ライフサイエンスコーパス: acetophenone

1 CH3COCF3 (trifluoroacetone), and C6H5COCH3 (acetophenone).

2 resulted in cAMP responses to the M71 ligand acetophenone.

3 beta-scission to yield phenoxyl radical and acetophenone.

4 nds 1-8 are significantly more reactive than acetophenone.

5 thanol but not of (R)-(+)-1-phenylethanol to acetophenone.

6 luding carvone, eugenol, cinnamaldehyde, and acetophenone.

7 onses of various ORs, including MOR161-2, to acetophenone.

8 enzene ring will change the odour percept of acetophenone.

9 ine precursors dissolved in benzaldehyde and acetophenone.

10 odor and less similar to the background odor acetophenone.

11 catalysts for the selective hydrogenation of acetophenone.

12 erted to the corresponding 1,1-disubstituted acetophenone.

13 ped models to predict receptor activation by acetophenone.

14 ty for the room temperature hydrogenation of acetophenone.

15 as the reaction would not proceed with just acetophenone.

16 scale of their addition to benzaldehyde and acetophenone.

17 rresponding homoallenic alcohol product from acetophenone.

18 y enantioselective in the hydrosilylation of acetophenone.

19 responses to a structurally similar odorant, acetophenone.

20 e will not be present for imines formed from acetophenone.

21 g odorant, or had nonassociative pairings of acetophenone.

22 eater responses to methyl salicylate than to acetophenone.

23 ioning or conditioned place preference using acetophenone.

24 eadily detect other odors in the presence of acetophenone.

25 ical case of the molecular radical cation of acetophenone.

26 nthesis sequence starting from p-substituted acetophenones.

27 e functionalization of the sp(3) C-H bond of acetophenones.

28 mitant halide migration to afford alpha-halo acetophenones.

29 n C-H activation chemistry; benzaldehyde and acetophenone/1-phenylethanol mixtures, respectively, are

30 s, i.e., 3,5-bis[4-(chlorosulfonyl)phenyl]-1-acetophenone (16), 3,5-bis(chlorosulfonyl)-1-acetophenon

31 acetophenone (16), 3,5-bis(chlorosulfonyl)-1-acetophenone (17), and 3,5-bis(4-(chlorosulfonyl)phenylo

32 , and 3,5-bis(4-(chlorosulfonyl)phenyloxy)-1-acetophenone (18) via a sequence of reactions, involving

33 e range of isostructural alpha-(ortho-tolyl)-acetophenone (1a) and alpha-(ortho-tolyl)-para-methylace

34 The acetophenone 2, on the other hand, forms only traces of

35 nt of base the benzyl ketones 1a and 1b, the acetophenone 2, the arylacetaldehyde 1c, and the methyl

36 linker 12, transmetalation with lithiated 4-acetophenone, 3-acetophenone, and 4-(4'methoxy)biphenyl

37 e superior to DNA matrices (e.g., trihydroxy-acetophenone, 3-hydroxypicolinic acid, picolinic acid).

38 ones resulted in a low yield of phlorin from acetophenone (5%) and no detectable phlorin from benzoph

39 The para-substituted acetophenone 9 could be anchored to the resin through ei

40 Early postnatal odor exposure to acetophenone, a ligand of M72 olfactory sensory neurons,

41 dent glycosyltransferase (UGT) to facilitate acetophenone accumulation in the plant.

42 he positive-ion mode, using 2,4,6-trihydroxy acetophenone-ammonium citrate matrix.

43 Hydroxy-methoxy acetophenone, an inhibitor of NADPH-dependent oxidase, a

44 base of glycine with o-[N-alpha-pycolylamino]acetophenone and (S)- or (R)-3-(E-enoyl)-4-phenyl-1,3-ox

45 we identified sets of ORs for two odorants, acetophenone and 2,5-dihydro-2,4,5-trimethylthiazoline (

46 the charged trimethylammonio trifluoromethyl acetophenone and acetylthiocholine.

47 We show that the odorants acetophenone and benzaldehyde are agonists for the M71 O

48 actors) were determined for methylhexanoate, acetophenone and ethyl dodecanoate.

49 ion of the triple bond with the formation of acetophenone and imidazoline fragments.

50 etophenone on MOR23 neurons and no effect of acetophenone and lyral on the M71 population.

51 MOR161-2 responded to both acetophenone and methyl salicylate in vivo.

52 uction mass spectrometry (MIMS) system, with acetophenone and toluene serving as model compounds.

53 pared in a four-step synthesis starting from acetophenone and tropylium substrates.

54 omatic bis(sulfonyl chlorides) containing an acetophenone and two sulfonyl chloride groups, i.e., 3,5

55 e reaction to synthesize 1,3,5-trizines from acetophenones and amidines.

56 We show that levels of these acetophenones and transcripts of the gene responsible fo

57 smetalation with lithiated 4-acetophenone, 3-acetophenone, and 4-(4'methoxy)biphenyl followed by Mits

58 ormation and consumption of 1-phenylethanol, acetophenone, and an as yet unidentified compound were o

59 mined by the oxidation of 1-phenylethanol to acetophenone, and by isozyme 1A2 in the oxidation of all

60 ylbenzoate, geraniol, cis-alpha-bergomotene, acetophenone, and ethyl dodecanoate.

61 enantioselective allylation of benzaldehyde, acetophenone, and methylethyl ketone under Nozaki-Hiyama

62 tiomeric alkyl phosphonates, trifluoromethyl acetophenones, and carboxyl esters.

63 For benzophenones, acetophenones, and dibenzyl ether, which are all prefere

64 Acetophenones are phenolic compounds involved in the res

65 for electrophilic ketones more reactive than acetophenone as the reaction would not proceed with just

66 yl isobutyl ketone, heptanone, nonanone, and acetophenone as the test compounds.

67 nverted to benzoate (benzoyl coenzyme A) via acetophenone as transient intermediate.

68 base of glycine with o-[N-alpha-picolylamino]acetophenone, as a nucleophilic glycine equivalent, and

69 ectroscopic data of symmetric and asymmetric acetophenone azines are presented in support of this des

70 Y = MeO (7), Y = PhO (8)) para-disubstituted acetophenone azines X-C6H4-CMe=N-N=CMe-C6H4-Y and of mod

71 ically on ethylbenzene, 1-phenylethanol, and acetophenone, but these activities were absent in benzoa

72 Host cell reactivation of UVB + acetophenone-, but not of UVC + photolyase-treated plasm

73 o generate a Pd-alkylperoxide that liberates acetophenone by at least two competitive processes, one

74 nto the catalytic cycle for hydrogenation of acetophenone by Noyori's catalyst, in the presence or ab

75 re p-methylstyrene was oxidized to 4'-methyl-acetophenone by PdCl(2) on the interior of a thimble and

76 The mechanism of catalytic hydrogenation of acetophenone by the chiral complex trans-[RuCl2{(S)-bina

77 P450-catalyzed 1-phenylethanol oxidation to acetophenone by the thiadiazoles does not correlate with

78 ded ketones, acetone, t-butyl methyl ketone, acetophenone, cyclohexyl methyl ketone, and cyclohexyl p

79 In the fragmentation of protonated acetophenones, deacetylation proceeds to give an interme

80 A variety of ketone substrates, including acetophenone derivatives and alpha,beta-unsaturated cycl

81 mide, and a series of 4'- and 2'-substituted acetophenone derivatives by SmI(2) were determined in dr

82 on and deamination to form the corresponding acetophenone derivatives in the absence of an amine acce

83 e highly enantioselective hydrosilylation of acetophenone derivatives without assistance of an additi

84 ion by laser flash photolysis of alpha-azido acetophenone derivatives, 1.

85 s but gives moderate results for more stable acetophenone derivatives.

86 A study of para-substituted acetophenone-derived bis(enones) reveals that substrate

87 ver, these mice cannot detect the M71 ligand acetophenone despite the observation that virtually all

88 tamate receptor 2 (mGlu2), phenyl-tetrazolyl acetophenones, e.g. 1-(2-hydroxy-3-propyl-4-[4-[4-(2H-te

89 raining with amyl acetate (Experiment 1) and acetophenone (Experiment 2).

90 aldehyde from benzphetamine N-demethylation, acetophenone from 1-phenylethanol oxidation, cyclohexano

91 e sequence of novel steps commencing from an acetophenone-functionalized resin.

92 razone derivative of tert-butyldimethylsilyl acetophenone gave 2-tert-butyldimethylsilyl-1-phenyldiaz

93 A series of diversely substituted 2-aryl acetophenones have been obtained in good yields by this

94 for the asymmetric transfer hydrogenation of acetophenone in basic isopropanol.

95 yed similar activity to complex 4, affording acetophenone in high yield.

96 responses to a structurally similar odorant, acetophenone, in the same Obp genes.

97 l odor exposure to the M72 glomerulus ligand acetophenone increased the strength of interglomerular l

98 Benzyl alcohol, 2-phenylethanol, 2-amino acetophenone, indole, 1-hexanol and nonanoic acid exhibi

99 arkably, these reaction conditions converted acetophenone into p-terphenyl (10%) and (E)-1,4-diphenyl

100 We suggest that acetophenone is formed from the palladium enolate interm

101 the substituent group on the phenyl unit of acetophenone is investigated in detail.

102 We also showed that 2,6-dihydroxy-acetophenone is superior to 2,5-dihydroxybenzoic acid as

103 zo[1,2-a]pyridines from 2-aminopyridines and acetophenones is achieved by a tandem, one-pot process s

104 Our results show that accumulation of acetophenones is an efficient resistance mechanism again

105 ously studied reductions of benzaldehyde and acetophenone, is also controlled, early along the reacti

106 t protein (GFP) and M71-GFP mice to lyral or acetophenone, ligands for MOR23 or M71, respectively.

107 During photolysis of acetophenone O-allylcarbamoyl oxime, the corresponding o

108 tor pair lyral-MOR23: there was no effect of acetophenone on MOR23 neurons and no effect of acetophen

109 ons of phenyl azide to enamines derived from acetophenone or phenylacetaldehyde and piperidine, morph

110 d shared amino acid residues specific to the acetophenone or TMT receptors and developed models to pr

111 rom the O-alkyl group), whereas O-tert-butyl acetophenone oxime (4) did not.

112 tophenone oximes all reacted readily to give acetophenone oxime as the major product (as well as an a

113 t palladium-catalyzed ortho-C-H arylation of acetophenone oxime ethers with aryl pinacol boronic este

114 ilar to the results obtained for a series of acetophenone oxime ethers.

115 O-methyl (1), O-ethyl (2), and O-benzyl (3) acetophenone oximes all reacted readily to give acetophe

116 diacal that undergoes cleavage to form 2 and acetophenone (Phi approximately 0.04).

117 ect (CE) around 290 nm is contributed by the acetophenone pi --> pi* transition of the ABC-flavanone

118 t SBW attack were reported to accumulate the acetophenones piceol and pungenol constitutively in thei

119 ned by varying the initial concentrations of acetophenone, precatalyst, base, and acetone and by vary

120 bstantial amounts of tert-butyldimethylsilyl acetophenone, presumably by reaction of the intermediate

121 elds in a single step from readily available acetophenones, propiophenones, and phenylacetophenones.

122 , the presence of a 2'-fluoro substituent on acetophenone provides a highly ordered transition state

123 GT5b in the biosynthesis of the glycosylated acetophenone pungenin in white spruce.

124 The acetophenones pungenol and piceol commonly accumulate in

125 utants of different polarities (naphthalene, acetophenone, quinoline, and 2-naphthol), and of the org

126 of Pcl with 2-amino-benzaldehyde or 2-amino-acetophenone reagents proceeds to near completion at neu

127 Among the 2'-substituted acetophenone series, the presence of a fluoro, amino, or

128 peroxide leads to [Cu(II)]-OCMe(2)Ph (3) and acetophenone suggesting the intermediacy of the PhMe(2)C

129 etric glycolate alkylation using a protected acetophenone surrogate under solid-liquid phase-transfer

130 nd subsequent radical recombination yielding acetophenone-tethered thioortho esters 4, alpha-[3-(2-al

131 is associated with higher response scores to acetophenone than the 610A allele, but with lower expres

132 When an odor (acetophenone) that activates a known odorant receptor (O

133 time to be good quenchers of triplet excited acetophenone, the main sensitized photoreaction of 7Z in

134 pyne and allene, the addition of acetone and acetophenone to methyl propargyl and methyl allenyl ethe

135 Conversion of acetophenone to methyl salicylate was observed in the me

136 t CYP1a2 affects OR activation by converting acetophenone to methyl salicylate.

137 ession of Obp99a, suggesting that binding of acetophenone to Opb99a might limit rather than facilitat

138 unique annulation that knits together three acetophenones to construct cyclopropanes.

139 eave only 6-4PP on the plasmid), or to UVB + acetophenone (to induce only CPD).

140 zed aldol condensation of benzaldehydes with acetophenones, to produce chalcones, is the final loss o

141 olysis of vinylazide 1, which has a built-in acetophenone triplet sensitizer, in argon-saturated tolu

142 7 as a precatalyst for the hydrogenation of acetophenone under mild conditions.

143 sensitivity of the F1 and F2 generations to acetophenone was complemented by an enhanced neuroanatom

144 se nasal cavity, the response of MOR161-2 to acetophenone was reduced, while that to methyl salicylat

145 eptor (specifically activated by the odorant acetophenone) were behaviorally trained with olfactory-d

146 Enantioselective aldol reactions of acetophenone with beta,gamma-unsaturated alpha-ketoester

147 plets were generated by emulsifying water in acetophenone with SPAN 80 surfactant.

148 catalytic hydrogenation of benzaldehyde and acetophenone with the Shvo hydrogenation catalysts were

149 studies have shown that this reaction yields acetophenones with high selectivity.

150 pling of ortho-[2-(4-methoxylphenyl)-alkynyl]acetophenones with ortho-alkynylbenzaldehydes affording