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1 as volatile (non-polar) VOC molecules (i.e., benzene).
2 id glass processed from 1,3,5(triethoxysilyl)benzene.
3 oximity to gasoline stations and exposure to benzene.
4 r in situ reductive dechlorination of MCB to benzene.
5 mination sequence starting from 2-fluoro-SF5-benzene.
6 termediate that is more highly oxidized than benzene.
7 best practices should include monitoring for benzene.
8 tadiene (OR = 3.15; 95% CI: 1.57, 6.32), and benzene.
9 degradation of daughter products, especially benzene.
10 shown to undergo an arylation reaction with benzene.
11 affinity for Ab dropped only slightly versus benzene.
12 ated for the production of benzaldehyde from benzene.
13 dent chemical shift value lower than that of benzene.
14 henylethynyl bromide or 1,4-bis(bromoethynyl)benzene.
15 ith very low level exposure to environmental benzene.
16 he reactions of MeTAD with other substituted benzenes.
17 ve hindered their application to substituted benzenes.
18 ed hydroxylations and nitrohydroxylations of benzenes.
19 lco sparverius) were exposed to a mixture of benzene (0.6 ppm), toluene (1 ppm), nitrogen dioxide (NO
20 VOCs studied here include aromatics such as benzene (1.03 pptv/ppbv CO), toluene (3.10 pptv/ppbv CO)
23 (HCO2)6] secondary building units (SBUs) and benzene-1,3,5-tribenzoate (BTB) bridging ligands is repo
24 2.5 mol %), both possessing a complementary benzene-1,3,5-tricarboxamide (BTA) central unit, were in
25 between two slightly structurally different benzene-1,3,5-tricarboxamide (BTA) monomers functionaliz
26 ation of different disc-shaped cores such as benzene-1,3,5-tricarboxamides (BTAs), perylenes bisimide
27 ing structure and disorder for four columnar benzene-1,3,5-trisamides by total X-ray scattering and D
28 AB = 4-aminobenzoate), which was linked with benzene-1,4-dialdehyde using imine condensation reaction
30 ation of a new MOF [Yb2(BDC)3(DMF)2]H2O (BDC=benzene-1,4-dicarboxylate and DMF=N,N-dimethylformamide)
34 of homoleptic Ta(0) complexes are known, Ta(benzene)2 and Ta(dmpe)3 , dmpe=1,2-bis(dimethylphosphano
35 he P2X antagonist pyridoxal phosphate-6-azo (benzene-2,4-disulfonic acid (PPADS) but not by the 5-HT3
36 Here we show that phenanthrene, a PAH with a benzene 3-ring structure, is the key moiety disrupting t
38 es is higher for diesel BC (62-85%) than for benzene (38-71%), reflecting the difference in these pol
39 utyldibenzo[d,h][1,3,6,2]dioxazaboronin-6-yl)benzene (4), as well as the free ligand 2-[[(3,5-di-tert
40 parent absence of aromatic compounds such as benzene, a lack of sulfur-bearing species, and very low
41 res and jobs have 1 common chemical exposure-benzene, a recognized cause of acute leukemia in adults-
42 e XB acceptor, the association in deuterated benzene/acetone/methanol 70:30:1 at 283 K reaches Ka =(2
43 OO)(L)], (H3btb = 1,3,5-tris(4-carboxyphenyl)benzene acid, L = methanol, water, or ethanol), has been
44 nation if exposed to H2 at 1 atm pressure in benzene, affording the silane borane 5-H2 , L(H2 )Si-R-B
45 is allowed to stand, clean conversion to the benzene analogue 3 occurs, and this complex may be preci
46 ine and pyridazine derivatives, close to the benzene analogues and significantly higher than thiophen
47 ff reaction between 1,3,5-tris(4-aminophenyl)benzene and 1,3,5-benzenetricarbaldehyde building blocks
48 On the other hand the systems with fused benzene and a six-membered ring formed atropisomers sepa
49 e studied by photoreaction of 1 in C6F6 with benzene and another substrate (HBpin, PhSiH3, or pentafl
50 alone is often insufficient: the carbons of benzene and cyclobutadiene, or those of diamond, graphen
54 pound Specific Isotope Analysis to determine benzene and monochlorobenzene (MCB) stable carbon isotop
55 Rate studies of the isotopic exchange of benzene and monosubstituted arenes with weakly activatin
57 to C2 (ethylene and acetylene) and aromatic (benzene and naphthalene) products, at the tested conditi
58 diarylethenes of furanone series containing benzene and oxazole derivatives as aryl residues has bee
59 ugh supramolecular chain collapse, to expose benzene and perfluorobenzene motifs that promote a hairp
62 ncer ancillary such as 2,6-diimidazolylidene benzene and the 6-pyrazolyl-2-phenoxylpyridine chromopho
66 oxidized by an acridinium catalyst, such as benzene and toluene, thus supporting a reactive amine ca
69 d included occupational and household use of benzenes and solvents, traffic density, and traffic-rela
70 mug/L (MTBE, BTEX, chlorinated ethenes, and benzenes) and 60-97 mug/L for delta(2)H (MTBE and BTEX).
72 e repair facilities may be another source of benzene, and in 3 studies assessing these sources, we id
73 stribution maps of, e.g., nitrogen monoxide, benzene, and oxygen concentrations were obtained at a ne
74 ix molecules), pi-ligands (alkenes, alkynes, benzene, and substituted benzenes), miscellaneous inorga
75 enzene at room temperature under hydrogen in benzene, and the turnover frequency (TOF) was higher tha
76 rated for regular and perdeuterated acetone, benzene, and toluene as well as toluene-(13)C7 in nitrog
77 3-butadiene (OR = 2.23; 95% CI: 1.28, 3.88), benzene, and toluene; and with IQR increases in exposure
78 ides rapid access to 1,2,3,4-tetraoxygenated benzenes, and has been exploited by application to the t
79 cal groups, that is, carbohydrates, phenols, benzenes, and lignin phenols, together accounting for 62
80 aromatic, rigid, sigma,pi-macrocyclic carbo-benzene archetypes of various substitution patterns, wit
82 al types of non-aromatic references of carbo-benzenes are then considered, i.e. freely rotating sigma
83 with a substituted 1,6-cyclodecadiyne using benzene as a solvent at room temperature as well as stud
85 the BN core, further endorsing the inorganic benzene as a versatile aromatic scaffold for engineering
86 alcium hydride-react with protio and deutero benzene at 60 degrees C through nucleophilic substitutio
88 hyl ketone (MEK), isobutyl alcohol (i-BuAl), benzene (B), toluene (T), p-xylene (p-X), m-xylene (m-X)
91 Since the discovery of the first "inorganic benzene" (borazine, B3N3H6), the synthesis of other nonc
92 s consisting of 1,4-bis[2-(4-pyridyl)ethenyl]benzene (BPEB) and PdCl2 of variable thicknesses (0-13.4
93 lamine redox centers that are connected to a benzene bridge via alkyne spacers at para- and meta-posi
94 d in para- or in meta-positions to a central benzene bridge, we investigated three series of mixed va
96 the branching ratio of SO4(*-) reacting with benzene, but inversely correlated with that of HO(*) or
97 second singlet excited states (S1 and S2) of benzene (C6H6) and square cyclobutadiene (C4H4) are inve
103 of the bis(imino)pyridine molybdenum eta(6)-benzene complex ((iPr)PDI)Mo(eta(6)-C6H6) ((iPr)PDI, 2,6
109 tion of MeOTf to 1 results in elimination of benzene concomitant with the formation of the phosphonio
110 om the market (n=170) further confirmed that benzene content is significantly correlated to the prese
111 NPA thermolysis in 1,3-cyclohexadiene and/or benzene-d6 are consistent with a model of unimolecular f
112 eters, i.e., alkalinity, pH, and chloride on benzene degradation via heterogeneous persulfate activat
113 ed the rates of persulfate decomposition and benzene degradation, which was associated with the forma
114 etized from 1,3,5-trihydroxybenzene or other benzene derivatives through dehydration and polymerizati
116 unts of monoterpenes, aliphatic alcohols and benzene derivatives, were released using pectinolytic pr
118 it to identify D-Cycloserine and furan-based benzene-derived compounds with known Mur ligase inhibiti
121 f two passive tracers--tetramethylsilane and benzene--dissolved in an organic solution of active Grub
122 t trapping of the cationic intermediate with benzene does not proceed via a Friedel-Crafts-type react
124 talytic system for the C-H bond arylation of benzene enables the formation of biaryl compounds in the
125 th extremely low dielectric constants (e.g., benzene, epsilon of 2.27, or cyclohexane, epsilon of 2.0
128 The direct and single-step conversion of benzene, ethylene, and a Cu(II) oxidant to styrene using
129 butadiene; TFA is trifluoroacetate] converts benzene, ethylene, and Cu(II) acetate to styrene, Cu(I)
130 aluated the association between occupational benzene exposure and NHL among 73,087 women enrolled in
136 e number of four-coordinate carbon atoms per benzene formula unit as the degree of saturation, a set
137 t with the rates of reductive elimination of benzene from a series of isoelectronic Ir(III) phenyl hy
138 ethane is lost with concomitant formation of benzene from an unstable phosphorus(V) intermediate, yie
139 so been associated with parental exposure to benzene, gasoline, motor vehicle-related jobs, painting,
140 derived from (3,3,3-trifluoroprop-1-yn-1-yl)benzene give access to functionalized ring-opening alkyn
142 f CoCl2 with 1,3,5-tri(1H-1,2,3-triazol-5-yl)benzene (H3BTTri) in N,N-dimethylformamide (DMF) and met
145 Recently, a direct arylation of unactivated benzene has been achieved in the presence of base (tBuOK
146 amended incubations confirmed that alkylated benzene hydrocarbons were metabolized via known anaerobi
147 rch on Cancer (IARC) working group evaluated benzene in 2009 and noted evidence for a positive associ
149 ble peripheral aromatic rings around central benzene in hexaarylbenzene (HAB) derivatives create a ve
151 the transient mixing dynamics of toluene and benzene in the fingerprint region (200-1500 cm(-1)) with
152 artitioning coefficients were determined for benzene in water/supercritical CO2 over the range 35-65
153 classical UV-vis electronic spectra of carbo-benzenes in solution (lambdamax = 445.5 +/- 1 nm, epsilo
154 dearomatization reagent TpW(NO)(PMe3)(eta(2)-benzene), in which the 1,3-dimethoxybenzene (DMB) analog
156 We observed a dose-dependent increase in benzene-induced chromosomal damage and estimated a bench
158 odine](+) and [1,2-bis((pyridine-2-ylethynyl)benzene)iodine](+) BF4(-) complexes substituted with ele
161 In contrast, the electron-rich pi-system of benzene is highly resistant to reactions with electron-r
162 hilic aromatic substitution of a C-H bond of benzene is one of the archetypal transformations of orga
163 between Naph(+*)(Pyr) and Bz(+*)(Pyr) (Bz is benzene) is understood by energy decomposition analysis.
164 H, H3BTTri =1,3,5-tris(1H-1,2,3-triazol-5-yl)benzene)), is found to be highly selective in the adsorp
165 hing features from its carbonaceous isostere benzene: its ability to serve as an NH hydrogen bond don
168 tered radicals has been achieved by treating benzene-linked allene-ynes with aryldiazonium tetrafluor
169 ](H2O) (L = 1,2,4,5-tetrakis(phosphonomethyl)benzene, Ln = La, Ce, Pr, Nd, Sm, Eu, Gd) have been synt
171 Flash vacuum pyrolysis of 1,3-bis-iodomethyl-benzene (m-C8H8I2) produces m-C8H8 in gas phase; we used
172 s, molecular units of alpha-graphyne ('carbo-benzene' macrocycles) can be inserted between two anilin
173 ecent victories in the C....._ C cleavage of benzene made possible by a four-pronged iridium gig that
174 pies for these compounds and caffeic acid in benzene, methanol, and water were used for thermodynamic
175 (alkenes, alkynes, benzene, and substituted benzenes), miscellaneous inorganic ligands, and biologic
177 in saturation of a one-dimensional stack of benzene molecules by enumerating the partially saturated
179 an convert polycrystalline or single-crystal benzene monomer into single-crystalline packings of carb
180 of terephthalaldehyde and tris(4-aminophenyl)benzene monomers on top of a poly(ether sulfone) (PES) u
181 zation of prochiral 1,3,5-tris(3-bromophenyl)benzene (mTBPB) directly on the surface using an Ullmann
182 racterization of p-dialkyl-tetraphenyl-carbo-benzenes (n = 2, 8, 14, 20) are thus presented and compa
183 n of (iii) cumene from its major impurities (benzene, n-propylbenzene, and diisopropylbenzene) highli
184 examples like molecular nitrogen and oxygen, benzene, naphthalene and their azaderivatives, porphyrin
185 ril tetramer backbone and terminal aromatic (benzene, naphthalene) sidewalls, to act as solubilizing
186 diene, indene, azulene, cycloheptatriene, or benzene, new families of porphyrin-like macrocycles were
187 urban enhancement emission ratios of TEX-to-benzene on a seasonal basis, two potential source signat
188 duced cyclization of 1,2-bis(2-phenylethynyl)benzene on Au(111) using scanning tunneling microscopy a
189 avity surface openings large enough to admit benzene on timescales congruent with known rates for ben
190 elaxometry experiments demonstrate that pure benzene or xylene confined in isoreticular metal-organic
191 hermore, the yields of two major products of benzene oxidation, i.e., phenol and aldehyde, were posit
192 e reactivity of soluble Fe(III) toward known benzene photooxidation products that include fumaric (tr
193 ature mediated by [bis(trifluoroacetoxy)iodo]benzene (PIFA) and N-bromosuccinimide (NBS) using cyanam
195 for two complementary PyC molecular markers, benzene polycarboxylic acids (BPCAs) and polycyclic arom
196 rsistent organic pollutants: polychlorinated benzenes, polychlorinated biphenyls, polychlorinated dib
197 t each of the four possible positions of the benzene portion of the 3-(3',4',5'-trimethoxyanilino)ben
198 ials, here we show that by using 1,3,5 silyl benzene precursors, the connectivity of a silicon atom w
199 n product is also obtained in the absence of benzene, presumably from a tricationic intermediate.
202 ric efficiency, as determined by the loss of benzene relative to the loss of persulfate, approached t
203 study introducing an Aspergillus strain for benzene removal and these results highlight that the dev
204 activity, substitutions at position 4 of the benzene ring A were associated with higher transcription
205 reas a new pathway yielding oxidation of the benzene ring after the cleavage of the piperazine ring (
206 model and an archetypal example of the para-benzene ring and are shown to be robust under a weak dis
207 5 to strengthen the interaction between this benzene ring and the agonist's quaternary ammonium (QA)
208 on the organic chemistry of an eta(2)-bound benzene ring are explored using the complex TpW(NO)(PMe3
209 arley straw adsorbent and pi* carbon atom in benzene ring attached to fluorine of levofloxacin was in
210 c transformations which include instances of benzene ring contraction to cyclopentadiene or the forma
211 ped coronene derivative in which the central benzene ring has been replaced by a borazine core is des
213 chiral open-shell hydrocarbon, in which one benzene ring is fused to [5]helicene, forming a phenalen
214 Introduction of a para-nitro group into the benzene ring of the diene enabled separation of the Z,E
215 on conditions, the central and most strained benzene ring of the p-terphenyl systems was susceptible
216 ion and excited state antiaromaticity of the benzene ring should be reflected in its photochemical re
217 a deamination reaction at position C4 of the benzene ring to substitute the amino group with an hydro
218 how heteroaromatic ring substitution of the benzene ring will change the odour percept of acetopheno
219 of aryl rings in the linkages to the central benzene ring, coupled with the presence of only one meso
222 hat noncovalent interactions with associated benzene rings (a simple model of aromatic amino acid sid
224 ndings demonstrate that directly linking the benzene rings of PIs with a single C-C bond is a viable
225 al calculations to explore how the fusion of benzene rings onto aromatic chameleonic units represente
226 rd pi-quartets or octets, enabling the outer benzene rings to adapt closed-shell singlet Clar pi-sext
227 somers with linear connectivity of the fused benzene rings to those with cis- or trans-bent connectiv
228 an even number of carbons (22, in six fused benzene rings), it is not possible to draw Kekule-style
229 irst examples of direct pi-stacking of carbo-benzene rings, with inter-ring distances very close to c
235 markably reactive, hydroxylating methane and benzene selectively at low temperature to form methanol
237 mined to be 0.05 wt % 1,4-bis(2-methylstyryl)benzene singlet fluorophore and 0.28 wt % Ir(3+), respec
239 activity studies indicated the importance of benzene substituted as 2- or 4-methyl, or 4-fluoro, and
241 nsive structure-activity relationship of the benzene-sulfonamide scaffold that yielded a series of hi
245 or the formation of phenol from oxidation of benzene (the *OH probe used), but a value of about 10 kJ
247 of the first pnictogen-silicon congeners of benzene, the triarsa- and the triphospha-trisilabenzene
248 The bis(arylethynyl)arenes were composed of benzene, thiophene, or thieno[3,2-b]thiophene moieties,
249 ing reaction between 4-fluoroiodobenzene and benzene through an outer sphere electron transfer pathwa
250 ar triangle (T) [L1 = 1,4-di(4-pyridylureido)benzene; tmen = N,N,N',N'-tetramethylethane-1,2-diamine]
253 ,N-diethylaniline, naphthalene, and even [D6]benzene to yield the compounds [Re2(CO)8(mu-H)(mu-eta(1)
255 roxies for oxygenated aromatics derived from benzene, toluene, and anisole) react at the air-water in
256 elta(2)H) of methyl tert-butyl ether (MTBE), benzene, toluene, ethylbenzene, and o-xylene (BTEX), and
257 matic compounds, including the BTEX mixture (benzene, toluene, ethylbenzene, and the regioisomers of
258 tream in a production plant for detection of benzene, toluene, ethylbenzene, and the three structural
259 ative to methane were determined for hexane, benzene, toluene, ethylbenzene, and xylene (BTEX compoun
260 atic hydrocarbon content (largely made up of benzene, toluene, ethylbenzene, and xylene (BTEX)) was a
261 (PN) (over 5.6 nm); black carbon (BC); NO2; benzene, toluene, ethylbenzene, and xylene (BTEX); carbo
262 land sediments caused by the introduction of benzene, toluene, ethylbenzene, and xylenes (BTEX) and e
263 exposed to vehicle emissions, with combined benzene, toluene, ethylbenzene, and xylenes (BTEX) conce
264 ds emissions between PFI and GDIs, including benzene, toluene, ethylbenzene, and xylenes (BTEX).
265 nd volatile organic compounds (VOCs, such as benzene, toluene, ethylbenzene, and xylenes, or BTEX), a
267 um (crude oil/fuel) often involve monitoring benzene, toluene, ethylbenzene, xylenes (BTEX), and styr
269 urements of CO2, CO, NOx, black carbon (BC), benzene, toluene, ethylbenzene-xylenes (BTEX), and size-
270 ganic compounds (four aromatic hydrocarbons (benzene, toluene, p-xylene, and styrene), six C2-C5 vola
272 works by auxiliary DCDPS/TCPP linkers (BTB = benzene tribenzoate, DCDPS = 4,4'-dicarboxydiphenyl sulf
273 OF consisting of Cu(II) centers connected by benzene-tricarboxylates (BTC) is prepared by thermoinduc
274 nyl-3,4-tetrahydroisoquinoline-1H-2-carbonyl)benzenes ulfonamide (30) exhibited a remarkable inhibiti
275 irm that benzaldehyde does indeed degrade to benzene under heating conditions, and especially in the
277 The AI confirms Clar's rule of disjoint benzene units in many cases, but corrects it in those ca
278 tic strategy starting from ortho-substituted benzene units to construct five-membered rings in this w
279 nvolves a change in the distance between the benzene units, which is common for azobenzene derivative
280 purposes, a comparably high contamination of benzene (up to 4.6mug/L) has been detected in cherry-fla
281 atistatin and (+)-7-deoxypancratistatin from benzene using an enantioselective, dearomative carboamin
282 ns, a sequence for the photocarbonylation of benzene using CO2 as the feedstock was constructed and d
284 The synthesis of the first tin-bridged bis(benzene) vanadium and trovacene sandwich compounds and t
285 paternal exposure, in studies that assessed benzene versus all solvents, and in studies of gestation
286 icating that SO4(*-) preferentially oxidized benzene via pathways involving fewer hydroxylation steps
289 groundwater ages >2500 years, indicating the benzene was from subsurface sources such as natural hydr
290 s ranging from 0.64 for p-xylene to 0.70 for benzene were mainly driven by traffic-related variables
293 es with a volatility equal to or lesser than benzene when employed in conjunction with TFME membranes
294 s was developed for efficient degradation of benzene, which can overcome the potential risk of leakag
295 ule published his theory of the structure of benzene, which he later reported had come to him in a da
296 luding a 2,000-fold decrease in emissions of benzene, which lowered health risks for response workers
298 tion metal-catalyzed persulfate oxidation of benzene with pure iron- and manganese-containing mineral
300 ctions were affected by the concentration of benzene, with rates of S2O8(2-) decomposition increasing
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