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1 subtly changing the structure of the achiral boronic acid.
2 tected using the fluorescent probe, coumarin boronic acid.
3 MR study of the protodeboronation of an aryl boronic acid.
4 mponent in the coupling reaction, namely the boronic acid.
5 on-promoted transmetalation reaction of aryl boronic acid.
6 which undergoes cross-coupling with the aryl boronic acid.
7 sceptible to potent reversible inhibition by boronic acids.
8 s, as well as arylammonium salts directly to boronic acids.
9 ing reaction of diaryl diselenides with aryl boronic acids.
10 les the generation of a variety of protected boronic acids.
11 al groups such as alcohols, amines, and even boronic acids.
12 clotrimers, which are readily intercepted by boronic acids.
13 of trisubstituted-alkenyl alcohols with aryl boronic acids.
14 fonylhydrazones with aryl and heteroaromatic boronic acids.
15 anocatalytic strategy for the formylation of boronic acids.
16 dentifying bortezomib and additional peptide boronic acids.
17 ve coupling of methylene C-H bonds with aryl boronic acids.
18 y accessible from the commercially available boronic acids.
19 aryl phosphonium salts and coupled with aryl boronic acids.
22 rotocol provide details for preparation of a boronic acid (3-cyanopheylboronic acid) and a boronic es
23 alogue of the sensor that does not contain a boronic acid (4) responded nearly identically to 3 in th
25 shared the same functional groups (halides, boronic acids, alkenes, and alkynes, among other groups)
26 omplexation of particular diol groups by the boronic acid also enables selective transformations of m
27 etrahedral adducts with the B(III) center of boronic acids, although there is also evidence for some
28 as solved through the development of a novel boronic acid-amine copromoter system for glycosyl accept
29 ming Petasis reaction occurring between aryl boronic acids, amines, and glyoxylic acids to prepare al
33 ep is a Suzuki-Miyaura coupling of a furan-3-boronic acid and an 8-halocoumarin, which is advantageou
34 red rate law includes a second order in both boronic acid and catechol moieties, and inverse second o
35 le an estimate of beta(11-1) for any pair of boronic acid and diol from their pKa values, is proposed
37 on of the E-ring aryl chloride to a reactive boronic acid and its use in the synthesis of a systemati
38 ly dependent on the electronic nature of the boronic acid and more subtle electronic effects of the a
39 d antibody immobilization via interaction of boronic acid and oligosaccharide moiety found on Fc regi
41 Two additional processes compete when the boronic acid and the boronate are present in sufficient
42 the fluorination to take place ortho to the boronic acid and the other, toward an ipso substitution.
45 a stereodynamic probe carrying complementary boronic acid and urea units achieves this goal with hydr
46 s allows greater reactivity with simple aryl boronic acids and allows coupling reactions to proceed t
48 H profiles gives shifted pKa values both for boronic acids and diol as a result of significant interd
50 e reaction was amenable to a variety of aryl boronic acids and disubstituted malononitriles, providin
54 ium catalyzed oxidative homocoupling of aryl boronic acids and esters to biphenyls has been recognize
56 rylating carbocyclization of allenynes using boronic acids and focuses on the correlation between rea
57 rboxylates with vicinal donor aryl groups by boronic acids and potassium organotrifluoroborates under
58 ed 1,3-stereoselective conjugate addition of boronic acids and potassium trifluoroborates under metal
60 Enantioconvergent arylation reactions of boronic acids and racemic beta-stereogenic alpha-keto es
63 mponent reaction involving terminal alkynes, boronic acids, and perfluoroalkyl iodides is presented h
64 reacting flow-generated diazo compounds with boronic acids, and their application in controlled itera
65 co-functionalizing AuNPs with 3-aminophenyl boronic acid (APB) and L-glutamic acid-(2,2,2)-trichloro
67 strategy, we present the use of fluorinated boronic acid-appended pyridinium salts in combination wi
69 mponent probes were assembled with up to six boronic acid-appended viologens (BBVs): 4,4'-o-BBV, 3,3'
73 nd amines via (2-(thiophen-2-ylmethyl)phenyl)boronic acid as a highly active bench-stable catalyst.
78 assisted amidation of readily available aryl boronic acids at room-temperature under open-flask condi
79 tidine residues direct oxidative coupling of boronic acids at the backbone NH of a neighboring amino
80 study is reported where folic acid (FA) and boronic acid (BA) based cytosensors and their analytical
83 able sensor is constructed of a fluorescent, boronic-acid based glucose indicating polymer coated ont
87 eficient, electron-rich or ortho-substituted boronic acids better results are obtained with racemic a
89 combination of glyco-gold nanoparticles and boronic acid biosensor system opens a way to study nonco
92 ely couples not only heteroaryl halides with boronic acids but also heteroaryl halides with boronate
93 sors are often based on fluorophore-appended boronic acids, but these severely lack discriminatory po
94 arious substituted alkynyl/alkenyl boronates/boronic acids by this procedure to furnish a library of
97 trabromopyrene and (4-(ethoxycarbonyl)phenyl)boronic acid can easily be coupled to prepare the requis
102 alkynyl bromide and pinacol ester of alkynyl boronic acid catalyzed by CuFe2O4 nanoparticles has been
103 H3Hg(+) ensued a fast transmetalation of TPE-boronic acid causing drastic reduction in the solubility
104 dy, we show that the profluorescent coumarin boronic acid (CBA) probe reacts with amino acid and prot
106 ng Pd-O-B linkages, a tri-coordinate (6-B-3) boronic acid complex and a tetra-coordinate (8-B-4) boro
108 adium-oxygen-boron linkages, a tricoordinate boronic acid complex, and two tetracoordinate boronate c
112 tants (Kd) of the biotin-avidin and dopamine-boronic acid complexes were determined to be 15 +/- 1 fM
113 eboronation of polyfluoroaryl and heteroaryl boronic acids complicates their use in Suzuki-Miyaura co
116 ns using a homologous series of seven phenyl boronic acids conjugated to a polyethylene glycol, eight
118 ide was developed through incorporation of a boronic acid-containing cleavable linker between polycat
119 al engineering, where double-H-bonding donor boronic acids could act as suitable organocatalysts or t
120 acilitated by Lewis acid assistance from the boronic acid coupling partner and an ionic S(N)1-like me
122 t can be converted to trifluoroborate salts, boronic acids, cyclopropylarenes, cyclopropylamines, and
123 ploys an air-stable diethanolamine-complexed boronic acid (DABO boronate) as the allyl transfer reage
124 f a new type of hybrid biomaterial, namely a boronic acid-decorated lectin (BAD-lectin), for efficien
125 eworks with compositions ranging from highly boronic acid-deficient to networks with catechol voids.
126 r molecule based on a 2-hydroxymethyl phenyl boronic acid derivative binds even at neutral pH to the
131 t synthesis of pyridine-based heteroaromatic boronic acid derivatives is reported through a novel dib
136 e variation of the dye structure through the boronic acid derived moiety (approach (b)) enables the f
139 acter spp were evaluated using the cefotetan-boronic acid disk test and the cefotetan-cloxacillin Ete
140 thereby facilitating synthesis of the alkyl boronic acid drugs Velcade and Ninlaro as well as a boro
141 ient where one molecule was attracted to the boronic acid end of the gradient, and the other to the c
144 he alkyne group of the alkyne-functionalized boronic acid exhibits a distinct Raman peak at 1996 cm(-
146 action scope, including the use of different boronic acids, five-, six-, and seven-membered cyclic en
148 Large collections of chemically diverse boronic acid fragments are commercially available becaus
149 olution greatly enhanced the emission of the boronic acid functionalized dye by a factor of up to 18.
150 olume resetting agent is incorporated into a boronic acid functionalized hydrogel containing an embed
152 1-naphthaleneboronic acid and acenaphthene-5-boronic acid gave corresponding o-naphthyl benzaldehydes
153 developed and optimized with N-Boc-indole-2-boronic acid giving access to alpha-indole-gamma-substit
154 functional groups, and should allow for the boronic acid group to be used as an effective traceless
155 nd reversible binding of the analyte via the boronic acid group, amplification of SERS signals by the
159 alkyl primary amines from the corresponding boronic acids has been achieved at ambient temperature m
160 ng reactivity of Au(III)-F species with aryl boronic acids has been studied in detail taking advantag
161 bis-boronic acid for the direct synthesis of boronic acids has greatly facilitated the two-step, one-
163 of the current methods for the synthesis of boronic acids, however, require transition metal catalys
165 sociation constant (Ka) of ortho-substituted boronic acids in solution showed that Ka for 1:1 associa
166 tuted-3-iodoquinolin-4(1H)-ones with several boronic acids in water using Pd(OAc)2 as a catalyst and
167 ng-opening reaction of vinylcyclopropanes by boronic acids in water, using palladium nanoparticles fo
170 conversion of aryl, heteroaryl, and alkenyl boronic acids into sulfinate intermediates, and onwards
172 idate that the ipso amination of substituted boronic acids involves the formation of cyanamidyl/arylc
179 its nitrile-N center with boron atom of the boronic acids, leading to chemoselective primary aminati
180 for aqueous-organic protodeboronation of 18 boronic acids, many widely viewed as unstable, have been
182 ol chemiluminescence (CL) biosensor based on boronic acid modified gold substrate has been developed
186 nsor, pnGFP, based on the incorporation of a boronic acid moiety into a circularly permuted green flu
187 is achieved by introduction of a C-terminal boronic acid moiety into dipeptidic inhibitors of the Zi
190 h conditions amenable to the presence of the boronic acid moiety which was considered important for t
192 preparation of reactive allylic and benzylic boronic acids, obtained by reacting flow-generated diazo
194 llowed expedient preparations of alpha-amino boronic acids, often with high stereoselectivity, thereb
195 show that the suppressive effect of peptide boronic acids on hyperactive Wnt signaling is dependent
196 the aid of boronate probes, e.g. coumarin-7-boronic acid or 4-boronobenzyl derivative of fluorescein
197 ent, the imino group that forms ortho to the boronic acid or boronate ester group can form a dative N
198 romodibenzo[15]crown-5 and the corresponding boronic acids or borolanes via Suzuki cross-coupling and
199 N-tosylhydrazones, dihalogenated arenes, and boronic acids or boronate esters was developed, producin
200 d in trimeric forms (RBO3) commonly known as boronic acids or boroxins; obtaining their monomers has
205 yl-Bpin, p-tolyl-Bcat) and the corresponding boronic acid (p-tolyl-B(OH)2) in this type of cross-coup
207 erine beta-lactamase inhibitors containing a boronic acid pharmacophore, with the goal of finding a p
209 presence of ostensibly equivalently reactive boronic acid pinacol (BPin) esters by kinetic discrimina
211 ) = 6-morpholino-2,2':6',2''-terpyridine-6''-boronic acid pinacol ester) to promote directed Lewis ac
214 d isocoumarins and 2-pyrones are isolated as boronic acids, pinacolboronate esters, or potassium orga
215 efficiency of arylboron-based nucleophiles, boronic acid, potassium trifluoroborate, neopentylglycol
217 d Luciferin-2 (PCL-2), a H(2)O(2)-responsive boronic acid probe that releases 6-hydroxy-2-cyanobenzot
219 tructure-activity analyses using a series of boronic acid proteasome inhibitors and correlate cytotox
220 ent coupling of Selectfluor, a styrene and a boronic acid, provides chiral monofluorinated compounds
223 ted using a SNAP-tag approach to install the boronic acid reagent onto the extracellular domain of th
228 died catalysts, meta-alkoxy substituted aryl boronic acids resulted in the (S)-enantiomer when used i
229 e nature of the adduct and the effect of the boronic acid's pK(a)(B) on the stability constant of the
230 rodeposited screen-printed electrode through boronic acid-saccharide interactions, with the boronic a
232 rol experiments in the presence of competing boronic acids showed no crossover side-products and conf
235 e including the final trapping of a reactive boronic acid species with an aldehyde to generate a rang
236 ic, squarylium cyanine dye functionalized by boronic acid ("SQ-BA") was designed and synthesized for
238 a data set in which both the phosphoric and boronic acid structures were systematically varied, key
239 H-bond paired the adenine moiety of ATP, the boronic acid substituent of thiophene 3 covalently bound
241 ween vicinal hydroxyl groups of arabitol and boronic acid substituents of the bithiophene functional
242 ithiophene) derivatives bearing cytosine and boronic acid substituents, in the presence of the inosin
246 ctions of benzylic alcohols, including other boronic acids such as 2,3,4,5-tetrafluorophenylboronic a
247 popular C-C bond forming reactions of these boronic acids, such as the Suzuki-Miyaura, Heck, and Hay
248 ons (hydrophobicity, aromaticity, branching, boronic acids) suggest that the best siCPDs act differen
249 BL detection by the CLSI disk test (CLSI), a boronic acid-supplemented CLSI disk test (CLSI plus BA),
251 ity exceeding 95%, with the exception of the boronic acid synergy test (88%) and modified Hodge test
252 ohort, sensitivities ranged from 72% for the boronic acid synergy test for the detection of KPC produ
253 arba assay, the Modified Carba NP assay, the boronic acid synergy test, and the metallo-beta-lactamas
254 ow protodeboronation, as do 3- and 4-pyridyl boronic acids (t0.5 > 1 week, pH 12, 70 degrees C).
256 elf-assembled monolayer (SAM) of thiophene-3-boronic acid (T3BA) is provided to modify the gold elect
257 DD.AA-type complexes of a series of aromatic boronic acids that adopt a syn-syn conformation with sui
259 enantioselective organocatalysed transfer of boronic acid to 5-hydroxyfuran-2(5H)-one, followed by an
261 ondary binding with an alkyne-functionalized boronic acid to form a glucose-alkyne-boronic acid compl
263 tal-free coupling of a tosyl hydrazone and a boronic acid to the preparation of a complex natural pro
265 action tolerates a variety of functionalized boronic acids to afford a cis-fused bicyclic framework c
266 ing of benzylic ammonium triflates with aryl boronic acids to afford diarylmethanes and diarylethanes
267 o-enol esters were subsequently coupled with boronic acids to afford tetrasubstituted alkene derivati
268 )-catalyzed enantioselective 1,4-addition of boronic acids to electron-deficient alkenes is reported.
269 the peculiar dynamic covalent reactivity of boronic acids to form tetraboronate derivatives, interes
270 lysed Csp(3) Suzuki coupling of acetals with boronic acids to generate benzylic ethers, a reaction th
272 ge of alkyl boronic esters and aryl or alkyl boronic acids to react with electron-deficient olefins v
273 OF-5 structure can form over a wide range of boronic acid-to-catechol ratios, thus producing framewor
274 arged dye molecules was demonstrated using a boronic acid-to-cationic gradient where one molecule was
275 ium-catalyzed carbonylative coupling of aryl boronic acids together with terminal alkynes and perfluo
280 ronic acid-saccharide interactions, with the boronic acid units specifically binding to the glycosyla
281 timal conditions for the slow release of the boronic acid using KOH as the base in biphasic THF/water
282 ere included in the investigations with each boronic acid varying in the substituent at its 4-positio
283 acid drugs Velcade and Ninlaro as well as a boronic acid version of the iconic antibiotic vancomycin
284 donocardia thermophila JCM 3095 (PtNHase) by boronic acids via kinetics and X-ray crystallography.
285 ion of aldehydes has been accomplished using boronic acids via the synergistic combination of copper
286 for the interconversion of diverse protected boronic acids, via intermediate organotrifluoroborates.
288 and p-halophenols with o-, m-, and p-phenol boronic acids were investigated for all combinations und
289 o preserve the often sensitive C-B bond, all boronic acids were readily converted to their more stabl
290 irect benzylation between tosylhydrazone and boronic acid, which allowed the generation of structural
291 on transition state analog, benzothiophene-2-boronic acid, which was also isotopically enriched with
292 ling reactions involving aryl sulfamates and boronic acids, which operates at a significantly lower c
293 hydrolysis, resulting in fast release of the boronic acid while reagents bearing, for example, alkyny
294 rocess involves etherification of an alkenyl boronic acid with N-hydroxyphthalimide followed by a [3,
296 described transnitrilative cyanation of aryl boronic acids with dialkylmalononitriles, the present re
297 This reaction is amenable to a wide range of boronic acids with different biorelevant functional grou
300 endent, and varied substantially between the boronic acids, with rate maxima that varied over 6 order
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