ライフサイエンスコーパス: alkoxyl

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1 H-atom transfer from pzH to alkyl, alkoxyl, and peroxyl radicals reveals that BDEs are not

2 trogen incoporation into a series of alkyl-, alkoxyl-, and dialkylamino-substituted diphenylamines ra

3 With a structural design involving long alkoxyl chains to envelop the porphyrin core to suppress

4 A variety of alkoxyl derivatives have been synthesized by heating the

5 olves replacement of the C2 hydroxyl with an alkoxyl group to yield solvolysis products that display

6 , seemingly because of the activation by the alkoxyl groups at the 6-positions, combine with electrop

7 kyl (k approximately 5 x 10(8) M(-1) s(-1)), alkoxyl (k approximately 1 x 10(9) M(-1) s(-1)), peroxyl

8 dicals are initially obtained, alkyl (L) and alkoxyl (LO) radicals which formed two types of adducts

9 )O]-labeled solvent demonstrated that the C2 alkoxyl of the solvolysis products originated from the s

10 roperoxide reduction and that the pathway of alkoxyl radical decomposition is influenced by the prote

11 des strong evidence for the production of an alkoxyl radical during 10-OOH-18:2 reduction by Mn-PGHS.

12 iniums, which leads to N-O bond cleavage and alkoxyl radical formation, is highly chain amplified in

13 The nature of predominantly present alkoxyl radical indicates ongoing lipid peroxidation dur

14 omponent of Mn-PGHS and the structure of the alkoxyl radical intermediate.

15 presumably arising from the enzyme-generated alkoxyl radical of 4-HPNE.

16 These observations confirm that in alkoxyl radical reactions specific hydrogen bond interac

17 alpha-Tocopherol acts as a peroxyl and alkoxyl radical scavenger in lipid environments, and thu

18 ramolecular hydrogen 1,5-abstraction with an alkoxyl radical undergo nucleophilic displacement provid

19 gave exclusively direct beta-scission of the alkoxyl radical.

20 the so-produced radical to yield HNO and an alkoxyl radical.

21 ETE followed by oxidation of an intermediate alkoxyl radical.

22 usefulness of the fragmentation of anomeric alkoxyl radicals (ARF) promoted by the PhIO/I2 system fo

23 m transfer (HAT) reaction promoted by 6-O-yl alkoxyl radicals between the two pyranose units in Hexp-

24 ggests that the competing cage escape of the alkoxyl radicals following N-O homolysis leads to signif

25 ion reactions) and also by interactions with alkoxyl radicals obtained by Fe(II) cleavage of lipid hy

26 alculations support a mechanism in which the alkoxyl radicals react with lutidine via proton-coupled

27 For alkoxyl radicals that fragment to produce benzaldehyde a

28 r flash photolysis (LFP) studies to generate alkoxyl radicals that fragmented to give the (2,2-diphen

29 red free radical species as well as t-BuO(*) alkoxyl radicals were observed in these two cell lines.

30 mechanistic description of the reactions of alkoxyl radicals with amines, showing that structural ef

31 educe t-BuOOH-induced oxoferryl and t-BuO(*) alkoxyl radicals.

32 f the radicals were consistent with those of alkoxyl radicals.

33 tent, the hydrogen abstraction reactivity of alkoxyl radicals.

34 amage through the production of hydroxyl and alkoxyl radicals; whether these mechanisms occur in vivo

35 Although transfer of electrophilic alkoxyl ("RO+") from organic peroxides to organometallic

36 Modifications focused on the alkoxyl substituent present on the aromatic ring led to

37 aring alkyl, aryl, heteroaryl, hydroxyl, and alkoxyl substituents, are effective in this process.

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