ライフサイエンスコーパス: achiral

1 spite the fact that the Fe(4)S(4) cluster is achiral.

2 -(-) so that nonactin has S4 symmetry and is achiral.

3 ders the resulting bis-bispidine macrocycles achiral.

4 o asymmetric variant of the rearrangement of achiral 1,5-dienes has emerged, despite the successes th

5 Thus, while achiral 1a bundles into thick filaments to form an organ

6 2,2-trifluoro-1-methylethylamino group or an achiral 2,2,2-trifluoroethylamino group is required at t

7 xose was accomplished in 19 total steps from achiral 2-acylfuran, and digitoxin was fashioned in 15 s

8 enantiomeric deoxycholic acid (ent-DCA) from achiral 2-methyl-1,3-cyclopentanedione.

9 ereocontrolling event, with the anion of the achiral acid being the structural element responsible fo

10 An essential role for the achiral acid cocatalyst is uncovered: upon condensation

11 simplest possible combination of chiral and achiral active stresses, yet this leads to an unpreceden

12 th 35 stereocenters was accomplished from an achiral acylfuran.

13 actones bearing two stereogenic centers from achiral aldehydes (both aromatic and aliphatic) and alky

14 markably high levels of stereoinduction with achiral aldehydes, leading preferentially to 1,5-anti re

15 enic centers, from disubstituted ketenes and achiral aldehydes.

16 s, the compounds with six and ten carbons of achiral alkoxy side chains were further subjected to stu

17 stereoselection in the coupling reactions of achiral allylic alcohols with chiral imines.

18 Oligomers of the achiral amino acid Aib adopt helical conformations in wh

19 gent catalysis is observed upon changing the achiral amino acid residue in the catalyst (at the i+2 p

20 , -Glu, -His, -Leu, -Ser, -Val and the three achiral amino acids Gly, beta-Ala, and GABA).

21 over the screw sense of a helical 17-mer of achiral amino acids, Aib(8)GlyAib(8), from a single chir

22 synthesizes proteins using exclusively L- or achiral aminoacyl-tRNAs (aa-tRNAs), despite the presence

23 the two optically pure enantiomers and their achiral analog have nearly the same degree of cell prote

24 ve stereogenic centers in a single step from achiral and acyclic substrates.

25 tion of an intermediate pyrazinone with both achiral and chiral acrylate-derived dienophiles provides

26 Analyzing the achiral and chiral amide I spectra, we conclude that DPP

27 kling induces a reversible switching between achiral and chiral configurations.

28 Various achiral and chiral Cu(I) salts have been prepared from m

29 and repeatability were achieved by combining achiral and chiral narrow-bore columns (2.1 mm x 100 mm

30 hane-A cage for biosensor applications, some achiral and chiral substituents such as left-handed amin

31 KMgCO3F crystallizes in the achiral and nonpolar NCS space group P62m, whereas Cs9Mg

32 hose bicyclopentane units can rotate but are achiral and produce no second-order optical response.

33 The most potent of the achiral and racemic aromatase inhibitor was 40 (IC 50 =

34 ated as a broad proof of concept for chiral, achiral, and HILIC separations of biologically important

35 ectively activate a mixture of two different achiral anhydrides as acyl donors under homogeneous cond

36 rms of their ability to recognize chiral and achiral anions.

37 bly, the preferred helicity of the stacks of achiral AOPV3 can be retained almost completely after a

38 The racemic mixture of helical stacks of achiral AOPV3 molecules is converted into homochiral hel

39 stacks being the seeds for self-assembly of achiral AOPV3.

40 ary to intuitive expectations, we utilize an achiral architecture to realize a chiral beam-splitting

41 to fail by steering discovery efforts toward achiral, aromatic compounds.

42 ed and relies on the subtle influence of the achiral aryl imine substituent on the cobalt catalyst.

43 s been established from chiral enynamines by achiral Au(III) catalysis.

44 and S enantiomers of CClHDT adsorbed on the achiral Au20 tetrahedral cluster.

45 enging because of the small signal and large achiral background.

46 e-type carbonyls by SmI2-H2O, convert simple achiral barbiturates in one step to hemiaminal- or enami

47 , there is no reaction in the absence of the achiral base, yet the presence of the achiral co-catalys

48 y diffraction revealed the molecule as being achiral based on C(i) symmetry.

49 Chiral and achiral basket-handle porphyrins (BHPs) with different p

50 The nanoporous host is itself an assembly of achiral, bent-core liquid crystal molecules that phase-s

51 o be transmitted from a chiral analyte to an achiral benzotriazole dye molecule in the vicinity of a

52 Hydrogen-atom abstraction affords an achiral benzylic radical that undergoes asymmetric C(sp(

53 itive" modifications to arrive at the simple achiral, biaryl target structures.

54 lyst by subtly changing the structure of the achiral boronic acid.

55 icted amide group, and 30 bearing a terminal achiral bromophenyl group.

56 Additionally, when an achiral Bronsted acid (TfOH) is used in slight excess of

57 n the presence of catalytic quantities of an achiral Bronsted acid.

58 ive functioning of the chiral Lewis acid and achiral Bronsted base components gives rise to in situ e

59 ed by performing the same experiment with an achiral BTA ligand, i.e. a phosphine-functionalized BTA

60 one-pot organocatalytic process merging two achiral building blocks into an octacyclic structure via

61 lly pure chiral amines, starting from simple achiral building blocks, are highly desirable because su

62 ard achieving full saturation: chiral versus achiral building blocks, certain forms of conformational

63 Here we report a simple method to assemble achiral building blocks, i.e., the asymmetric colloidal

64 the fabrication of homochiral surfaces using achiral building blocks.

65 ion of bulk porous homochiral materials from achiral building units is rare.

66 An achiral but helical foldamer carrying a basic binding si

67 also to lead highly selective separation of achiral C(2)H(2)/C(2)H(4) separation.

68 A new class of cationic achiral C3-symmetric gelator devoid of any conventional

69 tes, in the presence of < or = 2 mol % of an achiral catalyst to afford synthetically versatile produ

70 stereoselective cycloisomerizations using an achiral catalyst, and then explore phosphoramidite-compl

71 ntioselective transformations at an embedded achiral catalytic center, as illustrated by the oxidativ

72 the use of a diverse assortment of embedded achiral catalytic centers, promising a generation of syn

73 lies formed by BTA Ile and the intrinsically achiral catalytic rhodium catalyst, providing the hydrog

74 r a chiral IL composed of a chiral anion and achiral cation toward another chiral molecule such as a

75 n asymmetric reactions catalyzed in confined achiral cavities.

76 f catalytic asymmetric reactions and second, achiral chromatography can be used as a new, nonconventi

77 in this review clearly suggest that SDE via achiral chromatography might be expected for any given c

78 n is based on chirally perturbing the acting achiral chromophore by orthogonally tethering a single a

79 .g., those based on other highly luminescent achiral chromophores and/or chirally perturbing moieties

80 of the achiral base, yet the presence of the achiral co-catalyst gives rise to facile formation of pr

81 erintuitive strategy involving the use of an achiral co-catalyst structurally similar to the chiral c

82 s observed as a chiral compound comprised of achiral components in its single-crystal structure.

83 Enantiomerically rich, racemic, and achiral compositions undergo deracemization in the cryst

84 und numbers without parentheses represent an achiral compound or a single enantiomer] by extension at

85 Symmetries of achiral compounds facilitate semiquantitative correlatio

86 other combinations of R and S, and even from achiral compounds.

87 ion between petals in the cluster favors the achiral configuration, whereas out-of-plane attraction b

88 would ordinarily result in an S4-symmetric, achiral configuration.

89 ace coverage led to weak charge transfer, an achiral conformation, and 810 nm emission.

90 The obtained compounds can be considered as achiral conformationally restricted analogues of threoni

91 ns and rotatory strengths are calculated for achiral, conjugated hydrocarbons with the aim of determi

92 gen fiber, a conformation producing a strong achiral contribution to the second-order nonlinear effec

93 e is energetically unstable, with either the achiral conventional structure or a closed pore structur

94 An approach that modulates the achiral counterion (equimolar to the neutral chiral liga

95 Unlike the achiral counterpart, which adopts a random-fold, this pa

96 to be less prone to polymorphism than their achiral counterparts and compounds able to hydrogen bond

97 of D- and L-aspartic acid are exposed to an achiral Cu(111) surface, a small e.e. in the gas phase,

98 on can minimize the deleterious influence of achiral Cu-alkyl species, resulting in improved enantiom

99 copper-hydride elimination is faster with an achiral Cu-alkyl species.

100 ctive Cu-H elimination may be avoided and/or achiral Cu-boryl intermediates can be converted to allyl

101 ic core of C3 symmetry, was synthesized from achiral [Cu20H11{S2P(OiPr)2}9] (1H) of C(3h) symmetry by

102 sm (CD) is observed from J-aggregates of the achiral cyanine dye in association with a random coil CM

103 reactions of racemic benzylic bromides with achiral cycloalkylzinc reagents.

104 ,4-3,5)nG2-CH2-Boc-L-Tyr-L-Ala-OMe and their achiral dendritic alcohol (4-3,4-3,5)nG2-CH2OH precursor

105 ling the incorporation of a diverse range of achiral diamine motifs.

106 oselective Cope reaction that starts from an achiral diene.

107 of an amine with an allene that furnished an achiral dihydropyrrole in 22% yield, we have developed,

108 ImmH (K*i(1/4) 5 pM, fourth-generation) uses achiral dihydroxyaminoalcohol seramide as the ribocation

109 lly transported in either direction along an achiral (disregarding isotopic labeling) track.

110 ce, inducing a screw sense preference in the achiral domain of the maleamide-linked foldamers that is

111 ynthetic intermediates, including chiral and achiral drugs and metabolites, constitutional isomers, s

112 aphy on an achiral stationary phase using an achiral eluent, which leads to the substantial enantiome

113 mma-amino alcohols were produced from simple achiral enals in one flask by combining dienamine- and i

114 lic C6 carbon of HMMF, resulting in a cyclic achiral enolate intermediate that subsequently becomes p

115 mic and the enantio-enriched compounds in an achiral environment.

116 ith a reactive chiral face and an unreactive achiral face.

117 d chromatography (HPLC)) and a topologically achiral figure eight knot (18% by HPLC), competing produ

118 e/maleamide linker to couple a chiral and an achiral fragment allows the change in hydrogen bond netw

119 Our convergent approach couples two achiral fragments of similar complexity and employs an e

120 8a-epi-d-swainsonine has been developed from achiral furfural.

121 ntiotopic-group-selective cross-couplings of achiral geminal bis(pinacolboronates) provide a route fo

122 ene synthase) for conversion of the acyclic, achiral geranylgeranyl diphosphate to the polycyclic, ch

123 D) to discriminate between D-amino acids and achiral glycine.

124 control over the screw sense of an otherwise achiral helical peptide foldamer formed from the achiral

125 An achiral host, cucurbit[8]uril (CB[8]), was used for an a

126 to the design of a new protocol in which an achiral hydrogen bond donor thiourea catalyst was utiliz

127 njugated to its hydrophilic part (RF-NBD) or achiral hydrogenated and a red fluorescent dye in its hy

128 in their hydrophobic part (RF), one contains achiral hydrogenated dendrons (RH), while one denoted hy

129 ombination of chiral-racemic fluorinated and achiral hydrogenated dendrons (RHF) in its hydrophobic p

130 A series of achiral hypoxia-activated prodrugs were synthesized on t

131 As shown previously, oligomers derived from achiral imidazole amino acids fold into canonical helice

132 at the plasmonic and excitonic resonances of achiral inorganic nanocrystals (NCs) capped and/or forme

133 on between orthogonal DNA enantiomers via an achiral intermediary, opening the door for "heterochiral

134 antiomers interconvert (racemize) through an achiral intermediate involving a slight rotation of the

135 Interconversion presumably occurs via an achiral intermediate, either a rapidly inverting (via an

136 servation that the ordering exhibited by the achiral LCs is specific to the enantiomers used to form

137 ic system comprising a chiral Lewis acid, an achiral Lewis base, and a Bronstedt base.

138 squaramide catalyst, a mineral acid, and an achiral Lewis base.

139 lizing 4-pyrrolidinopyridine as an effective achiral Lewis base.

140 Mixtures containing an achiral ligand monomer (BTA(PPh2), 2 mol %) and an enant

141 ved from a combination of one chiral and one achiral ligand, where a synergistic interaction of the t

142 catalyst is introduced which contains solely achiral ligands and acquires its chirality entirely from

143 edral iridium(III) complex exclusively bears achiral ligands and effectively catalyzes the enantiosel

144 ed in the presence of different solvents and achiral ligands.

145 bstituted 1,3-dienes give almost exclusively achiral linear 1,4-addition products, unless the 2-posit

146 ues in which octanedioic acid was used as an achiral linker.

147 nt and induce a helical superstructure in an achiral liquid crystal host but also to be able to rever

148 When doped into a commercially available achiral liquid crystal host, the chiral switch was able

149 mmercially available, structurally different achiral liquid crystal hosts.

150 When doped in an achiral liquid crystal with a different concentration, t

151 moresponsive chiral molecular switch into an achiral liquid crystalline medium.

152 nable helical superstructure or to retain an achiral liquid-crystal phase whose helical superstructur

153 from right-handed to left-handed through an achiral liquid-crystal phase, whereas its reverse proces

154 taining different combinations of chiral and achiral macrocycle and axle components, the dominant inf

155 way in which handedness is transmitted into achiral materials is not yet understood at the atomic le

156 preference may furthermore be induced in the achiral, meso oligoureas by formation of a 1:1 hydrogen-

157 e, we study a metasurface composed of tilted achiral meta-atoms with no spatial variation of the unit

158 , supramolecular helical rods composed of an achiral metal complex and a complementary enantiopure mo

159 the vicinity of a plasmon resonance from an achiral metallic nanostructure.

160 rstanding of the chiroptical interactions in achiral metasurfaces, our work opens up new perspectives

161 rough diastereoselective reactions involving achiral Mo-based bispyrrolides and enantiomerically pure

162 es, and of prochiral molecules on chiral and achiral model surfaces, especially on well-defined metal

163 Treatment of an achiral molecular ladder of C(2h) symmetry composed of f

164 Substantial chiral-achiral molecular switching is observed in di(haloacetyl

165 The latter is an achiral molecule that converts spontaneously to the form

166 The common aeg-PNA is an achiral molecule with a flexible structure, whereas gamm

167 trization of prochiral C-H bonds on the same achiral molecule, using a chiral catalyst.

168 Nematic liquid crystals (NLCs) of achiral molecules and racemic mixtures of chiral ones fo

169 urface with preferred handedness composed of achiral molecules at the air/solid interface.

170 icomponent supramolecular networks formed by achiral molecules at the interface of a chiral solvent a

171 of LCs on surfaces presenting chiral versus achiral molecules provide insights into the molecular or

172 r knowledge, 20g and 23g represent the first achiral molecules that modulate selectively hUII and URP

173 layers formed from mixtures of chiral versus achiral molecules were compared.

174 y demonstrate a new nematic order, formed by achiral molecules, in which the director follows an obli

175 Although made of achiral molecules, the layers in these filaments are twi

176 ientation on surfaces presenting mixtures of achiral molecules.

177 lity--even though the phases are formed from achiral molecules.

178 ctural design to achieve CPL from inherently achiral monochromophore systems in simple organic molecu

179 Induction of chirality in achiral monolayers has garnered considerable attention i

180 reaction cascade leading from two identical achiral monomers to homodimericin A is presented, and ho

181 amounts of axially chiral phosphoric acids, achiral N,N'-binaphthyl hydrazines undergo a facile [3,3

182 o catalyze the oxidative desymmetrization of achiral N,N-dialkyl piperidine-4-carboxylates to give pr

183 The success of achiral N-heterocyclic carbenes (NHCs) as stable electro

184 tic kinetic resolution of cyclic amines with achiral N-heterocyclic carbenes and chiral hydroxamic ac

185 ew asymmetric catalytic Strecker reaction of achiral N-phosphonyl imines has been established.

186 Interestingly, achiral nematic LCs with comparatively small twist elast

187 By refilling the cast with an achiral nematic liquid crystal, we created templated blu

188 tivity between chiral NHC precursor 1 and an achiral NHC precursor.

189 reactions with the less sterically demanding achiral NHCs, the presence of MeOH is required for high

190 To understand why achiral nonactin is the naturally generated diastereoiso

191 The achiral nonpolar acentric material is second harmonic ge

192 nucleobase-peptide conjugates (NPCs), where achiral nucleobases are helically displayed on the surfa

193 lysis approach, namely the combination of an achiral nucleophilic catalyst and a chiral anion-binding

194 -butylphosphine was found to be an effective achiral nucleophilic catalyst, effecting good yield and

195 nction in concert such that one serves as an achiral nucleophilic promoter and the other performs as

196 pler 2D system of entropically driven, hard, achiral objects.

197 -(+)-herbertene by asymmetric cyclization of achiral olefinic alkyllithium precursors in the presence

198 An achiral oligo(p-phenylene vinylene) derivative with a ur

199 dimensional helical self-assembled stacks of achiral oligo(p-phenylenevinylene) ureidotriazine (AOPV3

200 This amine was displaced by an achiral one, while maintaining the stereochemistry of th

201 Achiral or chiral phosphines are widely used in two main

202 acyclic quaternary carbon stereocenters from achiral or chiral racemic reactants via transition metal

203 annulated perylenecarboxamides) endowed with achiral or chiral side chains is reported.

204 enium complexes with special emphasis on the achiral or chiral-at-ruthenium center.

205 and a chromophoric, CD-silent probe that is achiral or exists as a racemic mixture of rapidly interc

206 talytic enantioselective desymmetrisation of achiral or meso compounds is a powerful strategy for the

207 ic redox-relay oxidative Heck reaction using achiral or racemic acyclic alkenols and boronic acid der

208 ereoselectivity previously unavailable using achiral organometallic reagents.

209 Functionalization of the achiral parent ligand with a chiral 1-phenylethylamine s

210 umerical simulations result in defect-ridden achiral patterns, containing domains of either hand, due

211 mers of alpha-aminoisobutyric acid (Aib) are achiral peptides that typically adopt 310 helical confor

212 armacokinetic properties of a novel class of achiral peptidomimetic HCV NS3 protease inhibitors.

213 ferent backbone designs displaying chiral or achiral peptoid residues.

214 crowns substituted with chiral, racemic, or achiral peripheral alkyl chains, including enantiopure R

215 romic shift of fluorescence emission for the achiral perylene moiety as a chemical junction of the BC

216 ical purification of non-racemic mixtures by achiral-phase chromatography.

217 anes to carbodiimides yields both chiral and achiral phosphaguanidine boranes under ambient temperatu

218 was achieved using palladium catalysis with achiral phosphine ligands.

219 tunable helical superstructure or retain an achiral photoresponsive liquid crystal phase whose helic

220 chiral ((R)/(S)-BINOL, diethyl tartrate) and achiral (piperazine and trigol) linkers with varying ste

221 ess of intrinsically chiral NCs or arranging achiral plasmonic particles in chiral configurations.

222 ic molecules (tricyclic to pentacyclic) from achiral polyene precursors by enantioselective proton-in

223 erization of lactides starting from a single achiral precursor and the proper choice of an achiral si

224 on of key chiral intermediates from a simple achiral precursor, 2) the utility of a key 1,2-cyclobuta

225 ternatively, from the commercially available achiral precursor, monoprotected 1,4-cyclohexanedione.

226 s, has been developed starting from a single achiral precursor, the meso-diol 11.

227 ur tertiary stereocenters from a monocyclic, achiral precursor.

228 talo- and manno- configurations from simple achiral precursors through organocatalytic asymmetric in

229 bserved that conglomerate crystallization of achiral precursors yielding racemate metal organic frame

230 id core architecture in one step from simple achiral precursors.

231 s (1P, 1M and 2P, 2M) are prepared using the achiral precursors.

232 alcohols, and anti-cyclopropyl alcohols from achiral precursors.

233 nthesize enantioenriched chiral allenes from achiral precursors.

234 By switching the achiral proton source, both enantiomers of a series of t

235 We have evaluated the role of achiral pyrazolidinone templates in conjunction with chi

236 ension of this methodology from the study of achiral pyridine-based catalysis to chiral peptide-based

237 ral helical peptide foldamer formed from the achiral quaternary amino acids Aib and Ac6 c.

238 ctions in the active site, thus mimicking an achiral reaction intermediate.

239 In the achiral regime, the cusp defects have repulsive interact

240 ly simple system of hard Brownian particles: achiral regular triangles confined to two dimensions.

241 acid methyl ester and brefeldin A using only achiral rhodium catalysts.

242 ical rods are formed upon co-assembly of the achiral rhodium complex of BTA(PPh2) and the enantiopure

243 ross-metathesis (DROCM) reactions, involving achiral Ru catalysts and enantiomerically enriched allyl

244 nable efficiency through the use of existing achiral Ru or Mo catalysts.

245 her hand, polynuclear complexes based on the achiral [Ru(2,2':6',2''-terpyridine)2](2+) motif are eas

246 tum yield, as well as chiral transfer to the achiral segment of the fluorescent peptide amphiphile.

247 The helical handedness in achiral self-assemblies is mostly complex due to spontan

248 pped at the inlet of a (4)D column, on which achiral separation allows precise quantification of each

249 eparations are performed, the first being an achiral separation followed by a chiral separation of a

250 procedures for achieving ultrafast chiral or achiral separations in SFC mode.

251 Acyclic inhibitors with achiral serinol groups as the ribocation mimics also dis

252 glutathionyl-alpha-veratrylethanone) from an achiral side chain-truncated model substrate (beta-guaia

253 DAPs with chiral side-chains and flavin with achiral side-chains.

254 chiral precursor and the proper choice of an achiral silanol additive.

255 two independently CD-silent solutions of the achiral (soldier) and chiral (sergeant) monomers.

256 between RTT and LC with respect to chiral or achiral spectra.

257 ly efficient enantioselective synthesis from achiral starting material.

258 ols with up to four stereogenic centers from achiral starting materials.

259 of alkyl-substituted chiral aziridines from achiral starting materials.

260 thers in up to 94% ee from readily available achiral starting materials.

261 c amines bearing adjacent stereocenters from achiral starting materials.

262 compounds, subjected to chromatography on an achiral stationary phase using an achiral eluent, which

263 ce of a two-catalyst system consisting of an achiral strong Bronsted acid (o-nitrobenzenesulfonic aci

264 nsic or pseudo-chiral (meta)surfaces have an achiral structure, yet they can give rise to circular di

265 d method can discriminate between chiral and achiral structures regardless of their orientation.

266 at the interface of a chiral solvent and an achiral substrate.

267 e polybinaphthyls have been synthesized from achiral substrates by asymmetric oxidative phenolic coup

268 ions are mostly highly enantioselective with achiral substrates, and due to the accelerated nature of

269 ration of axial and point chirality from two achiral substrates.

270 N and C-S bond formation by activation of an achiral sulfenylating agent.

271 feasibility of asymmetric sulfinylations by achiral sulfinylating agents (from the perspective of Al

272 uid chromatography (UHPLC), core shell HPLC, achiral supercritical fluid chromatography (SFC) and chi

273 operties as L-sfAFP, because ice presents an achiral surface for sfAFP binding.

274 igate chiral symmetry breaking induced by an achiral surface in a racemate.

275 used to resolve thymidine enantiomers at an achiral surface with an OPV3T enantiomer as the resolvin

276 ane elasticity, geometrical frustration, and achiral symmetry breaking can be used to fold colloidal

277 As the concentration is lowered, breaking of achiral symmetry in the director configuration is observ

278 The choice of the anion of an achiral TBD-derived guanidinium salt, used as cocatalyst

279 rious dienes demonstrate the utility of this achiral template.

280 eration vibrational spectroscopy; chiral and achiral tensor elements were separated using different i

281 ontaining domains of either hand, due to the achiral terpolymeric starting molecules.

282 The efficient synthesis of chiral or achiral tertiary phosphines bearing an o-bromo (or iodo)

283 Lithiation of the achiral tetrahalogenated 4,4'-bipyridine 1 with alkyllit

284 Despite being achiral, the meso oligomers adopt chiral canonical 2.5-h

285 ere the building blocks of the structure are achiral themselves.

286 ted by a dual catalyst system composed of an achiral thiourea and a chiral primary aminothiourea.

287 a chiral primary aminothiourea and a second achiral thiourea.

288 nal groups--those that can be converted from achiral to chiral in a single step--that are accessible

289 crete catalysts--a chiral nucleophile and an achiral transition metal complex working in tandem.

290 key catalytic ring-closing metathesis of an achiral triene is used to establish the all-carbon quate

291 been conducted with complexes containing the achiral triphenylphosphite ligand.

292 However, the combination of achiral trisamide 1a with chiral but nonhelical bisamide

293 gh levels of reactivity found in the related achiral variants (1a and 1b).

294 the interface: energetic preference towards achiral versus the faster growth kinetics of chiral nano

295 ganizationally chiral domains even when R is achiral, while adatom binding leads to rectangular plane

296 ) nanoparticles (Fe NPs) functionalized with achiral (with 1) and chiral (with 2) PNNP-type tetradent

297 Multiple achiral x chiral and chiral x chiral 2D-LC examples (sin

298 the above system is that the precursors are achiral; yet, the tubules are formed from helical ribbon

299 ed in 10 steps and 31% overall yield from an achiral ynone.

300 g (mc-)AFM measurements, in which chiral and achiral Zn-porphyrins are compared.