ライフサイエンスコーパス: aminolysis

1 her the catalytic acid or catalytic base for aminolysis.

2 d into thiol-terminated microspheres through aminolysis.

3 -methylpyridinium iodide (CMPI), followed by aminolysis.

4 during a Sonogashira coupling and subsequent aminolysis.

5 ated by air plasma treatment, hydrolysis, or aminolysis.

6 ach is presented here based on aqueous-phase aminolysis.

7 After Boc protection, these products undergo aminolysis and acidic deprotection to generate 2-imino-5

8 ydrolysis at the sulfonyl center rather than aminolysis at either the sulfonyl or acyl center.

9 ubiquitin chains seems to be mediated by an aminolysis-based transfer reaction between two Ube2g2 mo

10 inhibitor was accomplished by a mild lactone aminolysis between an orthogonally protected bis-benzyli

11 the LRR domain selectively blocks productive aminolysis, but not the nonproductive discharge of Ub fr

12 beta-lactam ring opening with intramolecular aminolysis by a reaction similar to that for cephalexin

13 tioning of the acyl-enzyme intermediate, the aminolysis by D-phenylalanine of a cognate pair of depsi

14 l calculations rationalize the observed slow aminolysis by demonstrating that the diazeniumdiolate gr

15 netic isotope effects were also measured for aminolysis by hydroxylamine to study a reaction similar

16 This then partitions between hydrolysis and aminolysis by Lys 315, the latter to form an inactive, c

17 However, the rate of intramolecular aminolysis for the S-analogue is 3 orders of magnitude g

18 , such as hydrogen exchange, alcoholysis and aminolysis, hydrogen evolution, hydrogenation, and dehyd

19 c sulfonamides, beta-sultams, do not undergo aminolysis in aqueous solution but preferentially react

20 rthermore, unlike cephalexin, intramolecular aminolysis in the S-analogue occurs up to pH 14 with no

21 Prevention of polyimide aminolysis is achieved by using weakly alkaline ammonia

22 kinetics and mechanism of the hydrolysis and aminolysis of a series of acyclic depsipeptides, catalyz

23 pstream splice junction, consistent with the aminolysis of a thioester.

24 hydrolysis, activation of Glu-tRNA(Gln), and aminolysis of activated tRNA by Gln-derived NH(3).

25 olipids appears to arise from base-catalyzed aminolysis of arachidonate-containing glycerolipids, bec

26 The first enantioselective aminolysis of aromatic trans-2,3-epoxy sulfonamides has

27 generate benzylamides of D-diphenylAlaPro by aminolysis of Boc dipeptide Kaiser resin.

28 ring strain is relieved upon the sequential aminolysis of both BTF and BTP, it is only for the forme

29 The aminolysis of both the aryl the alkyl esters by D-phenyl

30 TF and BTP, the unusually fast and selective aminolysis of BTF is only fully explained through synerg

31 nding proteins, catalyzes the hydrolysis and aminolysis of d-alanyl-d-alanine-terminating peptides by

32 putational study and kinetic analysis of the aminolysis of dithioates, dithiobenzoates, trithiocarbon

33 in aqueous solution and in the ribosome, the aminolysis of esters in aqueous solution has been the su

34 y describe experimental observations for the aminolysis of N-acetyl-dl-homocysteine thiolactone with

35 The rate of intermolecular aminolysis of natural cephalosporins is dominated by a s

36 hanism of the uncatalyzed and base-catalyzed aminolysis of phenyl N-phenylcarbamate by theoretical qu

37 iously been shown to catalyze hydrolysis and aminolysis of small D-alanyl-D-alanine terminating pepti

38 to isolate its O(2)-benzylated derivative by aminolysis of the C horizontal lineN bond in PhC(NH2) ho

39 ential events consisted of lactonization and aminolysis of the lactone ring, which ultimately furnish

40 Aminolysis of the latter entity with an amino alcohol li

41 go ring-opening with benzylamine followed by aminolysis of the resulting CCl3 ketone to form a range

42 kane bridge to amide bonds formed during the aminolysis of the surface ester functionalities.

43 he integrity of fused-silica capillaries via aminolysis of their outer polyimide coating.

44 The Bronsted beta(nuc) for the aminolysis of thioxo-cephalosporin is +0.39, indicative

45 The aminolysis of three differently alpha-substituted gamma-

46 The first catalytic enantioselective aminolysis of trans-2,3-epoxy alcohols has been accompli

47 proved remarkably sluggish in comparison to aminolysis of unsubstituted benzamidine, and the desired

48 In this work, the procedures for aminolysis, photografting of linear polyacrylamide, and

49 f (phenylacetyl)-glycyl-D-thiolactate by the aminolysis product (phenylacetyl)glycyl-D-phenylalanine

50 established that contributes to the stepwise aminolysis rate differences and enhanced selectivity.

51 ate saturation conditions, and therefore the aminolysis reaction can be directly studied.

52 t differs in its details from an uncatalyzed aminolysis reaction in solution.

53 substituted phenyl N-phenylcarbamates in the aminolysis reaction was rationalized using theoretical a

54 the monoanion of alpha,omega-diaminoalkanes (aminolysis reaction) to yield amine-terminated PMMA surf

55 rors the coupling between Gln hydrolysis and aminolysis reactions during productive transamidation.

56 y to undergo highly selective and sequential aminolysis reactions in one-pot to afford multifunctiona

57 y smaller than that reported for uncatalyzed aminolysis reactions, which has important mechanistic im

58 ning a hydrolyzed end) for each protein, the aminolysis reactivity of each modified lysyl side chain

59 m indicates that the selectivity-determining aminolysis step occurs via a novel concerted pathway in

60 a one-pot TEMPO-induced radical cyclization/aminolysis that forms the C ring of 1.

61 n the synthesis of homopropargylic amides-by aminolysis using AlMe3, as well as of ketones-through th

62 se-catalyzed acylation, followed by chemical aminolysis, was used to generate vinyl carbonate and vin

63 tives, similar to acyl ones, usually undergo aminolysis with amines in water as nucleophilic attack b

64 ophosphate with ethyl isocyanate followed by aminolysis with ammonium hydroxide to form the desired p