ライフサイエンスコーパス: adsorbate

1 e solvation of the partly positively charged adsorbate.

2 structural parameters of a model (n)Bu2DTPA adsorbate.

3 tion of bulkier groups on the Ch atom of the adsorbate.

4 detailed electronic structure of a resonant adsorbate.

5 oduce an effective drag on the motion of the adsorbate.

6 plet-excited-state lifetime of the molecular adsorbate.

7 on is bound, and the h is transferred to the adsorbate.

8 g the binding energy between the surface and adsorbates.

9 stigate electron-transfer processes of redox adsorbates.

10 solely based on covalent binding of organic adsorbates.

11 vealed distinct individual properties of the adsorbates.

12 gold(I) ion are surprisingly small for both adsorbates.

13 the difference in chelation between the two adsorbates.

14 ch can be occupied or blocked by some of the adsorbates.

15 used to achieve this goal for electroactive adsorbates.

16 roism by Au nanoparticles modified by chiral adsorbates.

17 n activation energy for a range of spherical adsorbates.

18 or detection and identification of molecular adsorbates.

19 entify the atomic-scale structure of unknown adsorbates.

20 ission lifetimes due to electron transfer to adsorbates.

21 redominantly to study aggregation of racemic adsorbates.

22 ed on graphene and bulk graphite in terms of adsorbates.

23 ites, and bonding and orientation of surface adsorbates.

24 and hence vanishes in regions accessible by adsorbates.

25 mi level exchanges electrons with the oxygen adsorbates.

26 atic atomic-scale interrogation of molecular adsorbates.

27 esponds to where the refractive index of the adsorbate achieves its largest value, which occurs at wa

28 of achieving fast and controllable motion of adsorbates across material surfaces more generally.

29 id He cooling minimizes surface diffusion of adsorbates across the solid surface, allowing direct STM

30 of scanning tunneling microscopy and several adsorbate/additive combinations.

31 state properties will provide information on adsorbate-adsorbate and adsorbate-substrate interactions

32 ividual pores have been extensively studied, adsorbate-adsorbate interactions across pore walls have

33 , can give rise to collective and long-range adsorbate-adsorbate interactions and the formation of ad

34 or the low coverage limit (</=0.03 ML) where adsorbate-adsorbate interactions are negligible.

35 Adsorbate-adsorbate interactions increase the average CH

36 l to understand both adsorbent-adsorbate and adsorbate-adsorbate interactions, and also the energy re

37 he mean-field kinetic model includes lateral adsorbate-adsorbate interactions, and the BEEF-vdW error

38 ngmuirian Moreau isotherm due to significant adsorbate-adsorbate interactions, whereas the isotherms

39 adsorbate-substrate interaction and pairwise adsorbate-adsorbate interactions.

40 Substrate-mediated long-range adsorbate-adsorbate repulsion has been observed on aniso

41 akthrough profiles as well as the amounts of adsorbates adsorbed.

42 s in the bc crystallographic plane where the adsorbate-adsorbent interactions are maximized by both t

43 the contributions of the overall or specific adsorbate-adsorbent interactions to the adsorption.

44 Conformational flexure and both adsorbate/adsorbent and intermolecular interactions can

45 lute from solution and/or because the tested adsorbate:adsorbent ratios are not varied sufficiently.

46 by our data, with clear evidence for initial adsorbate aggregation in distinct domains and ordering b

47 The resulting surface adsorbate anchors are particularly relevant to engineeri

48 it is essential to understand both adsorbent-adsorbate and adsorbate-adsorbate interactions, and also

49 Effects of the adsorbate and adsorbent properties on Ea or EH then emer

50 and desorption efficiency and showing stable adsorbate and adsorbent properties, this paper suggests

51 ccount the van der Waals interaction between adsorbate and metal surface.

52 ion occurs is strongly dependent on both the adsorbate and the support, and this effect is general fo

53 akes to move an atom depends strongly on the adsorbate and the surface.

54 ave revealed unexpected interactions between adsorbates and defects that influence macroscopic reacti

55 , well-developed and accessible porosity for adsorbates and reactants, and are non-toxic, biocompatib

56 gh understanding of the interactions between adsorbates and SWNTs is therefore critical to predicting

57 ometric and electronic structures of the two adsorbates and that the energetic difference between mon

58 By experimentally quantifying the number of adsorbates and the average amount of charge carried by e

59 molecular forces and the interaction between adsorbates and the underlying substrate.

60 are determined by interactions involving the adsorbates and their porous host materials.

61 teraction strength between the adsorbent and adsorbate, and adsorption site heterogeneity.

62 ndent on exposure time, the concentration of adsorbate, and the ionic strength of the solution.

63 ar chiral ensembles made out of small chiral adsorbates, and by adsorption of more complex chiral mol

64 ere V is McGowan's characteristic volume for adsorbates, and S reflects the adsorbate's polarity/pola

65 thermal motion of the cation as well as the adsorbate are found.

66 new mechanism for surface diffusion whereby adsorbates are carried by propagating ripples in a motio

67 rast to (C16)2DTPA SAMs, in which 40% of the adsorbates are monodentate.

68 d to redox chemistry of adventitious organic adsorbates are observed, indicating that air exposure re

69 neration particularly when high-affinity VOC adsorbates are present.

70 erings of solid microparticles and molecular adsorbates are strongly coupled at the interfaces of LCs

71 Surface adsorbates are well-established choreographers of materi

72 elding information on distribution ratios of adsorbates at each type of site.

73 urement capabilities to simultaneously probe adsorbates at multiple length scales will provide new in

74 by coadsorbed water in the photochemistry of adsorbates at solid interfaces and the roles that molecu

75 hannel and Schottky contact formation due to adsorbates at the interface between the gold contacts an

76 gle-crystal structures of the different gold adsorbates Au(III)@1 and Au(I)@1 suggest that the select

77 metry and charge distribution to accommodate adsorbates better.

78 take and are strongly dependent on the metal-adsorbate binding strength.

79 ction potential, metal ion availability, and adsorbate binding strength.

80 We identify the adsorbate-binding energy as a descriptor for certain mol

81 demonstrate the ability to control the metal-adsorbate bond through external electronic modifications

82 iates while increasing those which result in adsorbate bond-breaking reactions.

83 face can induce dissociative reaction of one adsorbate bond.

84 oparticle size, it is generally assumed that adsorbates bond in an identical fashion as on a semiinfi

85 ) Lennard-Jones well-depth parameters of the adsorbates but approximately 13-fold larger.

86 Graphene is readily p-doped by adsorbates, but for device applications, it would be use

87 ion of zeolites and MOF-801 with water as an adsorbate by conducting desorption experiments with conv

88 f 10 by adding a mildly electron-withdrawing adsorbate, C60, which also modifies the step geometry.

89 Critically, individual benzonitrile adsorbates can be manipulated using scanning tunneling m

90 ayers (SAMs) of dialkyldithiophosphinic acid adsorbates [CH3(CH2)n]2P(S)SH (R2DTPA) (n = 5, 9, 11, 13

91 on of energetically favored, axially aligned adsorbate chains.

92 ms formed by e-beam evaporation in which all adsorbates chelate to gold, in contrast to (C16)2DTPA SA

93 hat incorporates the formation of homochiral adsorbate clusters on the surface.

94 r regeneration method detectably altered the adsorbate composition during desorption.

95 n, contact time, extent of modification, and adsorbate concentration on the biosorption capacity of C

96 ent removal in deionized water at low-target-adsorbate concentrations potentially suggests that DOM i

97 red spectroscopy all at identical saturation adsorbate coverage.

98 ct of scaling on surface thermochemistry and adsorbate coverage.

99 e calculate relative surface stabilities and adsorbate coverages of the most stable low-index surface

100 The high adsorbate coverages that form on the surfaces of many he

101 arge-scale 'before' and 'after' images of an adsorbate covered surface, the spatial extent of the non

102 The extent known-competitor adsorbates decrease target-adsorbate removal in the pres

103 reby preparing spatially inhomogeneous local adsorbate densities, could add a new design tool for MOF

104 alysis of the simulated heats of adsorption, adsorbate density distributions, and minimum energy 0 K

105 eral neighbouring pores, which have a higher adsorbate density than non-domain pores.

106 The structural dynamics-cluster size and adsorbate-dependent thermal behaviors of the metal-metal

107 es when k B T exceeds the barrier height for adsorbate diffusion across terraces.

108 of SAMs formed from the structurally similar adsorbate dihexadecyldithiophosphinic acid (C16)2DTPA.

109 on originates from a sizable cancellation of adsorbate dipole moments by mirror charges dynamically i

110 as elucidated by competitive adsorption and adsorbate displacement tests.

111 rafast charge separation in this quantum dot-adsorbate donor-acceptor complex provides a potential ap

112 depth values were achieved by incorporating adsorbate effects on substrate permittivity.

113 res can be functionalized with many types of adsorbates, enabling the use of OWL-generated structures

114 but on surfaces with palladium particles the adsorbates exhibit relative disorder at low surface cove

115 -nitrophenyl-acetylacetonate or coumarin 343 adsorbates, exhibit hole injection into surface states w

116 Both adsorbates exhibited pronounced island formation, though

117 d calculating the enthalpies of well-defined adsorbates, few measurements of the entropies of adsorba

118 ong CO-CO repulsion in the highly compressed adsorbate film.

119 we show that the chemical shift value of an adsorbate (formic acid) on metal colloid catalysts measu

120 re found to be the most energetically stable adsorbate forms.

121 Despite their importance, knowledge of how adsorbate frequencies scale across materials is lacking.

122 effect and negatively correlate with target-adsorbate-Freundlich 1/n values.

123 ar, the instrument has often been applied to adsorbates from a liquid phase and, also, to samples wit

124 t with a model describing energy transfer to adsorbates from a moving surface.

125 erials for evaluating the effects of surface adsorbates from the initial state for application-orient

126 igurations of the LC droplets induced by the adsorbates generate distinct changes in light scattering

127 orimetric, and infrared studies of the probe adsorbates H2, CO, and CO2 reveal the presence of severa

128 as a function of particle size (1-3 nm) and adsorbate (H2, CO) using synchrotron radiation pair dist

129 rbates, few measurements of the entropies of adsorbates have been reported.

130 is effect is characterized by strongly bound adsorbates (HCOx) on reducible oxide supports (TiO2 and

131 ngly affected by particle size, support, and adsorbates (here we use H2).

132 enter and the number of p electrons) and the adsorbates' highest occupied molecular orbital (HOMO) en

133 red spectroscopy to directly observe surface adsorbates, hydrogen atoms and methyl groups, chemisorbe

134 ity and strain are observed, indicating that adsorbates impart tension to the graphene.

135 energetic projectile directly reacts with an adsorbate in a single-collision event to form a hyperthe

136 tional evidence for the integral role of the adsorbate in determining ASJ reorganization dynamics.

137 nd is a function of relative pressure of the adsorbate in the feed gas.

138 roved understanding of the role of ligand or adsorbates in colloidal catalysis and photocatalysis and

139 n be controlled by variation of the ratio of adsorbates in solution.

140 pressures (0.03, 0.1, 0.2, 0.4, and 0.6) of adsorbates in the influent stream.

141 Adsorbate-induced band gap states in semiconductors are

142 re less than 10(-5) Langmuir, are not due to adsorbate-induced changes in the interfacial energy of t

143 The effect can be explained by adsorbate-induced changes of the surface stress, and can

144 gion is nonemissive (dead layer), surfactant adsorbate-induced modulation of the depletion layer widt

145 n of chemical and biological assays based on adsorbate-induced ordering transitions within LC droplet

146 While adsorbate-induced spin state transitions are well-known

147 This discovery shows that adsorbate-induced superstructures are not limited to spe

148 ing density functional theory predictions of adsorbate-induced surface reconstruction visually with a

149 clusters do exhibit, however, both size- and adsorbate-induced trends in bond strain that are similar

150 ter and stormwater was independent of target-adsorbate initial concentrations (C0) when C0s were belo

151 rption/desorption/reaction properties of the adsorbates inside such environments, screen and design n

152 e adsorption isotherms for a given adsorbent-adsorbate interaction at temperature/pressure conditions

153 ulations with appropriately chosen adsorbent-adsorbate interaction potentials.

154 Weak inter-adsorbate interactions are shown to play a crucial role

155 P structure can be diminished in favor of NP/adsorbate interactions when NP catalysts are prepared by

156 exchange due to both metal-support and metal-adsorbate interactions--play in mediating the structural

157 statistical description of particle-support-adsorbate interactions.

158 higher coverage and in a humid environment, adsorbate interchange was detected.

159 hene but from self-assembly of environmental adsorbates into a highly regular superlattice of stripes

160 Dissolution of adsorbates into organic matter may also affect the hyste

161 This leads to a classification of adsorbates into two groups, where adsorption energies in

162 , XRD (X-ray diffraction), IR (infrared) and adsorbate-IR, N2 and CO2 physisorption at 77 and 273 K,

163 The dative-bonded adsorbate is characterized by a N identical withC stretc

164 a transient positive feedback loop until the adsorbate is consumed completely.

165 With the formation of a well-ordered adsorbate layer, it is partially reestablished; however,

166 rmittivity following covalent binding of the adsorbate layer.

167 ation of the data obtained for heterogeneous adsorbate layers is not straightforward in particular if

168 s, organic films for polymer electronics and adsorbate layers) suffer degradation under the energetic

169 h nonreactive spectator species and reactive adsorbate layers.

170 resonance (LSPR) of metal nanostructures to adsorbates lends itself to a powerful class of label-fre

171 d empirically from the observed response for adsorbate loading on gold surface plasmon resonance (SPR

172 We conclude that both PEG adsorbates maintain a compact "brush" rather than an ext

173 significance of incorporating an additional adsorbate-metal bonding effect in the calculation is dem

174 space between graphene and metals, with the adsorbate-metal interaction being modified significantly

175 In general, for both adsorbate mixtures, competitive adsorption resulted in d

176 al role, which may represent a gas-molecular-adsorbate-modified growth in catalyst preparation.

177 themselves, via the formation of individual adsorbate:modifier adducts on the surface.

178 h is, in turn, inversely proportional to the adsorbate molecular size.

179 tive contributions of factors related to the adsorbate molecular structures that serve to strongly me

180 y transition at approximately 3 Al atoms per adsorbate molecule (3 EL) from formation of a buried app

181 s (up to 0.04 ML, where 1 ML is equal to one adsorbate molecule for every surface Pt atom) using sing

182 shows a significant mismatch of the average adsorbate molecule spacings with the spacings of an intr

183 e to states induced by the Fe-dopant and the adsorbate molecule, and crossing between excited states

184 ons (polaron formation) and, more slowly, by adsorbate molecules (solvation).

185 text of hydrophobic interactions between the adsorbate molecules and the methylated surface in the pr

186 ack and map the distribution and ordering of adsorbate molecules in five members of the mesoporous MO

187 difications in molecular conformation of the adsorbate molecules is introduced.

188 ctive energy migration pathways of monolayer adsorbate molecules on differently sized metal nanoparti

189 But, although the interactions of adsorbate molecules with the internal MOF surface and al

190 xhibit varying levels of binding strength to adsorbate molecules.

191 e approximately the same length scale as the adsorbate molecules.

192 AS results reveal that nanoframes which bind adsorbates more strongly have a rougher Pt surface cause

193 ing on the temperature and the nature of the adsorbate, more than one type of organic radical was for

194 Moreover, the adsorbate N identical withC vibrational frequency red-sh

195 F) with and without post-treatments by (31)P adsorbate nuclear magnetic resonance, supported by a ran

196 (PCET) and as an inhibitor in its role as an adsorbate of active sites.

197 ith four p-nitrophenyl acetylacetone (NPA-H) adsorbates, of which the atomic structure has been fully

198 selectivity previously reported for the same adsorbate on Pd(111).

199 or visualizing the distribution of molecular adsorbates on graphene semi-quantitatively using teraher

200 benchmark for electronic structure theory of adsorbates on metal surfaces.

201 paths from ethylene glycol to C1 oxygenated adsorbates on Pt.

202 Such excitations are not expected to affect adsorbates on RuO2 given its metallic properties.

203 and step sites, which should be general for adsorbates on surfaces at high temperatures.

204 ise engineering of the position of molecular adsorbates on surfaces of 2D materials is key to their d

205 Whether chiral adsorbates on surfaces preferentially aggregate into het

206 the molecular level by chiral and prochiral adsorbates on surfaces.

207 tionalized by the stronger binding energy of adsorbates on the (100) facet versus the (111) facet.

208 provided consistent results of the amount of adsorbates on the BAC after adsorption and/or regenerati

209 xcess variance between a small population of adsorbates on the ensemble of nanoparticles.

210 s work, we explore the influence of resonant adsorbates on the LSPR of bare Ag nanoparticles (lambda(

211 ion and chemical specificity of surfaces and adsorbates on the molecular scale at pressures of up to

212 quantum tunneling and hindered rotations of adsorbates on the rate of surface reactions have been in

213 EPFRs were produced by the chemisorption of adsorbates on the supported metal oxide surface and tran

214 lectronic effects in hydrogen formation from adsorbates on TiO2(110).

215 relations between vibrational frequencies of adsorbates on transition metal surfaces.

216 The interaction of LSPR with adsorbate orbitals can lead to the injection of energize

217 or diffusion and show how it also applies to adsorbates other than water, thus opening up the prospec

218 the mineral surface (i.e., the adsorption of adsorbates past the point of electrostatic equilibrium)

219 ctroscopy and site-selective spectroscopy of adsorbate populations on SERS-active particles.

220 The reaction between the titrant and the adsorbate provides a transient positive feedback loop un

221 the vibrational energy of a carbon monoxide adsorbate rapidly dissipates into the particle through e

222 by surface control using surface charges and adsorbates, reaching a low temperature value more than 2

223 investigated, which depends on the competing adsorbates' relative adsorbabilities and if they adsorb

224 known-competitor adsorbates decrease target-adsorbate removal in the presence of DOM is investigated

225 ch surfaces, apparently because surfaces and adsorbates restructure to balance CO surface binding and

226 ectrostatic field, and charged impurities or adsorbates, resulting in a tuneable photoresponsivity.

227 ghboring particles, which contributes to the adsorbate's apparent mass.

228 ic volume for adsorbates, and S reflects the adsorbate's polarity/polarizability.

229 ion and subsequent transformation of several adsorbate species was observed.

230 nstead of CA site-bridging and variations of adsorbate species were qualitatively illustrated.

231 energy and has a large spatial overlap with adsorbate states.

232 le that under-coordinated surface atoms bind adsorbates stronger, thereby providing the atomic-level

233 In addition to boiling point, adsorbate structure and functionality affected adsorptio

234 rticles play an apparent role in controlling adsorbate structures.

235 odynamic treatments to models that emphasize adsorbate structures.

236 The broad range of adsorbates studied here allows us to compare trends both

237 l stability is dependent on the interplay of adsorbate-substrate and ionic interactions and opens new

238 h is further subject to modifications by the adsorbate-substrate coupling.

239 acroscopic observations assuming a separable adsorbate-substrate interaction and pairwise adsorbate-a

240 explained by a nonlocal modification of the adsorbate-substrate interaction, reflecting a many-body

241 ovide information on adsorbate-adsorbate and adsorbate-substrate interactions and may allow for inver

242 g approach for unraveling the intricacies of adsorbate-substrate interactions that are inaccessible b

243 ealing additional chemical information about adsorbate-substrate interactions.

244 PA self-organize within SAMs on TS gold: (i) adsorbate-substrate interactions; (ii) gold substrate mo

245 ation of nonequilibrium energy states in the adsorbate-substrate system are proposed and discussed.

246 : on a clean single-layer graphene membrane, adsorbates such as atomic hydrogen and carbon can be see

247 e domain fracture results from tightly bound adsorbates, such as atomic O.

248 -adsorbate interactions and the formation of adsorbate superlattices that extend beyond an original M

249 However, the dependence on the adsorbate-surface coupling and the d-band filling varies

250 e used as an estimate of the strength of the adsorbate-surface interaction.

251 chical scheme to categorize the chirality of adsorbate-surface systems.

252 tals (LCs) dispersed in aqueous solutions of adsorbates (surfactants and phospholipids).

253 ybridization of the metal orbitals in the Pt-adsorbate system.

254 ically applicable polyelectrolyte multilayer adsorbate system.

255 ignificantly different for a thiol monolayer adsorbate system.

256 u, indicating faster kinetics in the colloid-adsorbate system.

257 a direct charge transfer within the molecule-adsorbate system.

258 tion/desorption processes of porous material-adsorbate systems, such as zeolites and metal-organic fr

259 ecursor for the bond-breaking step is a CHOC adsorbate that preferentially adsorbs on a square ensemb

260 in adsorption energies of a wide variety of adsorbates that attach to transition metal surfaces thro

261 patterning of platinum surfaces with cyanide adsorbates that can efficiently block the sites for adso

262 esults in vibrational energy migration among adsorbates that occurs on a twenty times slower timescal

263 By transferring electrons to or from the adsorbate, the process of bond weakening and/or cleavage

264 oiting the nonlinear optical response of the adsorbate, the temporal correlation of headgroup adsorpt

265 the nonzero intercept of a SPR shift versus adsorbate thickness calibration and incorporated into th

266 ion shows greater consistency over different adsorbate thicknesses and better agreement with theory d

267 ed from Maxwell's equation, particularly for adsorbate thicknesses that are much smaller (<5%) than t

268 omentum, part of which is transmitted to the adsorbate through scattering.

269 he Pt surface and report the amounts of this adsorbate through the SECM feedback response.

270 tions can sensitively report the presence of adsorbates through their impact on ballistic electron tr

271 -phase atom reacting directly with a surface adsorbate to form a molecular product.

272 surface and transfer of an electron from the adsorbate to the metal center, resulting in reduction of

273 e-Frenkel conduction threshold can stimulate adsorbates to desorb without heating the sensor substant

274 uch as to study the molecular orientation of adsorbates to films or protein conformation upon adsorpt

275 ent-like character in the binding of surface adsorbates to GaP, which results in a more rigid hydroge

276 f mechanical strain on the binding energy of adsorbates to late transition metals is believed to be e

277 e of surface oxygen vacancies, electrons and adsorbates to the electrochemical polarization at the ce

278 through the photocatalytic decomposition of adsorbates under UV irradiation.

279 ocess takes 13-36 h depending on the type of adsorbate used to functionalize the nanostructures.

280 was determined by the observation of reduced adsorbate using femtosecond IR spectroscopy.

281 rated through exposure of particles to three adsorbate vapors at 230 degrees C: phenol, 2-monochlorop

282 Adsorbate vibrational excitations are an important finge

283 The formation of an adsorbate was confirmed by X-ray absorption fine structu

284 the average amount of charge carried by each adsorbate, we find that the PAH is associated with only

285 nyl chloride as a model electron-withdrawing adsorbate, we show that reversible adsorption sites can

286 ection of energized charge carriers into the adsorbate, which can result in chemical transformations.

287 he position and orientation of the molecular adsorbates, which in turn determine the origin, directio

288 heterostructures are devoid of wrinkles and adsorbates, which is critical for 2D nanoelectronics.

289 the predominate magnetic interaction of the adsorbate with the framework.

290 h time and adsorption capacity of adsorbents/adsorbates with different dielectric properties.

291 Adsorbates with low HOMOs experience a higher level of P

292 opy (TERS) provides chemical information for adsorbates with nanoscale spatial resolution, single-mol

293 covery system (GRS) using ACFC-ESA for three adsorbates with relative pressures between 8.3 x 10(-5)

294 alkyl chain crystallinity; SAMs formed from adsorbates with short alkyl chains (n = 5) are ordered a

295 Even across the groups, adsorbates with similar HOMO energies are likely to have

296 The method searches for molecular adsorbates with suitable photoabsorption properties thro

297 e original characteristic energy (Eo), i.e., adsorbates with tendency to form stronger interactions w

298 tion, connecting binding energies of complex adsorbates with those of simpler ones (e.g., C, O), is u

299 ces reaction of both of the C-I bonds in the adsorbate, with an order-of-magnitude greater efficiency

300 oncentrations>5 muM, tetrahedral monodentate adsorbates (Zn-O 1.98 A) dominated, transitioning to a Z