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1 of three C-O bonds, and the generation of an asymmetric center.
2 here the R(1) or R(2) side chain in 7 has an asymmetric center.
3 bility to stereochemically differentiate the asymmetric center.
4 transformations to incorporate the remaining asymmetric centers.
5 stereoselective installation of the desired asymmetric centers and confirms the stereochemistry of t
6 m alpha-amino acids, affords imidazoles with asymmetric centers appended to N-1 or C-5 with excellent
7 s key step, cylobutanes with four contiguous asymmetric centers are generated with a high level of st
8 of poly-N-vinylpyrrolidinones containing an asymmetric center at C5 of the pyrrolidinone ring were s
9 folate (10-HCO-DHF), which no longer has the asymmetric center at carbon-6 and is metabolized by amin
10 ino acids in natural proteins have a chiral, asymmetric center at the alpha carbon that is of the L-c
11 sults in the stereoselective induction of an asymmetric center at the spiro carbon to give a mixture
12 ontrol has been employed to generate the key asymmetric centers at C(15), C(16), and C(20) in alkaloi
13 n strategy is based on the production of all asymmetric centers by selective placement of the oxygen
15 relative stereochemistry at five contiguous asymmetric centers can be controlled through the choice
16 mine whether the chirality of the amino acid asymmetric centers could influence the solution structur
18 The configuration of the newly created 5' asymmetric center has been unambiguously assigned by X-r
22 he polycyclic caged ketal 3, containing nine asymmetric centers, is prepared in 14 steps from alpha-D
24 ch to the synthesis of indolines bearing two asymmetric centers, one of which is all-carbon and quate
25 tereoisomers that incorporate two contiguous asymmetric centers, one tertiary and one an all-carbon-a
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