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1 utilizes the bridging hydroxide as a base to abstract a proton from a water molecule loosely associat
2 t with the proposed mechanism in which His98 abstracts a proton from an attacking water molecule boun
3 esidue Asp-38 (pK(a) 4.57) acts as a base to abstract a proton from C-4 of the substrate to form an i
4 as proposed in which an unspecified cysteine abstracts a proton from CoASH forming a nucleophilic thi
6 His 57, making it a more effective base for abstracting a proton from Ser 195 in the formation of th
7 the newly proposed mechanism, the carbanion abstracts a proton from Ser112, thereby completing tauto
8 tibody preorganizes Asp(H35) and Glu(L34) to abstract a proton from substrate and to orient a water m
10 "traditional" catalytic base that served to abstract a proton from the 4'-hydroxyl group of the UDP-
13 first step, Pro-1 acts as a general base to abstract a proton from the third carbon of the substrate
14 ggest that His 158 serves as a general base, abstracting a proton from the 3-OH group of the substrat
15 sed mechanism, base catalysis is involved in abstracting a proton from the alkane peroxyflavin interm
16 which is the proposed general base catalyst, abstracting a proton from the epsilon-amino group and fa
17 ase, whose role is to activate hydrolysis by abstracting a proton from the nucleophilic water, has no
18 as the essential general base catalyst that abstracts a proton from the 5'-OH during the kinase reac
20 is in a position to act also as a base that abstracts a proton from the C2 carbon atom of the covale
21 release in S1, while the P1 phosphate in S2 abstracts a proton from the lavandulyl carbocation to fo
22 ll members of the amidohydrolase superfamily abstracts a proton from the metal-bound water molecule (
23 of L455 functioning as a catalytic base that abstracts a proton from the N-terminal Gly ammonium of t
24 due, is proposed to function as a base which abstracts a proton from the protonated 4'-iminopyrimidin
25 y generalized base catalysis in which a base abstracts a proton from water and the resulting hydroxid
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