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1 ligand such as amide, cyclopentadienide, and aryloxide).
2 ke 1, catalysts containing ortho-substituted aryloxides, 2, do not give a strictly statistical distri
3 ination number of Zr is restricted to six in aryloxides 4 and 5, while seven-coordination is achieved
4 e process involving an enantiomerically pure aryloxide, a class of ligands scarcely used in enantiose
5 how that simple uranium complexes UX(3) (X = aryloxide, amide) spontaneously disproportionate, transf
6 (1)H NMR spectroscopic investigations of the aryloxide analogue La(2)(OAr)(6) (4) show that the bridg
7 of loss of the two possible leaving groups, aryloxide and hydroxamate, are essentially the same as t
8 ated Lewis pairs (FLPs) based on zirconocene aryloxide and phosphine moieties that exhibit a broad ra
9 e, carbene, amide, imide, nitride, alkoxide, aryloxide, and oxo compounds, 4) describes advances in t
11 the potassium salt of the uranium(III) tetra(aryloxide) anion, K[U(OAr)(4)], as a result of ligand re
12 have Ad groups at the ortho positions of the aryloxide arms is sufficient to stabilize a C(3v)-symmet
13 he equatorial plane (as defined by the three aryloxide arms of the ligand) in order to accommodate th
16 chanistic experiments revealed that iron bis(aryloxide) catalysts initiate polymerization with one al
20 ies of this analogous series of uranium tris-aryloxide complexes supported by triazacyclononane are d
22 ionic metathesis to form the anticipated bis(aryloxide) complexes Ar'Bi(OC(6)H(3)Me(2)-2,6)(2) (2) an
24 nd a dark-orange complex containing only one aryloxide-derived ligand bound via a Bi-C and not a Bi-O
26 )(6) (4) show that the bridging and terminal aryloxide groups exchange by a mechanism in which the di
27 de (MAP) complexes that contain OHIPT as the aryloxide (hexaisopropylterphenoxide) are effective cata
28 "small" imido (Ad = 1-adamantyl) and "large" aryloxide (HIPTO = O-2,6(2,4,6-i-Pr(3)C(6)H(2))C(6)H(3))
29 denum that contain a chiral bitetralin-based aryloxide ligand are efficient for ethenolysis of methyl
30 (ROM) of COE is due to the large size of the aryloxide ligand, which forces both the alkylidene and t
32 n of the methoxy C-H bond, followed by alpha-aryloxide migration to give cis-(PCP)Ir(H)(CH2)(OAr), fo
33 gh Z-selectivity is achieved because a large aryloxide only allows metallacyclobutanes to form that c
34 upies six coordination sites, with the three aryloxide pendant arms forming a trigonal plane at the m
35 monomeric LaX(3) (X = OPh or NHPh) with the aryloxide pi-arene interaction being stronger than the a
37 ity of the different species to the alkoxide/aryloxide ratio, the compounds were determined to be mix
38 has a similar absolute activity, though the aryloxide-rich catalysts are significantly longer-lived.
39 ips for a series of pseudotetrahedral Co(II) aryloxide, siloxide, arylthiolate, and silylthiolate com
41 methyl- and neopentyl (nP)-substituted tris(aryloxide) U(III) complex [(((nP,Me)ArO)3tacn)U(III)] (1
42 is exhibited by the well-known uranium tris(aryloxide) U(ODtbp)(3), U(OC(6)H(3)-Bu(t)(2)-2,6)(3), an
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