ライフサイエンスコーパス: arene

1 ter pi-surface of aromatic rings of pillar[5]arene.

2 synthesis starting from a prefunctionalized arene.

3 the different geometries allowed in calix[4]arene.

4 ionality displayed at different sites of the arene.

5 -bistriflate ester 2a of p-tert-butylcalix[4]arene.

6 llar[5]arene and per-O-methylated resorcin[4]arene.

7 egardless of the substitution pattern on the arene.

8 om the radical anion of the multifluorinated arene.

9 arylation directed to access functionalized arenes.

10 ith TMSCF2CF3 to afford pentafluoroethylated arenes.

11 patible with a wide variety of electron-rich arenes.

12 to the host-guest behavior of most pillar[5]arenes.

13 rrent processes that produce saturated alkyl arenes.

14 eaction, as are complex, biologically active arenes.

15 rry out C-H activation on electron-deficient arenes.

16 adiopharmaceuticals containing non-activated arenes.

17 ective C-H aryloxylation of heteroarenes and arenes.

18 ch as monofluorobenzenes and non-fluorinated arenes.

19 , OCHF2) of medicinal relevance onto (hetero)arenes.

20 tivity for the C-H borylation of unactivated arenes.

21 e-selective functionalization of polynuclear arenes.

22 y applied to preparation of multisubstituted arenes.

23 pling of iodoarenes, but not bromoarenes, to arenes.

24 ctly react with NHP esters to form alkylated arenes.

25 ylation and diaminodihydroxylation of simple arenes.

26 in the C(sp(2))-H borylation of fluorinated arenes.

27 verse bioactivities of C-glycopyranosyl (het)arenes.

28 the selective meta-C-H functionalisation of arenes.

29 or accessing functionalized multifluorinated arenes.

30 ty data for six series of electron deficient arenes.

31 distinctly different from those of analogous arenes.

32 O5, resulting in its distinct selectivity to arenes.

33 (SET), and b) hydride delivery reactions to arenes.

34 m nitroalkanes with a variety of fluorinated arenes.

35 ninnocent hydroquinone moiety as the central arene (1-H).

36 -mes)-9-(1'-1',2'-closo-C2 B10 H11 )-13-(eta-arene)-1,13,2,9-closo-Ru2 C2 B10 H11 ] by direct electro

37 Treatment of (diacetoxyiodo)arenes (1a-1u) with cyclotron-produced [(18)F]fluoride i

38 Thus, calix[5]arene 1c, bearing tert-butyl groups at the wide rim, was

39 zuki-Miyaura cross-coupling of chloro(hetero)arenes (40 examples) at low Pd loading, including the la

40 A facile synthesis of 1,3-diiodocalix[4]arene 6 has been achieved by copper-catalyzed iodination

41 llar[5]arene, mono- and polynuclear pillar[5]arenes, a new class of metalated host molecules, is prep

42 series of perfluorinated and polyfluorinated arenes across the Mg-Mg bond of a simple coordination co

43 In an extreme case, this through-space HO-arene activation is demonstrated to overcome the deactiv

44 Additionally, the HO-arene activation promotes tetrabromination of an increas

45 The fascinating intramolecular arene/allene cycloaddition discovered by Himbert affords

46 fferential functionalization of enantiotopic arenes, although additional studies unveiled a contribut

47 For many years, the range of (hetero)arenes amenable to (18)F-fluorination was limited by the

48 Arene amination is achieved by site-selective C-H zincat

49 nd describe the utility of this strategy for arene amination.

50 atives is sensitive to the reactivity of the arene and changes from reductive elimination to pi-compl

51 a scrambling experiment, involving pillar[5]arene and per-O-methylated resorcin[4]arene.

52 Stoichiometric studies show that arene and phenol products are released following reactio

53 Various functional groups on arene and thiol substituents are tolerated by the system

54 f carbon-carbon bonds between simple (hetero)arenes and (hetero)aryl halides, reducing both the numbe

55 from simple and commercially available iodo arenes and aldehydes, for the synthesis of a wide variet

56 t-catalyzed C-H oxygenation proved viable on arenes and alkenes with excellent levels of positional a

57 Various arenes and alkynes allow for this transformation.

58 A metal-free CH-CH-type coupling of arenes and alkynes, mediated by a multifunctional sulfox

59 functional groups-from amines and halides to arenes and alkynes-along with their air and moisture sta

60 icles to form a vast collection of colloidal arenes and colloidenes, the spontaneous dissociation of

61 xperiments including with electron-deficient arenes and deuterium labeling studies.

62 ng between electron-rich hetero-/carbocyclic arenes and electron-poor arenes bearing relatively acidi

63 Arenes and heteroarenes are privileged candidates for (1

64 system that shows (reversible) silylation of arenes and heteroarenes as well as reductive cleavage of

65 sulfoxonium ylides with C(sp(2) )-H bonds of arenes and heteroarenes in the presence of a rhodium cat

66 er acetate-DMSO promoted methylthiolation of arenes and heteroarenes in the presence of air has been

67 g unactivated alkyl halides and a variety of arenes and heteroarenes is described.

68 ts-type arylation with various electron-rich arenes and heteroarenes provides functionalized alpha-(h

69 e direct trifluoromethylation of unactivated arenes and heteroarenes under either ultraviolet or visi

70 rrent data on new methods of alkenylation of arenes and heteroarenes with alkynes by transition metal

71 ps, and enables the labeling of a variety of arenes and heteroarenes with radiochemical yields (RCYs,

72 f a useful azide group onto a broad scope of arenes and heteroarenes.

73 tion/insertion of more sterically encumbered arenes and influences hydrogenation rates and selectivit

74 supported on activated carbon and furnishes arenes and phenols in high yields without hydrogenation.

75 Metalations of activated disubstituted arenes and selected monosubstituted arenes are rapid at

76 ion of C-C bonds between halogenated (hetero)arenes and simple (hetero)arenes with active C-H bonds,

77 inexpensively prepared from aryl halides or arenes and widely used on both laboratory and industrial

78 Partially fluorinated alkanes, arenes, and alkenes can be transformed by a variety of t

79 ion between N-tosylhydrazones, dihalogenated arenes, and boronic acids or boronate esters was develop

80 indolin-1-one by using 2-formylbenzonitrile, arenes, and diaryliodonium salts.

81 fluorides and bromides, alcohols, aldehydes, arenes, and heteroarenes, were synthesized from an inter

82 ree novel tetra(thio)ureido dihomooxacalix[4]arene anion receptors (phenylurea 4a, phenylthiourea 4b,

83 Azido (18) F-arenes are important and versatile building blocks for t

84 stituted arenes and selected monosubstituted arenes are rapid at -78 degrees C.

85 Arene-arene interactions are more favorable and serve to

86 Cofacial fluoroarene-arene (ArF-ArH) interactions cause twisting in the PE ba

87 ic nano-inclusions using p-tertbutyl calix[4]arene as ionophore and polymeric matrix (polyvinyl chlor

88 ates non-directed C-H functionalization with arene as the limiting reagent.

89 tion capsules designed using sulfonylcalix[4]arenes as container precursors, are known for their tuna

90 to unsymmetrical diarylmethanes with various arenes as nucleophiles.

91 A new derivative of dipodal 1,3-calix[4]arene-based chemosensor (R), which was containing severa

92 ns, carboxylate linkers, and sulfonylcalix[4]arene-based container precursors exhibit great promise a

93 ugh the ruthenium-catalyzed C-H arylation of arenes bearing directing groups with haloarenes is well-

94 hetero-/carbocyclic arenes and electron-poor arenes bearing relatively acidic C-H bonds.

95 wide range of arenes, including nonactivated arenes bearing simple functionalities such as fluoride,

96 reductive elimination to pi-complexation for arenes bearing strongly electron-withdrawing substituent

97 (CSNAr) that is not limited to electron-poor arenes, because it does not proceed via a Meisenheimer i

98 n of an increasingly more electron-deficient arene before the unactivated "control" ring undergoes mo

99 ene isomers and substituted dihomooxacalix[4]arene bidentate urea derivatives.

100 ation of phenyl-substituted dihomooxacalix[4]arene bidentate urea, voltammetric responses evolve from

101 relation between the bond order of the fused arene bond and the paratropicity strength of the antiaro

102 he CF3 group is found to stabilize the metal-arene bond strength in 5 by roughly 3 kcal/mol compared

103 incer in the cobalt catalyst was faster than arene borylation.

104 cts are versatile, accessing polyfluorinated arene building blocks in substantial scale is important.

105 X)-Ar and lead to the pi-complexation of the arene by Ar-AuX2 becoming the turnover-limiting step.

106 ork, we demonstrate that the reduction of an arene by SmI2-water proceeds through an initial proton-c

107 e intramolecular gold-catalyzed arylation of arenes by aryl-trimethylsilanes has been investigated fr

108 Replacing benzene rings in arenes by thiadiazoles thereby provides a strategy for m

109 series of oxidatively induced intramolecular arene C-H activation reactions of Ni(II) model complexes

110 tionalization and transition-metal-catalyzed arene C-H amination.

111 Herein we report the intramolecular arene C-H and C-F bond oxygenation by tetranuclear iron

112 ity feasible route involving atom economical arene C-H bond arylation.

113 boration, aldehyde/ketone hydroboration, and arene C-H borylation.

114 Complementary biscalix[5]arene-C60, bisporphyrin-trinitrofluorenone (TNF), and Ha

115 Pd(II)-catalyzed Heck-type coupling between arene carboxylic acids and alkenes at room temperature.

116 rination affords moderate to good yields for arenes carrying electron-withdrawing (50-85%) or weakly

117 he inner cavities of self-folding resorcin[4]arene cavitands by the formation of covalent host-guest

118 n of this species and treatment with [Ru(eta-arene)Cl2 ]2 results in the 14-vertex/12-vertex species

119 -(pyridin-3-yl)propanoate)], a ruthenium(II)-arene complex with a perfluoroalkyl-modified ligand that

120 ng state of the catalyst is an NHC-Ni(eta(6)-arene) complex.

121 We screened 14 ruthenium-arene complexes and identified AH54 and AH63 as supra-ad

122 Dinuclear trihydroxido-bridged osmium-arene complexes are inert and biologically inactive, but

123 We postulated that ruthenium-arene complexes are radiosensitisers when used in combin

124 eta(6)-Me6C6)Cu(PR3)][PF6], the first copper-arene complexes to feature an unsupported eta(6) arene i

125 on-metal-based dearomatization (i.e., eta(6)-arene complexes).

126 dditional additive, yielding the substituted arene compounds.

127 eduction of five partially oxidized pillar[5]arenes containing variable numbers (1-5) of quinone unit

128 trimethylenethioureido spacers to a calix[4]arene core and differing for the presence of methoxy or

129 array of electron-rich to electron-deficient arenes could readily be transformed to their respective

130 The cone-calix[4]arene derivative (1H3)(2+), decorated at the upper rim w

131 4)-fold at 1 mM concentration of the calix[4]arene derivative.

132 ion of a large series of alkylated and fused arene derivatives to the corresponding all-cis-cyclohexa

133 ubstituted cyclohexenes to the corresponding arene derivatives.

134 rgo Pd-catalyzed Matsuda-Heck couplings with arene diazonium salts to alpha-benzyl butenolides or pen

135 ing (Matsuda-Heck reaction) of electron rich arene diazonium salts with electron deficient olefins ha

136 In the case of vinyl arenes, enantioselective borylacylation was possible.

137 Metalations of arenes, epoxides, ketones, hydrazones, dienes, and alkyl

138 he first examples of photochemically induced arene exchange/expansion reactions at a single carbon ce

139 ntial H2 delivery to a single catalyst-bound arene face, versus any competing intramolecular arene pi

140 tential revealed that the metalated pillar[5]arenes featured an electron-deficient cavity due to the

141 ates such as aldehydes, alcohols, and methyl arenes for a one-pot protocol, whereas TMSN3 is used as

142 tially and temporally resolved technique for arene formation using photolithography.

143 oportionation reaction with 1 equiv of ethyl arene formed for each equivalent of diarylbutadiene prod

144 Racemates of five chiral resorcin[4]arenes, four tetra-O-substituted and one hepta-O-substit

145 ere that linking dihydroxido-bridged Os(II) -arene fragments by a bridging di-imine to form a metalla

146 significantly larger than those of the free arenes from which they were derived.

147 ve plausible pathway for gold(III)-catalyzed arene functionalization reactions in future studies.

148 c C-H bonds is a long-standing challenge for arene functionalization reactions such as the hydroaryla

149 c substitution (SNAr) is a direct method for arene functionalization; however, it can be hampered by

150 The development and application of the arene-fused domino Michael/Mannich route to the tetrahyd

151 d polycyclic aromatics bearing two different arene fusions.

152 A dearomative 1,4-carboamination of arenes has been achieved using arenophile cycloaddition

153 peroxide-free ortho aroylation of directing arenes has been developed via cross dehydrogenative coup

154 A dearomative reduction of simple arenes has been developed which employs a visible-light-

155 ive method for the chlorination of activated arenes has been developed.

156 etween 3-ylidene oxindoles and electron-rich arenes has been successfully accomplished.

157 use a large excess of the radical-accepting arene have hindered their application to substituted ben

158 tion-metal-catalyzed alkylation reactions of arenes have become a central transformation in organic s

159 ribe the synthesis of three tetraureacalix[4]arenes having four appended terminal azobenzene groups.

160 lkylation of 2-bromo-1-(phenylsulfonylmethyl)arene/heteroarene with arylmethyl bromides/heteroarylmet

161 tuted alkyl iodides and -bromides with vinyl arenes/heteroarenes has been developed.

162 a comprehensive mechanism for diiron enzyme arene hydroxylation that accounts for many prior experim

163 )-oxo) might be responsible for the observed arene hydroxylation.

164 erved to react directly with a wide range of arenes in a step-wise and controlled manner.

165 to 1,4-dicarbofunctionalization of activated arenes in a tandem, one-pot transformation.

166 electrophilic chlorine species reacting with arenes in aromatic substitutions extends the method beyo

167 on complements prior trifluoromethylation of arenes in several ways.

168 sopropylamide (NaDA)-mediated metalations of arenes in tetrahydrofuran (THF)/hexane or THF/Me2NEt sol

169 e relative reactivities of different (hetero)arenes in the silylation reaction.

170 t state of 1 was found to engage a series of arenes in thermally reversible Buchner ring expansion re

171 ene ligand that delivers allylic substituted arenes in up to 95% yield and up to 98:2 er.

172 inated benzyl esters and main-chain terminal arenes, in turn controlling the conformations and interc

173 e base that is effective for a wide range of arenes, including nonactivated arenes bearing simple fun

174 resent unique examples of electron-deficient arenes instead undergoing preferential substitution in i

175 L)Fe which features an intramolecular eta(6)-arene interaction and can be utilized as an Fe(I) syntho

176 interaction to switch to the alternative HO-arene interaction in order to provide activation.

177 unknown propensity of a hydrogen-bonding OH-arene interaction to switch to the alternative HO-arene

178 e complexes to feature an unsupported eta(6) arene interaction.

179 could instead stabilize a positively charged arene intermediate or transition state, giving rise to n

180 onsistent with slow oxidation of a copper pi-arene intermediate.

181 t examples of a Lewis-acid catalyzed (hetero)arene interrupted, formal homo-Nazarov cyclization have

182 reactions convert simple, readily available arenes into more complex molecules with broader potentia

183 th electron-rich arenes, unless an excess of arene is used, which limits synthetic applications.

184 C-F functionalization of highly fluorinated arenes is a powerful method for accessing functionalized

185 The direct catalytic C-H amination of arenes is a powerful synthetic strategy with useful appl

186 The direct arylation of unactivated arenes is a very practical and highly convenient procedu

187 or Friedel-Crafts alkylations of unactivated arenes is an important objective of interest for the pro

188 cid-derived diazo reagent with electron-rich arenes is described.

189 line-1-carbonitriles and 1,2-bis(bromomethyl)arenes is described.

190 A broad range of CF3-substituted arenes is efficiently converted into unsymmetrical diary

191 iaryliodonium salts directly from iodine and arenes is presented.

192 ic cycle that involves a well-defined eta(6)-arene-ligand-free Ru(II) catalyst.

193 by the innate electronics of the fluorinated arene, limiting the synthetic utility of the chemistry.

194 The synthesis of the larger resorcin[5 and 6]arene macrocycles [5](OMe) and [6](OMe) has been realize

195 ket) guan)(Im(Dipp) N)Ti(OTf)2 (3) gives the arene-masked complex ((ket) guan)(eta(6) -Im(Dipp) N)Ti

196 When arene=mesitylene (mes), the diruthenium species is fluxi

197 n amine-containing aromatic molecules at the arene meta position.

198 he most recent strategies for chemoselective arene metalation on peptides.

199 g) to arrive at the newly incorporated large arene moieties.

200 clopentadienyl and M=Ir or Rh) with pillar[5]arene, mono- and polynuclear pillar[5]arenes, a new clas

201 ous compounds with the C-glycopyranosyl (het)arene motif were subjected to biological studies display

202 e in 1-2 steps from the commercial arenes or arene N-oxides (25-99%).

203 ation of discrete nickel-seamed pyrogallol[4]arene nanocapsules.

204 ns with only 1.2 equiv activated/deactivated arenes (no additional solvent) to access structurally an

205 bled by exclusively regioselective catalytic arene-norbornene annulation (CANAL) between dibromonapht

206 erocycles having C-sp(3) carbon (2-methylaza-arenes) occurs via deamination of benzylamine followed b

207 carboxylate of the peptides with the distal arene of the substrate.

208 lyzed reaction of phenols with electron-rich arene or heteroarene ligands of unsymmetrical diaryl-lam

209 here the carbonyl is directly attached to an arene or heteroarene.

210 accessible in 1-2 steps from the commercial arenes or arene N-oxides (25-99%).

211 olo[3,2-b]pyrroles fused with two peripheral arenes or heterocyclic units has been realized through t

212 Through-the-annulus threading of calix[5]arene penta-O-ethers by dialkylammonium cations coupled

213 nic frameworks based on C-pentylpyrogallol[4]arene (PgC5 ) with spacer molecules, such as 4,4'-bipyri

214 The family of iodido Os(II) arene phenylazopyridine complexes [Os(eta(6) -p-cym)(5-R

215 ne face, versus any competing intramolecular arene pi-face interchange.

216 r relies on the electrografting of a calix[4]arene platform bearing diazonium functionalities at its

217 nctionalities borne by these so-called dyn[4]arenes plays a crucial role on their structural features

218 equent reaction of these benzyl cations with arenes proceeds as Friedel-Crafts alkylation to afford 1

219 Ortho aroylation of directing arenes proceeds via decarbonylation of the in situ gener

220 ious nitrogen heterocycles and electron-rich arenes provided a series of analogues (5-10) of eudistid

221 Substrates activated by the metal include arenes, pyridines, pyrroles, pyrimidines, furans, and th

222 reduced in an organic solvent (reaction with arene radical anions in glyme).

223 clude coupling reactions of halobenzenes and arenes, reductive cleavages of dithianes, and SRN1 react

224 ve functionalization at the meta position of arenes remains a significant challenge.

225 ndergo addition to another molecule of vinyl arene, resulting in an overall disproportionation reacti

226 ertion of the metal into the otherwise inert arene ring C-C bonds.

227 al pseudomigration of the substituent on the arene ring of arylglyoxals.

228 ment is seen upon fluorination of the distal arene ring, arising from favorable enthalpic (DeltaDelta

229 approach is metal-induced deformation of the arene ring, which creates temporary ring strain and prom

230 l building blocks, two CoTPyP units and four arene-Ru clips, into a cofacial motif previously demonst

231 ancer candidates and biocatalysts, including arene ruthenium complexes, polypyridyl ruthenium complex

232 The elaboration of the resorcin[4]arene's aromatic cavity produced a self-folding, deep he

233 ctural conformation of 1,3-alternate-calix[4]arene scaffold and molecular electrostatic potential of

234 ngth depends on the chirality induced in the arene scaffold by the substituents rather than on the pr

235 ata show that preorganization of the calix[5]arene scaffold leads to great thermodynamic stability of

236 lenic cage (AAC) receptors with a resorcin[4]arene scaffold, from which four homochiral alleno-acetyl

237 irality model with excitons localized on the arene scaffold, here generalized to Cn symmetry, accurat

238 al mass yield of 35.5 wt% and an exceptional arene selectivity of 71 wt%.

239 ,3-dimethoxybenzene and related methoxylated arenes show exclusively monomer-based orthometalations w

240 nium unit connected by a 1,2-vicinal calix[4]arene spacer was investigated in the transesterification

241 Moreover, arene substituents and substitution patterns that curren

242 e turnover with stoichiometric quantities of arene substrate and B2Pin2.

243 (2))-H activation, using a model macrocyclic arene substrate.

244 ver, it can be hampered by low reactivity of arene substrates and their availability.

245 The visible-light driven cyclometalation of arene substrates containing an N-donor heteroaromatic mo

246 ive derivatization of a broad range of vinyl arene substrates.

247 ability to arylate neutral and electron-poor arenes-substrates that do not react at all in the interm

248 The structures comprise a central stack of arenes surrounded by a triple helix of interconnected ar

249 release is the rate-determining step in the arene syn-dihydroxylation reaction taking place at Riesk

250 elated bidentate phenylurea dihomooxacalix[4]arenes, tetraphenylurea 4a is more preorganized and the

251 tive fluorination of biaryls is to couple an arene that already possesses C-F bonds in the desired lo

252 ew methods for the dearomatization of simple arenes that also selectively introduce functionality.

253 d nicely differentiated 1,2,3-trisubstituted arenes that are difficult to access by other catalytic r

254 e also describe the ability to functionalize arenes that are not oxidized by an acridinium catalyst,

255 is the most commonly used method to generate arenes that contain (18)F for use in positron-emission t

256 regioselectivity; this reaction occurs with arenes that have not undergone site-selective and stereo

257 mild and rapid method for the iodination of arenes that utilizes silver(I) triflimide as a catalyst

258 Hybrid [n]arenes, the class of medium-sized macrocyclic compounds

259 advances in the incorporation of (18)F onto arenes, the development of general and efficient approac

260 For the four tetra-O-substituted resorcin[4]arenes, the ECD exciton couplet at longer wavelength dep

261 oped for the photoinduced dearomatization of arenes through an intramolecular cycloaddition with aza-

262 ion induced haptotropic rearrangement of the arene to form ((iPr)PDI)Mo(NH3)2(eta(2)-C6H6).

263 gOPiv ligated by a phosphine reacts with the arene to form an arylsilver(I) species, presumably throu

264 f a perfluoroarene and C-H bond of the other arene to provide an expedient route to multifluorinated

265 Tethering of the arene to the arylsilane provides not only a tool to prob

266 talyze the dehydrogenative coupling of vinyl arenes to afford predominantly (E,E)-1,4-diaryl-1,3-buta

267 eratures that allows the direct amination of arenes to be completed within 3 min at 90 degrees C.

268 A broad range of monomers, from simple arenes to complex functionalized heteroarenes, can now b

269 tes the C-H functionalization of unactivated arenes to form the biaryl products.

270 oanthracene and a variety of bis(arylethynyl)arenes to give polymers with molecular weights (Mn) of 9

271 e direct oxidative coupling of electron-rich arenes to the alpha-position of carbonyl functionality o

272 ylarenes, thereby allowing the conversion of arenes to trifluoromethylarenes.

273 radicals with high electron affinity elicit arene-to-radical charge transfer in the transition state

274 tion metal-free couplings of haloarenes with arenes, triggered by the use of alkali metal alkoxides i

275 2-a]pyrimidin-4-ones with bromo/iodo-(hetero)arenes under aqueous conditions has been developed.

276 sing 1,4-diketones as surrogates to strained arene units.

277 talysts are reactive only with electron-rich arenes, unless an excess of arene is used, which limits

278 was also modified for the radioiodination of arenes using a one-pot procedure involving the in situ g

279 H borylation of a range of substituted alkyl arenes using B2Pin2 (Pin = pinacolate) as the boron sour

280 of a commercially important multifluorinated arene via a defluorination strategy and is significantly

281 Here we report the selective production of arenes via direct hydrodeoxygenation of organosolv ligni

282 mers of pentahydroxy-functionalized pillar[5]arenes via the deprotection of their benzylated derivati

283 yl substituted alkene products via oxidative arene vinylation.

284 The bis(arylethynyl)arenes were composed of benzene, thiophene, or thieno[3,

285 The methoxy-resorcin[5 and 6]arenes were quantitatively demethylated by treatment wit

286 both cyclopropanation and ring expansion of arenes were rendered reversible.

287 The threading of the calix[5]arene wheels with the asymmetric pentylbenzylammonium ax

288 within the cavity of the trinuclear pillar[5]arenes, which is different to the host-guest behavior of

289 ydroxyl groups of C-propan-3-ol pyrogallol[4]arene with adjacent hexameric capsules via nickel-hydrox

290 of AgOPiv to afford the linear (E)-allylated arene with excellent regioselectivity; this reaction occ

291 survey of >40 benzenoid- and pyridine-based arenes with a range of substituents demonstrates the eff

292 alogenated (hetero)arenes and simple (hetero)arenes with active C-H bonds, thereby circumventing the

293 the palladium-catalyzed direct allylation of arenes with allylic pivalates in the presence of AgOPiv

294 ys a visible-light-mediated cycloaddition of arenes with an N-N-arenophile and in situ diimide reduct

295 s have reported the arylation of unactivated arenes with ArX, base (KO(t)Bu or NaO(t)Bu), and an orga

296 ra cross-coupling reaction of perfluorinated arenes with aryl boronate esters using NHC nickel comple

297 Only arenes with electron-withdrawing substituents can suffic

298 The catalytic C-H borylation of arenes with HBpin (pin = pinacolate) using POCOP-type pi

299 the C-H silylation of electron-rich (hetero)arenes with hydrosilanes.

300 ic conformational properties of cone calix[4]arenes with orientable groups at the upper rim were thor

301 opic exchange of benzene and monosubstituted arenes with weakly activating groups reveal analogous di