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1 e position and stereochemistry of the double bond.
2 eeds via alkene insertion into a Ni(II)-acyl bond.
3 decay is intrinsic to the nature of the Si-O bond.
4 eactions have also evolved to cleave the C-P bond.
5 the two local conformations around a single bond.
6 cleaved rather than the weaker aliphatic O-R bond.
7 or trans-configured Glu(18)-Pro(19) peptide bond.
8 ains of the target protein via an isopeptide bond.
9 nitrogen inversion or rotation about the N-O bond.
10 mplexes have free rotation around the CPh-B1 bond.
11 ndergo rapid internal rotation about the M-O bond.
12 2(H2O)n should be able to form very weak C-H bonds.
13 arization and oriented molecular vibrational bonds.
14 ion and the construction of both C-C and C-N bonds.
15 erparts, disilenes with Si horizontal lineSi bonds.
16 ies (O(MeAN)-LA) able to oxidize C-H and O-H bonds.
17 stead, misfolds, forming incorrect disulfide bonds.
18 chanisms, including force-strengthened catch bonds.
19 R: Cy (1), (i)Pr (2)) with discrete Ge-P exo bonds.
20 ical mechanisms for generating carbon-sulfur bonds.
21 nt cage and then to the symmetry of hydrogen bonds.
22 intramolecular amidation of gamma-C(sp(3))-H bonds.
23 oss nonpolar, polar, ionic, and charge-shift bonds.
24 ar solvent for formation of intramolecular H-bonds.
25 oselective and stereoselective carbon-carbon bonds.
26 n theme related to (changes in) metal-ligand bonding.
27 in-group metal-boron complexes with multiple bonding.
28 ding in all GLUT1 conformations via hydrogen bonding.
29 hin the planes and extremely weak interlayer bonding.
30 en bonds of type YH-X analogous to secondary bonding.
31 ssociated either with the mobilization of pi-bonded 2-pentene or with the equally large activation ba
34 ocyclic carbene (NHC) chemistry, a novel C-N bond activation and ring-opening process is described fo
35 ction with fluorobenzene afforded the CAr -H bond activation product [1-F-2-IMe -C6 H4 ](+) I(-) (3).
36 dioxazolone amidating agents via C(sp(3) )-H bond activation to generate the desired amidated product
39 d catalysis proceeds through five steps: C-H bond activation; C-C coupling via a concerted 1,2-aryl t
40 ionally, many transition-metal-catalyzed C-H bond additions to polarized pi bonds occur within cascad
42 ed with anthocyanins mainly through hydrogen bonding, although some hydrophobic interaction may also
45 been engineered to catalyze abiological C-H bond amination reactions, but the yields of these reacti
49 omophenyl 4'-nitrobenzoate where the halogen bonding and C-H...O hydrogen bonding are well-matched.
50 s and demonstrate the importance of hydrogen bonding and hydrophobic interactions in the oligomerizat
54 nal change driven by the collective hydrogen bonding and the sequence-mandated topology of the molecu
56 al view of the relative orientations between bonds and chemical shielding tensors, respectively, rega
58 charged molecules, held together by hydrogen bonds and Coulomb interactions, have attracted great int
60 r characterising the vibrations of molecular bonds and is therefore ideal for label-free detection of
61 teractions can be dissociated as sacrificial bonds and their facile reformation results in self-recov
63 is acid to polarize the carbon-carbon triple bond, and solid K3PO4 interacts with carbonyl oxygen, pr
74 agent, resulting in the formation of two C-C bonds at a single carbon center bearing a C(sp(3)) organ
81 n surveyed in terms of the nature of the C-H bond being activated (C(sp(2))-H or C(sp(3))-H), the nat
84 featuring an unsupported, terminal multiple bond between a Ce(IV) ion and a ligand fragment was also
85 in R411A-alpha2 is dynamic, reforming the H-bond between Y731 and Y730 to allow RT to propagate to Y
86 quare-shaped pieces due to the van der Waals bonding between the sulfur atoms of the quintuple layers
87 crystallines, which was believed to form the bonding between these two metals in addition to mechanic
88 hibition relies on the formation of hydrogen bonds between C-terminal residues of lentil peptides and
90 terfacial location is stabilized by hydrogen bonds between the 5-HT hydroxyl group and lipid headgrou
91 II active site zinc, as well as two hydrogen bonds between the oxazolidinedione ring oxygen and the C
92 analysis indicated the formation of hydrogen bonds between the polar zone of phospholipid and the OH
96 elated to illuminate atomic-level details of bond breaking and formation during the hydrolysis of a c
97 tonated phenyl tautomer (2H(+)) prior to C-C bond breaking would produce protonated CO2, an energetic
98 propyl]amine) that featured an elongated O-O bond but did not lead to O-O cleavage or reactivity towa
99 es) and dipole-dipole interactions (hydrogen bonds), but nevertheless represents a distinctive elemen
101 gs" arising from strengthened water hydrogen bonding, but there is no experimental evidence for enhan
102 aromatic heterocycles were converted to C-Si bonds by reaction with hydrosilanes under the catalytic
103 tinuous flow protocol has been developed for bond C-H activation which promotes the alpha-cyanation o
104 The directed activation of carbon-hydrogen bonds (C-H) is important in the development of synthetic
105 nhardtii (Cr) ChR2) (i) undergoes a hydrogen bond change in D --> K transition and (ii) deprotonates
107 of hydrogen bond, herein we focus on the Li bond chemistry in Li-S batteries through sophisticated q
108 antly lowers the activation barrier for C-OH bond cleavage from the metallocarboxylic acid intermedia
109 diphenyl sulfide also showed competitive C-S bond cleavage giving phenyl sulfinic acid and ionization
110 ovide a "bottom-up" fundamental insight, C-H bond cleavage in methane over Ni-based catalysts was inv
112 I2 and TBHP as the green oxidant via the C-H bond cleavage of the benzylic carbon under mild reaction
116 died in view of its ability to form triply H-bonded complexes with a suitably complementary 2,6-diace
118 r modeling calculations, rotation around the bond connecting the quinazolin-4(3H)-one nucleus to the
119 rocesses in hand that today achieve the same bond constructions characteristic of traditional organic
120 Spy0125 was in a folded state, its thioester bond could be cleaved with the small-molecule nucleophil
125 tic approach through inclusion of a hydrogen bond donor cocatalyst significantly improved enantiosele
126 eorganized and the higher number of hydrogen bond donor sites provides a remarkable enhancement of it
127 p, as it is considered a lipophilic hydrogen bond donor that may act as a bioisostere of hydroxyl, th
128 a new protocol in which an achiral hydrogen bond donor thiourea catalyst was utilized to enhance the
136 g(110) surfaces leads to the scission of C-I bonds followed by the formation of organometallic zigzag
137 sources: stereoelectronic assistance of C-C bond formation (i.e., "LUMO umpolung") and crossover fro
139 em iron enzyme capable of catalysing the C-S bond formation and sulfoxidation, herein, we discovered
140 osulfur ligands, we describe the gold-sulfur bond formation and the nature of the resulting interface
142 synchronous transition state allowing easier bond formation between two sterically hindered carbons.
143 lyst to promote stereocontrolled C-N and C-S bond formation by activation of an achiral sulfenylating
144 vide the first demonstrations of C-N and N-N bond formation from attack of C-based and N-based nucleo
147 tes these phosphorylation events and new C-C bond formation in the absence of biotin has remained a m
150 io calculations suggest that carbon-fluorine bond formation proceeds via a concerted transition state
151 tandem isomerization followed by C-O and C-C bond formation reaction strategy developed by our own gr
152 amic view of corticostriatal activity during bond formation, revealing how social interactions can re
158 has been accomplished via alkene vicinal C-N bonds formation of 2-bromo-2-alkenones with guanidine av
165 asses of enantioselective silylations of C-H bonds have been reported recently, but little mechanisti
166 n, the mixture of 2-5 and 3-5 phosphodiester bonds have emerged as a plausible structural element in
167 ng controversy on the nature of the hydrogen bond (HB) can be settled by looking at the effect of a v
169 table and biologically active as a disulfide-bonded heterodimer, whereas it forms inactive disulfide-
170 yridinyl)isophthalamide-barbiturate hydrogen-bonding host-guest complexes are separately incorporated
171 iction endonucleases catalyze phosphodiester bond hydrolysis within or close to their DNA target site
172 te scission of the B horizontal lineB double bond in 6 was achieved by the treatment with an isonitri
175 the [Formula: see text]-[Formula: see text] bond in dizincocene, and the Mn-Mn bond in dimanganese d
176 effects are illustrated by comparing the C-C bond in ethane against that in bis(diamantane), and disp
183 nd the important roles of CF2-H...O hydrogen bonds in influencing intermolecular interactions and con
184 of detecting specific organic and inorganic bonds in metal complexes and minerals and therefore, has
185 atom abstraction from the nitrogen-hydrogen bonds in purine nucleosides produces reactive intermedia
186 he GGA yields expanded lattices and softened bonds in relation to the LDA, but the SCAN meta-GGA syst
189 diboranes featuring two-center-two-electron bonds in the context of related compounds featuring mult
192 ion-pair formation, and we obtain NBO-based bonding indices to characterize other electronic, struct
193 le the benzonitrile group accepts a hydrogen-bonding interaction from the side chain residue of Asn31
194 nce combined with a weak allosteric hydrogen-bonding interaction that significantly lowers the activa
196 O6 coordination, and 3) binding via hydrogen-bonding interaction with the first-shell water molecules
197 ound aminoacyl-tRNA is initiated by hydrogen bond interactions between the first two nucleotides of t
198 he crystal structure shows that the hydrogen bonding interactions between pairs of 3 result in the fo
199 the prevalence and applications of chalcogen-bonding interactions continues to develop, debate still
200 c structure and orbitals responsible for the bonding interactions in the Sc-OCPPCO-Sc skeleton but al
201 Furthermore, G40 can also establish hydrogen bonding interactions with the nonbridging oxygen of the
202 HF moiety of GRL-09510 forms strong hydrogen-bond-interactions with HIV-1 protease (PR) active-site a
203 tigated the microstructure and phases at the bonding interface of ultrasonically welded aluminum to c
205 re of the reaction is that the stronger Ph-O bond is cleaved rather than the weaker aliphatic O-R bon
213 n N-terminal catalytic domain (LC) disulfide bond linked to a C-terminal heavy chain (HC) which inclu
215 l chromophore featuring a C(11)=C(12) double bond locked in its cis conformation (Rh6mr), employs an
216 shown that on the Au(111) surface this sigma-bond metathesis can be combined with Glaser coupling to
219 ctivity Value (OAV) and the number of double bonds mostly contributed to the modulation of habituatio
220 4 maintains solvent exclusion and the core H-bond network in the active site by relocating to replace
222 sitions, or communication along the hydrogen-bonded network depends on the protonation state of the K
223 d fucosylation mechanism facilitated by an H-bonded network, which is corroborated by mutagenesis exp
224 nds crystallize to form robust open hydrogen-bonded networks with parallel indenofluorenyl cores, sig
226 g the number of internal and external double bonds, number of methyl- and ethyl- functional groups, m
227 catalyzed C-H bond additions to polarized pi bonds occur within cascade reaction sequences to provide
228 eactions involving cleavage of the C(acyl)-O bond of aryl esters that proceed under mild conditions a
229 p*RhCl to accelerate the cleavage of the C-H bond of N-pentafluorophenylbenzamides, providing a new s
233 nships between the functional groups and C-H bonds of a substrate has been exploited to achieve meta-
236 rodimer, whereas it forms inactive disulfide-bonded oligomers at neutral pH that are caused by activa
237 ALP, but CES-catalyzed cleavage of the ester bond on the molecules results in disassembly of the nano
238 mental observation of Bi-B double and triple bonds, opening the door to design main-group metal-boron
241 ized-covalent Zr=P double bond, with a Mayer bond order of 1.48, and together with IR spectroscopic d
243 ow chemoselectivity for the amination of C-H bonds over competing reduction of the azide substrate to
244 for insertion of the nitrene units into C-H bonds over reduction of the azides to the sulfonamides t
245 ning formation of aggregates (1604cm(-1)), H-bonded parallel- and antiparallel-beta-sheets (1690cm(-1
247 the Trpin/Metout conformation, the hydrogen-bonding pattern conducive to the proton relay is not the
248 d did not occur with a linear (non-disulfide-bonded) peptide, or when the double disulfide-bonded Wnt
249 pentene in ZSM-5 and the localized hydrogen-bonded pi-complex at Bronsted acid sites, -36 kJ/mol.
250 ed endosomal escape in living cells.Hydrogen bonding plays a major role in determining the tridimensi
251 ) AChRs respond strongly to ACh because an H-bond positions the QA to interact optimally with the rin
252 d accurate determination of experimental one-bond proton-carbon coupling constants ((1)JCH) in small
253 reveals distinguishing features of chemical bonds ranging across nonpolar, polar, ionic, and charge-
255 From a molecular orbital perspective, the bonding scheme is reminiscent of XeO4 : an octet of elec
258 bone's carbonyl and amide groups in hydrogen-bond stabilization of helical structures is a major fact
259 n approach of local, randomized tailoring of bond stiffness via microalloying enhances creep performa
261 Here, we use genetic tethering and disulfide bonding strategies to construct HslU pseudohexamers cont
262 Fn-binding repeat-9 can significantly affect bond strength and influence the conformation of Fn upon
263 group is found to stabilize the metal-arene bond strength in 5 by roughly 3 kcal/mol compared to tha
270 ngs, and weakly to Cho because a different H-bond tethers the ligand to misalign the QA and form weak
272 The identification of essential disulfide bonds that underlie this process lays the basis for a si
273 oxidative addition of an activated amide C-N bond to a Ni(0) catalyst and proceeds via alkene inserti
274 lium groups that act together to CH-hydrogen-bond to halide anions when the macrocycle is located on
275 process only occurred when a nitro group is bonded to the 4-position of the initial enantiomerically
276 B hemispheres, geometrically rigidified by H-bonding to eight MeOH molecules and encapsulation of two
278 es O-O homolysis, where the phenol remains H-bonding to the peroxo OCu in the transition state (TS) a
279 rincipal amine compounds imposed by hydrogen bonding to water, where a pH-dependent excitation energy
281 e concept of forcing covalent and reversible bonds to mix at molecular scale to create a homogenous n
282 a non-metal-catalyzed hydrosilylation of P-P bonds to produce silylphosphines (R(1)R(2)P-SiR(3)R(4)R(
283 ho-specific nitration of aromatic C(sp(2))-H bonds using chelation-assisted removable vicinal diamine
284 lecular cross-coupling of C(sp(2))-H and N-H bonds using N-iodosuccinimide (NIS) has been demonstrate
285 from Gram-negative bacteria and a disulfide-bonded variant of the I91 human cardiac titin polyprotei
286 quent dissociation of the electron-rich HO-H bond via H transfer to N on the nickel surface, benefici
288 r reaction with halides in solution, halogen bonding was detected only in cases where brominated and
289 the biomimetic and organometallic Fe-C sigma bond, which enables bidirectional activity reminiscent o
290 ed to the population of the Fe(3+) -O-Co(3+) bonds, while the suppressed ferroelectric polarization i
292 X, which formed a metastable mixed disulfide bond with TG2, we demonstrated that these proteins speci
294 NESs also participate in main chain hydrogen bonding with human CRM1 Lys568 side chain, which acts as
295 drophilic exfoliated flakes and subsequently bonding with water, not possible in Nafion composites ba
296 ions reveal a polarized-covalent Zr=P double bond, with a Mayer bond order of 1.48, and together with
299 onded) peptide, or when the double disulfide-bonded Wnt peptide contained Ala substituted for the Ser
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