1 deprotonation of 1 occurs exclusively at the allylic position.

2 cyclohexenes with the stereogenic centers at allylic positions.

3 er multiple bonds with a functional group in allylic position and some examples of successful transfo

4 ity of 3-(4-methylphenyl)cyclopropene at the allylic position (delta H(o)acid = 398.6 +/- 1.4 kcal/mo

5 tuent (carbonyl or arene) is required at the allylic position for high levels of diastereoselection t

6 ning a new C-N, C-O, C-S, or C-C bond at the allylic position in good yield with a high branched-to-l

7 lyunsaturated fatty acids (PUFAs) at the bis-allylic position; indeed, pretreating cells with PUFAs c

8 n is alleviation of steric congestion at the allylic position of the alpha-silyloxy allylic silane an

9 n at a terminal olefinic position and at the allylic position of the diene.

10                  H/D exchange is achieved at allylic positions of alkenes using D(2)O in acetone and

11  amount of O(2) trapping at the central (bis-allylic) position of the pentadienyl radical also increa

12 ts of the SN2' reaction; i.e., attack at the allylic position remote from the leaving group with migr

13 , with methyl and phenyl substituents at the allylic position shown to provide exquisite stereocontro

14  (-)-(4S)-Limonene is hydroxylated at the C6 allylic position to give (-)-trans-carveol as the only p

15 s a lithium oxyanionic group in the proximal allylic position to the alkene greatly accelerates the c

16 n liquid ammonia, MCPs bearing a C-O bond at allylic position undergo both a reductive cleavage of th

17 - and 1,7-enynes substituted in the terminal allylic position with a tert-butyldimethylsilyl ether gr