ライフサイエンスコーパス: alicyclic

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1 ycins, in particular in the formation of the alicyclic 6-hydroxy function of the landomycin aglycon.

2 alogues, consisting of aliphatic carbamates, alicyclic amides, and heteroaromatic amides, were synthe

3 metal-free methods are accommodated and the alicyclic amine nucleophiles used here are unprecedented

4 e also described, including benzyl azide and alicyclic amine nucleophiles.

5 version of C-H bonds to C-C bonds on various alicyclic amine scaffolds.

6 te ions, primary aliphatic amines, secondary alicyclic amines (5H(+) only), and OH(-) (5H(+) only) we

7 h to selectively manipulate the C-H bonds of alicyclic amines at sites remote to nitrogen.

8 primary aliphatic and a series of secondary alicyclic amines in 50% MeCN-50% water (v/v) at 25 degre

9 )Z)CH(3)) by primary aliphatic and secondary alicyclic amines in 50% MeCN-50% water (v/v) at 25 degre

10 log k0 for the reaction of 4H with secondary alicyclic amines in water (1.22) is 1.81 log units highe

11 idene Meldrum's acids (2-SMe-Z) by secondary alicyclic amines occurs by a three-step mechanism.

12 Saturated nitrogen-containing heterocycles (alicyclic amines) feature prominently in pharmaceuticals

13 y OH(-), primary aliphatic amines, secondary alicyclic amines, and carboxylate ions have been determi

14 (4H) by primary aliphatic amines, secondary alicyclic amines, hydroxide ion, and water in water at 2

15 xylate ions, primary aliphatic and secondary alicyclic amines, water and OH(-) in 50% MeCN-50% water

16 However, N-alicyclic aminomethylene bisphosphonates, such as incadr

17 chemical structures of a range of synthetic alicyclic and aromatic acids and their acute toxicities

18 d straight-chained, branched, double-bonded, alicyclic, and aromatic features.

19 ation/functionalization of various aliphatic/alicyclic/aromatic carboxamide systems.

20 Analogues incorporating alicyclic beta-amino acids exhibited diverse receptor bi

21 Computational studies of alicyclic carbodiimides (RN horizontal lineC horizontal

22 the only biomolecule class with contiguous, alicyclic carbon backbones of this size.

23 -H arylation/acetoxylation of aliphatic- and alicyclic carboxamides afforded the corresponding beta-C

24 -directed arylation/benzylation of aliphatic/alicyclic carboxamides and benzamides were ascertained f

25 rivatives, together with high percentages of alicyclic compounds (triterpenoids, steroids, or tocophe

26 ne)Ru(II) precursors; thus, the isolation of alicyclic cyclohexadienone derivatives upon demetalation

27 the two different classes of epoxides, i.e., alicyclic (cyclohexene oxide) and aliphatic (propylene o

28 A common reaction pathway for alicyclic (cyclohexene oxide) and aliphatic (propylene o

29 The conformationally restricted alicyclic derivatives were not only more cytotoxic than

30 We have found that several aliphatic and alicyclic diols induce melanogenesis in cultured S91 mou

31 f observed reduced compounds corresponded to alicyclic hydrocarbons in the size range C10 to C17.

32 roborate several recent studies that suggest alicyclic hydrocarbons to be important components of lon

33 find an explanation of the low reactivity of alicyclic ketones such as cyclohexanone in reactions wit

34 nin-derived compounds and/or carboxylic rich alicyclic molecules (CRAM).

35 e identified as carbohydrates, carboxyl-rich alicyclic molecules, and aliphatic molecules.

36 s dissolved black carbon and carboxylic-rich alicyclic molecules, was also rapidly and extensively re

37 L(-1) of an OSPW subfraction containing only alicyclic NA, and considered by most authors to be NA se

38 ynthesis and characterization of a series of alicyclic organochalcogen compounds derived from 2-chlor

39 NMR investigations revealed that the alicyclic portion of the compounds thus formed displayed

40 e the cyclization reactions of the universal alicyclic precursor farnesyl pyrophosphate to produce mo

41 the exclusive formation of the dearomatized alicyclic products without subsequent rearomatization.

42 nted on alkynes bearing long alkyl chain, an alicyclic ring, hydroxy, ether, and ester functionality,

43 lkyl glycerol tetraethers (GDGTs with 0 to 8 alicyclic rings), including the complete resolution of G

44 .0.1(3,10).1(5,8)]dodecanes (DTDs) with rare alicyclic scaffolding in high overall yields.

45 of residue 92 leads to the production of the alicyclic sesquiterpenes (E)-beta- and (E,E)-alpha-farne

46 en replaced with Ala, produced almost 80% of alicyclic sesquiterpenes, suggesting an energetic separa

47 5-dimethoxybenzoic acid by making use of the alicyclic side chain in N as a "conformational lock".

48 Acyclic sulfones 4a-f and alicyclic sulfone 7 react with readily available N-acylb

49 VLCFA derivatives and less (if at all) with alicyclic wax constituents.

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