ライフサイエンスコーパス: atom

1 edict the structure of a 10 nm Cu NP (158555 atoms).

2 best overlap with the wavefunction around an atom.

3 (QWM) on a single superconducting artificial atom.

4 ingle step with a base-stabilized phosphorus atom.

5 through interaction with the carbonyl oxygen atom.

6 for oxidation reactions on single supported atom.

7 ost precise measurement performed on an anti-atom.

8 d by methylation of deoxyadenosine at the N1 atom.

9 efficiencies from 0.442-0.637 kcal/mol/heavy atom.

10 short Pd-Cu bond and a trigonal ipso carbon atom.

11 bound to an antiproton, is the simplest anti-atom.

12 triplet excited saccharin moiety and sulfur atom.

13 membered chelation complexes with the iodine atom.

14 o low-lying acceptor orbitals on the central atom.

15 ctance and the adsorption energy of hydrogen atoms.

16 ely 1,300 proteins with altogether 4 million atoms.

17 -atom RMSD by directing fewer than 1% of its atoms.

18 hundred ensembles, each containing a billion atoms.

19 yields, which can be promoted by core heavy atoms.

20 nteract almost symmetrically with both boron atoms.

21 reventing inward diffusion of the surface Au atoms.

22 cessary to determine the 3D positions of all atoms.

23 of covalently coordinating to eight silicon atoms.

24 ed and surrounded by sp(3)-hybridized carbon atoms.

25 electrons from the d yz orbitals of the iron atoms.

26 rehybridization of one of the alkyne carbon atoms.

27 platinum metal center and the surface oxygen atoms.

28 and violation of dipolar selection rules in atoms.

29 effects in microwave optics with artificial atoms.

30 termediate or nitrate on single supported Pd atoms.

31 st recently, magnetic data storage in single atoms.

32 e with the 6p x/y orbitals of surrounding Bi atoms.

33 )C chemical shifts for carbons bearing heavy atoms.

34 om different atomic configurations for these atoms.

35 ross the phase transition in large arrays of atoms.

36 the interface Si atoms to the neighboring B atoms.

37 m, transform these to a bright source of MeV atoms.

38 From a starting number of 2000 atoms, 1400 atoms reach quantum degeneracy in 300 millis

39 of epidermal keratins 1 and 10, based on all-atom 3D simulations of keratin primary amino acid sequen

40 olamide units was increased from four carbon atoms (4-LICAM(4-)) to five, six and eight (5-, 6-, 8-LI

41 The pi-trajectory for H atom abstraction (Fe(IV) horizontal lineO oriented perpe

42 d in the presence of this cluster both via H-atom abstraction and oxygenation with approximately 50%

43 ygen scavenging, electron transfer, hydrogen atom abstraction and radical adduct formation.

44 r)PDI)Mo(NH3)2(eta(2)-C2H4) enabled hydrogen atom abstraction and synthesis of a terminal nitride fro

45 3 is also formed via H-atom abstraction from the corresponding mu-1,1-hydropero

46 Formal hydrogen atom abstraction from the nitrogen-hydrogen bonds in pur

47 the reaction that is initiated by a hydrogen atom abstraction reaction, which enables a keto-enol tau

48 ate radicals, allowing their first use for H atom abstraction.

49 ts from a single release of the trapped anti-atoms accumulated from five consecutive cycles.Antihydro

50 the concurrent reconfiguration of In and Se atoms across the layers.

51 Hydrogen atom adsorption is the major driving force for this phas

52 nucleophilic substitution at an sp(2) carbon atom, allows the direct regioselective incorporation of

53 interaction between an electrophilic halogen atom and a Lewis base, with highly preorganized and conf

54 hly directional attraction between a halogen atom and an electron donor has been exploited in knowled

55 induced isomer the distance between hydrogen atom and carbon atom to which it migrates in the result

56 formed bound residues contained one nitrogen atom and had a molecular mass between 375 and 525 Da, wh

57 ribed so far, does not bind to the heme iron atom and has a novel binding mode.

58 rption of water via the electron-deficient H atom and the subsequent dissociation of the electron-ric

59 WCNT/Cu interface by reaction of diffused Cr atoms and amorphous carbon of MWCNTs would assist in imp

60 Laser cooling and trapping of atoms and atomic ions has led to advances including the

61 iety of physical systems including ultracold atoms and molecules in optical lattices, Josephson junct

62 f the light from the star is absorbed by the atoms and molecules in the planet's atmosphere, causing

63 nal laser source, the radiation lifetimes of atoms and molecules in these "universes" depend strongly

64 spectroscopy to explore electron dynamics in atoms and molecules.

65 s, with valence electrons separated from all atoms and occupying interstitial regions.

66 dation has contributions from both single Pd atoms and Pd particles.

67 focused mainly on the individual response of atoms and small molecules using soft X-rays with much lo

68 g each surface, leading to the removal of Ag atoms and the formation of covalently bonded zigzag poly

69 en the electrophilic and nucleophilic carbon atoms and the structure of the phosphorus moiety.

70 relation between the amount of charge on the atoms and their catalytic activity.

71 rs as a function of the number of metal core atoms and thiolates on the nanocluster shell.

72 with average elemental concentration of 0.4 atom% and 5 atom%) is mapped within the gold samples.

73 luding the nonbonded, bonded, cationic dummy atom, and combined models), polarizable models (e.g., th

74 reactions of unsaturated hydrocarbons with O atoms, and (b) on the very detailed dynamics of the abst

75 homo- and heteroarenes, rings of five to six atoms, and a variety of fluorine, bromine, and hydride l

76 ility, which benefits from a large number of atoms, and accuracy, which suffers from density-dependen

77 e visualization of the positions of hydrogen atoms, and computation to characterize the catalytic mec

78 material consists of a complex array of meta-atoms, and direct demonstration of image processing is c

79 contains a boroxinate core with three boron atoms, and these have proven to be effective catalysts f

80 ire spatially controlled interaction between atoms, and we propose an architecture that might take ad

81 rameters to the 4f states of encapsulated Gd atoms are discussed.

82 arent dioxygenase activity where both oxygen atoms are donated to a substrate.

83 ion sources, quantum dots, colour centres or atoms are fundamentally different in their frequencies a

84 Single bonds between carbon atoms are inherently challenging to activate using trans

85 This demonstrates that the atoms are predominantly coupled by the magnetic dipole-d

86 usly, we have found that single supported Pt atoms are remarkable NO oxidation catalysts.

87 tion in ReS2x Se2(1-x) alloy, where S and Se atoms are selectively occupied at different X sites in e

88 In this work, individual Ar atoms are trapped at 300 K in nano-cages consisting of (

89 The atoms are trapped in a two-dimensional optical lattice t

90 nd contacts, and hydrogen bonds and specific atom-aromatic ring (cation-pi, donor-pi, halogen-pi, and

91 This interaction is characterized by linear atom arrangement, with carbonyl O atom positioned on the

92 ation of the butadiene ligand to the element atom as it is typical for zirconocene or hafnocene butad

93 osed based on the incorporation of a [(13)C] atom at position 1 in specific amino acids.

94 utron irradiated to 9 dpa (displacements per atom) at approximately 1440 degrees C, began transformin

95 of the microscopic state, including dynamic atom-atom correlations in the superfluid state, are not

96 ins, at the same time, no less than twenty H-atoms available for either alpha- or beta-hydride elimin

97 les in deep ground states are localized on N atoms axially bonded to Mg acceptors.

98 nique to achieve a new sensitivity limit for atom-based, absolute radio-frequency electric field sens

99 ic waves, and also with electron, neutron or atom beams.

100 The single-atom bit represents the ultimate limit of the classical

101 isolated that differ in the number of copper atoms bound to the BB unit.

102 tom designs where the approximation for meta-atoms breaks down.

103 onalization of one of the boron-bound oxygen atoms by a second electrophile.

104 d upon substituting the transferred hydrogen atoms by deuterium, indicating that the process is gover

105 ple of the transmutation of Al atoms into Si atoms by electron donation.

106 This allowed the atom-by-atom fabrication of isolated platinum deposits,

107 l vector of 2.74-2.75 A and an intense light-atom (C/N/O) scattering interaction 1.8 A from the Fe.

108 prepared via pyrolysis are promising single-atom catalysts but often also comprise metallic particle

109 s of the entropic uncertainty relation of an atom-cavity interacting system under a bosonic reservoir

110 at they are derived from only a single heavy atom change in the structure.

111 und to be true geometric minima, with the He atoms clearly located in the first shell around the acti

112 num deposits, ranging from single atoms to 9-atom clusters.

113 ha,beta-unsaturated esters acting as a three-atom component to construct indoline units in a highly r

114 The in situ generated aryne acts as a two-atom component, and gamma-amino-alpha,beta-unsaturated e

115 ay crystallography, in which the triazolo N1 atom coordinates in a hitherto unreported monodentate in

116 The atom counts in core-shell structure of Au279 follows the

117 osphere, indicating the presence of active O atoms, crucial for oxidation catalysts.Improving platinu

118 we investigate in-plane centrosymmetric meta-atom designs where the approximation for meta-atoms brea

119 erate resolution makes accurate placement of atoms difficult.

120 Here, we present an NMR-guided all-atom discrete molecular dynamics (DMD) platform, iFoldNM

121 mpared to its oxygen counterpart, the sulfur atom displays a remarkable ability to interact with almo

122 The two-hydrogen atom donation process is frequently used to explain the

123 (Me)N2(amide)(Pr,Pr)](-) (8), shows that oxo atom donor reactivity correlates with the metal ion's ab

124 ly aligned two-dimensional layers and cobalt atoms doping demonstrated a high hydrogen evolution acti

125 e presence of Pd particles along with single atoms during CO oxidation experiments.

126 arting from simple anilines, representing an atom-economical preparation of an important class of org

127 Finally, this type of atom-economical rearrangement is envisioned to prompt th

128 e reactions are redox-neutral and completely atom-economical, exhibit broad functional group toleranc

129 r transition-metal-free conditions offers an atom-economical, inexpensive and environmentally benign

130 CH4 and CO2 is an ideal reaction with 100 % atom economy, but it is almost impossible by thermal cat

131 titutes the first example that connects high atom-efficiency C-H/C-H green catalysis with dye-sensiti

132 lly enhanced freedom of motion of the iodine atoms enables large deformations.

133 itals than for the Ag 4d(10) orbitals, Cu(I) atoms energetically favor 4-fold coordination, forming [

134 compact cluster consisting of few than three atoms energetically prefers a face-centered-cubic stacki

135 An atom-environment complexity measure, CA, to assess local

136 mperatures), these samples showed reduced Fe atom exchange (9-30% at pH 7) and inhibited secondary mi

137 mposed of a near linear arrangement of donor atoms, exhibits a large energy barrier to spin reversal

138 round-state methane (and isotopologues) with atoms (F, Cl, O) and diatoms (OH), with inclusion of als

139 This allowed the atom-by-atom fabrication of isolated platinum deposits, ranging

140 he relative energies of the spin states of O atom, Fe(2+) ion, and FeF2 and characterizes their excit

141 X(-) + RY with X and Y denoting the halogen atoms fluorine, chlorine and iodine.

142 erivatives with a redox-inactive coordinated atom follow the Gouterman four-orbital model.

143 An oxygen adatom and a vicinal Co-atom form a metal-oxygen site-pair that cleaves the C-H

144 The oxygen atoms form a bridged between MoSx and GO and play a cruc

145 atter-wave interference, haloes of scattered atoms, four-wave mixing and correlations between counter

146 hanism begins with abstraction of a hydrogen atom from C-4 (or possibly C-3) initiating the desaturat

147 through the group transfer of both P and Cl atoms from chloro-substituted dibenzo-7lambda(3) -phosph

148 ectrometry to analyze the fate of individual atoms from stable isotope-enriched precursors to product

149 plex 2, while 3 itself is able to abstract H-atoms from weaker X-H bonds such as TEMPO-H to re-form 2

150 activities of a variety of single supported atoms, however, the single supported atoms on inert subs

151 vestigated the quantum motion of an impurity atom immersed in a strongly interacting one-dimensional

152 ond while the oxygen abstracts the leaving H-atom in a concerted, four-center (H3C...*...H...O*)() tr

153 pic positional accuracy associated with each atom in a crystal structure determined by NMR crystallog

154 ics simulations calculate the motion of each atom in a protein based on classical approximations of i

155 etylene groups on either side of the central atom in this system.

156 The smaller fluorine atoms in [Fe(dftpy)2](2+) enable spin crossover with a T

157 demonstrate entanglement between millions of atoms in a solid-state quantum memory prepared by the he

158 ides of lanthanum can be synthesized with La atoms in an fcc lattice at 170 GPa upon heating to about

159 oordinates of 6,569 iron and 16,627 platinum atoms in an iron-platinum nanoparticle, and correlate ch

160 bstrates that have the transferring hydrogen atoms in close proximity, such as ortho-tetrachlorobenzo

161 theory (DFT), supported by quantum theory of atoms in molecules and natural bond orbital analysis.

162 By placing cold atoms in optical cavities and inducing strong coupling b

163 lacing stepwise the oxygen atoms with sulfur atoms in the carboxylate groups of sodium terephthalate

164 The rattling of guest atoms in the large cages results in a very low thermal c

165 clearly resolved together with the heavy La atoms in the reconstructed phase.

166 pressure on the breakdown of the ordering of atoms in the solid.

167 group fragments based on the number of (13)C atoms incorporated during derivatization.

168 ne protein structure-the ionization of heavy atoms increases the local radiation damage that is seen

169 mental mercury due to reactions with halogen atoms, influencing atmospheric composition and pollutant

170 *...H)() transition state, during which a Ni-atom inserts into the C-H bond and donates its electron

171 , which is a product expanded by one arsenic atom, instead of the expected complex [(Cp(Bn)Fe)2(mu,et

172 uccessful example of the transmutation of Al atoms into Si atoms by electron donation.

173 Intercalation, the insertion of guest atoms, ions or molecules between the atomic layers of a

174 hotochemical reactivity of a specific carbon atom is modified as a result of the presence of the exci

175 pating group of glycosyl donors by a halogen atom is shown to specifically induce degradation of tran

176 iron(V)oxo units (Fe(V)O), wherein the iron atom is two oxidation equivalents above the Fe(III) rest

177 exacoordinate environment around the silicon atoms is given by (29)Si nuclear magnetic resonance anal

178 sense that the mean squared displacement of atoms is not limited.

179 m based on size adjustment of the basic meta-atoms is proposed for ultra-wideband manipulation of ele

180 In this Perspective, the "necessary nitrogen atom" is shown to be a versatile high-impact design elem

181 elemental concentration of 0.4 atom% and 5 atom%) is mapped within the gold samples.

182 fects with material properties at the single-atom level.

183 s the lattice parameter as well as the basis atom locations in the unit cell.

184 omputational modeling performed with the all-atom MD simulations for Abeta(14-23) peptide shows that

185 d and pre-melted Ni NPs (Voter-Chen Embedded Atom Method potential) indicate a common dynamic heterog

186 Theoretical calculations on H-atom migration reactions are presented to rationalize th

187 or these five DNA nanoparticles and with all-atom molecular dynamics simulations for the tetrahedron

188 In this communication, we used all-atom molecular dynamics simulations to investigate the s

189 We use transition networks derived from all-atom molecular dynamics simulations to show that the oli

190 Massive all-atom molecular dynamics simulations were conducted acros

191 free energy perturbation method based on all-atom molecular dynamics simulations, can provide accurat

192 Using all-atom molecular dynamics simulations, we characterized th

193 um conformational ensemble of BAK1 using all-atom molecular dynamics simulations.

194 cal properties of the OMs and OprH using all-atom molecular dynamics simulations.

195 Monomers (5 Si atoms/molecule) and dimers (10 Si atoms/molecule) domina

196 mers (5 Si atoms/molecule) and dimers (10 Si atoms/molecule) dominated the mass spectra of aerosols a

197 ile ring-opened species (neither 5 nor 10 Si atoms/molecule) dominated the mass spectra of aerosols a

198 iffering time scales for proton versus heavy-atom motion.

199 ntially bearing three all-saturated nitrogen atoms (N-N-N motif).

200 up to two bonds in length emanating from an atom node.

201 Alternatively, the single-atom, O-to-S modification of peptide backbone thioamidat

202 crease in water uptake is a result of oxygen atoms occupying the vacancies in the hydrophilic exfolia

203 modifying the protein backbone at the Calpha atom of a Pro residue to produce 2-hydroxyproline (2-Hyp

204 SAM binds to the unique iron atom of a site-differentiated [4Fe-4S] cluster and is re

205 is laser excitation of a quantum state of an atom of antimatter represents the most precise measureme

206 re to demonstrate that the 6'-pro-R-hydrogen atom of GenX2 is stereoselectively abstracted by the 5'-

207 tary reactions with methane where the carbon atom of the product is oxidized and has a FOS less negat

208 lyzed by acids via the protonation of oxygen atom of the sulfonamide group.

209 thiolation reactions by donating the sulfur atom of their exclusive cysteine residues to the substra

210 rives from lone pair electrons on the oxygen atom of water molecules.

211 the 1S-2S transition in magnetically trapped atoms of antihydrogen.

212 l mode of H2 activation, in which the Si(II) atoms of the [Si(II)(Xant)Si(II)] ligand are involved in

213 mine building block that contains all carbon atoms of the D and E ring of the natural product could b

214 the van der Waals bonding between the sulfur atoms of the quintuple layers.

215 es (R)- or (S)-30, which contain the C11-C13 atoms of the target, to provide diastereomeric diketones

216 pported atoms, however, the single supported atoms on inert substrates (e.g. alumina) are limited to

217 ssion electron microscopy can identify metal atoms on protein only if the protein structure is solved

218 ifferent geometric configurations of surface atoms on supported metal nanoparticles have different ca

219 Even though sulfur atoms on the basal plane are known to be stable and iner

220 The introduction of chlorine atoms on the indole ring of malbrancheamide differentiat

221 oupling between light and excitations of the atoms, one can experimentally study phase transitions of

222 and synthesized by introducing fluorine (F) atoms onto the end-capping group 1,1-dicyanomethylene-3-

223 ed by a sequential abstraction of a hydrogen atom or proton-coupled electron transfer.

224 NMR and DFT calculations, that the chalcogen atoms oriented within the macrocycle cavity are able to

225 unneling of electrons into vibrating surface atoms, phonon oscillations can be observed on the atomic

226 by linear atom arrangement, with carbonyl O atom positioned on the three-fold symmetry axis of the N

227 ribbons of ultimate width, they are valuable atom-precise model systems for studying the properties o

228 ulations, we have demonstrated that hydrogen atoms preferentially occupy substitutional positions rep

229 inatively unsaturated gold atoms, two oxygen atoms preferentially share a gold atom with a bond dista

230 d (18) O2 unambiguously show that the oxygen atoms present in the Mn(IV) dimers originate from O2 .

231 te the origin of the highest (240)Pu/(239)Pu atom ratio of 0.293 +/- 0.028 we found close to FDNPP.

232 From a starting number of 2000 atoms, 1400 atoms reach quantum degeneracy in 300 milliseconds, as c

233 with tantalum vapor in a sophisticated metal-atom reactor.

234 ins containing between three and 21 fluorine atoms readily polymerize under controlled conditions.

235 us Se relates to the relative fraction of Se atoms residing in infinity1Se chains versus in Se8 rings

236 deling of electrostatic forces on individual atoms, residues, domains and molecules, and generates an

237 )Pr)2) (2), undergoes insertion of chalcogen atoms resulting in a series of thorium chalcogenolate co

238 roach goal conformations to within a low all-atom RMSD by directing fewer than 1% of its atoms.

239 entally determined structures with all-heavy-atom RMSDs ranging from 2.4 to 6.5 A.

240 , which is only identified due to the single atom sensitivity of APT.

241 according to our observations, dominates for atom separations greater than 1 nm.

242 ts show that this species is proximate to Al atoms, similar to the Bronsted acid site proton.

243 bination of coarse-grained "Martini" and all-atom simulations are used to identify two, to our knowle

244 All-atom simulations cannot reach the timescales relevant to

245 d subsequent trapping with either a hydrogen atom source (PhSiH3 ) or an electron-deficient olefin.

246 new distance- and orientation-dependent, all-atom statistical potential derived from side-chain packi

247 h as methyl transfer to electrophilic carbon atoms, sulfur to Calpha atom thioether bonds, or carbon-

248 rol and precision that is achievable in cold-atom systems.

249 revealed disordered vacancies of the same Ce atoms that were modulated in the first domain type, lead

250 n proceeds by H2O(+) abstracting a surface O-atom, then forming an excited precursor state, which dis

251 re colloidal synthesis of single-layer, five-atom-thick, beta-In2Se3 nanosheets with lateral sizes tu

252 electrophilic carbon atoms, sulfur to Calpha atom thioether bonds, or carbon-carbon bond formation.

253 uclear copper cluster to N2O via a single Cu atom to accomplish N-O bond cleavage.

254 zonitrile (2) substituting its para-fluorine atom to form 2-(4-cyanotetrafluorophenyl)-4,4,5,5-tetram

255 t involves coordination of the substrate's N-atom to haem-Fe(II) with electron transfer and concomita

256 polyatomic molecules that contain one heavy atom to ultra-intense (with intensities approaching 10(2

257 he distance between hydrogen atom and carbon atom to which it migrates in the result of the sigmatrop

258 lated platinum deposits, ranging from single atoms to 9-atom clusters.

259 By introducing two sulfur atoms to a single carboxylate scaffold, the molecular so

260 is study spans different spatial scales from atoms to cells by combining X-ray crystallography with e

261 disordered packings of objects ranging from atoms to grains, spanning seven orders of magnitude in d

262 transfer occurs mainly from the interface Si atoms to the neighboring B atoms.

263 c data are consistent with metal-mediated Cl atom transfer as the predominant pathway enabling dual C

264 Oxygen atom transfer by high-valent enzymatic intermediates rem

265 e reaction cycle and is followed by hydrogen-atom transfer from the CE1-H group of trimethyl histidin

266 n(II) vs. Fe(III)3 Mn(II) ) influence oxygen atom transfer in tetranuclear Fe3 Mn clusters.

267 rom the thermodynamic point of view hydrogen atom transfer is the preferred mechanism in the reaction

268 idyl methacrylate (GMA) by surface initiated atom transfer radical polymerization (SI-ATRP) and hexam

269 surface-initiated electrochemically mediated atom transfer radical polymerization (SI-eATRP).

270 mer was synthesized and chain extended using atom transfer radical polymerization from the model prot

271 essing CT states for photoredox catalysis of atom transfer radical polymerization lies in their abili

272 of mer-(ONO(Q))Re(V)O2(IMes) in this oxygen atom transfer reaction.

273 istal metal site leads to a change in oxygen atom transfer reactivity by ca. two orders of magnitude.

274 Thus, oxygen atom transfer takes place preferentially by direct reduc

275 the oxorhenium(VII) moiety (classical oxygen atom transfer) rather than through initial internal elec

276 ms such as single electron transfer, halogen atom transfer, and sigma-bond methatesis.

277 a competent oxidant in an intermetal oxygen atom transfer, C-H bond activation and olefin epoxidatio

278 sis characterized by intramolecular hydrogen atom transfer, radical fluorination, and ultimate restor

279 ns, and provides clear evidence for hydrogen atom tunneling in the H-isotopologue.

280 In this way, we discovered the heavy-atom tunneling reaction involving spontaneous ring expan

281 he results are interpreted in terms of heavy-atom tunneling.

282 urfaces with coordinatively unsaturated gold atoms, two oxygen atoms preferentially share a gold atom

283 The rapid agglomeration of Pd atoms under CO oxidation conditions even at 6 degrees C

284 Moreover, the artificial atom visualises photon-state statistics, distinguishing

285 struction of a LaB6 crystal in which light B atoms were clearly resolved together with the heavy La a

286 ifiable Lewis acids centered on the nitrogen atom, which provide stable and well-characterized adduct

287 of percolation clusters formed by subsets of atoms, which can have important consequences for structu

288 two oxygen atoms preferentially share a gold atom with a bond distance of 0.194-0.196 nm and addition

289 ength and duration of the interaction of the atom with different neighbours.

290 nced compared to that of an individual heavy atom with the same absorption cross-section.

291 ar gas-phase reaction of ground-state carbon atoms with 1,3,5-cycloheptatriene (C7 H8 ) on the triple

292 al to simultaneously interrogate millions of atoms with a high spectroscopic quality factor of 4 x 10

293 additionally bind to two other surface gold atoms with a larger bond distance of 0.203-0.213 nm, for

294 erators, to convert the fast ions to neutral atoms with little change in momentum, transform these to

295 actions and heterogeneous catalysis of metal atoms with low coordination numbers, such as found at at

296 tic transportation of Rubidium ((87)Rb) cold atoms with minimal loss and heating with as few as three

297 oxidation products with 2-6 catenated sulfur atoms with or without oxygen insertion, which accumulate

298 es obtained by replacing stepwise the oxygen atoms with sulfur atoms in the carboxylate groups of sod

299 e, the CO is coordinated to the heme a3 iron atom, with a bent Fe-C-O angle of approximately 142 degr

300 ne precursors, the connectivity of a silicon atom within the network extends beyond its chemical coor