ライフサイエンスコーパス: anisole

1 order of toluene > benzene > bromobenzene > anisole.

2 ethoxy-1,4-cyclohexadiene with 2.5 Li/mol of anisole.

3 e with added substituted benzenes, including anisole.

4 ts were done with several substrates, mainly anisoles.

5 The smallest value, 212 mV, was found in anisole/0.1 M [NBu4]Cl and the largest, 850 mV, in CH2Cl

6 Exchange of toluene for anisole, 1,3-butadiene, 1,3-cyclohexadiene, thiophenes,

7 tely k 3 [Ln (3+)] (1)[acetic anhydride] (1)[anisole] (1).

8 for reactions of each brominating agent with anisole, 2-bromoanisole, and 4-bromoanisole.

9 90, 120 and 150 ppm) and butylated hydroxyl anisole (200 ppm), were incorporated in anhydrous cow mi

10 avage of the product from the resin using HF/anisole (95/5) for 1.5 h at 0 degrees C gave the desired

11 nidines during cleavage from the resin by HF/anisole (95/5) for 1.5 h at 0 degrees C, the desired pro

12 of Ln(OTf) 3 (Ln = La, Eu, Yb, Lu)-mediated anisole acylation with acetic anhydride in nitromethane

13 larly effective complexation was provided by anisole and 1,3-dimethoxybenzene, which modulated the ra

14 sch-type additions of trichloroacetamides on anisole and enol acetates catalyzed by Grubbs' ruthenium

15 In the cleavage of the less basic ethers anisole and EtOSiEt(3), the cationic iridium silane comp

16 ed GC phase, the test mixture contained both anisole and fluoranthene.

17 Carbon atom reactions with anisole and methoxybenzaldehyde demonstrate the reversib

18 b, were prepared and treated separately with anisole and phenoxytriisopropylsilane under Lewis acid c

19 ochrome P450 (P450) 1A2 were addressed using anisoles and other substrates.

20 clization of acetoxy-containing 2-(1-alkynyl)anisoles and subsequent direct palladium-catalyzed carbo

21 A series of difluoromethyl anisoles and thioanisoles was prepared and their druglik

22 either methyl esters or methyl aryl ethers (anisoles) and L(2)PtMe(2), while the carbon-carbon reduc

23 was found to be general for a wide range of anisole, aniline, acetanilide, and phenol derivatives an

24 e subsequent chlorination of a wide range of anisole, aniline, acetanilide, and phenol derivatives.

25 matic compounds (toluene, benzene, p-xylene, anisole, aniline, and pyridine), temperature, and surfac

26 rosulfanyl)phenol and 4-(pentafluorosulfanyl)anisole are oxidized by 30% aqueous hydrogen peroxide in

27 In contrast, simple arenes, such as anisole, are characterized by poor reactivity and select

28 mpounds, along with the weak base, NaOAc, in anisole at 120 degrees C.

29 minative benzylations of benzene-toluene and anisole-benzene mixtures, the values of k(X)/k(B) and %

30 ioxidant widely used, the butylated hydroxyl anisole (BHA).

31 The regioselectivity of anisole bromination changed with pH, consistent with the

32 e constant determined for net bromination of anisole by HOBr is up to 3000-times less than reported i

33 es in the two-step deprotonation reaction of anisole by TMP-dialkyl zincates and show the relevance o

34 e computed addition-elimination mechanism of anisole chlorination in nonpolar media.

35 Experimental NMR investigations of the anisole chlorination reaction course at various temperat

36 nce for one coordination diastereomer of the anisole complex in the solid state and a Diels-Alder lik

37 Several eta(2)-coordinated anisole complexes were treated with various Michael acce

38 ; whereas 8 displays an open structure where anisole connects the two metals (in the same mode as in

39 With an anisole-containing polypyridylamine potential tetradenta

40 oming arene is C(6)D(6), chlorobenzene-d(5), anisole-d(8), fluorobenzene-d(5), toluene-d(8), o-xylene

41 s react with various dienophiles, furnishing anisole derivatives derived by loss of water from the in

42 yl ethers, vinyl methyl ethers, and unbiased anisole derivatives, thus representing a significant ste

43 d ortho and para substitution orientation of anisole easily.

44 s, such as tert-butyl methyl ether, dioxane, anisole, ethyl acetate, beta-chloroethyl ether, and mono

45 the other hand, tert-butyl methyl ether and anisole fail to form stable boron trichloride adducts an

46 tically active chiral cyclohex-2-enones from anisoles has been developed.

47 thyl-1,2,4-triazoline-3,5-dione (MeTAD) with anisole in the presence of trifluoroacetic acid affords

48 use of a previously intractable nucleophile, anisole, in an oxidative "cross-dehydrogenative coupling

49 so achieved with aromatic compounds (phenol, anisole, indole, and anilines) as nucleophiles.

50 The complex TpW(NO)(PMe3)(eta(2)-anisole) is combined with acrolein or methyl vinyl keton

51 thianthrenium perchlorate in the presence of anisole it was shown to produce the same disubstituted p

52 an orthogonal hot solvent (e.g., toluene or anisole) jet, which is generated by a heated nebulizer m

53 reaching ~60,000 cm(2) Vs(-1) for devices in anisole (kappa = 4.3).

54 he distinct metals are connected through the anisole ligand which binds in an ambidentate fashion (th

55 yme bovine carboxypeptidase A into fragments anisole, molecular nitrogen, carbonate, and phenylalanin

56 zation of bioactive compounds containing the anisole motif, allowing the construction of novel organi

57 r 1-methylimidazole (MeIm); L(Ar) = benzene, anisole, naphthalene, 1-methylpyrrole, furan, or thiophe

58 e same moiety found in (O)L, but without the anisole O-atom donor.

59 ediate; such relationships were not seen for anisole O-demethylation with P450 2B1.

60 in model solvent-water (toluene, hexadecane, anisole, octanol) and cellulose-water systems.

61 eatment with an electron-rich arene, such as anisole or thiophene, or with a functionalized arylstann

62 3 with acetic anhydride, followed by Ln (3+)-anisole pi-complexation, substrate-electrophile sigma-co

63 to a Cr(CO)3 unit enhances the reactivity of anisoles providing an unprecedented ortho-selective aryl

64 ontain ynone substituents, including indole, anisole, pyrrole, and benzofuran derivatives, into funct

65 aromatics derived from benzene, toluene, and anisole) react at the air-water interface with increasin

66 developed using H3PO4/anisole to produce the anisole solvate of the API in high yield and purity.

67 n arylation at the ortho or para position of anisole substrates, we find that arylation proceeds sele

68 In the case of anisole, the intermediate PhMeOSiEt(3)(+), 10, is reduce

69 Variously substituted arenes such as anisole, thioanisole, diphenyl ether, phenol, naphthol,

70 oxyphenethyl group was developed using H3PO4/anisole to produce the anisole solvate of the API in hig

71 activities contribute benzene, toluene, and anisole to the environment, which in the atmosphere are

72 sidues by mild trifluoromethanesulfonic acid/anisole treatment.

73 Benzene, anisole, veratrole, and ortho-xylene lead exclusively to

74 Anisole was also reduced to 1-methoxy-1,4-cyclohexadiene

75 Br toward rates of sequential bromination of anisole was quantified.

76 ning coefficients of thiophene, pyrrole, and anisole were measured in situ over a range of temperatur

77 s facilitated by single crystallization from anisole, where the product was obtained in 57% isolated

78 ic lanthanide triflate-mediated acylation of anisole with acetic anhydride.

79 xperimental investigation of the reaction of anisole with Cl2 in nonpolar CCl4 solution challenges tw

80 ed by co-complexation reactions of lithiated anisole with the relevant dialkylzinc compound and the r