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1 the chains depend on the structure-directing alkali metals.
2 ctra of analogous ions containing monovalent alkali metals.
3 only observed in electrochemical doping with alkali metals.
4 ntered cubic lattice, which is common to all alkali metals.
5 ether it can be replaced by any of the other alkali metals.
6 contain variable amounts of easily ionizable alkali metals.
7 apacity for Na but a high capacity for other alkali metals.
8 pproach has been realized using a rare earth/alkali metal/1,1'-BINOLate (REMB) heterobimetallic frame
9 kaline-earth metal), AFe(2)As(2), AFeAs (A = alkali metals), A(3)M(2)O(5)Fe(2)As(2) (M = transition m
10 d clusters (MPCs), Au25(SC2Ph)18, containing alkali metal acetate salts (MOAc) produce spectra in whi
13 stic charge-remote fragmentation patterns of alkali metal-adducted fatty acids following high energy
14 s spectrometry is hindered by two processes: alkali metal adduction and fragmentation of the intact i
15 r [M + K](+) ions of the FFAs, whereas other alkali metal adducts can be generated by treating the wi
17 ions reduce to Cu(I), Ni(I), and Fe(I) upon alkali metal adsorption, whereas Mn maintains its formal
18 Direct electron transfer would imply that alkali metal alkoxides are willing partners in these ele
19 oarenes with arenes, triggered by the use of alkali metal alkoxides in the presence of an organic add
24 llowing in situ the reactions of solids with alkali metal/ammonia solutions, using time-resolved X-ra
25 lline K(4)GeP(4)Se(12) outperforms the other alkali metal analogues and exhibits the strongest second
26 hows minimal interference effects from other alkali metal and alkaline earth metal cations and has go
28 (Z)-diazeniumdiolation products, namely, the alkali metal and NMe(4)(+) salts of methyl and ethylbute
30 rt, we show that direct interactions between alkali metals and arenes occur at or within the van der
33 abundance in the host rocks, such as carbon, alkali metals and halogens, illustrates a feedback betwe
34 that have been prepared using the different alkali metals and may indicate differences in the relati
37 steric effects, oxidation level, presence of alkali metals, and coordination number of the iron atoms
38 be thought of as an ion pair formed from an alkali metal anion (M(-)) and solvated cation (M(en)(3)(
41 nitrogen with trivalent lanthanide salts and alkali metals are strong reductants in their own right a
47 lectron doping through in situ deposition of alkali-metal atoms, angle-resolved photoemission spectra
48 re metathetical reactions between N5SbF6 and alkali metal azides in different solvents, resulting in
49 isphosphite ligands combined with a suitable alkali metal BArF salt as a regulation agent (RA) provid
55 s of amides involving the direct coupling of alkali metal carboxylate salts with amines is described.
57 ed, enabled by tunable hemilability based on alkali metal cation binding with a macrocyclic "pincer-c
58 nd, the results suggest that the size of the alkali metal cation can control the number of Fe atoms t
59 Binding constants of several crown ether-alkali metal cation complexes that were previously studi
61 abeling) point to a bridging function for an alkali metal cation connecting the sulfonate anion and a
62 f "alkali control," where the presence of an alkali metal cation enables the reduction of N2 under mi
63 3-methylimidazolium hexafluorophosphate, the alkali metal cation extraction selectivity and efficienc
65 and 18-crown-6 are utilized for competitive alkali metal cation extractions from aqueous solutions i
66 nown to be influenced by the identity of the alkali metal cation in the electrolyte; however, a satis
69 at include M-M-C angle, Coulombic repulsion, alkali metal cation size, and the character of the molec
70 r mild conditions, and then chelation of the alkali metal cation uncovers a highly reactive species t
71 r the An[Co(OH2)(6-6m)][Fe(CN)6]m.xH2O (An = alkali metal cation) family of three-dimensional Prussia
72 d by the diastereomers when cationized by an alkali metal cation, [M + X](+) where X = Li, Na, K, and
81 The gas-phase structures of protonated and alkali metal cationized arginine (Arg) and arginine meth
82 raction with the N terminus as zwitterionic, alkali metal cationized arginine, yet both are unambiguo
83 ermore, the unique structures adopted by the alkali metal-cationized cis- and trans-proline variants
84 it was observed that the resolution between alkali metal-cationized cis- and trans-proline variants
85 ons than for ArgGly is due to the ability of alkali metal-cationized GlyArg to adopt a nearly linear
86 determining the structures of protonated and alkali metal-cationized glycyl-L-arginine (GlyArg) and L
88 can be rationalized as Zintl phases with 14 alkali metal cations A(+) (A = K, Rb), two tetrahedral [
89 hides and selenides containing highly mobile alkali metal cations as charge-balancing extra-framework
90 oxide) spacer lengths between phthalates and alkali metal cations as counterions are designed for imp
94 remarkable color response upon extraction of alkali metal cations from basic aqueous solutions into c
95 analysis of the complexes of 18-crown-6 with alkali metal cations in an ESI quadrupole ion trap mass
96 mical calculations that encapsulation of the alkali metal cations in the cavity of 1 predominantly oc
97 ions in the absence or presence of different alkali metal cations in the matrix, discrete lipid class
98 was orders of magnitude below the number of alkali metal cations in the zeolites but was similar to
99 functional theory calculations show that the alkali metal cations influence the distribution of produ
100 e molecule is found to encapsulate the light alkali metal cations Li(+) and Na(+) in the absence of a
105 nteractions and of cation/pi interactions of alkali metal cations with aromatic rings was conducted.
106 hly sensitive to increased concentrations of alkali metal cations, a situation that remains unexplain
108 twork of gamma-cyclodextrins (gamma-CDs) and alkali metal cations, can separate a wide range of benze
109 w that direct lipid bilayer translocation of alkali metal cations, Cl(-), and a charged arginine side
110 opensities of inorganic cations, such as the alkali metal cations, have received relatively little at
111 take, storage, and efflux mechanisms for the alkali metal cations, Na(+) and K(+), the divalent catio
117 onformation and binding of calix[4]arenes to alkali-metal cations has been studied using a dehydroxyl
118 7.24-nm(3) cavities containing exchangeable alkali-metal cations that can be replaced by transition-
119 h membranes decay rapidly in the presence of alkali-metal cations, but can be maintained in the absen
123 Under the same conditions, extraction of alkali metal chlorides into solutions of DC18C6 in chlor
124 e solvent extraction of aqueous solutions of alkali metal chlorides with solutions of dicyclohexano-1
125 olecular organometallic compounds with mixed-alkali-metal cluster cores, LiK5 and Li3 K3 , sandwiched
128 Infrared multiphoton dissociation (IRMPD) of alkali metal-coordinated oligosaccharides was obtained i
129 ions indicate that reduction of the iron and alkali metal coordination cooperatively weaken the N-N b
130 f the molecular salts are independent of the alkali metal counterions and have a value of 2.0 eV for
131 ido complexes demonstrated the impact of the alkali metal counterions on the geometry of the [Ce hori
133 on of alkali metal borates to 1 afforded the alkali metal disilicon(0) borates 1M[BAr4] (M = Li, Ar =
136 e C60 molecules follows the general trend of alkali metal-doped C60 and suggests routes to even highe
137 a systematic investigation of the effects of alkali metal doping on the charge state and crystal fiel
139 nd with zinc enolates generated by quenching alkali metal enolates of esters with zinc chloride.
143 in which a neutral molecule binds the light alkali metals exclusively through cation-pi interactions
144 presence of montmorillonite and other salts, alkali metal fluorides did not yield any detectable olig
145 bly to traditional halex fluorinations using alkali metal fluorides, which generally require temperat
146 ydride complexes, providing a high-yielding, alkali metal-free route to strongly activated early-meta
149 Superconductivity in the A(3)C(60) (A = alkali metal) fullerides has been exclusively associated
150 on of the corresponding arylmetal halides by alkali metal/graphite (Zn or Hg) or sodium hydride (Cd).
151 Herein we demonstrate that the presence of alkali metal halide salts, in conjunction with low coppe
152 .Li and HC6.Cs indicate that the size of the alkali metal has some influence on the conformation of c
153 olymeric anionic chains, but the size of the alkali-metals has a profound effect on the packing of th
155 active CF3(-) adduct can be synthesized from alkali metal hydride, HCF3, and borazine Lewis acids in
158 n the presence of inexpensive and air-stable alkali metal hydroxide bases and Pd[P(t-Bu)3]2 as cataly
162 also used to study the other A(2)PtH(6) (A = alkali metal) including, the at present, unknown Li salt
163 scovered phenomena such as complex phases of alkali metals, incommensurate host-guest structures, and
164 of face-centred-cubic (f.c.c.) A(3)C(60) (A=alkali metal) increases monotonically with inter C(60) s
166 ectrocatalyst was assembled with a different alkali metal intercalated between two nanosheets (NS) of
170 ny atomic analogue, is isomorphic to certain alkali-metal intercalation compounds of fullerene C(60)
172 ns (Ln=rare earth metal; A=anionic ligand; M=alkali metal) involving reduction of Sc(NR2 )3 with K in
173 lectively determined KI compare to different alkali metal iodides: NaI, RbI, CsI; also investigation
176 e in the proton affinity, an increase in the alkali metal ion binding affinities, an increase in the
178 e the following features: (i) new motifs for alkali metal ion complexation (i.e., cationic receptors
180 (HC4) illustrate the great influence of the alkali metal ion on the solid state structure of calixan
182 crown-6 ether)(H(2)O)(1-4) complexes for the alkali metal ion series were probed using infrared predi
183 e half-reaction kinetic parameters depend on alkali metal ion size in a manner similar to that observ
184 ation of a supramolecular system "Pt complex-alkali metal ion"; the latter is supported by restoratio
185 particularly sensitive method for detecting alkali metal ion-binding sites in nucleic acid crystals.
188 ntly used as negative electrode material for alkali-metal-ion batteries, similar to its oxide analogu
194 5) and CsBi(3)Se(5) have stepped layers with alkali metal ions found disordered in several trigonal p
195 ity of the title compounds to associate with alkali metal ions in solution and the gas phase has demo
196 uracil and its noncovalent interactions with alkali metal ions is investigated both experimentally an
197 atures most conducive to complexation of the alkali metal ions Li(+), Na(+), and K(+) in a series of
199 d that differences in folding with different alkali metal ions observed at high concentration arise f
203 the positive mode involves the depletion of alkali metal ions via ion evaporation of metal ions solv
206 shows no measurable tendency to complex with alkali metal ions, 3 binds strongly to Li(+) and Na(+) i
207 lectivities for Na(+), Ca(2+), Ba(2+), other alkali metal ions, and Cl(-) thus can be predicted by vo
208 he crown-TTF disulfides 7c,d,f can recognize alkali metal ions, and the process can be monitored foll
210 ion was achieved after adduct formation with alkali metal ions, however, and efficiency was shown to
211 as a "bridge" between the smaller and larger alkali metal ions, is consistent with the well-known spe
212 reover, FeSe-based systems intercalated with alkali metal ions, NH3 molecules or organic molecules ar
222 mmable polymer nitrocellulose patterned with alkali metal ions; this pattern encodes the information.
223 e alkaline-earth ions Ba(2+) and Ca(2+), the alkali-metal ions Li(+), Na(+), K(+), and Cs(+), and the
225 e organocations, as opposed to, for example, alkali-metal ions, play a pivotal role in reorganizing t
228 c structures, the coordination number of the alkali metal is raised by binding of Lewis-basic solvent
229 e higher response for heavier cations of the alkali metals is consistent with the periodic trends of
231 roximate square planar Al(4)(2-) unit and an alkali metal led to the suggestion that Al(4)(2-) is aro
232 th" that has been applied to measure BDEs of alkali metal (Li+) adducts and halide (Cl-) adducts of m
233 lated InsPs have a much greater affinity for alkali metals (Li(+) > Na(+) > K(+)) than quaternary amm
234 ere we describe its intercalation by several alkali metals (Li, K, Rb and Cs) and alkali-earth Ca.
236 tron reduction of [Co(II)((R)salophen)] with alkali metals (M = Li, Na, K) leads to either ligand-cen
237 mination of the known SHG active AMCO3F (A = alkali metal, M = alkaline earth metal, Zn, Cd, or Pb) m
239 c in that magnesiation can only work through alkali-metal mediation, these reactions add magnesium to
240 ve strong mass spectra of molecular ions and alkali metal molecular ion adducts, with lower Na and K
241 s common to prior research in the field with alkali metal nitrate molten salt electrolytes and operat
242 The controlled reaction of Na and Cs, two alkali metals of different ionic sizes and binding abili
245 ish that reduction of ((i)PrPDI)FeCl(2) with alkali metal or borohydride reagents results in sequenti
247 cations, however, aggregates composed of the alkali metal-oxide cations template various cage compoun
252 s demonstrates that the Ln[N(SiMe(3))(2)](3)/alkali metal reaction can mimic divalent lanthanide redu
253 e ECR-34, which can be prepared from a mixed alkali metal reaction gel containing tetraethylammonium
256 ed by either alkane reductive elimination or alkali metal reduction of a suitable zirconium(IV) dihal
258 road oscillations in the PDF show that added alkali metals remain in the pores as nanoscale metal clu
259 s(+) derived from the highly electropositive alkali metals represent prototypical charged spheres tha
261 ne polymer electrolytes containing different alkali metal salts (Na(+), K(+) and Rb(+)), including th
264 A complete series of X-ray structures of the alkali metal salts of calix[4]arene (HC4) illustrate the
265 was evaluated using several inorganic salts (alkali metal salts of chloride) and a weak acid of commo
266 are more conformationally flexible than the alkali metal salts of dianionic calix[6]arenes, which ha
267 of p-tert-butylcalix[4]arene (Bu(t)C4), the alkali metal salts of monoanionic Bu(t)C4 exist in monom
270 rough metathesis reaction between halide and alkali metal salts of two cationic and three anionic Ir
271 ion with twelve pendant hydroxyl groups, the alkali metal salts surprisingly displayed low water solu
278 vided a method to obtain rates of ligand and alkali metal self-exchange in the RE/Li frameworks, demo
280 bles: (1) identification of stable, isolable alkali metal silanolates, (2) identification of conditio
282 containing anions are common in concentrated alkali-metal silicate solutions, but reveal no evidence
285 can cause large electron transfer from light alkali metals such as Li to Cs, causing Cs to become ani
286 roscopic analysis of the separate effects of alkali metal sulfates (Na2SO4, Rb2SO4), GdmCl, and Gdm2S
287 aceted role in a variety of media, including alkali metal-sulfur batteries, aqueous solutions at high
289 -generated models reveal that on addition of alkali metal the solvent molecules form voids of approxi
291 Our system uses the thermal excitation of alkali metals to transmit an encoded signal over long di
292 hemical reactions--the thermal excitation of alkali metals--to transmit coded alphanumeric informatio
293 involving reduction of trivalent salts with alkali metals used with lanthanides can also be applied
294 ped magnetometers (OPMs) based on lasers and alkali-metal vapor cells are currently the most sensitiv
297 tion metalate of the series A(x)MnO(2), (A = alkali metal) where a complete 1:1 charge ordering of Mn
298 clear nitride, complete encapsulation of the alkali metal with cryptand provides the terminally bound
299 ity in materials obtained by the reaction of alkali metals with polyaromatic hydrocarbons, such as ph
300 benefit of reducing common adducts, such as alkali metals, without the addition of solution additive
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