Yellowstone compared wit
109 igh-yield spin-exchange optical pumping (129)Xe polarizer, custom-built radiofrequency coils, and an
110 and gas-exchange imaging showed reduced (129)Xe uptake by red blood cells early in the progression of
112 -3) automated batch-mode clinical-scale (129)Xe hyperpolarizer utilizing continuous high-power (~170
117 rate is maximal, (ii) "warm"-where the (129)Xe hyperpolarization approaches unity, and (iii) "cool"-
118 emperature regimes: (i) "hot"-where the (129)Xe hyperpolarization rate is maximal, (ii) "warm"-where
123 demonstrated here to obtain near-unity (129)Xe polarization values in a 0.5 L optical pumping cell,
124 e the effectiveness and safety of using (129)Xe magnetic resonance imaging ((129)Xe MRI) to prioritiz
127 psulation of spin-hyperpolarized xenon ((129)Xe) atoms in cryptophane-A-monoacid (CrAma) and their in
128 bservations show that the lower (129)Xe/(130)Xe ratios in OIBs are due to a lower I/Xe ratio in the O
129 1 millicurie) of the metastable isomer (131m)Xe that were polarized using the laser technique of spin
131 ack of correlation of (84)Kr/(36)Ar and (132)Xe/(36)Ar fractionation levels along with (4)He/(20)Ne w
133 (35)S), gaseous radionuclides ((85)Kr, (133)Xe, (135)Xe) or radionuclides with very long half-lives
134 alues greater than 10(5) barns(3-6) are (135)Xe (2.6 x 10(6) barns), a fission product that was first
135 gaseous radionuclides ((85)Kr, (133)Xe, (135)Xe) or radionuclides with very long half-lives (e.g., (3
138 , the neutrinoless double beta decay of (136)Xe could be established by detecting the daughter atom,
140 ondition (humid), CO(2) permeance and CO(2) /Xe selectivity stabilized at 2.0x10(-8) mol m(-2) s(-1)
143 saturated with nitrogen (N2) or Xe gas (70% Xe or N2, with 5% CO2 balanced with O2) for 24 or 48 h.
146 ts into diamond via momentum transfer from a Xe(+) focused ion beam (FIB) to thin films of the group
149 kly evolves chlorine upon irradiation with a Xe lamp, leading to [Cl2Sb(IV)Pt(I)Cl(o-dppp)2] (1) as t
150 Xe over Kr under ambient conditions, with a Xe/Kr selectivity of about 10 and a Xe capacity of 27.07
152 as with the three components (H(2), N(2) and Xe), the successive separations and the switch between t
154 e Lewis acid-base complexes involving CO and Xe can be cleaved photochemically and reformed by mildly
156 el plants may be strongly enriched in Kr and Xe which are potentially valuable subsurface tracers.
157 2-formyl phenylazide isolated in Ar, Kr, and Xe matrixes and characterized by IR, UV-vis, and EPR spe
159 (H2, D2, Ne, N2, CO, CH4, C2H6, Ar, Kr, and Xe) on the metal-organic framework (MOF) NU-1000, which
162 The phenylnitrene was isolated in solid Ar, Xe, mixtures of these rare gases with O2, and even in pu
163 and Ar/Kr, and 2.5% or better for Ne/Xe, Ar/Xe, and Kr/Xe using air as the only calibration standard
164 acy improves to 0.6% or better for Ne/Xe, Ar/Xe, and Kr/Xe when the data is calibrated using discrete
168 initial isotopic composition of atmospheric Xe remains unknown, as do the mechanisms involved in its
169 , highlight limitations of cryptophane-based Xe sensing, and offer insights into the design of monome
171 (129)Xe NMR peak corresponding to AFCA-bound Xe was directly observed at high (100 muM) AFCA concentr
172 ave been hindered by the inability to bubble Xe through the desired media as a result of viscosity or
173 broke through the column first, followed by Xe, which confirmed that SBMOF-2 has a real practical po
174 osphere is distinct from Solar or Chondritic Xe but similar to a theoretical component called U-Xe.
176 terization of the first compounds to contain Xe-Br bonds and their chlorine analogues are described i
179 To investigate key features of cryptophane-Xe sensing behavior, we designed a novel water-soluble c
183 ir pore spaces are predicted to be efficient Xe/Kr solid-state adsorbents, but no experimental insigh
185 Ion pair interactions occur through Re-Fmu---Xe bridges, which are predominantly electrostatic in nat
189 (AFCA) was synthesized and characterized for Xe affinity, (129)Xe NMR signal, and aggregation state a
191 and approximately 30% have been measured for Xe loadings of approximately 300, approximately 500, app
192 arth's inner core is a natural reservoir for Xe storage and provides a solution to the missing Xe par
195 hange rate between the encapsulated and free Xe was determined to be about 10 Hz, potentially allowin
197 ical synthesis switches the selectivity from Xe-selective to CH(4) -selective, which is understood us
201 4[Br4(XeO3)4], in which the cage anions have Xe-Br bond lengths that range from 3.0838(3) to 3.3181(8
204 To a cryptophane host molecule with high Xe affinity, we conjugated a 30mer EALA-repeat peptide t
207 /(130)Xe ratios in OIBs are due to a lower I/Xe ratio in the OIB mantle source and cannot be explaine
211 % vs 90.1% +/- 0.8%, for a 500 Torr (67 kPa) Xe cell loading-corresponding to nuclear magnetic resona
212 aSb, GaAs, GaP) and ion species (Ne, Ar, Kr, Xe) to determine new parametric trends regarding nanostr
213 trometer (GC-MS) for analysis of Ne, Ar, Kr, Xe, N2, and O2 and an electron capture detector (GC-ECD)
214 ous measurement of dissolved He, Ne, Ar, Kr, Xe, SF6, N2, and O2 concentrations in a single water sam
215 1) clathrates (guest = H2O, N2, Ar, CH4, Kr, Xe, C2H4, C2H6, CH3F, CO2, H2S, CH3Cl, CH3OCH3, CH3Br, C
217 s to 0.6% or better for Ne/Xe, Ar/Xe, and Kr/Xe when the data is calibrated using discrete water samp
218 cifically, SAPO-34 membranes can separate Kr/Xe mixtures with Kr permeances as high as 1.2 x 10 (-7)
219 e SAPO-34 membranes effectively separated Kr/Xe gas mixtures at industrially relevant compositions.
220 In addition, SAPO-34 membranes separated Kr/Xe mixtures with Kr permeances as high as 1.2 x 10 (-7)
222 n of up to 4 orders of magnitude by membrane Xe-recycling (>99+%) allows the use of the precious Xe a
224 voir have been proposed, whether the missing Xe could be contained in the Earth's inner core has not
227 e electron kinetic energy spectra from mixed Xe core - Ar shell clusters ionized by intense extreme-u
228 Ne/Ar, and Ar/Kr, and 2.5% or better for Ne/Xe, Ar/Xe, and Kr/Xe using air as the only calibration s
229 d accuracy improves to 0.6% or better for Ne/Xe, Ar/Xe, and Kr/Xe when the data is calibrated using d
230 ewis acidity of Hg(OTeF5)2 toward NgF2 (Ng = Xe, Kr) was investigated in SO2ClF solvent and shown to
231 l bonds are rare, and prior to this work, no Xe-Br bonded compound had been isolated in macroscopic q
233 effects of long-term oral administration of Xe-enriched solutions on cardiovascular function were ev
234 that more than 90% of the expected amount of Xe is depleted, a finding often referred to as the 'miss
236 l treatment showed that dynamical effects of Xe motion as well as relativistic effects have significa
240 searching techniques, a chemical reaction of Xe with Fe/Ni at the temperatures and pressures found in
241 ressing this issue lies in the reactivity of Xe with Fe/Ni, the main constituents of the Earth's core
243 icant contributions to the chemical shift of Xe in the cage and enabled the replication of the observ
244 t clinical implications, in which the use of Xe ex vivo could enhance the marginal donor pool of rena
245 ed to aid in the vibrational assignments of [Xe(16/18)OXe(16/18)OXe][mu-F(Re(16/18)O2F3)2]2 and to as
246 Reversible encapsulation of CH(2) Cl(2) or Xe in a non-porous solid-state molecular organometallic
249 4 degrees C, saturated with nitrogen (N2) or Xe gas (70% Xe or N2, with 5% CO2 balanced with O2) for
251 ted by diffusivity selectivity of CO(2) over Xe in DD3R zeolite membranes, whereby rigidity of the ze
252 ide FeO(2), forming robust xenon-iron oxides Xe(2)FeO(2) and XeFe(3)O(6) with significant Xe-O bondin
255 ly high (129)Xe nuclear spin polarization (P(Xe)) remains a significant challenge--particularly at hi
257 xenon-iron oxides are predicted as potential Xe hosts in Earth's lower mantle and could provide the r
258 cling (>99+%) allows the use of the precious Xe as anaesthetics gas a viable general option in surger
260 the distinct ratio of (129)Xe to primordial Xe isotopes in Yellowstone compared with mid-ocean ridge
263 d xenon adsorption capacity and a remarkable Xe/Kr selectivity under conditions pertinent to nuclear
264 O2F3)2]2 rapidly decomposes to XeF2, ReO2F3, Xe, and O2 when the solid or its HF solutions are warmed
267 Xe(2)FeO(2) and XeFe(3)O(6) with significant Xe-O bonding in a wide range of pressure-temperature con
269 ct the existence of thermodynamically stable Xe-O compounds at high pressures (XeO, XeO(2) and XeO(3)
271 ssed, undergoes a transition to a tetragonal Xe(N2)2-II phase at 14 GPa; this phase appears to be une
272 0.40 A, respectively), one could assume that Xe(VIII) can be incorporated into hyperbaric frameworks
274 dy thus demonstrated for the first time that Xe confers renoprotection on renal grafts ex vivo and is
282 l function was significantly improved in the Xe-treated grafts, and macrophage infiltration and fibro
284 lated geometries and binding energies of the Xe complexes of the sigma(0)pi(6) singlet ground state o
286 le-crystal diffraction results show that the Xe selectivity may be attributed to the specific geometr
288 mechanism, and geological viability of these Xe-Fe oxides, which advance fundamental knowledge for un
289 Total Body hypothermia plus Xenon (TOBY-Xe) was a proof-of-concept, randomised, open-label, para
290 on time (T1 = 2.19 +/- 0.06 h) for 1000 Torr Xe were in excellent agreement with the ratio of the gas
291 proximately 760 and approximately 1,545 torr Xe loadings) have been measured after transfer to Tedlar
292 ) in the xenon-rich regime (up to 1,800 torr Xe in 500 cc) in either single-batch or stopped-flow mod
293 designated SBMOF-2) that is selective toward Xe over Kr under ambient conditions, with a Xe/Kr select
299 The interaction energy of 1,2-azaborine with Xe is 3 kcal mol(-1) according to quantum chemical compu
302 eservative solution supplemented with xenon (Xe), when used on ex vivo kidney grafts in a rat renal t