ライフサイエンスコーパス: aliphatic

1 for conjugated aromatic substrates than for aliphatics.

2 tained by employing aryl bromides containing aliphatic 1 degrees , 2 degrees , and 3 degrees amine su

3 group tolerance allow access to a variety of aliphatic [(18)F]CF3S compounds in high yields.

4 yzed arylation of gamma-C(sp(3) )-H bonds of aliphatic acid-derived amides was developed by using qui

5 on aromatic, heteroaromatic, and unsaturated aliphatic acids and utilize a prenylated flavin mononucl

6 ry C-H bonds of alpha-amino acids and simple aliphatic acids is reported.

7 e active site is designed to accommodate the aliphatic acyl chains of each substrate.

8 The aliphatic acyl chains vary in length and branching and a

9 The aliphatic alcohol 1,6-hexanediol melted FG domain polyme

10 Hexacosanol (9.71-28.15 mg/kg) was the major aliphatic alcohol.

11 Considerably larger amounts of monoterpenes, aliphatic alcohols and benzene derivatives, were release

12 Both aliphatic alcohols and benzyl alcohols are suitable subs

13 All four permutations of benzylic/aliphatic alcohols and primary/secondary amines are viab

14 applied to a range of benzylic and saturated aliphatic alcohols containing halide and (thio)ether sub

15 -induced Pd-catalyzed remote desaturation of aliphatic alcohols into valuable allylic, homoallylic, a

16 rination on the lipophilicity of fluorinated aliphatic alcohols was determined, and the log P values

17 branched or linear adducts from benzylic or aliphatic alcohols, respectively.

18 a structurally diverse range of aromatic and aliphatic alcohols, yielding up to 96% conversion and 99

19 chemoselective for aromatic aldehydes, as an aliphatic aldehyde was unreactive under these conditions

20 n-phosphorylated polar aldehyde, a non-polar aliphatic aldehyde, and finally a non-polar aromatic ald

21 thmatic patients, metabolomics (using target aliphatic aldehydes and alkanes) was carried out using s

22 ope of the reaction is limited to unbranched aliphatic aldehydes and was tolerant of a number of func

23 The aryl and aliphatic aldehydes both gave the trans-aziridines with

24 imal protocol for the trans-aziridination of aliphatic aldehydes did not require prereaction of the c

25 Aliphatic aldehydes react with similarly excellent resul

26 different reaction pathway when compared to aliphatic aldehydes that yield the syn adduct as major i

27 thiosemicarbazones derived from aromatic and aliphatic aldehydes using equimolar amounts of reagents

28 A total of 10 aliphatic aldehydes were examined and found to give tran

29 efficiently oxidize an array of aromatic and aliphatic aldehydes, including the reactive carbonyl spe

30 y with aromatic, alpha,beta-unsaturated, and aliphatic aldehydes, respectively.

31 ightly different for aryl aldehydes than for aliphatic aldehydes.

32 ,beta-unsaturated ketones and alpha-branched aliphatic aldehydes.

33 s opposite for those formed from aryl versus aliphatic aldehydes.

34 For less activated (aliphatic) aldehydes, a cooperative catalytic strategy h

35 yzed, ABTD-directed arylation/benzylation of aliphatic/alicyclic carboxamides and benzamides were asc

36 C-H activation/functionalization of various aliphatic/alicyclic/aromatic carboxamide systems.

37 neralized in the case of aromatic as well as aliphatic alkyne partners to afford good yields and high

38 ing between ketone beta-C(sp(3))-H bonds and aliphatic alkynes using an in situ-installed directing g

39 beta-substituted vinylarenes and unactivated aliphatic alpha-olefins.

40 zed ester and aromatic amide hydrolysis, but aliphatic amide hydrolysis has been elusive.

41 tion of gamma-methylene C(sp(3) )-H bonds of aliphatic amides and delta-methylene C(sp(3) )-H bonds o

42 tionalization of beta-methylene C-H bonds in aliphatic amides.

43 d by single-electron transfer to unactivated aliphatic amides; however, little variation in terms of

44 catalytic C-H functionalization, the use of aliphatic amine coupling partners is limited.

45 ryliodonium salt electrophiles and secondary aliphatic amine nucleophiles.

46 n conditions a series of simple and unbiased aliphatic amine starting materials can be oxidized to va

47 r of the reactions revealed that aniline and aliphatic amines (e.g., methylamine) prefer to attack C8

48 tion process that combines readily available aliphatic amines and the feedstock gas carbon monoxide t

49 A range of unprotected aliphatic amines are suitable substrates, undergoing sit

50 n reaction, the selective mono-alkylation of aliphatic amines by unactivated, hindered halides persis

51 We report herein that primary aliphatic amines can be cleanly mono-alkylated by unacti

52 attack on a palladium anhydride to transform aliphatic amines into beta-lactams.

53 eactions of methylene C-H bonds in secondary aliphatic amines lead to the formation of trans-disubsti

54 e found that the aromatic ring of the phenyl aliphatic amines may form cation-pi interaction with the

55 ening reaction to give highly functionalized aliphatic amines through a consecutive process.

56 A novel method for direct C-H oxygenation of aliphatic amines through a metal-free activation of mole

57 enantioselective intermolecular addition of aliphatic amines to acyclic 1,3-dienes.

58 An efficient, rapid oxidation of various aliphatic amines to oximes using m-CPBA as an oxidant in

59 yl anilines, N,N-dialkyl amines, and primary aliphatic amines using this class of ligands.

60 Anilines, aliphatic amines, alpha-chiral aliphatic amines, or even

61 Anilines, aliphatic amines, alpha-chiral aliphatic amines, or even ammonia were used as amine cou

62 Aliphatic amines, oxygenated at remote positions within

63 In this study, we hypothesize that aliphatic amines, which are highly abundant among organi

64 all-molecule catalyzed kinetic resolution of aliphatic amines.

65 ion of unactivated primary beta C-H bonds of aliphatic amines.

66 ion of enzymatic substrate scope, to include aliphatic amines.

67 nalized with alpha-halocarbonyls and aryl or aliphatic amines.

68 ent free energy of partitioning of unnatural aliphatic amino acids on TM segments is proportional to

69 Aliphatic and aliphatic-aromatic variations at position

70 substituted isochroman derivatives from both aliphatic and aromatic aldehydes with high yields and ex

71 hly enantioselective homocrotylation of both aliphatic and aromatic aldehydes, as well as double dias

72 The reaction is general and works well using aliphatic and aromatic aldehydes.

73 yze the asymmetric Prins cyclization of both aliphatic and aromatic aldehydes.

74 gh branched selectivity is obtained for both aliphatic and aromatic alkenes using a cationic iridium

75 Specifically, primary and secondary aliphatic and aromatic amines, heterocycles, such as ind

76 Both aliphatic and aromatic anhydrides are formed on convenie

77 aneous occurrence of several charge-assisted aliphatic and aromatic C-H noncovalent interactions, i.e

78 ETCOR) NMR indicated aryl-aliphatic ketones, aliphatic and aromatic carboxyl groups, phenol, and meth

79 the regioselective nitration of a series of aliphatic and aromatic carboxylic acids to their corresp

80 the organic matter consists of a mixture of aliphatic and aromatic compounds and functional groups s

81 Suberin, a polymer composed of both aliphatic and aromatic domains, is deposited as a rough

82 ssorted forms of ferric iron, producing both aliphatic and aromatic forms of organobromine.

83 Lossen rearrangements, and can be applied to aliphatic and aromatic hydroxamic acids.

84 when presented with a substrate bearing both aliphatic and aromatic hydroxy groups the enzyme prefere

85 synchronize the transcriptional induction of aliphatic and aromatic monomer biosynthesis and transpor

86 nalysis was the absorption of laser light by aliphatic and aromatic nitrogen functionalities in the p

87 ging of secondary organic aerosol (SOA) from aliphatic and aromatic precursors in heterogeneous/multi

88 y hydrophobic and pi-pi interactions between aliphatic and aromatic residues and the conjugated CBN s

89 Aliphatic and aromatic secondary amines were obtained in

90 or, we found that under anaerobic conditions aliphatic and aromatic thiols (as well as selenols) are

91 n of p-cresol-based N-phenylbenzoxazine with aliphatic and aromatic thiols was investigated in solven

92 e number of isomeric organic compounds, both aliphatic and aromatic, between C12-C36, in the previous

93 e present the controlled monochlorination of aliphatic and benzylic hydrocarbons with only 1 equiv of

94 Aliphatic and indole glucosinolates reached concentratio

95 The differences in reactivity between N-aliphatic and N-aromatic phosphoramidates were verified

96 were demonstrated for all compounds: sugars, aliphatic and total GLSs increased throughout plant deve

97 N fertilization; whereas reduced N increased aliphatic and total GLSs.

98 g a large number of isomeric compounds, both aliphatics and cyclics.

99 nthesis process is compatible with aromatic, aliphatic, and cinnamic aldehydes, providing facile acce

100 nces to measure solvent effects on aromatic, aliphatic, and fluorous nonpolar interactions.

101 irected sp(3) C-H arylation/acetoxylation of aliphatic- and alicyclic carboxamides afforded the corre

102 Thus, a variety of aliphatic- and aromatic-substituted thioureayl alanines

103 ical transformations, showing an increase in aliphatic, aromatic and amide functional groups.

104 und-specific rates of biodegradation for 125 aliphatic, aromatic, and biomarker petroleum hydrocarbon

105 ompounds ionized by LDI can be classified as aliphatic, aromatic, and condensed aromatics in approxim

106 Solutions of aminoborohydride reduce aliphatic, aromatic, and heteroaromatic tertiary amides

107 demonstrated in the hydrogenation of diverse aliphatic, aromatic, and heterocyclic ketones as well as

108 In contrast, the amounts of nonpolar, aliphatic, aromatic, hydroxylated and sulfur-rich amino

109 Aliphatic and aliphatic-aromatic variations at position 5 and 6 reveal

110 fficient stimuli, while carboxylic acids and aliphatics/aromatics were comparatively less effective i

111 tive N-dealkylation/carbonylation of various aliphatic as well as cyclic tertiary amines with alkynes

112 hesis of 2,5-disubstituted pyrrolidines from aliphatic azides.

113 Recent attempts that replace the aliphatic backbone with a conjugated one have not met wi

114 Yet a major challenge is the polymer's aliphatic backbone, resulting in a low electronic conduc

115 Thiol, hydroxyl, and aliphatic-based side chains at the i-1 position had high

116 Several amines such as aliphatics, benzylics, or aromatics are compatible with

117 ts an increase in the number of aromatic and aliphatic bonds for MnOx(s) reacted with organic compoun

118 Site-selective aliphatic C(sp(3))-H bond oxidation reactions serve as t

119 pper-catalyzed C(sp(3))-Si cross-coupling of aliphatic C(sp(3))-I electrophiles using a Si-B reagent

120 se in reduced carbon forms (aromatic/alkene, aliphatic C), a relative increase in amide/carboxyl func

121 In addition, the aliphatic C-F bond is the preferred acceptor in the pres

122 An unprecedented intermolecular aliphatic C-F...H-C interaction was observed in the X-ra

123 tively weak, anion binding using hydrophobic aliphatic C-H (Cali-H) groups has generally been conside

124 ine-sized residues promoted stabilization of aliphatic C-H and carboxylic C=O compounds associated wi

125 Surprisingly, in P4H, a strong aliphatic C-H bond is activated, while thermodynamically

126 Each phase requires cleavage of an aliphatic C-H bond of the substrate: the pro-S-CCys,beta

127 um-catalyzed direct arylation of unactivated aliphatic C-H bonds in free primary amines.

128 rogen atom transfer (HAT) reactions from the aliphatic C-H bonds of a series of 1-Z-pentyl, 1-Z-propy

129 hat in hydrogen atom transfer (HAT) from the aliphatic C-H bonds of alkane, ether, alcohol, amide, an

130 Intermolecular functionalizations of aliphatic C-H bonds offer unique strategies for the synt

131 e selective functionalization of unactivated aliphatic C-H bonds over intrinsically more reactive one

132 actical, intermolecular functionalization of aliphatic C-H bonds remain a paramount goal of organic s

133 itions are reported for the hydroxylation of aliphatic C-H bonds through radical translocation, oxida

134 , we report a site-selective chlorination of aliphatic C-H bonds using readily available N-chloroamid

135 een unsaturated hydrocarbons and unactivated aliphatic C-H bonds via a metal-hydride pathway.

136 ge of substrates including those with strong aliphatic C-H bonds, indicating the direct involvement o

137 icals remove hydrogen atoms from unactivated aliphatic C-H bonds.

138 sign that can accommodate a broader range of aliphatic C-H chemistry.

139 ly poses major challenges in chemoselective, aliphatic C-H functionalization.

140 ndole alkaloids with chlorine via late-stage aliphatic C-H group functionalization.

141 tivated, while thermodynamically much weaker aliphatic C-H groups, that is, at the C(3) and C(5) posi

142 protection strategies known to enable remote aliphatic C-H oxidations.

143 Since the aliphatic C-H...anion interaction is relatively weak, an

144 playing six protein functional groups-sp(3) (aliphatic) C; sp(2) (aromatic, amide, carboxylate) C; am

145 coupling reaction of 2-chlorobenzazoles with aliphatic carbamates, alcohols, and ethers is presented.

146 llenging reaction requiring activation of an aliphatic carbon atom, has remained enigmatic.

147 ctive late-stage modification of unactivated aliphatic carbon centers in small molecules with halogen

148 ibute to the widely observed accumulation of aliphatic carbon in soil, which cannot be explained by s

149 cular weight and the content of aromatic and aliphatic carbon, are reported more comprehensively and

150 Also, the aliphatic carbons of Q17 partially sequester the nonpola

151 ct gamma- C(sp(3))-H alkylation of saturated aliphatic carbonyl compounds.

152 anic matter rich in monocarboxylic acids and aliphatic carbonyls originating from cooking activities

153 A broad range of aliphatic carboxamides and alkyl chloroformates are comp

154 n to achieve the decarboxylative coupling of aliphatic carboxylic acid derivatives (specifically, rea

155 Aliphatic carboxylic acids and sulfonamides could not be

156 Both aliphatic carboxylic acids and sulfonamides yield severa

157 om each other and also from sulfonamides and aliphatic carboxylic acids based on reactions with TMMS

158 The direct conversion of aliphatic carboxylic acids to the corresponding alkyl fl

159 Both aromatic and aliphatic carboxylic acids were converted to the corresp

160 n and decomposition routes for furanoids and aliphatic carboxylic acids, and mechanistic pathways for

161 alyzed esterification of amides derived from aliphatic carboxylic acids.

162 ocol for the synthesis of (18)F-radiolabeled aliphatic CF3-containing compounds, enabling the prepara

163 olidine as a cap group and a six carbon long aliphatic chain as a linker was found to inhibit HDACs.

164 vely restored with amino acids of increasing aliphatic chain length and fully recovered with residues

165 on of both glycogen and lipid with increased aliphatic chain length.

166 th a carboxylic acid moiety at the end of an aliphatic chain of varying length and attached to the st

167 his functionality in combination with a long aliphatic chain or a chain carrying an appropriate aroma

168 sitive region close to alpha1-heme while its aliphatic chain snakes along a shallow cavity making hyd

169 SAR analysis revealed the size of the aliphatic chains and presence of nitrogen atoms are impo

170 The use of ancillary ligands having aliphatic chains and/or pi-extended aromatic units decre

171 in oxidized CLs and the release of oxidized aliphatic chains from CL in experiments with purified re

172 zyme responsible for the release of oxidized aliphatic chains from CL.

173 aphyne has been envisaged by decoration with aliphatic chains R = n-CnH2n+1.

174 edented cyanobacterial glycolipids featuring aliphatic chains with chlorine substituents and C-glycos

175 c carbon into soil carbohydrate, protein and aliphatic compounds and differentiate these from existin

176 etal-catalyzed C(sp(3))-H bond activation in aliphatic compounds are of current interest.

177 matics in approximately equal measure, while aliphatic compounds dominated the ESI spectra of SRFA.

178 or the delta(37)Cl determination in volatile aliphatic compounds using gas chromatography coupled wit

179 ransformation pathways, and sinks of organic aliphatic compounds, many of them being priority polluta

180 ric cold plasma processing affected more the aliphatic compounds.

181 and currently increasingly investigated for aliphatic compounds.

182 ncentration and oxygen, heteroaliphatic, and aliphatic content.

183 in the iodine(iii) mediated fluorinations of aliphatic Csp(2)-carbon atoms with special focus on the

184 ydrophobic interaction between the proline's aliphatic cyclic structure and the 5-methyl group of the

185 ns of the phospholane ring, and a variety of aliphatic, cyclic and aryl P-electrophiles are tolerated

186 the reaction to proceed via a nonstabilized, aliphatic, cyclic oxocarbenium ion intermediate paired w

187 um reveals (2)H line shapes for 140 resolved aliphatic deuterium sites.

188 ds in the Staudinger reduction of long-chain aliphatic diazides (C8 , C10 , and C12 ).

189 ecular complexity through the combination of aliphatic, dipeptidic, glucosidic, and lipidic isocyanid

190 particles, molecular linker (aromatic versus aliphatic dithiols and the length of the intermediate ch

191 effect, decreasing the intra-oral release of aliphatic esters (ethyl hexanoate).

192 ated and wild tomatoes these are mixtures of aliphatic esters of sucrose and glucose of varying struc

193 ylic substitution with enolates derived from aliphatic esters under mild conditions remains challengi

194 relatively neutral conditions, the allylated aliphatic esters were obtained with excellent regioselec

195 gesting that, after oxidation by chlorinated aliphatics, FeS can be regenerated by addition or microb

196 In the realm of aliphatic fluorination, the problem of reactivity has be

197 Herein, we disclose a general strategy for aliphatic gamma-C(sp(3) )-H functionalization guided by

198 enteen week old kale plants showed decreased aliphatic GLSs at split dose N fertilization; whereas re

199 Across three field trials, we quantified aliphatic glucosinolate (GSL) defense chemistry, leaf da

200 itism with localized elevation of indole and aliphatic glucosinolates.

201 We found that aliphatic GSL accumulation was primarily influenced by a

202 bidopsis thaliana varying at pairs of causal aliphatic GSL defense genes to test the impact of epista

203 Derived calibrations for total-GSLs, aliphatic-GSLs, glucoraphanin and 4-methoxyglucobrassici

204 son of AmbO5 with a previously characterized aliphatic halogenase homolog WelO5 that has a restricted

205 AmbO5 protein as a promiscuous non-heme iron aliphatic halogenase.

206 atalyst displays superior properties for the aliphatic halogenation of recalcitrant, electron-deficie

207 concentration, and carbon, oxygen, nitrogen, aliphatic, heteroaliphatic, and aromatic content) and 4-

208 imide in the catalytic aerobic oxidations of aliphatic hydrocarbons characterized by relatively high

209 of groundwater contaminated with chlorinated aliphatic hydrocarbons such as perchloroethene and trich

210 d on the enzymatic reaction with halogenated aliphatic hydrocarbons that is accompanied by the fluore

211 ups found in the extracts were phenolics and aliphatic hydroxy acids typical of royal jelly and unsat

212 a cleavage preference at bonds where P1' is aliphatic in both isoprenylated and non-prenylated subst

213 ategy for diverse hydrofunctionalizations of aliphatic internal alkenes with high regioselectivity an

214 ped the first synthetic method for preparing aliphatic isocyanates via direct C-H activation.

215 , and it has been accomplished with aryl and aliphatic isocyanates.

216 The acid lability of aliphatic ketals, which often serve as protection groups

217 y by stereoselective ketal formation with an aliphatic ketone.

218 Aliphatic ketones containing a chloride and alkene were

219 QDs) were synthesized via hydrosilylation of aliphatic ketones on hydride-terminated SiQD (H-SiQD) su

220 r correlation (2D HETCOR) NMR indicated aryl-aliphatic ketones, aliphatic and aromatic carboxyl group

221 Aliphatic ketones, alkylpyrazines, some furans and pyrid

222 We demonstrated that photoexcited aliphatic ketones, such as acetone and diacetyl, can be

223 7) with non-, partially- and per-fluorinated aliphatic (linear or branched at the alpha-carbon) and a

224 ompound 19 induces MDM2 dimerization via the aliphatic linker.

225 d imidazole scaffold which are appended with aliphatic linkers that enable coupling to bioactive carr

226 all classes of alcohols (benzylic, allylic, aliphatic), mediate efficient lactonization of 1,4-, 1,5

227 of the mature aromatic fungal pigment, these aliphatic moieties form a chemically resistant framework

228 ogenation of electron-deficient and strained aliphatic molecules is rare.

229 that carboxyl-rich aromatic and N-containing aliphatic molecules of DOM are correlated with high adhe

230 The selective C-H functionalization of aliphatic molecules remains a challenge in organic synth

231 These probes included aliphatic -N-acyllysine modifications with hydrocarbon l

232 for efficient reduction of both aromatic and aliphatic nitriles including industrially relevant dinit

233 c Michael addition reaction of non-activated aliphatic nitriles to alpha,beta-unsaturated carbonyl co

234 Several (hetero)aromatic, benzylic, and aliphatic nitriles undergo hydrogenation to the correspo

235 licability for the reduction of aromatic and aliphatic nitro-derivatives to amines has been investiga

236 ts the product of a formal enantioconvergent aliphatic nucleophile addition.

237 Ph-O bond is cleaved rather than the weaker aliphatic O-R bond.

238 demonstrates that they constitute the major aliphatics of suberin-associated waxes in the form of AH

239 ure hydrocarbons (particularly aromatics and aliphatics) of the engine exhaust decreased with increas

240 n and polyester to laundry water was >80% of aliphatic OPEs (log KOW < 4), < 50% of OPEs with an arom

241 e molecular recognition of a wide variety of aliphatic or aromatic aldehydes and ketones, as demonstr

242 replacing it with a series of residues with aliphatic or aromatic side chains of decreasing chain le

243 amides can be orthogonal to that of amines (aliphatic or aromatic) and phenol derivatives.

244 This signature is characteristic of aliphatic organic matter and is mainly localized on a br

245 Selective stabilization of aliphatic over aromatic carbon can greatly contribute to

246 ion of the void within the pocket by growing aliphatic P1' substituents (H, Me, iPr, iBu) reveals a d

247 -polar side chains interact largely with the aliphatic part of the lysine side chain.

248 o- and heterodipeptides (including aromatic, aliphatic, polar and charged amino acids) are subjected

249 d that HsvA displays a preference for linear aliphatic polyamines as the amidino acceptor substrate,

250 al groups through ortho ester linkages on an aliphatic polycarbonate.

251 Aliphatic polyesters and polycarbonates are a class of b

252 Among potential candidates, aliphatic polyesters and polycarbonates are promising ma

253 nalysis of the enzymatic hydrolysis of eight aliphatic polyesters by two fungal esterases (FsC and Rh

254 s of technologically important biodegradable aliphatic polyesters from cyclic esters or lactones.

255 nthesis of well-defined and functionalizable aliphatic polyesters remains a key challenge in the adva

256 ences in the hydrolysis rates and extents of aliphatic polyesters varying in the length of their dica

257 ions were controlled mainly by the amount of aliphatic polyether porogen.

258 nitrile as the macroporogen and a variety of aliphatic polyethers and triblock copolymeric surfactant

259 ut a smaller distance at detachment than the aliphatic polyimide for all of the three methodologies.

260 abled the enantioselective propargylation of aliphatic polyols.

261 Exchanging O- with N-aliphatics prevented apFr, due to higher electron densit

262 , a significant advancement has been made on aliphatic primary alcohol deoxygenation by employing a r

263 the direct sp(3) C-O defunctionalization of aliphatic primary alcohols.

264 hile nucleophilic primary amines (typically, aliphatic primary amines) often lead to quantitative rea

265 ectivity was observed with both aromatic and aliphatic primary amines.

266 ct analysis and identification of long chain aliphatic primary diamine Duomeen O (n-oleyl-1,3-diamino

267 only, we exploit (i) the narrow resonance of aliphatic protons in free substrate for selective radio-

268 papain with a preference for hydrophobic and aliphatic residues in subsite S2 and for positively char

269 mutations of Pro-102 or Pro-105 to noncyclic aliphatic residues such as the Gerstmann-Straussler-Sche

270 revealed lower values for the electron-rich aliphatics, showing no apFr, preventing a nucleophilic a

271 rsors with a conjugated double bond in their aliphatic side chain disrupts this coordinated cell-cell

272 rsors with a conjugated double bond in their aliphatic side chain specifically disrupts cell-cell com

273 d by attaching TPP(+) to Met via a 10-carbon aliphatic side chain, was nearly 1,000 times more effica

274 nces with a sterically hindered alpha-chiral aliphatic side chain.

275 dinium interacts with non-polar aromatic and aliphatic side chains above and below the guanidinium pl

276 CELA3B, and CELA1 was similar; all preferred aliphatic side chains at the so-called P1 position, the

277 ecognize selectively a very stringent set of aliphatic side chains such as valine, leucine, and isole

278 bly of amphiphilic block copolypeptoids with aliphatic side chains.

279 This interface would disfavor large aliphatic side chains.

280 elical peptoids containing only alpha-chiral aliphatic side chains.

281 tive release represents a new mechanism that aliphatic soil organic matter was stabilized by associat

282 naphthalene with amide sp(2)O, amide sp(2)N, aliphatic sp(3)C, and amide and aromatic sp(2)C unified

283 es attached on either ends of a linear, C-12 aliphatic spacer.

284 ysaccharide in facilitating the diffusion of aliphatic species toward specific targets within the bio

285 a 6 + 5 fused ring heterocycle linked to an aliphatic substituent via a urea moiety.

286 y very subtle steric differences between two aliphatic substituents.

287 carbon quaternary stereogenic center with an aliphatic-substituted allylic electrophile is disclosed.

288 ly electron-donating groups (31-73%); cyclic aliphatic substrates provide low yields (24-38%).

289 emical techniques applicable to nonactivated aliphatic systems remain largely elusive due to the chal

290 position of the steroid ring (LKM38) or the aliphatic tail (KK174), we mapped a binding pocket in mV

291 We demonstrate that the aliphatic tail length (i) can be used as a handle to sys

292 rotein, and renders the interaction with the aliphatic tails of lipids more energetically favorable.

293 e hydrophobic tunnel, which accommodates the aliphatic tale of LTA4 during EH reaction.

294 The unique properties of entirely aliphatic TAML activator [Fe(III){(Me2CNCOCMe2NCO)2CMe2}

295 xamine an interesting direct arylation of an aliphatic tertiary amide by using density functional the

296 s from a broad range of (hetero)aromatic and aliphatic tertiary amides, and N-alkyl lactams is report

297 As a result, simpler aliphatic thioaldehydes could be selectively synthesized

298 ytic reactions, from saturated status (e.g., aliphatic) to graphitized status (e.g., polyaromatics),

299 Two kinds of polyimides, aromatic and aliphatic type, are considered to demonstrate the rigidi

300 (including acids, carbonyls, aromatics, and aliphatics) were calculated to characterize the exhaust