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1 d) or stepwise manner (weak acid then strong anion).
2 using an ionic liquid having a preorganized anion.
3 7 degrees C or in the presence of superoxide anion.
4 nate, and activated water in the imidazolate anion.
5 ion of the stable radical to its diamagnetic anion.
6 of virus, type of salts in solution (cation, anion.
7 oavailability by forming toxic peroxynitrite anion.
8 luding an ammonium cation group and a halide anion.
9 gen radical moiety Fe(III)-N. and a phenoxyl anion.
10 M without any interference from other tested anions.
11 by the crystal chemistries of the available anions.
12 intained a high selectivity for cations over anions.
13 of the binding units in the presence of the anions.
14 ts ability to bind alpha,omega-dicarboxylate anions.
15 arbanions, e.g., Meldrum's acid and dimedone anions.
16 kable progress in the binding and sensing of anions.
17 rs and are therefore rather inaccessible for anions.
18 cept of "dipole-discriminating electrophilic anions."
19 on of the neutral forms led first to radical anions (2(*-) and 3(*-)) and then to a bis(radical anion
21 couple that recombines either as a peroxide anion 7' to afford the aldehyde-to-carboxylic acid produ
22 including KCC2, and extracellular impermeant anions ([A]o) of the extracellular matrix are both propo
26 he thiyl radical generated from the thiolate anion adsorbed on a CdSe QD plays a key role by abstract
28 ichael acceptors and their calculated methyl anion affinities, particularly when solvation by dimethy
29 in the relationship between pKa and chloride anion affinity of these receptors that will be important
30 the different hydrophilic characters of the anions allied to the hydration of the binding units in t
31 chemical diversity offered by the additional anion allows the integration of two common structural un
32 ogen bond-stabilization of the pyrazine (Pz) anion, an unstable anion in isolation due to its neutral
33 with a trifunctional column, combining RPLC, anion and cation exchange, which allows the simultaneous
35 ed on the vibrational modes of a coordinated anion and compare reactivities of various iron(IV)-oxo c
36 FVPY) were found able to scavenge superoxide anion and hydroxyl radicals, organic nitro-radicals (ABT
37 Finally, the chemically generated radical anion and polyanion states, Xn-Hex(*-) and Xn-Hex(n(*-))
39 n the oxidized photocatalyst and the bromide anion and thus the ability to realize a controlled radic
40 d along the pore that interact with permeant anions and affect anion selectivity, as well as seven po
42 The NSP4 VPD was selective for cations over anions and channel activity was observed to have both we
43 l X-ray structures of three of their radical anions and of three of their dianions were obtained.
44 through its reconfigurable network of mobile anions and restrict polysulfide diffusion from mesoporou
48 The SICA effect is primarily determined by anions, and cations exhibit a secondary effect that modu
49 ortality of patients with lactic, unmeasured anions, and hyperchloremic metabolic acidosis with that
50 binding toward the spherical F(-) and Cl(-) anions, and the linear CN(-) (log Kass = 3.46, 3.50, and
51 elf-templated strategy, including sequential anion- and cation-exchange reactions, integrates two dis
52 of complexes formed from anti-electrostatic anion-anion homodimers of organophosphates and cyanostar
54 nd multiple active sites in the preorganized anion are the driving force for the superior CO2 capacit
56 These computational results reveal that PFOS anions are immobilized in SCU-8 by driving forces includ
57 phingomyelin (SM) cations with dicarboxylate anions are shown to charge-invert the positively charged
59 /or sodium-driven transport of (14C)-citrate anion, as well as the organic monovalent cation, ethidiu
60 the transferability of H-bond parameters for anions between different solvents and different HBD part
61 uted compounds where the complex borohydride anion, BH4(-), is replaced by another anion, i.e. a hali
62 However, their potential in solution-phase anion binding applications is only just beginning to be
63 putational studies demonstrate that fluoride anion binding is assisted by the formation of a C-HF hyd
64 e-step process, and was investigated for its anion binding properties by (1)H NMR titrations, 2D NOES
66 , unprecedented charge-assisted ChB-mediated anion binding was also studied in aqueous solvent mixtur
71 part of the heavy chain, the gamma-loop, and anion-binding exosite 1, the main allosteric binding sit
72 tive sites of C1s and MASP-2, as well as the anion-binding exosites of the enzymes via sulfotyrosine
73 rylene diimide (PDI) unit and two triazolium anion-binding motifs, mechanically bonded with two small
74 rtantly, unprecedented solvent-dependent and anion-binding-induced circumrotatory motion in a hetero[
75 was also found to bind two dianionic sulfate anions bridged by two water molecules in the solid state
76 udies reveal that 2 readily binds a fluoride anion by formation of a unique B-FH-O-B hydrogen bond.
79 strate, for the first time, that the TcO4(-) anion can be incorporated into the sodalite structure.
81 then discuss a number of processes by which anions can be created and destroyed in these environment
83 Advances in the design of small molecule anion carriers are reviewed in addition to advances in t
84 For certain substrate classes, the chiral anion catalysts were modulated to minimize the formation
85 their diverse applications in catalysis; as anion, cation, and neutral substrate receptors; as ligan
89 inducer, overexpression of voltage-dependent anion channel 1 (VDAC1) induced Parkin translocation to
90 lycine directly bounded to voltage dependent anion channel 1 (VDAC1) on the mitochondrial outer membr
91 ns, including the abundant voltage-dependent anion channel and the cation-preferring protein-conducti
92 smembrane conductance regulator (CFTR) is an anion channel evolved from an ATP-binding cassette trans
94 the ubiquitously expressed vertebrate Cl(-) /anion channel that is composed of proteins belonging to
95 d ligand in the IMP, mouse voltage-dependent anion channel-1 (mVDAC1), and top-down MS confirmed a si
96 ion of iChS by chemical modifications favors anion channeling at the expense of substrate transport,
98 s appear, including with the plasma membrane anion channels and H(+)-ATPase and with the tonoplast TP
100 malate transporters (ALMTs) form a family of anion channels in plants, but little is known about most
104 applied for the electrochemical detection of anions (Cl(-), SO4(2-), and Br(-)) in a highly diluted w
105 used a case study focused on the perchlorate anion (ClO4(-)) to highlight the value of the AOP framew
106 this process produces polycation-surfactant anion coacervates that entrain the agent and enhance its
108 charge density and/or mobile cation (and/or anion) concentrations alter the localization and functio
109 r study thus reveals the structural basis of anion conduction in a TMEM16 channel and it defines the
113 d product selectivity resulted from a chiral anion dependent lowering of the activation barrier for t
116 ral observations that show that the fluoride anion does not act as a one-electron reducing agent towa
117 aO, which facilitates the transport of O(2-) anions, drastically improves the reaction kinetics, and
119 g cartridges containing materials for strong anion exchange (SAX) chromatography increased yield and
120 rates were quantified using high-performance anion exchange chromatography (HPAEC) with pulsed ampero
123 th the protein kinase A inhibitor H89 or the anion exchange inhibitor 4,4'-diisothiocyano-2,2'-stilbe
125 sess the unique capability of post-synthesis anion exchange providing facile tunability of the optica
127 porating polar embedded reversed phase, weak anion exchange, and strong cation exchange material.
134 The development of cationic polymers for anion-exchange membranes (AEMs) with high alkaline stabi
135 ented in this study can be extended to other anion-exchange polymer chemistries and, therefore, offer
139 reaction inside red blood cells, and band 3 [anion exchanger 1 (AE1)] provides a passage for HCO3(-)
143 f less hydrophilic trifluoromethanesulfonate anions for hydrophilic sulfate; the resulting water-solu
146 r the first time, it is reported that dimsyl anion, formed from a strong base and DMSO (solvent), is
147 ructure translates into a tunable density of anion Frenkel disorder while cations remain ordered.
149 different cooperativity in binding pairs of anions from the fullerene-free parent: in one case, posi
150 ynthesis and characterization of the cluster anions [Ge18Pd3{Si(i)Pr3}6](2-) (1) with a core of face-
153 ondissociated acid form, and the carboxylate anion group, representing the dissociated form, over a w
155 photoelectron spectroscopy of the vinylidene anions H2CC- and D2CC- and quantum dynamics calculations
157 in interstitial spaces periodically serve as anions-have attracted broad attention for their exotic p
158 rent work, we report a self-assembled triple anion helicate (host 2) featuring a cavity resembling th
160 utral organic HBAs, and the non-coordinating anion hexafluorophosphate is the weakest acceptor, with
161 lexes at Au/MAPbI3 interface, whereas iodine anions (I(-)) can react with Ag contacts, leading to int
162 ydride anion, BH4(-), is replaced by another anion, i.e. a halide or amide ion; and metal borohydride
163 dissociative photochemistry of the triiodide anion (I3(-)) in single-crystal tetra-n-butylammonium tr
165 , including a compound containing the PCO(-) anion in an unprecedented mu(2) :eta(2) ,eta(2) -binding
167 tion of the pyrazine (Pz) anion, an unstable anion in isolation due to its neutral counterpart having
172 this article, we review the observations of anions in interstellar clouds, circumstellar envelopes,
174 properties of SCU-8 were explored with many anions including small oxo anions like ReO4(-) and Cr2O7
175 sment of a large number of different counter anions, including those that are synthetically challengi
176 nionic ligands X revealed that the nature of anion influences the reactivity more than the spin state
180 xplored with many anions including small oxo anions like ReO4(-) and Cr2O7(2-) as well as anionic org
183 de diffusion from mesoporous carbon hosts by anion metathesis, which we show is selective for higher
185 had considered some processes through which anions might form in interstellar clouds and circumstell
188 st due to the unique features of the hydride anion, most notably the absence of valence p orbitals.
189 ction of an alkyl iodide (R-I) with an azide anion (N3(-)) to reversibly generate the corresponding a
190 o the presence of a remote basic site in the anion namely, OH of bicarbonate, NH of prolinate, and ac
191 vels of lipid peroxidation and of superoxide anion (O2(* horizontal line )) were higher in Prdx6 (-/-
192 e in class I b RNRs that requires superoxide anion (O2(.-) ), rather than dioxygen (O2 ), to access a
194 and energetics of o-, m-, and p-quinonimide anions (OC6H4N(-)) and quinoniminyl radicals have been i
197 Here we show via a high-pressure study of anion-ordered strontium vanadium oxyhydride SrVO2H that
198 ementing a highly hydrophobic perfluorinated anion (perfluorooctanesulfonate, PFOS(-)) as doping ion
199 mic pH as a read-out, indicated that lactate anions permeate gap junctions faster than highly-buffere
206 to the pi-electron-deficient ClBDPPV through anion-pi electronic interactions is strongly corroborate
209 shorter than standard pi-pi interactions and anion-pi interactions on planar surfaces, and alternativ
211 f neuronal [Cl(-)]i - cytoplasmic impermeant anions, polyanionic extracellular matrix (ECM) glycoprot
213 identified four new channel activities: two anion-preferring channels and two cation-preferring chan
214 ation which leads to Ca(2+) rise, superoxide anion production, ATP drop and late NADP(H) depletion as
216 The reaction of dichloro ketones with azide anions provides acyl azides, through in situ formation o
217 nthetic electron transfer, detoxification of anion radicals, citrate cycle, and tetrapyrrole biogenes
218 [Ta6Br12(H2O)6]@2CD}(2+) and the Dawson-type anion, react together to give a three-component, well-or
219 simple nucleophiles, such as azido or cyano anions, react with unexpected stereo- or regioselectivit
221 he higher binding constant of Cl(-) with the anion receptor and the stronger electronic effect betwee
225 , which revealed considerable differences in anion recognition behavior in comparison with chalcogen-
227 ative study of 1,2,3-triazole and triazolium anion recognition units containing sulfoxide, sulfone, a
228 mics simulations are used to investigate the anion recognition- and solvent-dependent dynamic propert
231 al oxide positive electrodes offer access to anion redox at high potentials, thereby promising high e
233 This finding together with the observed anion reduction as the redox center is of broad interest
234 s finding demonstrates a general paradigm of anion-regulated evolution of distinctive TMSs, providing
235 ey synthetic transformations include Type II Anion Relay Chemistry (ARC) to construct the polyol chai
237 electronic structure of the para-quinonimide anion require both an accurate account of electron corre
238 h steric and electrostatic forces, where the anions reside in equidistant "clefts" between coordinati
239 d spectral diffusion of the linear triatomic anion, SeCN(-), in poly(ether sulfone) (PES) membranes a
240 in the limit of detection of potentiometric anion-selective electrodes aiming at determining nutrien
242 ophyte species, showing that all of them are anion-selective, and thus expanded this protein family t
243 hat interact with permeant anions and affect anion selectivity, as well as seven pore-lining residues
244 ique and sophisticated mechanism for optical anion sensing in competitive protic organic and aqueous-
245 s examined as an initial example of this new anion sensing platform for measurements of fluoride leve
246 photoelectron spectrum of the m-quinonimide anion shows that the ion undergoes several different rea
247 ch individual seesaw-shaped tin (II) bromide anions (SnBr4(2-) ) are co-crystallized with 1-butyl-1-m
248 hydroxyl radical ((*)OH) and sulfate radical anion (SO4(*-)) were measured from ultrasonic activation
249 than (18)F-BF4(-) The ability of a range of anions, some containing fluorine, to block (99m)TcO4(-)
250 ect detection of the 4,4'-bipyridine radical anion species localized in the plasmonic hot spots of in
251 C-terminus and causes aggregation of citrate anion-stabilized silver nanoparticles (AgNPs) in the abs
254 hich suggested that small localized fluoride anions substituted the hydroxyl anions in hydroxyapatite
255 dride derivatives have also been discovered: anion-substituted compounds where the complex borohydrid
257 lectivity for chloride over major lipophilic anions such as salicylate ( [Formula: see text] ) and th
262 ic organic cation and inorganic (or organic) anion that loosely fit together, is extending the proper
266 ng can also proceed in a cooperative (strong anion then weak acid) or stepwise manner (weak acid then
267 zes the H2O2-dependent oxidation of chloride anion to generate hypochlorous acid, a potent antimicrob
268 ngbone packings by reorienting the molecular anions to create multiple potassium sites within initial
272 have a 7 + 7 inverted repeat structure with anion transport initiated by chloride binding at the int
275 thus inserts into lipid bilayers to turn on anion transport, which can then be turned off through ad
276 clude two "drug" transporters of the organic anion transporter (OAT) family: OAT1 (SLC22A6, originall
277 GLUT1, the glucose transporter; SLC4A1, the anion transporter; RhAG, the Rh-associated glycoprotein;
278 deled, based on structural data from related anion transporters (SLC26Dg and UraA), to have a 7 + 7 i
282 s were determined in wild-type (WT), organic anion transporting polypeptide (OATP) knockout mice (lac
283 Here, we investigated the role of organic anion transporting polypeptide (OATP) transporters to th
285 .5)1 thin film superlattices possessing both anion-vacancy order and Sr and Ca chemical order at the
288 Aa1, whereas dual selectivity (to cations or anions) was observed for the pores formed by the trypsin
289 The nucleophilic reactivities of barbiturate anions were compared with those of structurally related
291 t act together to CH-hydrogen-bond to halide anions when the macrocycle is located on an alternative
292 and decarboxylation to form an aryl radical anion which is then oxidized by the [4Fe-4S](+2) cluster
293 oduced a mono-substituted [BH3 N(NO2 )2 ](-) anion, which contains a B-N connected dinitramido ligand
295 ion-state dynamics by the photodetachment of anions with an equilibrium geometry similar to the neutr
296 ble cage is flexible and able to encapsulate anions with volumes ranging from 35 to 219 A(3) via hydr
297 of a C-based nucleophile, namely the phenyl anion, with the ferric heme nitrosyl [(OEP)Fe(NO)(5-MeIm
299 of convenient sources of nucleophilic boryl anions would open up a wealth of opportunity for the dev
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