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1 awing on the unique and varied reactivity of boron.
2 lting temperature above the melting point of boron.
3 ore substituents as well as substitutions at boron.
4 s an exploration of possible one-dimensional boron.
11 quantum yields are dramatically improved by boron alkylation, whereas alkylation in the meso-methyl
13 Foliar boron did not correlate with soil boron along a local scale gradient of boron availability
14 to the development of a remarkable family of boron, aluminium and gallium [(18)F]-fluoride anion comp
17 itution patterns, along with a wide range of boron and alkenyl nucleophiles that couple under palladi
18 in the area of low-coordinated compounds of boron and group-14 atoms C-Sn in the last decade is pres
19 new combinations of light elements including boron and hydrogen, leading to complex hydrides with ext
20 other elements source (sulphur, phosphorus, boron and iron), and porous g-C3N4 as both template and
23 w insight into the stability mechanism of 2D boron and open new ways for the control of the lattice s
25 inorganic geochemistry indicators, including boron and strontium isotope ratios, along with groundwat
26 sphonate that contain amine substitutions at boron and the incorporation of these derivatives into th
27 ing greater orbital interactions between the boron and transition metal atoms than those observed wit
29 work (ICOF), which contains sp(3) hybridized boron anionic centers and tunable countercations, was co
33 time series allows the determination of the boron atmospheric inputs to this forest ecosystem and co
34 bis(boranils) differently substituted at the boron atom and iminophenyl groups were synthesized from
35 dissociation products are observed where the boron atom bridges the two systems by forming very stabl
37 fic interaction of its nitrile-N center with boron atom of the boronic acids, leading to chemoselecti
38 H atoms were selectively abstracted from the boron atoms by t-butoxyl radicals and this enabled borir
39 ase, the reactions are capable of connecting boron atoms in unusual ways, leading to unprecedented bo
40 metal (BB)-carboryne complex containing two boron atoms of the icosahedral cage connected to a singl
42 s that contains a boroxinate core with three boron atoms, and these have proven to be effective catal
49 tions were performed with 0.5-2.5 mol % of a boron-based catalyst, generated in situ from a readily a
50 access azaborininones (carbonyl-containing, boron-based heterocyclic scaffolds) using simple reagent
51 we report that readily available silyl- and boron-based Lewis acids in combination with chiral coppe
52 heory-combined with an efficient sequence of boron-based synthetic transformations, which allowed an
53 tory insertion of the alkene into the carbon-boron bond, similar to the mechanism for hydroboration.
54 arinus (Rma cyt c) were found to form carbon-boron bonds in the presence of borane-Lewis base complex
57 ported fluorescent copper(I) pi-complexes of boron-boron double bonds, the Cun-pi-diboryne compounds
58 ted the first pi-complexes of compounds with boron-boron triple bonds with transition metals, in this
59 ruthenium carbonyl has demonstrated that the boron-bound carbon atoms of all of these reaction produc
61 ferrocenophane containing an unsaturated two-boron bridge, isoelectronic with a C=C double bond, was
62 a tropical forest increased plant-available boron by 70% but did not significantly change tree produ
64 CNTs can be considered to be a novel form of boron carbide consisting of boron doped, distorted multi
66 num nanoparticles supported on graphite-rich boron carbide show a 50-100% increase in activity in aci
67 rystalline, porous COFs from light elements (boron, carbon, nitrogen, oxygen, and silicon) that are c
71 dy demonstrates the first example of tunable boron chemistry in a folded nonnative protein, which off
73 met need to develop chemoselective access to boron chemotypes, we report herein the synthesis of alph
75 odecacarboranyl-1-thio)propanoic acid (3), a boron cluster amino acid that exhibits self-assembly to
78 e that this review will be of great value to boron cluster scientists and researchers working in the
79 coordination polymers containing icosahedral boron clusters in the last few decades, which have recei
80 was converted to its corresponding difluoro boron complex, and the extent of pi-conjugation was exte
81 cle reports the synthesis of four-coordinate boron complexes based on the unexplored 7-(azaheteroaryl
85 onstrate how the interactions of sugars with boron compounds can be combined with transition metal ca
86 ture Database counts 1253 entries for binary boron compounds!), it is surprising that the application
88 ot significantly change tree productivity or boron concentrations in live leaves, wood or leaf litter
89 , Zinc, Iron, Manganese, Copper, Sulphur and Boron concentrations under salinity were also mapped.
91 acterization of a novel series of main-chain boron-containing conjugated polymers (CPs), boron "doped
92 h represent the first examples of main-chain boron-containing CPs without aromatic moieties within th
94 ods that enhance the heteroatom diversity of boron-containing molecules within a limited set of scaff
97 on of low cytotoxicity, amphiphilicity, high boron content, high cellular uptake, and moderate BBB pe
102 lomb (de)stabilization originating from the "boron core" and "halogen shell" and the extension of the
103 e most positively charged region, viz., the "boron core" for X = F, Cl, and the surrounding "halogen
105 ization of rhamnogalacturonan-II (RG-II) via boron cross-links contributes to the assembly and biophy
107 ropical tree species revealed no evidence of boron deficiency or toxicity at concentrations likely to
110 rmeability renders these compounds promising boron delivery agents for the BNCT of brain tumors.
112 followed by an intramolecular version of the boron deprotection reaction can be applied to access the
113 n of two new fluorescent molecular rotors of boron derived from Schiff bases: (2,4,8,10-tetra-tert-bu
118 sical properties of three simple DIPYR dyes: boron dipyridylmethene, boron diquinolylmethene, and bor
119 rin, chlorin, bacteriochlorin), chromophore (boron-dipyrrin, perylene, terrylene), and attachment sit
123 as menadione (a quinone redox center), to a boron-dipyrromethene (BODIPY) fluorophore (a lipophilic
124 igand-photosensitizer construct, IYIY-diiodo-boron-dipyrromethene (IYIY-I2-BODIPY) and its scrambled
126 e simple DIPYR dyes: boron dipyridylmethene, boron diquinolylmethene, and boron diisoquinolylmethene.
128 a novel form of boron carbide consisting of boron doped, distorted multiwalled carbon nanotubes (MWC
129 boron-containing conjugated polymers (CPs), boron "doped" polyacetylenes (BPAs), which represent the
131 HOBr) oxidants was evaluated on Ti-IrO2 and boron-doped diamond (BDD) electrodes using a suite of tr
133 ge (HV > 80 GPa) by examining single-crystal boron-doped diamond (BDD) with boron contents ranging fr
134 ng electrodes, including glassy carbon (GC), boron-doped diamond (BDD), and screen-printed graphitic
135 seemingly catalytically inactive electrode, boron-doped diamond (BDD), is found to be active for CO2
136 l production activity (6.6 x 10(-14) M) with boron-doped diamond (BDD, 7.4 x 10(-14) M) electrodes.
138 e amperometry with a cathodically pretreated boron-doped diamond electrode, using 0.30molL(-1) H2SO4
143 log of an Arabidopsis (Arabidopsis thaliana) boron efflux transporter displayed boron deficiency phen
144 1 plays a key role in tolerance to high soil boron, facilitating the efflux of borate from cells.
146 ed good chelating abilities toward trivalent boron fragments such as BF2 or BPh2 to yield the corresp
148 rrent with advances in the synthesis of pure boron fullerenes and atom-thin layers, motivates an expl
150 may be drawn with the oxidative addition of boron-hydrogen and silicon-hydrogen bonds to transition
152 ygen and radical scavengers, we propose that boron-imidates form under the basic reaction conditions
153 ccounts for a considerable proportion of the boron in annual litterfall and is similar to the pool of
154 l that Bi forms triple and double bonds with boron in BiB2 O(-) ([Bi identical withB-B identical with
157 nd is similar to the pool of plant-available boron in the soil, and is therefore sufficient to preclu
160 agon concentration in the ground state of 2D boron increases to 1/7 from 1/8 in its charge-neutral st
161 the operative mechanistic pathway is through boron-induced activation of the alkyne followed by elect
164 antioenriched alkylboronate esters, in which boron is bound to a stereogenic carbon, and we highlight
165 t atomic layer of the as-deposited amorphous boron is the dominant factor leading to the formation of
168 ining corrugated layers of covalently bonded boron, is a superhard metallic compound with a microhard
171 nergy and electronic bandgap varied with the boron isotope mass, the latter due to the quantum effect
172 onal boron nitride crystals with nearly pure boron isotopes ((10)B and (11)B) compared to those with
175 istics made by depositing an atomically thin boron layer at a relatively low temperature where no dop
177 contains only the more active graphene-like boron layers) by a 5-times increase of its surface area.
180 amines are more chemically stable than their boron-linked counterparts, making them more promising fo
181 gradual decomposition of the preformed metal-boron (M-B, M=Fe, Co, Ni, NiCo) composite nanospheres wh
182 s that the predicted unusual behaviors of 1D boron may find powerful applications in nanoscale electr
187 d theory, we show that nanoalloying Pt7 with boron modifies the alkene-binding affinity to reduce cok
188 However, using pinacol boronic esters, the boron moiety migrates to the adjacent carbon resulting i
193 accomplished by an in-plane rotation of the boron network, which maximizes the in-plane hybridizatio
196 actuator made of carbon nanotubes (CNTs) and boron nitride (BN) is developed that can withstand high
199 based on graphene-like 2D materials, such as boron nitride (BN), graphite-carbon nitride (g-C3N4), tr
200 s for the large-scale synthesis of hexagonal boron nitride (h-BN) by chemical vapour deposition (CVD)
202 pattern in highly aligned graphene/hexagonal boron nitride (h-BN) heterostructures is a lateral super
203 heterostructures with graphene and hexagonal-boron nitride (h-BN) inks, and use them to fabricate all
204 The controlled exfoliation of hexagonal boron nitride (h-BN) into single- or few-layered nanoshe
205 ication of individual nanopores in hexagonal boron nitride (h-BN) with atomically precise control of
208 ul growth of MoSe2 on single-layer hexagonal boron nitride (hBN) on the Ru(0001) substrate using mole
209 ted from atomic defects in layered hexagonal boron nitride (hBN), but controlling inhomogeneous spect
212 y the unoccupied band structure of graphite, boron nitride and their heterostructures using angle-res
214 lamellar compounds by synthesizing hexagonal boron nitride crystals with nearly pure boron isotopes (
215 pothesis in which oxygen-terminated armchair boron nitride edges are proposed to be the catalytic act
216 ormance is enabled by epitaxial growth on 2D boron nitride for chemical-free transfer to a soft, flex
217 Pristine graphene encapsulated in hexagonal boron nitride has transport properties rivalling suspend
218 trate a device in which a graphene/hexagonal boron nitride heterostructure is suspended over a gold n
219 monolayer graphene and multilayer hexagonal boron nitride heterostructures, we discuss the potential
222 eter-thin molybdenum disulfide and hexagonal boron nitride microcrystals, the most-promising van der
223 gh quality, 2-dimensional single crystalline boron nitride nanosheets (BNNSs) at a low substrate temp
225 cles assembled on vacancy-abundant hexagonal boron nitride nanosheets and their use as a model cataly
226 omposites with silver nanoparticle-deposited boron nitride nanosheets as fillers could effectively en
227 composite with silver nanoparticle-deposited boron nitride nanosheets outperforms the one with boron
229 nitride nanosheets outperforms the one with boron nitride nanosheets, owning to the lower thermal co
232 ctural stability and mechanical integrity of boron nitride nanotubes (BNNTs) in high temperature envi
234 t that iron (Fe) quantum dots functionalized boron nitride nanotubes (QDs-BNNTs) can be used as the f
235 eport atmospheric oxygen induced cleavage of boron nitride nanotubes at temperatures exceeding 750 de
236 page in carbon nanotubes, and no slippage in boron nitride nanotubes that are crystallographically si
237 orphological and chemical transformations in boron nitride nanotubes under high temperature atmospher
240 ogenide, graphitic carbon nitride, hexagonal boron nitride, and phosphorene) are emerging extraordina
241 t defects emerging in graphene and hexagonal boron nitride, as probed by atomically resolved electron
242 o the emergence and development of hexagonal boron nitride, black phosphorus, and transition metal di
244 iquids, such as those (e.g., carbon nitride, boron nitride, metal-organic frameworks, covalent organi
245 ted effect with phonon-polaritonic hexagonal boron nitride, plasmonic super-lattices and hyperbolic m
246 ngle-layer graphene, and few-layer hexagonal boron nitride, respectively, are utilized to design high
248 ase of aligned or nearly-aligned graphene on boron nitride, the graphene lattice can stretch and comp
249 anomaterials (e.g. graphitic carbon nitride, boron nitride, transition metal dichalcogenides, and tra
252 uctor/insulator/metal layers (WSe2/hexagonal boron nitride/graphene) in a semifloating gate field-eff
258 preferred structure of two-dimensional (2D) boron, or "borophene", on charge doping controlled by a
260 onding, the hybridization among out-of-plane boron orbitals is crucial for determining the relative s
261 correlate to the hybridization states of the boron orbitals that form the B-B bonds and to the streng
262 herto longest periacene analogue with oxygen-boron-oxygen (OBO) segments along the zigzag edges, that
263 (1) there is an absence of dynamics but the boron pairs are crystallographically equivalent or (2) t
264 e crystallographically equivalent or (2) the boron pairs are crystallographically inequivalent but ar
265 Recently discovered two-dimensional (2D) boron polymorphs, collectively tagged borophene, are all
266 time as removable protecting groups for the boron position of 1,2-azaborines during reactions that a
267 found that samples prepared with a metal to boron ratio of 1:11.6 to 1:9 have similar hardness value
268 DABCO as the catalyst and H-Bpin as both the boron reagent and stoichiometric hydride source has been
269 ic studies via UV-vis spectroscopy with this boron reagent found second-order kinetics, supporting th
270 (18)F-fluorination for a representative aryl boron reagent, and on the labeling of more than 50 (hete
271 e copper-mediated (18)F-fluorination of aryl boron reagents with (18)F-fluoride as a model reaction.
273 gh-like evolution of the atmospheric gaseous boron reservoir with possible but limited anthropogenic
275 With both electrodes made from the same boron-rich alloy, we found that the arc operation unstab
276 ion and arc synthesis were achieved with the boron-rich anode and the cathode made from a refractory
277 ly synthesized by a dc arc discharge using a boron-rich anode as synthesis feedstock in a nitrogen ga
278 ted as resulting from localized spreading of boron-rich fertilizers, thus indicating a significant lo
279 er 2D materials have been suggested based on boron, silicon, germanium, phosphorus, tin, and metal di
280 ommercially available external electrophilic boron source (B-chlorocatecholborane) in good to high yi
283 wever, is limited by the behaviour of common boron starting materials as archetypal Lewis acids such
287 ve 1,1-diboration provided products with two boron substituents that exhibit differential reactivity.
289 triggering the 1,2-migration of the group on boron to carbon giving a dearomatized bromoallene interm
291 s of the transfer of the organic moiety from boron to palladium in the key transmetalation step.
294 lamines by triethylsilane in the presence of boron trifluoride etherate is studied and found to incre
295 acted with excess pyrrole in the presence of boron trifluoride etherate to give a tripyrrane analogue
296 Solid Phase Extraction (SPE), methylated by boron trifluoride in methanol, and injected into GC-FID
297 es the formation of B-O and B-N bonds at all boron vertices (B(2), B(4), B(5), and B(9)) of meta-carb
299 ride alloys with a variable concentration of boron were prepared by arc-melting and investigated for
300 ODIPYs with PEG substituents attached to the boron, whereas in the second series, PEG substituents ar
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